Photoconductive elements containing organo-metallic photoconductors |
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申请号 | US3719486D | 申请日 | 1971-06-17 | 公开(公告)号 | US3719486A | 公开(公告)日 | 1973-03-06 |
申请人 | EASTMAN KODAK CO; | 发明人 | GOLDMAN M; JOHNSON A; | ||||
摘要 | Photoconductive compositions and elements containing a Group Va organo-metallic photoconductive compound. | ||||||
权利要求 | 1. An electrophotographic element comprising an electrically conducting support having thereon a photoconductive composition comprising an electrically insulating, film- forming polymeric binder and a Group Va organo-metallic photoconductive compound having attached to a Group Va metal atom at least one amino-aryl group. 2. An electrophotographic element comprising an electrically conducting support having thereon a photoconductive composition comprising an electrically insulating, film-forming polymeric binder and a Group Va organo-metallic photoconductive compound having attached to a Group Va metal atom (1) at least one amino-aryl group, and (2) at least one substituent selected from the group consisting of a hydrogen atom, an oxygen atom, an alkyl radical and an aryl radical. 3. An electrophotographic element comprising an electrically conducting support having thereon a photoconductive composition comprising an electrically insulating, film-forming polymeric binder and a photoconductor represented by the formula: wherein: T is an amino radical; Ar is an aryl radical; Mb is a Group Va metal; and E and J are selected from the group consisting of a hydrogen atom, an alkyl radical, an aryl radical and, when taken together, an oxygen atom. 4. An electrophotographic element comprising an electrically conducting support having thereon a photoconductive composition comprising an electrically insulating, film-forming polymeric binder and a photoconductor represented by the formula: wherein: T is an amino radical; Ar is an aryl radical; M is a Group Va metal; and L and Q are each selected from the group consisting of a hydrogen atom, an alkyl radical and an aryl radical; and E and J are each selected from the group consisting of an alkyl radical, an aryl radical and, when taken together, an oxygen atom. 5. A photoconductive composition comprising an electrically insulating, film-forming polymeric binder containing at least 1 percent by weight of a Group Va organo-metallic photoconductive compound having attached to a Group Va metal atom (1) at least one amino-aryl group, and (2) at least one substituent selected from the group consisting of a hydrogen atom, an oxygen atom, an alkyl radical and an aryl radical. 6. A photoconductive composition comprising an electrically insulating, film-forming polymeric binder containing at least 1 percent by weight of a photoconductor represented by the formula: wherein: T is an amino radical; Ar is an aryl radical; Mb is a Group Va metal; L and Q are each selected from the group consisting of a hydrogen atom, an alkyl radical and an aryl radical; and E and J are each selected from the group consisting of an alkyl radical, an aryl radical and, when taken together, an oxygen atom. 7. A photoconductive composition comprising an electrically insulating, film-forming polymeric binder containing at least 1 percent by weight of a photoconductor represented by the formula: wherein: R1 and R2 are alkyl radicals having one to eight carbon atoms; R3 is selected from the group consisting of a hydrogen atom and an alkyl radical having one to eight carbon atoms; Mb is a Group Va metal; and E and J are each selected from the group consisting of an alkyl radical having one to eight carbon atoms, a phenyl radical and, when taken together, an oxygen atom. 8. The photoconductive composition of claim 7 wherein the photoconductor is sensitized with a compound selected from the group consisting of pyrylium, thiapyrylium and selenapyrylium salts. 9. A photoconductive composition comprising an electrically insulating, film-forming polymeric binder containing at least 1 percent by weight of a photoconductor represented by the formula: wherein: R1 and R2 are alkyl radicals having one to eight carboN atoms; Mb is a Group Va metal; L and Q are each selected from the group consisting of a hydrogen atom, an alkyl radical having one to eight carbon atoms and a phenyl radical; and E and J are each selected from the group consisting of an alkyl radical having one to eight carbon atoms, a phenyl radical and, when taken together, an oxygen atom. 10. The photoconductive composition of claim 9 wherein the photoconductor is sensitized with a compound selected from the group consisting of pyrylium, thiapyrylium and selenapyrylium salts. 11. An electrophotographic element comprising an electrically conducting support having thereon a photoconductive composition comprising an electrically insulating, film-forming polymeric binder and a photoconductor represented by the formula: wherein: R1 and R2 are alkyl radicals having one to eight carbon atoms; R3 is selected from the group consisting of a hydrogen atom and an alkyl radical having one to eight carbon atoms; Mb is a Group Va metal; and E and J are each selected from the group consisting of an alkyl radical having one to eight carbon atoms, a phenyl radical and, when taken together, an oxygen atom. 12. The electrophotographic element of claim 11 wherein the photoconductor is sensitized with a compound selected from the group consisting of pyrylium, thiapyrylium and selenapyrylium salts. 13. An electrophotographic element comprising an electrically conducting support having thereon a photoconductive composition comprising an electrically insulating, film-forming polymeric binder and a photoconductor represented by the formula: wherein: R1 and R2 are alkyl radicals having one to eight carbon atoms; Mb is a Group Va metal; L and Q are each selected from the group consisting of a hydrogen atom, an alkyl radical having one to eight carbon atoms and a phenyl radical; and E and J are each selected from the group consisting of an alkyl radical having one to eight carbon atoms, a phenyl radical and, when taken together, an oxygen atom. 14. The electrophotographic element of claim 13 wherein the photoconductor is sensitized with a compound selected from the group consisting of pyrylium, thiapyrylium and selenapyrylium salts. |
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