141 |
JPS4864032A - |
JP12261572 |
1972-12-08 |
JPS4864032A |
1973-09-05 |
|
|
142 |
VANADIUM PHTHALOCYANINE COMPOUNDS AND NEAR-INFRARED ABSORPTION FILTER USING THE SAME |
PCT/KR2009006494 |
2009-11-05 |
WO2010076968A2 |
2010-07-08 |
CHANG YU-MI; KANG JU-SIK; PARK JEONG-HO |
Disclosed are novel vanadium phthalocyanine compounds with low absorption efficiency in the visible light domain and high absorption efficiency in the near-infrared light domain, and a near-infrared absorption filter using the same. The near-infrared absorption vanadium phthalocyanine compounds have chemical formula 1. In the chemical formula 1: A2, A3, A6, A7, A10, A11, A14, and A15 individually represent OR1, SR2, or a halogen atom, wherein at least four thereof represent OR1; A1, A4, A5, A8, A9, A12, A13, and A16 individually represent OR1, SR2, NR3R4,or a halogen atom, wherein at least one thereof represents NR3R4 andat least four thereof represent OR1; R1, R2, R3, and R4 individually represent an alkyl group with 1-10 carbons, an aryl group with 6-10 carbons, or an aralkyl group with 7-15 carbons. |
143 |
PROCESS FOR THE PREPARATION OF A POLYOLEFIN |
PCT/EP2004008709 |
2004-08-03 |
WO2005014601A3 |
2005-11-03 |
IJPEIJ EDWIN GERARD; ARTS HENRICUS JOHANNES; VAN DOREMAELE GERARDUS HENRICU; BEIJER FELIX HUGO; VAN DER BURGT FRANCIS; ZUIDEVELD MARTIN ALEXANDER |
The invention related to a process for the polymerization of at least one aliphatic or aromatic hydrocarbyl C2-20 mono- or multiolefin in the presence of a catalyst and a boron comprising co-catalyst, wherein the catalyst comprises a composition of a metal-organic reagent, a spectator ligand and optionally at least one equivalent of a hydrocarbylating agent. The invention further relates to a polymer obtainable by the process of the invention. |
144 |
Tantalum compound and methods of forming thin film and fabricating integrated circuit device by using the same |
US15298275 |
2016-10-20 |
US10134582B2 |
2018-11-20 |
Seung-min Ryu; Takanori Koide; Naoki Yamada; Jae-soon Lim; Tsubasa Shiratori; Youn-joung Cho |
A tantalum compound, a method of forming a thin film, and a method of fabricating an integrated circuit device, the tantalum compound being represented by the following General Formula (I): |
145 |
Single-source synthesis of ceramic oxide nanoparticles |
US15901776 |
2018-02-21 |
US20180179112A1 |
2018-06-28 |
Timothy J. Boyle; Rana Chan; Jeremiah Matthew Sears; Bernadette A. Hernandez-Sanchez |
The tris(trimethylsilyl)silanol (H-SST) ligand can be reacted with a Group 4 or 5 metal alkoxides in a solvent to form an SST-modified metal alkoxide precursor. Exemplary Group 4 precursors include [Ti(SST)2(OR)2] (OR=OPri, OBut, ONep); [Ti(SST)3(OBun)]; [Zr(SST)2(OBut)2(py)]; [Zr(SST)3(OR)] (OR=OBut, ONep); [Hf(SST)2(OBut)2]; and [Hf(SST)2(ONep)2(py)n] (n=1, 2), where OPri=OCH(CH3)2, OBut=OC(CH3)3, OBun=O(CH2)3CH3, ONep=OCH2C(CH3)3, and py=pyridine. Exemplary Group 5 precursors include [V(SST)3(py)2]; [Nb(SST)3(OEt)2]; [Nb(O)(SST)3(py)]; 2[H][(Nb(μ-O)2(SST))6(μ6-O)]; [Nb8O10(OEt)18(SST)2.⅕Na2O]; [Ta(SST)(μ-OEt)(OEt)3]2; and [Ta(SST)3(OEt)2]; where OEt=OCH2CH3. When thermally processed, the precursors can form unusual core-shell nanoparticles. For example, HfO2/SiO2 core/shell nanoparticles have demonstrated resistance to damage in extreme irradiation and thermal environments. |
146 |
LIQUID ELECTROLYTE, AND METHOD FOR MANUFACTURING PHOSPHATE |
US15323761 |
2015-07-07 |
US20170149087A1 |
2017-05-25 |
Atsushi MARUO; Shigeaki YAMAZAKI; Hideo SAKATA; Shinichi KINOSHITA |
An electrolyte solution capable of providing electrochemical devices whose internal resistance is less likely to increase even after repeated charge and discharge and whose cycle capacity retention ratio is high. The electrolyte solution contains a solvent, an electrolyte salt, and a phosphate in an amount of 0.001 to 15 mass % relative to the solvent and represented by the formula (1): (R11O)(R12O)PO2M, where R11, R12 and M are as defined herein. |
147 |
Group 5 cyclopentadienyl transition metal-containing precursors for deposition of group 5 transition metal-containing films |
US14106241 |
2013-12-13 |
US09518075B2 |
2016-12-13 |
Clément Lansalot-Matras; Wontae Noh |
Transition metal-containing precursors are disclosed. Also disclosed are methods of synthesizing and using the disclosed precursors to deposit transition metal-containing films on one or more substrates via a vapor deposition process. |
148 |
