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序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
101	Chemical vapor deposition of transistion metals	US210079	1988-06-22	US4992305A	1991-02-12	Ahmet Erbil
Coatings of Group IIA metals and compounds thereof are formed by chemical vapor deposition, in which a heat decomposable organometallic compound of the formula (I) ##STR1## wherein M is a transition metal of Group VB, VIB, VIIB or VIII, R.sub.1 is a lower alkyl or alkenyl radical containing from 2 to about 6 carbon atoms, R.sub.2 is a hydrogen or lower alkyl or alkenyl radical, n is the valence of M and is an integer from 2 to 4, and p is an integer from 0 to (n-1), is contacted with a heated substrate which is above the decomposition temperature of the organometallic compound. The pure metal is obtained when the compound of the formula I is the sole heat decomposable compound present and deposition is carried out under nonoxidizing conditions. Intermetallic compounds such as manganese telluride can be deposited from a manganese compound of formula I and a heat decomposable tellurium compound under nonoxidizing conditions.
102	Metal complex and method for preparing	US830513	1977-09-06	US4120865A	1978-10-17	Clifford Ward
Disclosed is a catalyst and method for converting mercaptans and mercaptide compounds in aqueous alkaline solution to disulfides. Catalytic agent is a metal complex synthesized from 3,3',4,4'-benzophenonetetracarboxylic dianhydride and converted to either the alkali metal salt or to the acid form. The method for oxidizing the mercaptide compounds comprises contacting mercaptans and mercaptide compounds in aqueous alkaline solution with air in the presence of the catalyst and subsequently separating alkaline solution from the resultant disulfide compounds.
103	Cyclooctatetraene complexes of niobium and tantalum	US478966	1974-06-13	US3932477A	1976-01-13	Richard Royce Schrock
Reaction of tantalum or niobium pentachloride with dipotassium cyclooctatetraene(2-) yields K.sup.+M(C.sub.8 H.sub.8).sub.3 .sup.- and ClM(C.sub.8 H.sub.8).sub.2 (M is Ta or Nb). Likewise BrM(C.sub.8 H.sub.8).sub.2 can be prepared from MBr.sub.5. Reaction of (Cl, Br) M(C.sub.8 H.sub.8).sub.2 with a lithium alkyl or aryl gives RM(C.sub.8 H.sub.8).sub.2 where R is alkyl or aryl. The potassium ion of K.sup.+M(C.sub.8 H.sub.8).sub.3 .sup.- can be replaced with other alkali metal ions, alkaline earth metal ions, ammonium, phosphonium, or arsonium ions by metathesis. Likewise, (CH.sub.3).sub.3 TaCl.sub.2 and CH.sub.3 MCl.sub.4 react with dipotassium cyclooctatetraene(2-) to give (CH.sub.3).sub.3 Ta(C.sub.8 H.sub.8) and CH.sub.3 M(C.sub.8 H.sub.8).sub.2, respectively. The cyclooctatetraene complexes are catalysts for the oligomerization of ethylene and are useful as oxygen scavengers.
104	Photoconductive elements containing organo-metallic photoconductors	US3719486D	1971-06-17	US3719486A	1973-03-06	GOLDMAN M; JOHNSON A
Photoconductive compositions and elements containing a Group Va organo-metallic photoconductive compound.
105	Photoconductive compositions and electrophotographic elements containing group iva or group va organometallic photoconductors	US3647429D	1967-07-03	US3647429A	1972-03-07	GOLDMAN MARTIN; JOHNSON ARTHUR L
Photoconductive compositions and electrophotographic elements containing as photoconductors organometallic compounds having at least one aminoaryl group attached to a Group IVa or Group Va metal atom through an aryl moiety.
106	Tetraacetonitrilolithiumhexafluorophosphate and method for the preparation thereof	US3594402D	1969-05-29	US3594402A	1971-07-20	WIESBOECK ROBERT A
TETRAACETONIRILOLITHIUMHEXAFLUOROPHOSPHATE, A NEW COMPOUND PREPARED BY REACTING LITHIUM FLUORIDE AND PF5 OR PREVIOUSLY PREPARED LIPF6 WITH EXCESS CH3CN, IS DISCLOSED. TETRAACETIONITRILOLITHIUMHEXAFLUOROPHOSPHATE IS USEFUL FOR THE PRODUCTION OF HIGH PURITY EXCEPTIONALLY ACTIVE LIPF6 WHICH IS ALSO A NEW COMPOSITION OF MATTER. THE PREPARATIONS OF THESE NEW COMPOSITIONS ARE ALSO DISCLOSED.
107	Preparation of cyclopentadienyl metal olefin compounds	US3474017D	1966-05-23	US3474017A	1969-10-21	WERNER ROBERT P

