子分类：
| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 101 | Process for converting a hydrocarbon to an oxygenate or a nitrile | US10429286 | 2003-05-02 | US20040220434A1 | 2004-11-04 | John H. Brophy; Frederick A. Pesa; Anna Lee Tonkovich; Jeffrey S. McDaniel; Kai Tod Paul Jarosch |
| This invention relates to a process for converting a hydrocarbon reactant to a product comprising an oxygenate or a nitrile, the process comprising: (A) flowing a reactant composition comprising the hydrocarbon reactant, and oxygen or a source of oxygen, and optionally ammonia, through a microchannel reactor in contact with a catalyst to convert the hydrocarbon reactant to the product, the hydrocarbon reactant undergoing an exothermic reaction in the microchannel reactor; (B) transferring heat from the microchannel reactor to a heat exchanger during step (A); and (C) quenching the product from step (A). | ||||||
| 102 | Process for producing carbonyl or hydroxy compound | US10760523 | 2004-01-21 | US20040152592A1 | 2004-08-05 | Koji Hagiya; Naoyuki Takano; Akio Kurihara |
| There are disclosed are a method for producing at least one compound selected from a carbonyl compound and a hydroxy adduct compound by an oxidative cleavage or addition reaction of an olefinic double bond of an olefin compound, which contains reacting an olefin compound with hydrogen peroxide, utilizing as a catalyst, at least one member selected from (a) tungsten, (b) molybdenum, or (c) a tungsten or molybdenum metal compound containing (ia) tungsten or (ib) molybdenum and (ii) an element of Group IIIb, IVb, Vb or VIb excluding oxygen, and a catalyst composition. | ||||||
| 103 | Intrinsically safe oxidation process | US09882519 | 2001-06-15 | US06768013B1 | 2004-07-27 | Peter R. Pujado |
| A novel process for the direct oxidation of hydrogen and hydrocarbons is disclosed, where the explosion risks inherent in gas phase oxidations are substantially eliminated. Gaseous oxidation reactants are soluble in a first reaction solvent phase such as a perfluorocarbon (e.g. C8F18) and the oxidation product is preferentially soluble in a second product solvent phase such as water or a dilute acid. A solid catalyst such as palladium on alumina is then contacted with the dissolved reactants. The oxidation product such as hydrogen peroxide may be separated from the reaction solvent phase by extraction into the immiscible product solvent phase and then separated from it by distillation, thereby allowing re-use of the aqueous phase. The present invention may be carried out using a two-phase reaction system whereby both the reaction solvent and product solvent are contained within a reaction vessel into which the solid catalyst is slurried and mechanically agitated to promote the reaction. | ||||||
| 104 | Method for regenerating a zeolitic catalyst | US10061282 | 2002-02-04 | US06710002B2 | 2004-03-23 | Georg Heinrich Grosch; Ulrich Mueller; Andreas Walch; Norbert Rieber; Wolfgang Harder |
| A process for regenerating a zeolite catalyst comprises the following stages: (I) Heating a partially or completely deactivated catalyst to 250-600° C. in an atmosphere which contains less than 2% by volume of oxygen, (II) treating the catalyst at from 250 to 800° C., preferably from 350 to 600° C., with a gas stream which contains from 0.1 to 4% by volume of an oxygen-donating substance or of oxygen or of a mixture of two or more thereof, and (III) treating the catalyst at from 250 to 800° C., preferably from 350 to 600° C., with a gas stream which contains from more than 4 to 100% by volume of an oxygen-donating substance or of oxygen or of a mixture of two or more thereof. | ||||||
| 105 | Catalytic oxidation of organic substrates by transition metal complexes in organic solvent media expanded by supercritical or subcritical carbon dioxide | US10205863 | 2002-07-26 | US20030100805A1 | 2003-05-29 | Bala Subramaniam; Daryle H. Busch; Ghezai T. Musie; Ming Wei |