Heterocyclic compound and organic light emitting device using the same |
US14373541 |
2014-02-07 |
US09221820B2 |
2015-12-29 |
Tae Yoon Park; Minseung Chun; Dongheon Kim; Jiyeon Ahn; Hyoung Seok Kim |
The present specification provides a heterocyclic compound, and an organic light emitting device including: a first electrode, a second electrode, and organic material layers formed of one or more layers including a light emitting layer disposed between the first electrode and the second electrode, in which one or more layers of the organic material layers include the heterocyclic compound or a compound in which a heat-curable or photo-curable functional group is introduced into the heterocyclic compound. |
149 |
INORGANIC FILM-FORMING COMPOSITION FOR MULTILAYER RESIST PROCESSES, AND PATTERN-FORMING METHOD |
US14833718 |
2015-08-24 |
US20150364332A1 |
2015-12-17 |
Hisashi Nakagawa; Tatsuya Sakai; Shunsuke Kurita; Satoshi Dei; Kazunori Takanashi; Yoshio Takimoto; Masayuki Motonari |
An inorganic film-forming composition for multilayer resist processes includes a complex that includes: metal atoms; at least one bridging ligand; and a ligand which is other than the at least one bridging ligand and which is derived from a hydroxy acid ester, a β-diketone, a β-keto ester, a β-dicarboxylic acid ester or a combination thereof. The at least one bridging ligand includes a first bridging ligand derived from a compound represented by formula (1). An amount of the first bridging ligand is no less than 50 mol % with respect to a total of the bridging ligand. In the formula (1), R1 represents an organic group having a valency of n. X represents —OH, —COOH, —NCO or —NHRa, wherein Ra represents a hydrogen atom or a monovalent organic group. n is an integer of 2 to 4. R1X)n (1) |
150 |
NOVEL COMPLEX AND USE OF SAME |
US14443888 |
2013-11-20 |
US20150291635A1 |
2015-10-15 |
Zhaomin Hou; Takanori Shima; Shaowei Hu; Yoshinori Endo |
A novel complex capable of fixing dinitrogen and use thereof are provided. A complex represented by formula (1A) or (1B) or a cationic or anionic complex from the complex: wherein M1 to M4 (M1 to M3 in the case of formula (1A)) are each independently Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, or W, and L1 to L4 (L1 to L3 in the case of formula (1A)) are each independently a ligand selected from among a ligand (Cp) including a substituted or unsubstituted cyclopentadienyl derivative, a diphenylamine ligand, a diphenylphosphine ligand, and a carboimideamide ligand. |
151 |
Bisamineazaallylic ligands and their use in atomic layer deposition methods |
US13908359 |
2013-06-03 |
US09127031B2 |
2015-09-08 |
David Thompson; Jeffrey W. Anthis |
Methods for deposition of elemental metal films on surfaces using metal coordination complexes comprising bisamineazaallylic ligands are provided. Also provided are bisamineazaallylic ligands useful in the methods of the invention and metal coordination complexes comprising these ligands. |
152 |
Catalyst Compositions Containing Transition Metal Complexes With Thiolate Ligands |
US14093809 |
2013-12-02 |
US20140094577A1 |
2014-04-03 |
Mark L. Hlavinka |
The present invention discloses catalyst compositions employing transition metal complexes with a thiolate ligand. Methods for making these transition metal complexes and for using such compounds in catalyst compositions for the polymerization of olefins also are provided. |
153 |
Vanadium phthalocyanine compounds and near-infrared absorption filter using the same |
US13142722 |
2009-11-05 |
US08669358B2 |
2014-03-11 |
Yu-Mi Chang; Ju-Sik Kang; Jeong-Ho Park |
A vanadium phthalocyanine compound with low absorptivity in the visible light region and high absorptivity in the near-infrared light region, and represented by the following Formula: |
154 |
Metal hydrazide materials |
US12998984 |
2009-12-22 |
US08562717B2 |
2013-10-22 |
David Michael Antonelli |
The present invention provides the following new polymers which are useful for hydrogen storage: (i) a polymer comprising -[MN2]— as a repeating unit, wherein M is selected from the group consisting Sc, Ti, V, Cr, Mn, Fe, Co, Zr, Nb, Mo, and mixtures thereof; and (ii) a polymer comprising -[M2N3]— as a repeating unit, wherein M is selected from the group consisting Sc, Ti, V, Cr, Mn, Fe, Co, Zr, Nb, Mo, and mixtures thereof. |
155 |
Bisamineazaallylic Ligands And Their Use In Atomic Layer Deposition Methods |
US13908359 |
2013-06-03 |
US20130267709A1 |
2013-10-10 |
David Thompson; Jeffrey W. Anthis |
