101 |
More improved process for the preparation of transition metal hydride - organic, including the aryl or alkyl as a hydrogen storage material |
JP2009185465 |
2009-08-10 |
JP5250503B2 |
2013-07-31 |
ジョンシク キム; ドンオク キム; ヘボク ユン; ジソン パク; ヒョジン チョン; ガイリョン アン; ドンウク キム; ジソン イム; ムンヒュン チャ |
|
102 |
Gold complex |
JP2012555480 |
2011-03-02 |
JP2013521268A |
2013-06-10 |
ピー ノーラン スティーブン |
Z−Au−OH形状の水酸化金(I)錯体と、Z−Au−(μOH)−Au−Z形状の二金錯体(ここで、基Zは2電子供与体である)とを提供する。 基Zは、カルベン、例えば窒素含有複素環式カルベン(NHC)、ホスフィン又はホスフェイトとし得る。 錯体は、例えばニトリルの水和、エニンの骨格転位、エニンのアルコキシ環化、アルキン水和、マイヤー・シュスター反応、アリル性アセテートの3,3'転位、プロパギル性アセテートの環化、ベックマン転位及びヒドロアミノ化のような反応における触媒として用いることができる。 錯体は医薬、例えば癌の治療に用いることができる。 |
103 |
Organic silver complex compounds, a method of producing this and the thin film forming method using the same |
JP2007554024 |
2006-02-07 |
JP5001860B2 |
2012-08-15 |
ソンヨン ウム; ミョンソン コン; ヨンクヮン ソ; ヒュンナム チョ; クヮンチュン チョン; ドンフン ナム; ジョンビン パク; イスプ ハン |
The present invention relates to a novel organic silver complex and its preparation method by reacting a silver compound with an ammonium carbamate compound or an ammonium carbonate compound. |
104 |
Catalytic depolymerization of polymer containing electrophilic linkage using nucleophilic reagent |
JP2010023779 |
2010-02-05 |
JP2010159418A |
2010-07-22 |
HEDRICK JAMES L; KILICKIRAN PINAR; NYCE GREGORY W; WAYMOUTH ROBERT M |
<P>PROBLEM TO BE SOLVED: To provide an improved method for carrying out depolymerization of a polymer. <P>SOLUTION: The method is provided for carrying out depolymerization of the polymer containing an electrophilic linkage in the presence of a catalyst and a nucleophilic reagent, wherein production of undesirable byproducts resulting from polymer degradation is minimized. The reaction can be carried out at a temperature of 80°C or lower, and generally involves the use of an organic, nonmetallic catalyst, thereby ensuring that the depolymerization product(s) are substantially free of metal contaminants. In an exemplary depolymerization method, the catalyst is a carbene compound such as an N-heterocyclic carbene, or is a precursor to a carbene compound. The method provides an important alternative to current recycling techniques such as those used in the degradation of polyesters, polyamides, and the like. <P>COPYRIGHT: (C)2010,JPO&INPIT |
105 |
Catalyst depolymerization using a nucleophilic reagent polymer containing electrophilic linking group (polymer) |
JP2004565712 |
2003-12-23 |
JP4478581B2 |
2010-06-09 |
ウェイマウス、ロバート、エム; キリッキラン、ピナー; ニース、グレゴリ、ダブリュ; ヘドリック、ジェームス、エル |
A method is provided for carrying out depolymerization of a polymer containing electrophilic linkages in the presence of a catalyst and a nucleophilic reagent, wherein production of undesirable byproducts resulting from polymer degradation is minimized. The reaction can be carried out at a temperature of 80° C. or less, and generally involves the use of an organic, nonmetallic catalyst, thereby ensuring that the depolymerization product(s) are substantially free of metal contaminants. In an exemplary depolymerization method, the catalyst is a carbene compound such as an N-heterocyclic carbene, or is a precursor to a carbene compound. The method provides an important alternative to current recycling techniques such as those used in the degradation of polyesters, polyamides, and the like. |
106 |
Ethynyl group substituted fused heterocyclic compound heavy metal complex, to a process for the preparation thereof, the synthetic intermediates and their preparation as well as the organic electroluminescent element |
JP2006513046 |
2005-05-12 |
JP4470940B2 |
2010-06-02 |
博 佐藤; 貴文 城野; 真治 安田; 貴文 岩佐; 康裕 田中; 利一 町田; 謙二 福永; 整 藤村 |
