| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 1 | 分离技术、有机底物的光氧化以及光催化剂 | CN201280056017.8 | 2012-11-13 | CN104203874A | 2014-12-10 | 马丁·波利亚科夫; 迈克·W·乔治; 理查德·A·伯恩; 韩雪; 杰茜卡·F·B·哈勒 |
| 本发明公开了一种用于光氧化有机底物以形成有机产物的方法，包括：a)混合氧、超临界流体、光催化剂、液态氟溶剂和有机底物以形成混合物；和b)照射混合物以形成有机产物。还公开了一种用于从有机产物中分离光催化剂的方法，包括以下步骤：a)提供包含超临界流体；有机产物；氟溶剂；光催化剂；和可选的有机底物和可选的氧的混合物；其中所述有机产物、氟溶剂、光催化剂和可选的有机底物以及可选的氧溶解于超临界流体中；和b)将混合物的压力降低至低于超临界流体的临界压力的压力，从而形成气相。 | ||||||
| 2 | 一种利用经改性的钼酸盐LDH催化剂通过单线态氧氧化有机底物的方法 | CN200680012576.3 | 2006-03-18 | CN101160273A | 2008-04-09 | 迪克·德沃斯; 皮埃尔·雅各布斯; 约斯·瓦兰; 保罗·阿尔斯特斯; 沃尔特·雅里 |
| 本发明公开了一种通过单线态氧氧化有机底物的方法，所述方法包括：在由乙二醇、聚乙二醇或多元醇进行改性的钼酸盐LDH催化剂的存在下，将与1O2反应的有机底物与10－70％H2O2在有机溶剂中进行混合，并且在H2O2催化分解成水和1O2后，发生氧化，得到相应的氧化产物，本发明还涉及一种经改性的钼酸盐LDH催化剂。 | ||||||
| 3 | How the oxidation of organic substrates using the singlet oxygen | JP2000613796 | 2000-03-23 | JP2002543049A | 2002-12-17 | アルスターズ・パウル; オウブリー・ジャン−マリー; ラタヤ−ナルデロ・ベロニク |
| (57)【要約】 触媒としてのランタノイドの存在下、水、有機溶媒またはこれらの混合物中で、 1 O 2と反応する有機基質を30〜70％濃度のH 2 O 2と反応させ、この際、水及び 1 O 2を与えるH 2 O 2の接触分解に次いで、対応する酸化生成物を与える酸化が起こる、 1 O 2により有機基質を酸化する方法。 | ||||||
| 4 | How the oxidation of organic substrates using the singlet oxygen | JP2000610802 | 2000-03-23 | JP2002541227A | 2002-12-03 | アルスターズ・パウル; オウブリー・ジャン−マリー; ラタヤ−ナルデロ・ベロニク |
| (57)【要約】 不均一系または均一系触媒の存在下に有機溶媒中において、 1 O 2と反応する疎水性有機基質を30〜70％濃度のH 2 O 2と反応させ、この際、水及び 1 O 2を与えるH 2 O 2の接触的分解に次いで、対応する酸化生成物を与える酸化が起こる、 1 O 2を用いた有機基質の酸化方法。 | ||||||
| 5 | METHOD FOR PRODUCING POWDERED LAUROYL PEROXIDE | US15531546 | 2015-11-26 | US20180044289A1 | 2018-02-15 | Dominik HERMANN; Iris NAGL; Hanno WOLF |
| The present application relates to a method for producing powdered lauroyl peroxide which is characterised in that a reaction mixture is used which comprises water, lauric acid chloride, hydrogen peroxide, an inorganic base and an alkane. | ||||||
| 6 | Process for Oxidizing Organic Substrates By Means of Singlet Oxygen Using a Modified Molybdate LDH Catalyst | US11918131 | 2006-03-18 | US20110098488A1 | 2011-04-28 | Dirk De Vos; Pierre Jacobs; Joos Wahlen; Paul Alsters; Walther Jary |
| Oxidation of organic substrates by means of singlet oxygen, in which organic substrates which react with 1O2 are admixed with 10-70% H2O2 in an organic solvent in the presence of a molybdate LDH catalyst modified by ethylene glycol, polyethylene glycol or polyol, and the catalytic decomposition of H2O2 to water and 1O2 is then followed by the oxidation to the corresponding oxidation products, and also modified molybdate LDH catalysts. | ||||||
| 7 | Selective thermal oxidation of hydrocarbons in zeolites by oxygen | US335441 | 1999-06-17 | US6150562A | 2000-11-21 | Heinz Frei; Fritz Blatter; Hai Sun |
| A process for selective thermal oxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls is carried out in solvent free zeolites under dark thermal conditions. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts. | ||||||
| 8 | Method for producing powdered lauroyl peroxide | US15531546 | 2015-11-26 | US09951006B2 | 2018-04-24 | Dominik Hermann; Iris Nagl; Hanno Wolf |
| The present application relates to a method for producing powdered lauroyl peroxide which is characterized in that a reaction mixture is used which comprises water, lauric acid chloride, hydrogen peroxide, an inorganic base and an alkane. | ||||||
| 9 | SEPARATION TECHNIQUE, PHOTO-OXIDATION OF ORGANIC SUBSTRATES, AND PHOTO CATALYSTS | US14358578 | 2012-11-13 | US20140288328A1 | 2014-09-25 | Martyn Poliakoff; Mike W. George; Richard A. Bourne; Xue Han; Jessica F. B. Hall |
| A method for photo-oxidising an organic substrate to form an organic product is disclosed comprising: a) mixing oxygen, a supercritical fluid, a photocatalyst, a liquid fluorous solvent and an organic substrate to form a mixture; and b) irradiating the mixture to form an organic product. Also disclosed is a method for separating a photocatalyst from an organic product comprising the steps of: a) providing a mixture comprising a supercritical fluid; an organic product; a fluorous solvent; a photocatalyst; and optionally an organic substrate and optionally oxygen; wherein the organic product, fluorous solvent, photocatalyst and optional organic substrate and optional oxygen are dissolved in the supercritical fluid; and b) reducing the pressure of the mixture to a pressure below the critical pressure of the supercritical fluid in order to form a gaseous phase. | ||||||
| 10 | Singlet oxygen oxidation of organic substrates | US09937725 | 2001-09-28 | US06486360B1 | 2002-11-26 | Jean-Marie Aubry; Veronique Rataj-Nardello; Paul Alsters |