| Improved oxidation methods are provided wherein a reaction mixture comprising a substrate to be oxidized (e.g., phenols, alkenes) and an oxidation catalyst (typically dispersed in an organic solvent system) is supplemented with a compressed gas which expands the reaction mixture, thus accelerating the oxidation reaction. In preferred practice pressurized subcritical or supercritical carbon dioxide is used as the expanding gas, which is introduced into the reaction mixture together with an oxidizing agent. The inventive methods improve the substrate conversion and product selectivity by increasing the solubility of the oxidizing agent in the reaction mixture. | ||||||
| 106 | Method for oxidizing an organic compound containing at least one C-C double bond | US09424847 | 1999-12-06 | US06518441B2 | 2003-02-11 | Georg Heinrich Grosch; Ulrich Müller; Andreas Walch; Norbert Rieber; Martin Fischer; Stefan Quaiser; Wolfgang Harder; Karsten Eller; Peter Bassler; Anne Wenzel; Gerd Kaibel; Achim Stammer; Jochem Henkelmann; Arnd Böttcher; Joaquim Henrique Teles; Michael Schulz; Gert Treiber |
| A process for oxidizing an organic compound having at least one C—C double bond or a mixture of two or more thereof comprises the following steps: (I) preparing a hydroperoxide, (II) reacting an organic compound having at least one C—C double bond or a mixture of two or more thereof with the hydroperoxide prepared in step (I) in the presence of a zeolite catalyst, (III) regenerating the at least partially deactivated zeolite catalyst used in step (II), and (IV) conducting the reaction of step (II) using a zeolite catalyst containing the catalyst regenerated in step (III). | ||||||
| 107 | Process for the catalytic selective oxidation of a hydrocarbon compound in presence of mesoporous zeolite | US09961019 | 2001-09-21 | US06476275B2 | 2002-11-05 | Iver Schmidt; Michael Brorson; Claus J. H. Jacobsen |
| Processes applying mesoporous titanium containing zeolite based catalysts for selective oxidation or epoxidation of hydrocarbons by peroxides. | ||||||
| 108 | PROCESS FOR PREPARATION OF SUBSTITUTED AROMATIC COMPOUND | US10018424 | 2001-12-20 | US20020161227A1 | 2002-10-31 | Tadahito Nobori; Setsuko Fujiyoshi; Isao Hara; Takaomi Hayashi; Atsushi Shibahara; Katsuhiko Funaki; Kazumi Mizutani; Shinji Kiyono |
| A substituted aromatic compound substituted with Q is obtained by reacting a phosphazenium compound represented by formula (1) 1 (in the formula, Qnull represents an anion in a form derived by elimination of a proton from an inorganic acid, or an active hydrogen compound having an active hydrogen on an oxygen atom, a nitrogen atom or a sulfur atom; a, b, c and d, each independently, is 0 or 1, but all of them are not 0 simultaneously; and R groups represent the same or different hydrocarbon groups having 1 to 10 carbon atoms, or two Rs on each common nitrogen atom may be bonded together to form a ring structure) with a halogenated aromatic compound having halogen atoms; whereby, at least one halogen atom in the halogenated aromatic compound is substituted with Q (where, Q represents an inorganic group or an organic group in a form derived by elimination of one electron from Qnull in formula (1)). | ||||||
| 109 | METHOD FOR OXIDIZING AN ORGANIC COMPOUND CONTAINING AT LEAST ON C-C DOUBLE BOND | US09424847 | 1999-12-06 | US20020120158A1 | 2002-08-29 | GEORG HEINRICH GROSCH; ULRICH MULLER; ANDREAS WALCH; NORBERT RIEBER; MARTIN FISCHER; STEFAN QUAISER; WOLFGANG HARDER; KARSTEN ELLER; PETER BASSLER; ANNE WENZEL; GERD KAIBEL; ACHIM STAMMER; JOCHEM HENKELMANN; ARND BOTTCHER; JOAQUIN HENRIQUE TELES; MICHAEL SCHULZ; GERT TREIBER |
| A process for oxidizing an organic compound having at least one CnullC double bond or a mixture of two or more thereof comprises the following steps: (I) preparing a hydroperoxide, (II) reacting an organic compound having at least one CnullC double bond or a mixture of two or more thereof with the hydroperoxide prepared in step (I) in the presence of a zeolite catalyst, (III) regenerating the at least partially deactivated zeolite catalyst used in step (II), and (IV) conducting the reaction of step (II) using a zeolite catalyst containing the catalyst regenerated in step (III). | ||||||