108	Metal organophosphorus compounds	US3467683D	1965-12-06	US3467683A	1969-09-16	HARSON SAMUEL EDWARD; FOGG EDWARD

109	Method of producing onium-salt complex compounds	US3448127D	1964-03-27	US3448127A	1969-06-03	DOTZER RICHARD
Onium salts having a complex anion are prepared by the reaction of (a) an electron donor compound of formula R1kHlkY, (b) a electron acceptor compound of formula MR11nX1mn and (c) an organic compound RX, wherein R, R1 and R11 are alkyl or aryl groups, X is halogen, pseudohalogen or an acid residue, X1 is halogen or hydrogen, Y is N, P, As, Sb, Bi, S, Se or Te, M is Be, Zn, Cd, B, Al, In, Ga, Tl, Si, Ge, Pb or Sn, l and m are integers representing the capacities of Y and M respectively to combine with hydrogen, and k and n are 0 or an integer from 1 to l or m respectively. The reaction in its simplest form may be represented by:-D + A + RX --> [DR]+[AX]-wherein D represents the electron donor and A the electron acceptor, but compounds formed by the reaction of two molecules of acceptor with one each of donor and RX ar also disclosed. The reaction may be carried out by first forming a co-ordination compound between donor and acceptor and reacting this with RX, or an adduct or mixture may be formed from the acceptor and RX which is then reacted with the donor, or the donor and RX may be first mixed and then reacted with the acceptor. Trimethylammonium triethylchloroaluminate obtained by first passing triethylamine gas into triethylaluminium to form a 1 : 1 complex and passing methyl chloride into the product. By passing further methyl chloride there is obtained the complex Triethylpropylstibonium triethylbromoindanate is prepared by reacting methylantimony and triethylindium under an inert gas and adding N :propyl bromide to the product. Further examples are indicated by the equations:- The complex onium salts may be degraded by such methods as solvolysis with methanol or water, oxidative cleavage or displacement with a stronger complexing agent for the acceptor compound to give the simple onium salt (DR)+X- where D represents the donor compound. For example, tetraethylstibonium triethyl bromoaluminate in solution in dichloromethane is added to methanol, ethane is evolved and aluminium methoxide removed by decantation, and the residue worked up to yield tetraethylstibonium bromide.
110	Process of producing pai-allyl metal anion compounds	US3424777D	1964-08-06	US3424777A	1969-01-28	WILKE GUNTHER
Olefines such as mono-olefines and diolefines or mixtures thereof may be oligomerized using p -allyl metal compounds or p -allyl metal halides wherein the metal is a transition metal of Groups IV-VIII. Lewis acids such as organoaluminium compounds and aluminium halides, and Lewis bases such as (a) the alkyl, cycloalkyl, aralkyl or aryl compounds of elements of Group V other than nitrogen, (b) the tri-alkyl, -cycloalkyl, -aralkyl or -aryl esters of elements of Group V other than nitrogen, as well as their triamides and (e) dialkyl sulphoxides may be