| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 81 | Subvalent halide compounds tetraselenofulvalene and tetrathiofulvalene subvalent halides | US85351 | 1979-10-16 | US4530789A | 1985-07-23 | James D. Wilson; Malcolm G. Miles |
| Subvalent organic halide compounds of variable, non-integral stoichiometry are described. Related subvalent double cation, halide compounds of variable non-integral stoichiometry are described where the double cation is comprised of an organic cation in combination with a single valent transition metal. | ||||||
| 82 | Process for producing chalcogen containing compounds | US149993 | 1980-05-15 | US4462938A | 1984-07-31 | Fred Wudl |
| Phosgene iminium chloride has been used as a reagent in a variety of reactions to produce compounds useful in the preparation of organic conductors, inorganic complexes, and heterocyclic compounds. This reagent undergoes expedient reactions with either H.sub.2 Se or H.sub.2 S. Of particular interest is a synthetic process beginning with the production of dichalcogen carbamate by the reaction of phosgene iminium chloride with, for example, H.sub.2 Se followed by subsequent processing steps to produce tetramethyl tetraselenafulvalene. | ||||||
| 83 | Substituted benzotelluropyrones | US279300 | 1981-07-01 | US4434098A | 1984-02-28 | Michael R. Detty; Bruce J. Murray; Jerome H. Perlstein |
| The present invention discloses novel substituted benzotelluropyrones and a novel method for making such compositions. The compositions are useful as intermediates for making benzotelluropyrylium and benzotelluropyrylium diketonate electron dye sensitizers for electron donating photoconductive compositions and elements. | ||||||
| 84 | Heterofulvalene geminal dithiolate compounds and their selenium and tellurium analogs and a method of fabricating the same | US293569 | 1981-08-17 | US4405515A | 1983-09-20 | Edward M. Engler; Vishnubhai V. Patel; Robert R. Schumaker |
| The invention is directed to novel heterofulvalene geminal dithiolate compounds and their selenium and tellurium analogs having the general formula ##STR1## Wherein X is selected from S, Se and Te. R is selected from hydrogen, alkyl, aryl, or together form a ring of carbon atoms, cyano and dithiocarbonate groups and R.sup.1 is selected from alkali, alkaline earth and transition metals, alkyl, aryl, cyclic and heterocyclic groups.A novel method for preparing these compounds is also provided. | ||||||
| 85 | Substituted teraselenafulvalenes and high pressure synthesis thereof | US303542 | 1981-09-18 | US4402875A | 1983-09-06 | Yoshiyuki Okamoto; Piotr S. Wojciechowski |
| A process is disclosed for one-step preparation of substituted tetraselenafulvalenes by reaction of carbon diselenide with acetylenic compounds under pressures of at least about 1,000 atmospheres. Substituted tetraselenafulvalenes made by this process are useful as precursors to very pure tetraselenafulvalene and are useful in forming complexes with certain inorganic anions to provide charge-transfer salts having very high electrical conductivity. | ||||||
| 86 | Heterofulvalene geminal dithiolate compounds and their selenium and tellurium analogs and a method of fabricating the same | US293568 | 1981-08-17 | US4363919A | 1982-12-14 | Edward M. Engler; Vishnubhai V. Patel; Robert R. Schumaker |
| The invention is directed to novel heterofulvalene geminal dithiolate compounds and their selenium and tellurium analogs having the general formula ##STR1## Wherein X is selected from S, Se and Te. R is selected from hydrogen, alkyl, aryl, or together form a ring of carbon atoms, cyano and dithiocarbonate groups and R.sup.1 is selected from alkali, alkaline earth and transition metals, alkyl, aryl, cyclic and heterocyclic groups.A novel method for preparing these compounds is also provided. | ||||||
