子分类：
| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 161 | Catalysts and their use in oxidation of saturated hydrocarbons | US374588 | 1995-04-19 | US5739076A | 1998-04-14 | Diane Renata Cornelia Huybrechts; Philip Luc Buskens; Georges Marie Karel Mathys; Luc Roger Marc Martens |
| New titanium zeolite Beta catalysts which have been found to be useful as catalysts for the oxidation of organic compounds using organic hydroperoxides as oxidation catalysts. They are particularly useful as ring opening oxidation catalysts and may be used to produce adipic acid from cyclohexane. | ||||||
| 162 | Process for the selective oxidation of aromatic compounds | US459836 | 1995-06-02 | US5710292A | 1998-01-20 | Wolfgang Anton Herrmann; Joao Domingos Galamba Correia; Richard Walter Fischer |
| The invention relates to the use of compounds of the formula Re.sub.a O.sub.b X.sub.c L.sub.d, (I) in which X=F, Cl, Br, I or OH, L=Lewis base, a=an integer 1, 2 or 3 b=zero or an integer from 2 to 9, c=zero or an integer from 1 to 9, d=zero or an integer from 1 to 6, and the sum of a, b and c is such that it is appropriate to the zerovalency or trivalency to heptovalency of the rhenium with the proviso that if b is not equal to zero, b.gtoreq.2.multidot.a, as catalysts for the oxidation of electron-rich aromatic compounds and derivatives thereof and a process for the oxidation of electron-rich aromatic compounds, in which electron-rich C.sub.6 -C.sub.22 aryl compounds and derivatives thereof are oxidized in an organic solvent in the presence of a catalyst of the formula (I) and of a peroxide-containing compound. | ||||||
| 163 | Process for the production of petrochemicals | US494293 | 1995-06-23 | US5646304A | 1997-07-08 | Divyanshu R. Acharya; Satish S. Tamhankar |
| A petrochemical is produced by the vapor phase reaction of a hydrocarbon with air in the presence of a suitable catalyst. The petrochemical is removed from the reactor effluent, and part or all of the remaining petrochemical-free gas stream is passed through a hydrocarbon-selective adsorbent, which adsorbs hydrocarbon from the gas stream, leaving a hydrocarbon-depleted waste gas. Hydrocarbon is purged from the adsorbent with air, and the air-hydrocarbon mixture is recycled to the partial oxidation reactor. The purge air, and preferably both the purge air and the petrochemical-free gas stream are dried by passage through beds of zeolite 3A prior to being introduced into the hydrocarbon-selective adsorbent, and the beds of zeolite 3A are regenerated by passing heated hydrocarbon-depleted waste gas therethrough. | ||||||
| 164 | Process for the production of hydrocarbon partial oxidation products | US232544 | 1994-04-22 | US5466837A | 1995-11-14 | Ramakrishnan Ramachandran; Loc H. Dao |
| An ethylene stream which contains ethane as an impurity or a propylene stream which contains propane as an impurity is subjected to adsorption at a temperature of 50.degree. to 200.degree. C. in a bed of adsorbent which selectively adsorbs ethylene or propylene, thereby adsorbing substantially all of the ethylene or propylene. The purified ethylene or propylene stream is then subjected to partial oxidation in the presence of oxygen and, optionally ammonia to produce various partial oxidation products. The process is operated on a low per pass conversion with recycle of unreacted ethylene or propylene. In the system of the invention the adsorption unit may be upstream or downstream of the partial oxidation reactor. | ||||||