| 110 | Method for regenerating a zeolitic catalyst | US09424854 | 2000-01-13 | US06380119B1 | 2002-04-30 | Georg Heinrich Grosch; Ulrich Müller; Andreas Walch; Norbert Rieber; Wolfgang Harder |
| A process for regenerating a zeolite catalyst comprises the following stages: (I) Heating a partially or completely deactivated catalyst to 250-600° C. in an atmosphere which contains less than 2% by volume of oxygen, (II) treating the catalyst at from 250 to 800° C., preferably from 350 to 600° C., with a gas stream which contains from 0.1 to 4% by volume of an oxygen-donating substance or of oxygen or of a mixture of two or more thereof, and (III) treating the catalyst at from 250 to 800° C., preferably from 350 to 600° C., with a gas stream which contains from more than 4 to 100% by volume of an oxygen-donating substance or of oxygen or of a mixture of two or more thereof. | ||||||
| 111 | Process for preparing alcohol derivatives | US09583777 | 2000-05-31 | US06372923B1 | 2002-04-16 | Mitsuru Uno; Munehisa Okutsu; Tomohito Kitsuki |
| The present invention provides a process for preparing an alcohol derivative, where the alcohol derivative is an ester, acetal, ketal, ether glycoside, or alkyl glycoside, by reacting an alcohol with a carbonyl compound, alcohol, olefin, epoxy compound or saccharide, where C2-4 vicinal alkylene oxides are excluded, in the presence of (A) an aluminum alkoxide and (B) sulfuric acid or phosphoric acid. | ||||||
| 112 | Method for starting up reactor | US09919024 | 2001-07-31 | US20020037488A1 | 2002-03-28 | Harunori Hirao; Yukihiro Matsumoto; Sei Nakahara; Kunihiko Suzuki |
| In the reaction of catalytic gas phase oxidation induced by the supply of at least a raw material to be oxidized and a molecular oxygen-containing gas to a reactor for catalytic gas phase oxidation, a method for starting up the reactor for catalytic gas phase oxidation is disclosed which is characterized by causing the raw material and the molecular oxygen-containing gas to pass a range in which the concentration of the raw material is less than the lower explosion limit of the raw material and the concentration of oxygen is not less than the limiting oxygen concentration, but excluding the concentration of the raw material of 0 vol. %. The method enables the reactor to be started up economically and safely by avoiding the explosion range induced by the composition of a raw material and a molecular oxygen-containing gas supplied to the reactor and decreasing the amount of a diluting gas to be supplied. | ||||||
| 113 | Process for producing carbonyl or hydroxy compound | US09925523 | 2001-08-10 | US20020025906A1 | 2002-02-28 | Koji Hagiya; Naoyuki Takano; Akio Kurihara |
| There are disclosed are a method for producing at least one compound selected from a carbonyl compound and a hydroxy adduct compound by an oxidative cleavage or addition reaction of an olefinic double bond of an olefin compound, which contains reacting an olefin compound with hydrogen peroxide, utilizing as a catalyst, at least one member selected from (a) tungsten, (b) molybdenum, or (c) a tungsten or molybdenum metal compound containing (ia) tungsten or (ib) molybdenum and (ii) an element of Group IIIb, IVb, Vb or VIb excluding oxygen, and a catalyst composition | ||||||
| 114 | Low thickness antifragmentation plates | US08917109 | 1997-08-25 | US06344274B1 | 2002-02-05 | Alberto Luca Stasi; Donato Stanco |
| Multilayer transparent, antireflex, coloured or opaline plates, with smooth or embossed surfaces, optionally thermouldable with external layers in acrylic polymers, low thickness, in the range of 1.5 up to lower thicknesses of 10 mm, by employing one or more polymeric continuous films which have the property to have elastic modulus lower than the one of PMMA of at least 30%, and/or elongation at break higher than at least 40%, measured by the test according to ISO 527 for plates or films, placed inside the panel. | ||||||