|
107 |
Metal compounds for use as an initiator |
JP2009538662 |
2007-10-18 |
JP2010511083A |
2010-04-08 |
ウルリケ・シュミット−フライターク; ウルリッヒ・アルノルト; エミリー・バリオ; フェリペ・ウォルフ・ファブリス; フォルカー・アルトシュテット; マルセル・ロート; マンフレート・デーリング; ヤン・ザントラー |
本発明は、一般式:{[M(L)
a ]X
b }
nで示される開始剤に関する。 これらの開始剤は、好ましくは対イオンとして(SbF
6
- )を有し、対応する金属SbF
6
-塩と対応するリガンド(L)との錯化反応によって得られる。 さらに本発明は、該開始剤を含有し、特に、非熱的および/または熱的に硬化させうる調製物およびエポキシ樹脂系に関する。 |
108 |
置換フェニルエチニル金−含窒素へテロ環カルベン錯体 |
JP2008517899 |
2007-05-25 |
JPWO2007139001A1 |
2009-10-08 |
藤村 整; 整 藤村; 福永 謙二; 謙二 福永; 貴志 本間; 利一 町田 |
本発明は、一般式(1)又は(2)式中、Lは、含窒素へテロ環カルベン配位子を示し、Xは、アルキル基、シクロアルキル基、アリール基、アラルキル基、ヘテロ環基、アルコキシ基、アリールオキシ基、アルキルメルカプト基、アリールメルカプト基又は置換アミノ基を示す;なお、Xの炭素原子上のひとつ又は複数の水素原子が、独立して、ハロゲン原子、アルキル基、シクロアルキル基、アルケニル基、アリール基、アラルキル基、アルコキシ基、アリールオキシ基、アルキルメルカプト基、アリールメルカプト基又は置換アミノ基で置換されていても良い、で示される置換フェニルエチニル金−含窒素へテロ環カルベン錯体に関する。 |
109 |
Polymer compound and element given by using the same |
JP2005374248 |
2005-12-27 |
JP2006219663A |
2006-08-24 |
SHIRASAWA NOBUHIKO; AKINO YOSHIHIKO; NAKATANI TOMOYA |
<P>PROBLEM TO BE SOLVED: To provide a polymer compound having a structure of a conjugated polymer and a structure of a metal complex in an identical molecule and capable of giving a light emitting element having such excellent practicability as to have high efficiency and to be driven at a low voltage, when used as the light emitting element. <P>SOLUTION: This polymer compound has the structure of the conjugated polymer (A) and the structure of the metal complex (B) in the identical molecule, wherein the metal complex (B) has one or more tridentate ligands and an atomic number of a central metal thereof is not less than 21. The element has a layer containing the polymer compound between electrodes comprising a positive electrode and a negative electrode. <P>COPYRIGHT: (C)2006,JPO&NCIPI |
110 |
Catalyst depolymerization using a nucleophilic reagent polymer containing electrophilic linking group (polymer) |
JP2004565712 |
2003-12-23 |
JP2006512460A |
2006-04-13 |
ウェイマウス、ロバート、エム; キリッキラン、ピナー; ニース、グレゴリ、ダブリュ; ヘドリック、ジェームス、エル |
A method is provided for carrying out depolymerization of a polymer containing electrophilic linkages in the presence of a catalyst and a nucleophilic reagent, wherein production of undesirable byproducts resulting from polymer degradation is minimized. The reaction can be carried out at a temperature of 80° C. or less, and generally involves the use of an organic, nonmetallic catalyst, thereby ensuring that the depolymerization product(s) are substantially free of metal contaminants. In an exemplary depolymerization method, the catalyst is a carbene compound such as an N-heterocyclic carbene, or is a precursor to a carbene compound. The method provides an important alternative to current recycling techniques such as those used in the degradation of polyesters, polyamides, and the like. |
111 |
Purification method of the organic metal compound or heteroatom compounds according hydrogenated getter alloy |
JP2001576967 |
2001-04-13 |
JP2003531151A |
2003-10-21 |
スッチ,マルコ; ベルガーニ,ジョルジオ |
(57)【要約】 酸素及び水から、並びに水及び酸素と純化しようとする有機金属化合物又はヘテロ原子化合物との反応によってもたらされる化合物から、有機金属化合物又はヘテロ原子化合物を純化する方法。 この方法は、液体状態、又は純粋な蒸気若しくはキャリアガス中の蒸気の状態の純化する有機金属化合物又はヘテロ原子化合物を、水素化されたゲッター合金、及び随意に多孔質支持体上のパラジウム、並びにゼオライトに支持された鉄及びマンガンの混合物から選択される1又は複数の気体吸収剤と接触させる操作を含む。 |
112 |
Organometallic compound for forming metal pattern and method for forming metal pattern using the same |
JP2002265556 |
2002-09-11 |
JP2003183257A |
2003-07-03 |
JUNG MIN CHUL; HWANG SOON TAIK; BYUN YOUNG HUN; HWANG EUK CHE |
PROBLEM TO BE SOLVED: To provide a new organometallic compound and a method for forming a metal pattern using the compound.