| 165 | Metal phthalocyanine oxidation catalysts | US862038 | 1992-04-02 | US5254740A | 1993-10-19 | Paul E. Ellis, Jr.; James E. Lyons |
| As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Method of oxidizing alkanes by contact with a catalyst comprising diazido derivative of a metal phthalocyanine, including halogenated phthalocyanines. Method of oxidizing alkanes by contact with a catalyst comprising a metal phthalocyanine or halide thereof, including halogenated phthalocyanines, and an alkali metal or ammonium or tetraalkylammonium azide. | ||||||
| 166 | Catalytic oxidation of the organic substrate by transition metal complexes in organic solvents inflated by supercritical or subcritical carbon dioxide | JP2001575532 | 2001-04-03 | JP4927289B2 | 2012-05-09 | ミン ウェイ; バラ スブラマニアム; ダライル エイチ． ブッシュ; ゲザイ ティー． ムジー |
| Improved oxidation methods are provided wherein a reaction mixture comprising a substrate to be oxidized (e.g., phenols, alkenes) and an oxidation catalyst (typically dispersed in an organic solvent system) is supplemented with a compressed gas which expands the reaction mixture, thus accelerating the oxidation reaction. In preferred practice pressurized subcritical or supercritical carbon dioxide is used as the expanding gas, which is introduced into the reaction mixture together with an oxidizing agent. The inventive methods improve the substrate conversion and product selectivity by increasing the solubility of the oxidizing agent in the reaction mixture. | ||||||
| 167 | Reactor start-up method | JP2000238419 | 2000-08-07 | JP4871441B2 | 2012-02-08 | 整 中原; 晴紀 平尾; 行弘 松本; 邦彦 鈴木 |
| 168 | Method of manufacturing a higher-order oxide than alcohol | JP2001565316 | 2001-03-09 | JP4801866B2 | 2011-10-26 | 豊 亀山; 秀雄 田中 |
| 169 | Carbon by deprotonation of a different atom - method of manufacturing an organic metal organic intermediate having a different atomic bonds | JP2004535121 | 2003-08-21 | JP2005537331A | 2005-12-08 | アンドレアス、モイト; クラウス、フォルスティンガー; ベルント、レーネマン; ミヒャエル、エルベス |
| 本発明は、異原子−炭素結合を形成させる方法に関する。 該方法により、脂肪族または芳香族ハロゲン化合物(I)を金属リチウムと反応させてリチウム化合物(II)を先ず発生させ、次いで該化合物を使用して化合物(III)または(V)を脱プロトン化する。 該脱プロトン化により得られた式(IV)または(VI)のリチウム塩を続いて適当な炭素求電子試薬と反応させ（式Ｉ）、異原子−炭素結合を形成させて、生成物(VIII)または(VIII)を製造する（式Ｉ）。
【化１】 |
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| 170 | Saturated alcohols, ketones, preparation of aldehydes and carboxylic acids | JP2003510415 | 2002-06-12 | JP2004533477A | 2004-11-04 | キューンレ アードルフ; ヴェー ツェー エー アーレンツ イザベラ; ヨスト カールステン; エム エム シャテル サンドリーヌ; アーサー シェルダン ロジャー |
| 出発化合物として不飽和炭化水素を使用し、触媒として、式Ｉの化合物を使用し、まず第一に、前記不飽和炭化水素を、酸素含有ガスを用いて触媒の使用下にラジカル開始剤の存在で酸化させる、飽和アルコール、ケトン、アルデヒド及びカルボン酸の製造法において、酸化生成物を引き続く水素添加により還元し、飽和アルコール、ケトン、アルデヒド及び／又はケトンを形成させることを特徴とする、飽和アルコール、ケトン、アルデヒド及びカルボン酸の製造法。 | ||||||
| 171 | Integrated method for selectively oxidizing organic compound | JP2003282420 | 2003-07-30 | JP2004238388A | 2004-08-26 | DE FRUTOS ESCRIG PILAR; ANA PADILLA POLO; RIESCO JOSE MANUEL G; CAMPOS MARTIN JOSE MIGUEL; BLANCO BRIEVA GEMA; CANO SERRANO ENCARNACION; CAPEL SANCHEZ MARIA DEL CARMEN; GARCIA FIERRO JOSE LUIS |
