序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
81 NOVEL POLYGODIAL ANALOGS FOR THE TREATMENT OF CANCER AND OTHER PROLIFERATIVE DISEASES US15752960 2016-08-17 US20180237362A1 2018-08-23 Cara B. GONZALES; Alexander KORNIENKO; Ramesh DASARI
The present disclosure relates generally to derivatives of polygodial and methods of use thereof. In some aspects, the present disclosure relates to using polygodial derivatives to treat cancer or other hyperproliferative diseases.
82 METAL ORGANIC FRAMEWORK ABSORBENT PLATFORMS FOR REMOVAL OF CO2 AND H2S FROM NATURAL GAS US15564935 2016-04-07 US20180093218A1 2018-04-05 Mohamed EDDAOUDI; Amandine CADIAU; Prashant M. BHATT; Karim ADIL; Youssef BELMABKHOUT
Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Methods include capturing one or more of H2S, H2O, and CO2 from fluid compositions, such as natural gas.
83 TANTALUM COMPOUND AND METHODS OF FORMING THIN FILM AND FABRICATING INTEGRATED CIRCUIT DEVICE BY USING THE SAME US15298275 2016-10-20 US20170178961A1 2017-06-22 Seung-min RYU; Takanori KOIDE; Naoki YAMADA; Jae-soon LIM; Tsubasa SHIRATORI; Youn-joung CHO
A tantalum compound, a method of forming a thin film, and a method of fabricating an integrated circuit device, the tantalum compound being represented by the following General Formula (I):
84 GROUP 5 METAL OXO-ALKOXO COMPLEX, METHOD FOR PRODUCING SAME, AND METHOD FOR MANUFACTURING GROUP 5 METAL OXIDE FILM US14758142 2013-12-27 US20150353588A1 2015-12-10 Sachio ASANO; Tomoyuki KINOSHITA; Yasushi HARA; Daiji HARA; Ryoji TANAKA; Ken-ichi TADA
A compound useful for the manufacture of a Group 5 metal oxide film is provided. The compound is a Group 5 metal oxo-alkoxo complex represented by the following formula (A), and after preparing a film-forming material solution containing the compound and an organic solvent, a Group 5 metal oxide film can be manufactured using the film-forming material solution: Mα(μ4-O)β(μ3-O)γ(μ-O)δ(μ-ORA)∈(ORA)ζ(RAOH)ηXθYι  (A) (wherein M represents a niobium atom, etc.; RA represents an alkyl group; X represents an alkylenedioxy group; Y represents a carboxy group, etc.; α represents an integer of 3 to 10; β represents 0 or 1; γ represents an integer of 0 to 8; δ represents an integer of 2 to 9; ∈ represents an integer of 0 to 6; ζ represents an integer of 6 to 16; η represents an integer of 0 to 4; θ represents an integer of 0 to 2; and ι represents an integer of 0 to 6).
85 Niobium and vanadium organometallic precursors for thin film deposition US13888970 2013-05-07 US09040372B2 2015-05-26 Nicolas Blasco; Antony Correia-Anacleto; Audrey Pinchart; Andreas Zauner
Disclosed are methods for forming a metal-containing layer on a substrate. The methods include providing a vapor and at least one reaction gas and reacting the vapor and the reaction gas with the substrate by a deposition process. The vapor may be selected from the group consisting of (Cp)V(═NtBu)(NEt2)2; (Cp)V(═NtBu)(NMe2)2; (Cp)V(═NtBu)(NEtMe)2; (Cp)V(═NiPr)(NEt2)2; (Cp)V(═NiPr)(NMe2)2; (Cp)V(═NiPr)(NEtMe)2; (Cp)V(═NC5H11)(NEt2)2; (Cp)V(═NC5H11)(NMe2)2; (Cp)V(═NC5H11)(NEtMe)2; (Cp)Nb(═NtBu)(NEt2)2; (Cp)Nb(═NtBu)(NMe2)2; (Cp)Nb(═NtBu)(NEtMe)2; (Cp)Nb(═NiPr)(NEt2)2; (Cp)Nb(═NiPr)(NMe2)2; (Cp)Nb(═NiPr)(NEtMe)2; (Cp)Nb(═NC5H11)(NEt2)2; (Cp)Nb(═NC5H11)(NMe2)2; and (Cp)Nb(═NC5H11)(NEtMe)2. The reaction gas may be selected from the group consisting of hydrogen, hydrogen sulfide, hydrogen selenide, hydrogen telluride, carbon monoxide, ammonia, organic amine, silane, disilane, higher silanes, silylamines, diborane, hydrazine, methylhydrazine, chlorosilane, chloropolysilane, metal alkyl, arsine, phosphine, trialkylboron, oxygen, hydrogen peroxide, nitrous oxide, nitrogen monoxide, nitrogen dioxide, alcohols, plasma comprising fragments of those species, and combinations thereof.