| The invention relates to a method for oxidizing organic substrate by using 1O2. According to the inventive method, organic substrates that react with 1O2 are mixed with 30-70% H2O2 in water, in an organic solvent or in a mixture thereof in the presence of a lanthanide as the catalyst. H2O2 is catalytically decomposed to water and 1O2 and is then oxidized to the corresponding oxidation products. | ||||||
| 11 | Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen | US09709221 | 2000-11-10 | US06329553B1 | 2001-12-11 | Heinz Frei; Fritz Blatter; Hai Sun |
| A process for a combined selective thermal oxidation and photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly combined selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts. | ||||||
| 12 | Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen | US874679 | 1997-06-13 | US5914013A | 1999-06-22 | Heinz Frei; Fritz Blatter; Hai Sun |
| A process for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts. | ||||||
| 13 | PROCESS FOR OXIDIZING ORGANIC SUBSTRATES BY MEANS OF SINGLET OXYGEN USING A MODIFIED MOLYBDATE LDH CATALYST | EP06707607.5 | 2006-03-18 | EP1874710A1 | 2008-01-09 | DE VOS, Dirk; JACOBS, Pierre; WAHLEN, Joos; ALSTERS, Paul; JARY, Walther |
| Oxidation of organic substrates by means of singlet oxygen, in which organic substrates which react with 1O2 are admixed with 10-70% H2O2 in an organic solvent in the presence of a molybdate LDH catalyst modified by ethylene glycol, polyethylene glycol or polyol, and the catalytic decomposition of H2O2 to water and 1O2 is then followed by the oxidation to the corresponding oxidation products, and also modified molybdate LDH catalysts. | ||||||
| 14 | SINGLET SAUERSTOFF OXIDATION VON ORGANISCHEN SUBSTRATEN | EP00922539.2 | 2000-03-23 | EP1169281B1 | 2004-02-18 | AUBRY, Jean-Marie; RATAJ-NARDELLO, Véronique; ALSTERS, Paul |
| The invention relates to a method for oxidizing organic substrates using 1O2 in which hydrophobic organic substrates that react with 1O¿2 are added to an organic solvent in the presence of a heterogeneous or homogeneous catalyst with 30-70 % being comprised of H¿2?O2. Afterwards, H2O2 is catalytically decomposed into water and ?1O¿2, and the oxidation into corresponding oxidation products ensues. | ||||||
| 15 | PREPARATION OF COMPOUNDS FROM LEVULINIC ACID | US15547041 | 2016-01-29 | US20180029980A1 | 2018-02-01 | Mark Mascal; Saikat Dutta; Linglin Wu |
| The present invention provides a method of making carboxylic acids from levulinic acid, such as succinic acid and 3-hydroxypropanoic acid, by reacting levulinic acid with an oxidant such as hydrogen peroxide under acidic or basic conditions. | ||||||
| 16 | Process and catalyst for producing hydroperoxides | US11311037 | 2005-12-19 | US07361792B2 | 2008-04-22 | Timothy A. Brandvold; Gregory J. Lewis; Lisa M. King; Lawrence E. Brewer |
| A process and catalyst for preparing organic hydroperoxides by oxidizing hydrocarbon compounds in the presence of an oxygen-containing gas and a catalyst containing a transition metal on a solid support. | ||||||
| 17 | Process and catalyst for producing hydroperoxides | US11311037 | 2005-12-19 | US20060094907A1 | 2006-05-04 | Timothy Brandvold; Gregory Lewis; Lisa King; Lawrence Brewer |
| A process and catalyst for preparing organic hydroperoxides by oxidizing hydrocarbon compounds in the presence of an oxygen-containing gas and a catalyst containing a transition metal on a solid support. | ||||||
| 18 | Singlet oxygen oxidation of organic substrates | US09937724 | 2000-03-23 | US06956137B1 | 2005-10-18 | Jean-Marie Aubry; Veronique Rataj-Nardello; Paul Alsters |
| The invention relates to a method for oxidizing organic substrates using 1O2 in which hydrophobic organic substrates that react with 1O2 are added to an organic solvent in the presence of a heterogeneous or homogeneous catalyst with 30–70% being compr Afterwards, H2O2 is catalytically decomposed into water and 1O2, and the oxidation into corresponding oxidation products ensues. | ||||||
| 19 | Selective photooxidation of hydrocarbons in zeolites by oxygen | US710031 | 1996-09-11 | US5827406A | 1998-10-27 | Heinz Frei; Fritz Blatter; Hai Sun |
| A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative. | ||||||
| 20 | VERFAHREN ZUR HERSTELLUNG VON PULVERFÖRMIGEM LAUROYLPEROXID | EP15801785.5 | 2015-11-26 | EP3224244A1 | 2017-10-04 | HERMANN, Dominik; NAGL, Iris; WOLF, Hanno |
| The invention relates to a method for producing powdery lauroyl peroxide, which is characterized by the fact that a reaction mixture which contains water, lauric acid chloride, hydrogen peroxide, inorganic bases and an alkane, is used. | ||||||
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