| 87 | Process for preparing tetraselenofulvalenes, and conductive salts obtained therefrom | US899465 | 1978-04-24 | US4246173A | 1981-01-20 | Dwaine O. Cowan; Aaron N. Bloch; Klaus Bechgaard |
| A multistep process for preparing tetraselenofulvalenes involving the synthesis of 1,3-diselenole-2-selones and -2-thiones from diselenocarbamates and .alpha.-haloketones followed by coupling of the selone or thione using a dechalkogenizing reagent. New highly conductive salts obtained by coupling certain tetraselenofulvalenes with acceptor compounds are also disclosed. | ||||||
| 88 | Tetraselenofulvalene, dithiodiselenofulvalene and the TCNQ salts thereof | US477553 | 1974-06-10 | US4028346A | 1977-06-07 | Edward M. Engler; Vishnubhai V. Patel |
| Organic molecules can be coupled via their selenocarbonyl derivatives. Generally, the synthesis can be described by the following reaction equation: ##STR1## where C can be a cyclic or heterocyclic organic compound and R can be alkoxy, phenoxy or phenyl, preferably CH.sub.3 O, C.sub.2 H.sub.5 O, C.sub.6 H.sub.5 O, C.sub.6 H.sub.5 and the like. The reaction is usually carried out in a refluxing solvent, the choice of the solvent being determined by the stability and by the ease of coupling of a particular substrate. Groups that tend to stabilize the selenocarbonyl require higher boiling solvents and longer refluxing times. Aromatic solvents, such as benzene or toluene are well-suited for the coupling reaction. In some cases, refluxing the substrate in the alkoxy-phosphorus base as solvent may be advantageous. This new coupling procedure permits the synthesis of the hitherto unknown compounds: tetraselenofulvalene (TSeF), the selenium analogue of tetrathiofulvalene (TTF), and diselenodithiofulvalene (DSeDTF). Highly conducting charge transfer salts of tetraselenofulvalene and diselenodithiofulvalene with tetracyano-p-quinodimethane have also been prepared. The materials of this invention are useful in the organic electronic devices described in copending application Ser. no. 450,541 to Arieh Aviram et al. and assigned to the same assignee as is the present application. | ||||||
| 89 | Fluorocarbon metalloid compounds of tetrafluoroethylene and sulfur, selenium or phosphorus and their preparation | US67845157 | 1957-08-15 | US2931803A | 1960-04-05 | KRESPAN CARL G |
| 90 | Manufacture of 3-hydroxyselenonaphthene | US66776133 | 1933-04-24 | US1949815A | 1934-03-06 | WILHELM SCHNEIDER |
| 91 | 헤테로아센 화합물의 중간체 및 이를 이용한 헤테로아센 화합물의 합성 방법 | KR1020150146686 | 2015-10-21 | KR1020170046399A | 2017-05-02 | 미야자키에이고; 박정일; 이은경 |
| 하기화학식 1로표현되는헤테로아센화합물의중간체를제공한다. [화학식 1]상기화학식 1에서, Ar및 Ar는각각독립적으로치환또는비치환된방향족고리, 치환또는비치환된헤테로방향족고리및 이들중둘 이상의축합고리에서선택되고, Z는에텐(ethene)기및 에틴(ethyne)기에서선택되고, X및 X는각각독립적으로 O, S, Se 및 Te에서선택되고, L및 L는각각독립적으로이탈기(leaving group)이다. | ||||||
| 92 | 유기 셀레늄 재료들 및 유기 발광 소자들에서 이들의 사용 | KR1020167017199 | 2009-09-24 | KR1020160078526A | 2016-07-04 | 시아추안쥔; 크웡레이몬드; 마빈; 린춘 |
| 본발명은디벤조셀레노펜, 벤조[b]셀레노펜또는벤조[c]셀레노펜을포함하는유기셀레늄화합물들및 유기발광소자들에서이들의사용을제공한다. | ||||||
| 93 | 유기 반도체 저분자 및 이를 포함하는 유기 박막트랜지스터 | KR1020100017120 | 2010-02-25 | KR1020110097327A | 2011-08-31 | 조남성; 이정애; 송인범 |
| 본 발명은 하기 화학식 1 또는 2로 표시되는 파이렌 고리화합물 또는 방향족 화합물을 포함하는 유기 반도체 저분자를 제공한다.
[화학식 1] [화학식 2] 상기 화학식 1 또는 2에서, Y는 이중 결합 또는 삼중 결합으로 직접 연결된 방향족 고리화합물 또는 노말 알킬 체인 중 적어도 하나이고, R은 탄소수 4 내지 10의 노말 알킬 체인, 트리에틸실릴 또는 트리이소프로필실릴 중 적어도 하나이다. |
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| 94 | 유기 셀레늄 재료들 및 유기 발광 소자들에서 이들의 사용 | KR1020117005445 | 2009-09-24 | KR1020110071061A | 2011-06-28 | 시아추안쥔; 크웡레이몬드; 마빈; 린춘 |
| 본 발명은 디벤조셀레노펜, 벤조[b]셀레노펜 또는 벤조[c]셀레노펜을 포함하는 유기 셀레늄 화합물들 및 유기 발광 소자들에서 이들의 사용을 제공한다.