86 METHODS FOR PREPARING VANADIUM DIOXIDE COMPOSITE POWDERS, VANADIUM DIOXIDE POWDER SLURRY, AND VANADIUM DIOXIDE COATING FOR INTELLIGENT TEMPERATURE CONTROL US14373302 2012-03-07 US20150132494A1 2015-05-14 Hongjie Luo; Yiliao Liu; Yanfeng Gao; Zhaohui Cai; Yuwei Lin; Chuanxiang Cao; Shaobo Wang; Minoru Kanehira
A vanadium dioxide coating for intelligent temperature control is formed by mixing a vanadium dioxide powder slurry, a polymer emulsion, and coating additives, and then coating the mixture onto a substrate. The vanadium dioxide powdery slurry comprises vanadium dioxide composite powders and a dispersion medium, the composite powders comprising vanadium dioxide nanopowders having a chemical composition of V1−xMxO2, and the surface of the vanadium dioxide nanopowders being attached to organic modified long-chain molecules, wherein M is a doped element, and 0≦x≦0.5. Through using the vanadium dioxide powders and the slurry thereof having an organic modified surface, the coating has higher visible light transmittance, can almost completely screen ultraviolet rays, and simultaneously intelligently adjust infrared rays.
87 NOVEL ARYLALCOHOLS AND METAL COMPLEXES THEREOF US13753732 2013-01-30 US20140213805A1 2014-07-31 Daniel J. Mindiola; Ba L. Tran
Provided herein is a compound of Formula 1: or an isomer thereof, or a salt of the compound or of an isomer thereof, wherein R1 and R2 are each independently selected from the group consisting of hydrogen, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, dialkylamino, halodialkylamino, hydroxyalkyl, and cyano, and R is selected from the group consisting of alkyl, haloalkyl, cyanoalkyl, alkoxy, dialkylamino, and cyano.
88 METHOD FOR PREPARING POROUS ORGANIC-INORGANIC HYBRID MATERIALS US14123161 2012-06-01 US20140200361A1 2014-07-17 U-Hwang Lee; Jong-San Chang; Young Kyu Hwang; You-Kyong Seo; Christian Serre; Patricia Horcajada; Hubert Chevreau; Florence Ragon; Thomas Devic
The present invention relates to a method for preparing a porous organic-inorganic hybrid, which comprises gelling a reaction mixture containing a metal precursor, a water-soluble additive and water or water-containing organic solvent at a gelling temperature of 30° C.˜100° C. to obtain an organogel-containing solution having a viscosity of 2 to 50,000 (cps), subsequently ageing the solution at said gelling temperature under stirring; and subsequently heating the organogel-containing solution at a temperature between said gelling temperature and 250° C. to crystallize the solution.According to the method for preparation of the present invention, it is possible to commercially practice the present invention since the reaction can be carried out in water or a water-containing organic solvent at an ambient pressure or a slightly raised pressure under a reflux condition, as well as it is possible to mass-produce a porous organic-inorganic hybrid having a high crystallinity and a large surface even in a high mol ratio of 1:1˜1:30 of solvent to metal.