| <P>PROBLEM TO BE SOLVED: To provide a method for selectively oxidizing an organic compound. <P>SOLUTION: This integrated oxidation method comprises processes I and II, wherein the process I comprises producing hydrogen peroxide from hydrogen and oxygen in the presence of a solvent and a catalyst which comprises at least one kind of noble metal or semi-noble metal supported on an acidic resin not containing halogen, and the process II comprises directly mixing a solution of the hydrogen peroxide with the organic compound, another suitable catalyst, and, if necessary, the solvent, so as to form an oxide compound corresponding to the organic compound. The integrated oxidation method does not require a process for treating the hydrogen peroxide and is especially suitable for producing propylene oxide. <P>COPYRIGHT: (C)2004,JPO&NCIPI | ||||||
| 172 | Process for the oxidation of hydrocarbons to acid | JP2001565323 | 2001-03-07 | JP2004514645A | 2004-05-20 | エリック ファシュ |
| The present invention relates to a process for oxidizing hydrocarbons, in particular branched or unbranched saturated aliphatic hydrocarbons, cycloaliphatic or alkylaromatic hydrocarbons to acidic or polyacidic compounds. The invention relates more particularly to the oxidation, with an oxidizing agent containing molecular oxygen, of cyclohexane to adipic acid, in the presence of organic acid of lipophilic nature and in the absence of adipic acid. The separation and recycling of the unoxidized cyclohexane, the oxidation intermediates and the catalysts are easier than in the presence of acetic acid. | ||||||
| 173 | Catalytic oxidation of the organic substrate by transition metal complexes in organic solvents inflated by supercritical or subcritical carbon dioxide | JP2001575532 | 2001-04-03 | JP2004500418A | 2004-01-08 | ウェイ ミン; スブラマニアム バラ; ブッシュ ダライル エイチ．; ムジー ゲザイ ティー． |
| Improved oxidation methods are provided wherein a reaction mixture comprising a substrate to be oxidized (e.g., phenols, alkenes) and an oxidation catalyst (typically dispersed in an organic solvent system) is supplemented with a compressed gas which expands the reaction mixture, thus accelerating the oxidation reaction. In preferred practice pressurized subcritical or supercritical carbon dioxide is used as the expanding gas, which is introduced into the reaction mixture together with an oxidizing agent. The inventive methods improve the substrate conversion and product selectivity by increasing the solubility of the oxidizing agent in the reaction mixture. | ||||||
| 174 | Regeneration method of the zeolite catalyst | JP50154799 | 1998-06-05 | JP2002504014A | 2002-02-05 | ヴァルヒ アンドレアス; ハーダー ヴォルフガング; ミュラー ウルリッヒ; ハインリッヒ グローシュ ゲオルク; リーバー ノルベルト |
| (57)【要約】 次の工程からなるゼオライト触媒の再生法：（I）酸素２容量％未満を有する雰囲気中で部分的に又は完全に失活化した触媒を２５０〜６００℃に加熱し、かつ（II）２５０〜８００℃、有利に３５０〜６００℃で触媒を酸素供与物質又は酸素又はそれら２種以上の混合物０．１〜４容量％を有するガス流で処理し、その際、前記ガス流は工程（Ｉ）中の雰囲気に比較してより多い量の酸素を有し、（III）２５０〜８００℃、有利に３５０〜６００℃で触媒を酸素供与物質又は酸素又はそれら２種以上の混合物を４容量％より多く１００容量％まで含有するガス流で処理する。 | ||||||
| 175 | Production of organic compound by using imide as catalyst | JP2000179185 | 2000-06-14 | JP2001354596A | 2001-12-25 | KITAYAMA KENJI; TATSUMI JUNRO; TERADA MASAHIKO; HIRAI NARIHISA |
| PROBLEM TO BE SOLVED: To provide a chemical process that can produce the objective organic compound in higher conversion and selectivity by using an imide, for example, N-hydroxy-phthalimide, as a reaction catalyst. SOLUTION: In this process for producing an organic compound according to this invention, an imide represented by the following formula (1) (wherein R1 and R2 are each an alkyl, an aryl, a cycloalkyl and the like and they may be connected to each other to form a double bond or an aromatic or nonaromatic ring; X is an O atom or a hydroxyl group) is used as a catalyst. This imide catalyst is sequentially added to the reaction system whereby the reaction is carried out. As examples of the reactions, are cited oxidation, carboxylation, nitration, sulfonation, carbon - carbon bond formation, and the like. COPYRIGHT: (C)2001,JPO | ||||||