added. In the examples, butadiene, ethylene, propylene and butene-2 are separately oligomerized, mostly to dimers; also butene-2 and ethylene; ethylene and propylene; and ethylene and cyclohexene are codimerized.ALSO:Olefines such as mono-olefines and diolefines may be polymerized using p -allyl metal compounds or p -allyl metal halides wherein the metal is from Group IVa to VIIa or VIII of the specified Periodic System. Lewis acids such as organo aluminium compounds or aluminium halides and Lewis bases such as (a) the alkyl, cycloalkyl, aralkyl or aryl compounds of elements of Group V other than nitrogen, (b) the tri-alkyl, -cycloalkyl, -aralkyl or -aryl esters of elements of Group V other than nitrogen, as well as their triamides and (c) dialkyl sulphoxides, may also be present. In the examples:-(1) ethylene is polymerized using tris-p -allyl chromium, bis-p -allyl chromium iodide or bisp -allyl chromium chloride; (2) butadiene is polymerized using tetra-p -allyl chromium, tris-p -allyl-vanadium, p -allyl-nickel chloride and ethyl aluminium dichloride, tris-p -allyl chromium, tris-p -allyl cobalt, bis-p -allyl cobalt iodide and ethyl aluminium dichloride, bis-p -allyl cobalt iodide and aluminium bromide, bis-p -allyl cobalt chloride and diethyl aluminium chloride or ethyl aluminium dichloride, p -allyl cobalt diiodide, triphenyl phosphine and aluminium bromide; (3) propylene is polymerized using vanadium tetrachloride and p -allyl-magnesium chloride and (4) isoprene is polymerized using p -allyl nickel chloride and ethyl aluminium dichloride.ALSO:Catalysts for the oligomerization and polymerization of olefines comprise p -allyl compounds of metals or p -allyl metal halides wherein the metal is from Group IVA to VIIA or VIII of the specified Periodic System together with a Lewis acid and/or a Lewis base. The Lewis acids may be organoaluminium compounds or aluminium halides and the Lewis bases may be (a) the alkyl, cycloalkyl, aralkyl or aryl compounds of Group V elements other than nitrogen, (b) the tri-alkyl, -cycloalkyl, -aralkyl or-aryl esters of Group V elements other than nitrogen, as well as their triamides and (c) dialkyl sulphoxides. Many examples are given, the p -allyl compounds or halides used being tris-p -allyl chromium, bis-p -allyl chromium iodide, bis-p -allyl-chromium chloride, tris-p -allyl cobalt, bis-p -allyl cobalt iodide, bis-p -allyl cobalt chloride, p -allyl cobalt di-iodide, p -cyclooctatrienyl-nickel chloride, p -cyclo-octenyl nickel chloride, p -allyl-nickel iodide, p -allyl magnesium chloride, p -pineneyl-nickel bromide, p -allyl nickel bromide, p -crotyl nickel iodide, p -cinanmyl nickel chloride; 1, 2, 3-triphenyl-p -cyclopropenyl nickel bromide; p -allyl palladium chloride, p -allyl nickel chloride, tetra-p -allyl zirconium, tris-p -allyl vanadium and C12 H19 NiCl.
111	Acids and salts in which the anion has a transition metal attached to one to three-s(cf3) c=c(cf3)s-groups	US31879063	1963-10-25	US3398167A	1968-08-20	WALTER MAHLER