89 Metal Hydrazide Materials US14026838 2013-09-13 US20140007974A1 2014-01-09 David Michael Antonelli
The present invention provides the following new polymers which are useful for hydrogen storage: (i) a polymer comprising -[MN2]— as a repeating unit, wherein M is selected from the group consisting Sc, Ti, V, Cr, Mn, Fe, Co, Zr, Nb, Mo, and mixtures thereof; and (ii) a polymer comprising -[M2N3]— as a repeating unit, wherein M is selected from the group consisting Sc, Ti, V, Cr, Mn, Fe, Co, Zr, Nb, Mo, and mixtures thereof.
90 Catalyst compositions containing transition metal complexes with thiolate ligands US13042807 2011-03-08 US08618229B2 2013-12-31 Mark L. Hlavinka
The present invention discloses catalyst compositions employing transition metal complexes with a thiolate ligand. Methods for making these transition metal complexes and for using such compounds in catalyst compositions for the polymerization of olefins also are provided.
91 Niobium and vanadium organometallic precursors for thin film deposition US13123013 2009-10-06 US08460989B2 2013-06-11 Nicolas Blasco; Anthony Correia-Anacleto; Audrey Pinchart; Andreas Zauner
Disclosed are methods for forming a metal-containing layer on a substrate. A vapor comprising at least one precursor compound selected from the group consisting of (Cp)V(=NtBu)(NEt2)2; (Cp)V(=NtBu)(NMe2)2; (Cp)V(=NtBu)(NEtMe)2; (Cp)V(═NiPr)(NEt2)2; (Cp)V(═NiPr)(NMe2)2; (Cp)V(═NiPr)(NEtMe)2; (Cp)V(═NC5H11)(NEt2)2; (Cp)V(═NC5H11)(NMe2)2; (Cp)V(═NC5H11)(NEtMe)2; (Cp)Nb(=NtBu)(NEt2)2; (Cp)Nb(=NtBu)(NMe2)2; (Cp)Nb(=NtBu)(NEtMe)2; (Cp)Nb(═NiPr)(NEt2)2; (Cp)Nb(═NiPr)(NMe2)2; (Cp)Nb(═NiPr)(NEtMe)2; (Cp)Nb(═NC5H11)(NEt2)2; (Cp)Nb(═NC5H11)(NMe2)2; and (Cp)Nb(═NC5H11)(NEtMe)2 is provided. At least one reaction gas selected from the group consisting of ozone and water is provided. The vapor and the reaction gas react with the substrate according to a deposition process to form the metal-containing layer on at least one surface of the substrate.
92 1′-substituted-carba-nucleoside prodrugs for antiviral treatment US13117060 2011-05-26 US08415308B2 2013-04-09 Aesop Cho; Choung U. Kim; Adrian S. Ray; Lijun Zhang
Provided are prodrugs of pyrrolo[1,2-f][1,2,4]triazin-7-yl nucleoside phosphates wherein the 1′ position of the nucleoside sugar is substituted with CN. The compounds, compositions, and methods provided are useful for the treatment Hepatitis C infections.
93 1'-SUBSTITUTED-CARBA-NUCLEOSIDE PRODRUGS FOR ANTIVIRAL TREATMENT US13117060 2011-05-26 US20120020921A1 2012-01-26 Aesop CHO; Choung U. Kim; Adrian S. Ray; Lijun Zhang
Provided are prodrugs of pyrrolo[1,2-f][1,2,4]triazin-7-yl nucleoside phosphates wherein the 1′ position of the nucleoside sugar is substituted with CN. The compounds, compositions, and methods provided are useful for the treatment Hepatitis C infections.