| 115 | Process for the production of petrochemicals | US721493 | 1996-09-27 | US5726327A | 1998-03-10 | Divyanshu R. Acharya; Ravi Kumar; Ramakrishnan Ramachandran |
| Petrochemicals are produced by the vapor phase reaction of a hydrocarbon with air in the presence of a suitable catalyst. The petrochemical product is removed from the product gas stream, and unreacted hydrocarbon in part or all of the remaining gas stream is recovered by subjecting the gas stream to a TSA process in which the adsorbed hydrocarbon is desorbed at elevated pressure by purging the adsorbent with hot compressed air, the air being heated by compression. The compressed air-desorbed hydrocarbon mixture is recycled to the reactor. | ||||||
| 116 | Process for the selective oxidation of compounds | US414966 | 1995-03-31 | US5698744A | 1997-12-16 | Ross Albert Lee |
| Selective oxidation employs ferromagnetic chromium dioxide followed by magnetic separation. | ||||||
| 117 | Process for the partial oxidation of alkanes | US598920 | 1996-02-09 | US5654491A | 1997-08-05 | Duane A. Goetsch; Lanny D. Schmidt |
| A process for catalytic partial oxidation of a hydrocarbon is provided. The process includes: providing a feed gas mixture comprising an oxygen-containing gas and a hydrocarbon gas comprising one or more normal (C.sub.2 -C.sub.4)alkanes; providing a catalyst structure having a transparency of at least about 40%; and passing the feed gas mixture through the catalyst structure at a rate such that the superficial contact time of the feed gas mixture with the catalyst structure is no greater than about 1000 microseconds to produce an exit gas mixture comprising partial oxidation products. | ||||||
| 118 | Process for oxidizing organic compounds | US981595 | 1992-11-25 | US5252758A | 1993-10-12 | Mario G. Clerici; Patrizia Ingallina |
| Process for oxidizing organic compounds with hydrogen peroxide in the presence of titanium-silicalite and of a water-alcohol solvent which, after the preliminary separation of the oxidation product and of the water formed during the reaction, is used again in order to extract hydrogen peroxide produced in a redox process with alkyl-anthraquinone and is fed again to the oxidation reaction. | ||||||
| 119 | 디시클로펜타디엔다이머의 에폭시화 반응용 고활성 촉매 및 이의 제조방법 | KR1020110129705 | 2011-12-06 | KR1020130063274A | 2013-06-14 | 윤병태; 김성보; 정근우; 김영운; 고문규 |
| PURPOSE: A catalyst for epoxidation of dicyclopentadiene dimer and a manufacturing method thereof are provided to be able to show a high selectivity to dicyclopentadien dimer with a large molecular size and a high conversion ratio, and to be able to obtain a dicyclopentadiene dimer epoxy compound with a high yield. CONSTITUTION: A catalyst for epoxidation of dicyclopentadiene dimer has a structure in which metals in a zeolite molecular sieve of macro pores more than 7 angstrom are substituted with titanium. The catalyst is a heterogeneous catalyst used in a process of manufacturing dicyclopentadiene dimer epoxy compound by epoxidation of dicyclopentadiene dimer. A manufacturing method of the catalyst comprises the following steps: a step of processing a zeolite molecular sieve of macro pores more than 7 angstrom with acid; and a step of substituting aluminum of the acid-treated zeolite molecular sieve with titanium by stirring the acid-treated zeolite molecular sieve with titanium precursor. | ||||||
| 120 | 유기 화합물을 선택적으로 산화시키기 위한 통합 방법 | KR1020030036619 | 2003-06-07 | KR100615114B1 | 2006-08-22 | 에스크릭,필라르드프루토스; 폴로,아나파딜라; 리에스코가르시아,호세마뉴엘; 캄포스마틴,호세미구엘; 브리에바,제마블랑코; 세라노,안카르나시옹카노; 카펠산체스,마델카르멘; 가르시아피에로,호세루이스 |
| 액체상에서 연속적인 통합 방법으로 산화 화합물을 제조하며, 이 방법은 귀금속 촉매를 이용한 촉매 반응에 의해 수소와 산소간 직접 반응으로 비산성 과산화수소 용액을 합성하는 단계 I과, 이 과산화수소 용액을 유기 기질, 적절한 촉매 및 임의로 용매와 직접 혼합시키는 단계 II를 포함한다. 본 통합 방법은 처리 단계를 필요로 하지 않으며, 특히 프로필렌 옥사이드의 제조에 매우 적합하다. 비산성 과산화수소, 유기 화합물, 산화, 정제 | ||||||
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