Methods for deposition of elemental metal films on surfaces using metal coordination complexes comprising bisamineazaallylic ligands are provided. Also provided are bisamineazaallylic ligands useful in the methods of the invention and metal coordination complexes comprising these ligands. |
156 |
Bisamineazaallylic ligands and their use in atomic layer deposition methods |
US13189644 |
2011-07-25 |
US08481119B2 |
2013-07-09 |
David Thompson; Jeffrey W. Anthis |
Methods for deposition of elemental metal films on surfaces using metal coordination complexes comprising bisamineazaallylic ligands are provided. Also provided are bisamineazaallylic ligands useful in the methods of the invention and metal coordination complexes comprising these ligands. |
157 |
CATALYST COMPOSITIONS CONTAINING TRANSITION METAL COMPLEXES WITH THIOLATE LIGANDS |
US13042807 |
2011-03-08 |
US20120232235A1 |
2012-09-13 |
Mark L. Hlavinka |
The present invention discloses catalyst compositions employing transition metal complexes with a thiolate ligand. Methods for making these transition metal complexes and for using such compounds in catalyst compositions for the polymerization of olefins also are provided. |
158 |
Process for the preparation of a metal-organic compound comprising at least one imine ligand |
US10567156 |
2004-08-03 |
US07737070B2 |
2010-06-15 |
Edwin Ijpeij; Henricus Arts; Gerardus van Doremaele; Felix Beijer; Francis Van Der Burgt; Martin Alexander Zuideveld |
A process for the preparation of a metal-organic compound, comprising at least one imine ligand, characterized in that an imine ligand according to formula (1) or the HA adduct thereof, wherein HA represents an acid, of which H represents its proton and A its conjugate base, is contacted with a metal-organic reagent of formula (2) in the presence of at least 1, respectively at least 2 equivalents of a base, with Y═N—R as formula (1), wherein Y is selected from a substituted carbon, or nitrogen atom and R represents a substituent, and with Mv(L1)k(L2)l(L3)m(L4)nx as formula (2), wherein: M represents a group 4 or group 5 metal ion, V represents the valency of the metal ion, being 3, 4 or 5, L1, L2, L3, and L4 represent a ligand or a group 17 halogen atom on M and may be equal or different, X represents a group 17 halogen atom, k, l, m, n=0, 1, 2, 3, 4 with k+l+m+n+l=V. The invention further relates to a process for the preparation of a polyolefin by making a metal-organic compound according to the process of the invention, wherein the base is an olefin polymerisation compatible base, which metal-organic compound is activated anywhere in, or before a polymerisation reactor. |
159 |
Organometallic compounds |
US11540072 |
2006-09-29 |
US07531458B2 |
2009-05-12 |
Deodatta Vinayak Shenai-Khatkhate; Qing Min Wang |
Organometallic compounds containing an electron donating group-substituted alkenyl ligand are provided. Such compounds are particularly suitable for use as vapor deposition precursors. Also provided are methods of depositing thin films, such as by ALD and CVD, using such compounds. |
160 |
Process for the Preparation of an Metal-Organic Compound Comprising at Least One Imine Ligand |
US10566839 |
2004-08-03 |
US20080027195A1 |
2008-01-31 |
Edwin Ijpeij; Henricus Arts; Gerardus Van Doremaele; Felix Beijer; Francis Van der Burgt; Martin Alexander Zuideveld |
The invention relates to a process for the preparation of a metal-organic compound, comprising at least one phosphinimine ligand, characterized in that the HA adduct of a phosphinimine ligand according to formula (1) is contacted with a metal-organic reagent of formula (2) in the presence of 1, respectively 2 equivalents of a base, wherein HA represents an acid, of which H represents its proton and A its conjugate base, with Y=N−H as formula (1), and Mv(L1)k(L2)l(L3)m(L4)nX as formula (2), and wherein Y is a substituted phosphorous atom, and M represents a group 4 or group 5 metal ion, V represents the valency of the metal ion, being 3, 4 or 5 L1, L2, L3, and L4 represent a ligand or a group 17 halogen atom on M and may be equal or different, k, l, m, n=0, 1, 2, 3, 4 with k+l+m+n+1=V, and X represents a group 17 halogen atom. The invention further relates to a process for the preparation of a polyolefin by making a metal-organic compound according to the process of the invention, wherein the base is an olefin polymerisation compatible base, which metal-organic compound is activated anywhere in, or before a polymerisation reactor. |