94 METAL HYDRAZIDE MATERIALS US12998984 2009-12-22 US20110308971A1 2011-12-22 David Michael Antonelli
The present invention provides the following new polymers which are useful for hydrogen storage: (i) a polymer comprising -[MN2]— as a repeating unit, wherein M is selected from the group consisting Sc, Ti, V, Cr, Mn, Fe, Co, Zr, Nb, Mo, and mixtures thereof; and (ii) a polymer comprising -[M2N3]— as a repeating unit, wherein M is selected from the group consisting Sc, Ti, V, Cr, Mn, Fe, Co, Zr, Nb, Mo, and mixtures thereof.
95 VANADIUM PHTHALOCYANINE COMPOUNDS AND NEAR-INFRARED ABSORPTION FILTER USING THE SAME US13142722 2009-11-05 US20110275847A1 2011-11-10 Yu-Mi Chang; Ju-Sik Kang; Jeong-Ho Park
A novel vanadium phthalocyanine compound with low absorptivity in the visible light region and high absorptivity in the near-infrared light region, and a near-infrared absorption filter using the same are disclosed. The near-infrared absorption vanadium phthalocyanine compound is represented by Formula 1 of claim 1. In Formula 1, A2, A3, A6, A7, A10, A11, A14 and A15 are independently OR1, SR2 or a halogen atom, wherein at least four thereof are OR1; A1, A4, A5, A8, A9, A12, A13 and A16 are independently OR1, SR2, NR3R4 or a halogen atom, wherein at least one thereof is NR3R4, and at least four thereof are OR1; R1, R2, R3 and R4 are independently an alkyl group of 1 to 10 carbon atoms, an aryl group of 6 to 10 carbon atoms, or an aralkyl group of 7 to 15 carbon atoms.
96 Polymerization of olefins US10791242 2004-03-02 US20040171481A1 2004-09-02 Ying Wang; Steven Dale Ittel
Olefins, such as ethylene, are polymerized using as a polymerization catalyst a complex of a selected transition metal with an anionic ligand that has at least three atoms that may coordinate to the transition metal. Also disclosed are the above selected transition metal complexes, and intermediates thereto.
97 Catalyst compounds with beta-diiminate anionic ligands and processes for polymerizing olefins US10319818 2002-12-16 US20040063574A1 2004-04-01 Klaus H. Theopold; Woo-Kyu Kim; Leonard A. MacAdams; John M. Power; Javier M. Mora; Albert P. Masino
The present invention relates to catalyst systems, processes for making such catalysts, intermediates for such catalysts, and olefin polymerization processes using such catalysts wherein such catalyst includes a component represented by the following formula IA: 1 wherein R and Rnull independently represent a hydrogen atom, or a substituted or unsubstituted, branched or unbranched hydrocarbyl or organosilyl radical; R1, R2, and R3 independently represent a hydrogen atom, or a substituted or unsubstituted, branched or unbranched hydrocarbyl radical; M is a group IIIB, IVB, VB, VIB, VIIB or VIII transition metal; T independently represents a univalent anionic ligand such as a hydrogen atom, or a substituted or unsubstituted hydrocarbyl, halogeno, aryloxido, arylorganosilyl, alkylorganosilyl, amido, arylamido, phosphido, or arylphosphido group, or two T groups taken together represent an alkylidene or a cyclometallated hydrocarbyl bidentate ligand; L independently represents a sigma donor stabilizing ligand; X, which is optional, represents a relatively weakly coordinated anion; and anull0 to 4 inclusive, bnull0 to 4 inclusive, provided anullbnull4.