| 176 | Selective oxidation method of the organic compound | JP2000522094 | 1998-11-12 | JP2001524475A | 2001-12-04 | ステファン シュワルツ; マイケル ブライアン ダモール |
| (57)【要約】 有機化合物を酸化するための方法が開示されている。 シリカで修飾されたチタニア／シリカ含有触媒の存在下で、過酸化水素を用いて、酸化可能な有機基質を酸化する。 ジエトキシシランとチタン酸エチルとの共重合体を用いる触媒を調製するための方法もまた開示されている。 | ||||||
| 177 | Selective oxidation method of the organic compound | JP2000521054 | 1998-11-12 | JP2001523651A | 2001-11-27 | ジャック エヌ． ジュニア ウェンツ; キース アール． オレウィン; プララド アール． シン; ジェラルド ピー． テコ |
| (57)【要約】 有機化合物の酸化方法が開示されている。 酸化可能な有機基質を酸化するのにシリカ変性チタニア／シリカ含有触媒の存在下、過酸化水素を用いる。 ジエトキシシランおよびチタン酸エチルのコポリマーを用いる触媒の調製方法も開示されている。 | ||||||
| 178 | Contact additional method of nucleophilic agents to alkynes or allenes | JP52171397 | 1996-12-06 | JP2000502077A | 2000-02-22 | シュルツ ミヒャエル; ヘンリク テレス ヨアキム |
| (57)【要約】 アルキン類またはアレン類に求核試薬を接触付加してその求核剤で置換されたアルケン類を製造し、そして必要な場合、前記求核剤を用いてさらに反応および／または異性化を行う方法を開示する。 使用される触媒は、少なくとも一部分がイオン化された形態で存在する１価の金の錯体である。 | ||||||
| 179 | Production of aldehyde and ketone or its derivative, production of x-ray amorphous zinc silicate, roentgenamorph zinc silicate, its production and its use as catalyst | JP17505698 | 1998-06-22 | JPH1171314A | 1999-03-16 | TELES JOAQUIM HENRIQUE DR; RIEBER NORBERT DR; BREUER KLAUS DR; DEMUTH DIRK DR; HIBST HARTMUT; HAGEMEYER ALFRED DR |
| PROBLEM TO BE SOLVED: To safely obtain the subject compound, by adding a hydroxyl group- containing compound to an alkyne, etc., in the presence of a roentgenamorph zinc silicate catalyst, etc. SOLUTION: A compound of the formula R<1> OH (R<1> is H, an aliphatic or alicyclic group) is added to an acetylene or allene of formula I or formula II (R is H, an aliphatic or alicyclic group) in a gas phase by using a catalyst containing a zinc silicate as an active ingredient obtained by precipitation from an aqueous solution comprising a soluble silicon compound and zinc compound to give the objective compound of formula III or formula IV ((m) is 0 or 1). The zinc silicate is X-ray amorphous zinc silicate of the formula Zna Sic Oa+2c-0.5e (OH)e .fH2 O ((e) is a value from 0 to 2a+2c; a/c is 1-3.5 and f/a is 0 to 200) and/or a crystal zinc silicate having a hemimorphite structure of the formula Zn4 Si2 O7 ) (OH)2 .H2 O. Zinc exists in a deficient amount or an excessive amount of 25% in terms of stoichiometric composition. | ||||||
| 180 | Anti-breaking thin plate | JP22998097 | 1997-08-26 | JPH10128922A | 1998-05-19 | STASI ALBERTO LUCA; STANCO DONATO |
| PROBLEM TO BE SOLVED: To form panels with an excellent break resisting property relative to breakdown and/or an improved mechanical property. SOLUTION: The plate is that when measured by an ISO 527 standard for a plate or film installed in a panel, it has a smooth or mold-pressed surface formed by the use of 1 or more polymer continuous films having an elastic modulus lower than PMMA by at least 30% and/or a rupture extension larger than at least 40% and an exterior layer being susceptible of an arbitrary thermal molding of acrylic polymer. The multi-layer plate is transparent or reflection-preventive, or colored or opalescent, having a low thickness in the range of 1.5-10mn. | ||||||
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