SOLUTION: This organometallic compound for forming the metal pattern is represented by chemical formula (1) L'-M-L (1) (wherein, M is one kind of transition metal selected from the group consisting of Ag, Au, Cu, Pd, Ni and Pt: L is an imidazolylidene compound having a specific structure; and L' is an imidazolylidene compound having a specific structure or a β-diketonate having a specific structure). Since L', M and L are present on the nearly same plane, the compound is capable of reducing the bulkiness of an organic ligand which is the largest cause of metal film shrinkage. Furthermore, L' and L have characteristics of readily degrading and eliminating the ligand with light. Thereby, cracking can be suppressed when the metal pattern is formed.
COPYRIGHT: (C)2003,JPO |
113 |
Method of manufacturing a pyrrole derivative |
JP6490489 |
1989-03-16 |
JP2791488B2 |
1998-08-27 |
BURUUNO SHAUPU; HANSUURUEJI KENEERU; PEETAA ATSUKAAMAN |
|
114 |
Contact alkylation processes |
JP22244895 |
1995-07-28 |
JP2775239B2 |
1998-07-16 |
ROBAATO CHAARUZU MORISON; RANDEI UINFURETSUDO HOORU; BOBU TOROI DOOBAA; KONRADO UIRIAMU KAMINSUKII; JON FURANSHISU ENJERU |
|
115 |
Contact alkylation processes |
JP23254492 |
1992-07-17 |
JP2551901B2 |
1996-11-06 |
ROBAATO CHAARUZU MORISON; RANDEI UINFURETSUDO HOORU; BOBU TOROI DOOBAA; KONRADO UIRIAMU KAMINSUKII; JON FURANSHISU ENJERU |
|
116 |
Vapor deposition method |
JP51189694 |
1993-11-19 |
JPH08507870A |
1996-08-20 |
ジェームス ケアンズ; ジェームス トムソン |
There is described a method of chemically depositing a substance. The method is of utility in the direct manufacture of integrated circuits and in the manufacture of a photomask for use in production of integrated circuits. The method involves the use of a compound which degrades into a deposit and a residue when a radiant beam (e.g. a laser beam) or a particle beam (e.g. an electron beam) is applied. The residue and any unreacted compound may be washed off the substrate to which it has been applied. Nanoscale dimensions of the deposit can be achieved. A particularly suitable organometallic compound is tetra-sec butyl diaurum difluoride. |
117 |
Catalyzed hydrocarbyllithiu7m process |
JP9282394 |
1994-03-23 |
JPH06298772A |
1994-10-25 |
ROBAATO CHIYAARUZU MORISON; RANDEI UINFURETSUDO HOORU; JIEEMUSU ANSONII SHIYUUINDOMAN; KONRADO UIRIAMU KAMIENSUKII; JIYON FURANSHISU ENJIERU |
PURPOSE: To provide a process for alkylating an alkali metal with an alkyl halide containing 3 to 20 carbon atoms.
CONSTITUTION: An alkali metal selected from lithium, sodium and potassium is reacted in a hydrocarbon solvent in the presence of the a catalytic compound of the formula (RR
1R
2M
a)
yA(R
3)
x (R, R
1 and R
2 are each selected from H, halogen, 1-13C alkyl and alkenyl groups 3-10C cycloalkyl group and 6-18C aryl group; R
3 is selected from 1-10C alkyl group and 2-5C alkylene group; Ma is selected from silicon, carbon, germanium and tin; (x) and (y) are each independently 0 to 3).
COPYRIGHT: (C)1994,JPO |
118 |
JPH05502020A - |
JP51557790 |
1990-10-15 |
JPH05502020A |
1993-04-15 |
|
|
119 |
JPS6125037B2 - |
JP9404777 |
1977-08-05 |
JPS6125037B2 |
1986-06-13 |
JOSEFU MERUBIN FUREMONTO |
|
120 |
JPS6110475B2 - |
JP15034076 |
1976-12-16 |
JPS6110475B2 |
1986-03-29 |
HARA HAJIME; KAIYA ATSUSHI; ARAKI YOSHIHIKO |
|