98 Method for producing silasequioxane metal complexes, novel silasesquioxane metal complexes and use thereof US403260 1999-10-18 US6127557A 2000-10-03 Rutger Anthony Van Santen; Hendrikus Cornesis Louis Abbenhuis; Martinus Lambertus Wilhelmus Vorstenbosch
A method for producing silasesquioxane metal complexes of the formula (II)((R.sup.1 SiO.sub.1,5).sub.n (R.sup.2a SiO.sub.1,5).sub.m ((B).sub.q (O).sub.r)).sub.u (M).sub.v (Y).sub.win which R.sup.1 represents C.sub.5 -C.sub.10 -cycloalkyl, norbornyl or adamantyl; R.sup.2a represents oxygen; B represents H, OH, halogen, alkoxy, SiR.sup.3.sub.y in which R.sup.3 can be C.sub.1 -C.sub.4 alkyl, aryl or substituted silyl groups, and y represents 2 or 3, and R.sup.1 and R.sup.3 can be functionalized; M represents metals of the 4.sup.th to 7.sup.th subgroups of the periodic system of elements; Y represents C.sub.1 -C.sub.20 alkyl or aryl groups devoid of beta-hydrogen, silyl, alkoxy, OH, halogen, oxo, imido, fluorenyl, indenyl, cyclopentadienyl, in which the individual ligands can be substituted; n=6 or 7; m=0 or 1; q=0-2; r=0-2; u=1-4; v=1-4; w=0-12, in which a metal compound of the 4.sup.th to 7.sup.th subgroups of the periodic system of elements and at least one silasesquioxane compound of the formula (I)(R.sup.1 SiO.sub.1,5).sub.n (R.sup.2 SiO.sub.1,5).sub.m ((H).sub.p (B).sub.q (O).sub.r))in which R.sup.1, B, n, m, q and r have the above meanings; R.sup.2 represents OH, and p equals 0-4, are suspended in an alkylated aromatic hydrocarbon, optionally in the presence of a basic compound, with stirring at -80 to +110.degree. C., and a reaction product is separated at room temperature. The invention also relates to metal complexes which include an oxidic metal cluster containing titanium atoms, in which each titanium atom has been coordinated .times.6, and to the use of such metal complexes as catalysts for oxidation or epoxidation of unsaturated hydrocarbons or alcohols in an aqueous medium.
99 Tantalum compound, process of producing the same, and material for forming tantalum oxide films US346009 1994-11-29 US5508063A 1996-04-16 Toshiyuki Suzuki; Hideyuki Mori; Kouichi Nakamura
A novel tantalum compound represented by the formula (1): Ta(CH.sub.3).sub.3 (OR).sub.2, wherein R is an alkyl group having from 2 to 7 carbon atoms. The novel tantalum compound is produced by reacting a haloalkoxytantalum compound represented by the formula (2): TaX.sub.n (OR).sub.5-n, wherein X is halogen, R is an alkyl group having from 2 to 7 carbon atoms, and n is an integer of from 0 to 4, with a methylmetal compound; and recovering the tantalum compound represented by the above formula (1) by reduced pressure distillation. The tantalum compound has a high vapor pressure and permits effective formation of a uniform film of tantalum oxide with good properties by a CVD method. Therefore, the tantalum compound is very useful for manufacturing semiconductor devices.
100 Halogenated alkoxyphthalocyanines US723589 1991-07-01 US5270463A 1993-12-14 Hisato Itoh; Katashi Enomoto; Takahisa Oguchi; Tutomu Nishizawa
A method for preparing a halogenated alkoxyphthalocyanine represented by the formula (7) ##STR1## wherein R.sup.3 to R.sup.6 may be different and each of them is a secondary alkyl group, X is a halogen atom, n is the number of X and in the range of from 1 to 4, and Met is two hydrogen atoms, a divalent metal atom, or a trivalent or a tetravalent metallic derivative, which comprises the step of reacting a metal or a metallic compound with one to four kinds of raw materials selected from the group consisting of phthalonitriles represented by the following formula (1) and diiminoisoindolines represented by the following formula (2) ##STR2## wherein R.sup.1 is a secondary alkyl group, X is a halogen atom, and each of p and q is 0 or 1, but in at least one raw material, p or q is 1, and halogenated alkoxyphthalocyanine prepared by said method.
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