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| 95 | 플러렌 유도체, 이를 포함하는 유기태양전지, 및 이를 포함하는 유기박막트랜지스터 | KR1020090022201 | 2009-03-16 | KR1020100062794A | 2010-06-10 | 김동유; 윤진문 |
| PURPOSE: A fullerene derivative, organic photovoltaic cell containing the same, and organic thin film transistor are provided to form improved charge transfer property and to improve current density and efficiency. CONSTITUTION: A fullerene derivative is denoted by chemical formula 1. In chemical formula 1, A is fullerene of C60, C70, C72, C76, C78, C84, or C90; R1 is substituted or non-substituted selenophene, tellurophene, or thienothiophene. An organic photovoltaic cell comprises: a first electrode placed on a substrate; organic active layer containing fulluerene derivative of chemical formula 1, which is placed on the first electrode; and a second electrode placed on the organic active layer. An organic thin film transistor comprises: an organic semiconductor layer containing fullerene derivative of chemical formula 1; a gate electrode which is overlapped with the organic semiconductor layer; and source electrode and drain electrode. | ||||||
| 96 | 씨엔에스 질병의 치료를 위한 도파민-디3 리간드로서헤테로아렌 카복스아미드의 용도 | KR1020047021525 | 2003-07-02 | KR1020050075281A | 2005-07-20 | 피터,게마이너; 하랄드,휘브너; 카린,쉬로터 |
| The invention relates to neuroreceptor active N-[(4-phenyl-1-piperazinyl)alkyl]-substituted heteroarene carboxamide of general formula (I) and to structure analogous 2- ferrocenyl compounds of general formula (II) and the utilization thereof for the treatment of CNS diseases, for example, schizophrenia, different forms of depression, neurodegenerative disorders, sexual dysfunctions, cocaine, alcohol, opiate and nicotine addiction, in addition to glaucoma, cognitive disorders, restless leg syndrome, hyperactivity syndrome (ADHS), hyperprolactinemia, hyperprolactinoma, locomotion disorders associated with Parkinson's disease, treatment of L-DOPA and neuroleptic-induced locomotion disorders, for example, akathisia, rigor, dystonia and dyskinesia, wherein the substituents are defined in the description. | ||||||
| 97 | 셀레늄 유기화합물의 제조방법 | KR1019830002383 | 1983-05-27 | KR1019840004760A | 1984-10-24 | 엠마뉴엘레비키 |
| 내용없음 | ||||||
| 98 | GLUTATHIONE PEROXIDASE MIMETICS AND USES THEREOF | PCT/US2006039343 | 2006-10-06 | WO2007044641A3 | 2007-11-22 | BACK THOMAS G; KUZMA DUSAN; BERKOWITZ NOAH |
| This invention relates to novel organoselenium and tellurium compounds, processes of producing the same and methods of use thereof. The compounds function as mimetics for the catalyst selenoenzyme glutathione peroxidase, which protects cells from oxidative stress. | ||||||
| 99 | GLYCOSIDASE INHIBITORS AND PREPARATION THEREOF | PCT/CA0100010 | 2001-01-05 | WO0149674A3 | 2001-11-29 | PINTO BRIAN M; JOHNSTON BLAIR D; GHAVAMI AHMAD |
| A method for synthesizing Salacinol, its stereoisomers, and non-naturally occurring selenium and nitrogen analogues thereof having formula (I). The compounds are potentially useful as glycosidase inhibitors. The synthetic schemes comprise reacting a cyclic sulfate with a 5-membered ring sugar containing a heteroatom (X). The heteroatom preferably comprises sulfur, selenium, or nitrogen. The cyclic sulfate and ring sugar reagents may be readily prepared from carbohydrate precursors, such as D-glucose, L-glucose, D-xylose and L-xylose. The target compounds are prepared by opening of the cyclic sulfates by nucleophilic attack of the heteroatoms on the 5-membered ring sugars. The resulting heterocyclic compounds have a stable, inner salt structure comprising a heteroatom cation and a sulfate anion. The synthetic schemes yield various stereoisomers of the target compounds in moderate to good yields with limited side-reactions. In an alternative embodiment of the invention, the cyclic sulfate may be similarly reacted with a 6-membered ring sugar containing a heteroatom (X) to yield a compound having formula (XII). | ||||||
| 100 | 新規有機電荷移動錯体及びその製造方法 | JP2014052727 | 2014-03-14 | JP6300311B2 | 2018-03-28 | 緒方 啓典; ジーン フレデリック デラ クエバ ガガベ; 大塚 祐一郎; 中村 雅哉; 大原 誠資 |
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