Photoconductive elements containing organo-metallic photoconductors

申请号 US3719486D 申请日 1971-06-17 公开(公告)号 US3719486A 公开(公告)日 1973-03-06
申请人 EASTMAN KODAK CO; 发明人 GOLDMAN M; JOHNSON A;
摘要 Photoconductive compositions and elements containing a Group Va organo-metallic photoconductive compound.
权利要求
1. An electrophotographic element comprising an electrically conducting support having thereon a photoconductive composition comprising an electrically insulating, film- forming polymeric binder and a Group Va organo-metallic photoconductive compound having attached to a Group Va metal atom at least one amino-aryl group.
2. An electrophotographic element comprising an electrically conducting support having thereon a photoconductive composition comprising an electrically insulating, film-forming polymeric binder and a Group Va organo-metallic photoconductive compound having attached to a Group Va metal atom (1) at least one amino-aryl group, and (2) at least one substituent selected from the group consisting of a hydrogen atom, an oxygen atom, an alkyl radical and an aryl radical.
3. An electrophotographic element comprising an electrically conducting support having thereon a photoconductive composition comprising an electrically insulating, film-forming polymeric binder and a photoconductor represented by the formula: wherein: T is an amino radical; Ar is an aryl radical; Mb is a Group Va metal; and E and J are selected from the group consisting of a hydrogen atom, an alkyl radical, an aryl radical and, when taken together, an oxygen atom.
4. An electrophotographic element comprising an electrically conducting support having thereon a photoconductive composition comprising an electrically insulating, film-forming polymeric binder and a photoconductor represented by the formula: wherein: T is an amino radical; Ar is an aryl radical; M is a Group Va metal; and L and Q are each selected from the group consisting of a hydrogen atom, an alkyl radical and an aryl radical; and E and J are each selected from the group consisting of an alkyl radical, an aryl radical and, when taken together, an oxygen atom.
5. A photoconductive composition comprising an electrically insulating, film-forming polymeric binder containing at least 1 percent by weight of a Group Va organo-metallic photoconductive compound having attached to a Group Va metal atom (1) at least one amino-aryl group, and (2) at least one substituent selected from the group consisting of a hydrogen atom, an oxygen atom, an alkyl radical and an aryl radical.
6. A photoconductive composition comprising an electrically insulating, film-forming polymeric binder containing at least 1 percent by weight of a photoconductor represented by the formula: wherein: T is an amino radical; Ar is an aryl radical; Mb is a Group Va metal; L and Q are each selected from the group consisting of a hydrogen atom, an alkyl radical and an aryl radical; and E and J are each selected from the group consisting of an alkyl radical, an aryl radical and, when taken together, an oxygen atom.
7. A photoconductive composition comprising an electrically insulating, film-forming polymeric binder containing at least 1 percent by weight of a photoconductor represented by the formula: wherein: R1 and R2 are alkyl radicals having one to eight carbon atoms; R3 is selected from the group consisting of a hydrogen atom and an alkyl radical having one to eight carbon atoms; Mb is a Group Va metal; and E and J are each selected from the group consisting of an alkyl radical having one to eight carbon atoms, a phenyl radical and, when taken together, an oxygen atom.
8. The photoconductive composition of claim 7 wherein the photoconductor is sensitized with a compound selected from the group consisting of pyrylium, thiapyrylium and selenapyrylium salts.
9. A photoconductive composition comprising an electrically insulating, film-forming polymeric binder containing at least 1 percent by weight of a photoconductor represented by the formula: wherein: R1 and R2 are alkyl radicals having one to eight carboN atoms; Mb is a Group Va metal; L and Q are each selected from the group consisting of a hydrogen atom, an alkyl radical having one to eight carbon atoms and a phenyl radical; and E and J are each selected from the group consisting of an alkyl radical having one to eight carbon atoms, a phenyl radical and, when taken together, an oxygen atom.
10. The photoconductive composition of claim 9 wherein the photoconductor is sensitized with a compound selected from the group consisting of pyrylium, thiapyrylium and selenapyrylium salts.
11. An electrophotographic element comprising an electrically conducting support having thereon a photoconductive composition comprising an electrically insulating, film-forming polymeric binder and a photoconductor represented by the formula: wherein: R1 and R2 are alkyl radicals having one to eight carbon atoms; R3 is selected from the group consisting of a hydrogen atom and an alkyl radical having one to eight carbon atoms; Mb is a Group Va metal; and E and J are each selected from the group consisting of an alkyl radical having one to eight carbon atoms, a phenyl radical and, when taken together, an oxygen atom.
12. The electrophotographic element of claim 11 wherein the photoconductor is sensitized with a compound selected from the group consisting of pyrylium, thiapyrylium and selenapyrylium salts.
13. An electrophotographic element comprising an electrically conducting support having thereon a photoconductive composition comprising an electrically insulating, film-forming polymeric binder and a photoconductor represented by the formula: wherein: R1 and R2 are alkyl radicals having one to eight carbon atoms; Mb is a Group Va metal; L and Q are each selected from the group consisting of a hydrogen atom, an alkyl radical having one to eight carbon atoms and a phenyl radical; and E and J are each selected from the group consisting of an alkyl radical having one to eight carbon atoms, a phenyl radical and, when taken together, an oxygen atom.
14. The electrophotographic element of claim 13 wherein the photoconductor is sensitized with a compound selected from the group consisting of pyrylium, thiapyrylium and selenapyrylium salts.
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