112	Cyclooligomerization using nickel (0) polydentate ligand	US52923166	1966-02-23	US3364273A	1968-01-16	CLARK REGINALD F; STORRS CHARLES D; BARNES GEORGE B

113	Silylorganocyclopentadienylmetalcarbonyls and process therefor	US28352663	1963-05-27	US3329695A	1967-07-04	WILKUS EDWARD V; ABE BERGER

114	Organo vanadium tetracarbonyl compounds	US19019862	1962-04-23	US3247233A	1966-04-19	WERNER ROBERT P M

115	Method of reacting a reactive hydrogen compound and an isocyanate in the presence of an organic antimony, arsenic or bismuth catalyst	US31235263	1963-09-30	US3235518A	1966-02-15	FRITZ HOSTETTLER; COX EUGENE F

116	2,3-dimercapto-quinoxalines	US16419062	1962-01-03	US3223706A	1965-12-14	KLAUS SASSE; RICHARD WEGLER; GUNTER UNTERSTENHOFER
The invention comprises 2,3-dimercapto-quinoxalines of the general formula: wherein R represents a hydrogen or halogen atom or a nitro, trifluoromethyl, C1-C4 alkyl or C1-C4 alkoxy radical; R1 represents a hydrogen atom or a hydroxy, alkyl, cycloalkyl, aryl, chloroaryl, aralkyl, alkylsulphonyl, arylsulphonyl or primary or secondary amino radical; and R2 represents a hydrogen atom or an acyl, alkyl, cycloalkyl, aralkyl, aryl, alkoxy, alkylmercapto, arylmercapto or a primary or secondary amino radical. They may be prepared by reacting a 2,3-dimercapto-quinoxaline of the general formula: or an alkali metal or ammonium salt thereof, with a compound of the general formula: in an aqueous or aqueous organic medium at -20 DEG to + 100 DEG C. and preferably in the presence of an acid-binding agent. The compounds of the formula: wherein R1 and R2 represent alkyl, cycloalkyl, aryl, chloroaryl or aralkyl radicals, may also be prepared by reacting the 2,3-dimercapto-quinoxaline starting material specified above with two molecules of a carbodiimide of the general formula: R1-N=C=N-R2. Several examples are given and the compounds of the invention are stated to be pest control agents (see Division A5).ALSO:Compounds of the general formula wherein R represents a hydrogen or halogen atom or a nitro, trifluoromethyl, C1 to C4 alkyl or C1-C4 alkoxy radical; R1 represents a hydrogen atom or a hydroxy, alkyl, cycloalkyl, aryl, chloroaryl, aralkyl, alkylsulphonyl, arylsulphonyl or primary or secondary amino radical; and R2 represents a hydrogen atom or an acyl, alkyl, cycloalkyl, aralkyl, aryl, alkoxy, aryloxy, alkylmercapto, arylmercapto, or primary or secondary amino radical, are stated to be pest control agents which may be employed in admixture with solid or liquid, diluents or carriers.
117	Chemical process for preparing a salt of a metal of groups (iv)a and (v)a and salt	US8337861	1961-01-18	US3211768A	1965-10-12	CONSIDINE WILLIAM J

118	2, 3-dimercaptoquinoxaline derivatives	US82382559	1959-06-30	US3091613A	1963-05-28	KLAUS SASSE; RICHARD WEGLER; GUNTER UNTERSTENHOFER
The invention comprises 2,3-dimercapto-quinoxalines of the general formula: wherein R represents a hydrogen or halogen atom or a nitro, trifluoromethyl, C1-C4 alkyl or C1-C4 alkoxy radical; R1 represents a hydrogen atom or a hydroxy, alkyl, cycloalkyl, aryl, chloroaryl, aralkyl, alkylsulphonyl, arylsulphonyl or primary or secondary amino radical; and R2 represents a hydrogen atom or an acyl, alkyl, cycloalkyl, aralkyl, aryl, alkoxy, alkylmercapto, arylmercapto or a primary or secondary amino radical. They may be prepared by reacting a 2,3-dimercapto-quinoxaline of the general formula: or an alkali metal or ammonium salt thereof, with a compound of the general formula: in an aqueous or aqueous organic medium at -20 DEG to + 100 DEG C. and preferably in the presence of an acid-binding agent. The compounds of the formula: wherein R1 and R2 represent alkyl, cycloalkyl, aryl, chloroaryl or aralkyl radicals, may also be prepared by reacting the 2,3-dimercapto-quinoxaline starting material specified above with two molecules of a carbodiimide of the general formula: R1-N=C=N-R2. Several examples are given and the compounds of the invention are stated to be pest control agents (see Division A5).ALSO:Compounds of the general formula wherein R represents a hydrogen or halogen atom or a nitro, trifluoromethyl, C1 to C4 alkyl or C1-C4 alkoxy radical; R1 represents a hydrogen atom or a hydroxy, alkyl, cycloalkyl, aryl, chloroaryl, aralkyl, alkylsulphonyl, arylsulphonyl or primary or secondary amino radical; and R2 represents a hydrogen atom or an acyl, alkyl, cycloalkyl, aralkyl, aryl, alkoxy, aryloxy, alkylmercapto, arylmercapto, or primary or secondary amino radical, are stated to be pest control agents which may be employed in admixture with solid or liquid, diluents or carriers.
119	Organo bimetallic compositions	US9967961	1961-03-31	US3030397A	1962-04-17	GORSICH RICHARD D

120	Aziridine-methylolphosphorus polymers and flame resistant organic textiles	US58956256	1956-06-05	US2886539A	1959-05-12	DRAKE JR GEORGE L; REEVES WILSON A; CHANCE LEON H

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