序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
141 JPS5543473B2 - JP8719372 1972-09-01 JPS5543473B2 1980-11-06
142 Poly cyclic amines and novel intermediates thereof JP8150176 1976-07-10 JPS5210201A 1977-01-26 EDOGAA ERIKUSUU
143 JPS4836184A - JP8719372 1972-09-01 JPS4836184A 1973-05-28
144 NONAQUEOUS ELECTROLYTE, CAPACITOR DEVICE USING SAME, AND CARBOXYLIC ACID ESTER COMPOUND USED IN SAME US16286914 2019-02-27 US20190198928A1 2019-06-27 Kei Shimamoto; Koji Abe; Shoji Shikita; Kazuhiro Miyoshi
The present invention provides a nonaqueous electrolytic solution capable of improving electrochemical characteristics in the case of using an energy storage device at a high temperature and at a high voltage and further capable of inhibiting the gas generation while maintaining a capacity retention rate after storage at a high temperature and at a high voltage and also provides an energy storage device using the same. Disclosed is a nonaqueous electrolytic solution having an electrolyte salt dissolved in a nonaqueous solvent, the nonaqueous electrolytic solution containing a carboxylic acid ester compound represented by the following general formula (I). In the formula, each of R1 and R2 independently represents a hydrogen atom, a —C(═O)—OR4 group, or the like, and R1 and R2 may be bonded to each other to form a ring structure. R3 represents a hydrogen atom or the like, and n represents an integer of 1 to 3. When n is 1, then L and R4 represent an alkyl group having 1 to 6 carbon atoms or the like; and when n is 2 or 3, then L represents an n-valent connecting group, X represents a —C(═O)— group, an —S(═O)— group, an —S(═O)2— group, an —S(═O)2—R5—S(═O)2— group or a CR6R7 group, R5 represents an alkylene group having 1 to 4 carbon atoms, and each of R6 and R7 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms.
145 Method for Producing Fluorine-Containing Cyclopropane Carboxylic Acid Compound US15741020 2016-06-24 US20180186763A1 2018-07-05 Takashi KASHIWABA; Takako YAMAZAKI; Shoko ISHII; Shunsuke MIMURA; Masanori FUSHIMI; Ryuichi OKAMOTO; Haruki KOBAYASHI; Manabu YASUMOTO
The present invention provides an industrially applicable method for production of a fluorine-containing cyclopropane carboxylic acid compound useful as an intermediate for pharmaceutical and agrichemical products. A fluorine-containing cyclopropane monoester is obtained by: forming a fluorine-containing cyclic sulfate with the use of a fluorine-containing dial compound and sulfuryl fluoride (as a cyclic sulfuric esterification step); reacting the fluorine-containing cyclic sulfate with a malonic diester, thereby forming a fluorine-containing cyclopropane diester (as a cyclopropanation step); and hydrolyzing the fluorine-containing cyclopropane diester (as a hydrolysis step). The fluorine-containing cyclopropane carboxylic acid compound, such as fluorine-containing cyclopropane monoester or its salt, can be obtained with high chemical and optical purity by mixing the fluorine-containing cyclopropane monoester with an amine and subjecting the resulting salt of the fluorine-containing cyclopropane monoester and amine to recrystallization purification.
146 Non-aqueous electrolyte solution for battery and lithium secondary battery US14915550 2014-09-17 US09899704B2 2018-02-20 Masataka Miyasato; Satoko Fujiyama; Takashi Hayashi
A non-aqueous electrolyte solution for a battery includes: an additive A which is a compound represented by formula (I); and an additive B which is at least one selected from the group consisting of an aromatic compound having at least one of a halogen atom or an alkyl group and a carbamate, and which is a compound other than carbonates or a cyclic sulfates. In formula (I), R1 represents a group represented by formula (II) or a group represented by formula (III) and R2 represents H, a C1-6 alkyl group, a group represented by formula (II), or a group represented by formula (III); or R1 and R2 represent groups which combine to form a benzene ring or cyclohexyl ring. In formula (II), R3 represents a halogen atom, a C1-6 alkyl group, a C1-6 alkyl halide group, a C1-6 alkoxy group, or a group represented by formula (IV).
147 Oxathiazine derivatives as antibacterial and anticancer agents US14958225 2015-12-03 US09624187B2 2017-04-18 Rolf W. Pfirrmann
New oxathiazin-like compounds and their derivatives are useful as antineoplastic and antimicrobial agents. Compositions and methods of using oxathiazin-like compounds and their derivatives are disclosed.
148 NON-AQUEOUS ELECTROLYTE SOLUTION FOR BATTERY AND LITHIUM SECONDARY BATTERY US14915550 2014-09-17 US20160211551A1 2016-07-21 Masataka MIYASATO; Satoko FUJIYAMA; Takashi HAYASHI
A non-aqueous electrolyte solution for a battery includes: an additive A which is a compound represented by formula (I); and an additive B which is at least one selected from the group consisting of an aromatic compound having at least one of a halogen atom or an alkyl group and a carbamate, and which is a compound other than carbonates or a cyclic sulfates. In formula (I), R1 represents a group represented by formula (II) or a group represented by formula (III) and R2 represents H, a C1-6 alkyl group, a group represented by formula (II), or a group represented by formula (III); or R1 and R2 represent groups which combine to form a benzene ring or cyclohexyl ring. In formula (II), R3 represents a halogen atom, a C1-6 alkyl group, a C1-6 alkyl halide group, a C1-6 alkoxy group, or a group represented by formula (IV).
149 Cyclic (poly)Glycerol Sulphates and Preparation and Use Thereof US14356512 2011-11-10 US20150299158A1 2015-10-22 Pascal Metivier; Yan Zhao; Zhaoyu Fan; Chenjiang Zhu
The present invention relates to novel cyclic sulphates of (poly)glycerol, particularly to the novel compound of 4-(hydroxymethyl)-1,3,2-dioxathiolane-2,2-dioxide. The present invention also relates to the preparation process of the cyclic sulphate compounds, and to the use thereof as an intermediate to prepare green surfactants containing sulphate groups.
150 POLYUNSATURATED FATTY ACID MONOGLYCERIDES, DERIVATIVES, AND USES THEREOF US14303641 2014-06-13 US20140296344A1 2014-10-02 Samuel FORTIN
There are provided various polyunsaturated fatty acid monoglycerides and derivatives thereof. These compounds can be useful as cancer chemopreventive agents, cancer treating agent, inhibiting tumor growth or cell proliferation, reducing tumor growth or as radioenhencers for radiotherapy of cancer.
151 Polyunsaturated fatty acid monoglycerides, derivatives, and uses thereof US13666002 2012-11-01 US08816110B2 2014-08-26 Samuel Fortin
There are provided various polyunsaturated fatty acid monoglycerides and derivatives thereof. These compounds can be useful as cancer chemopreventive agents, cancer treating agent, inhibiting tumor growth or cell proliferation, reducing tumor growth or as radioenhencers for radiotherapy of cancer.
152 METHOD FOR PRODUCING CYCLIC SULFONIC ACID ESTER AND INTERMEDIATE THEREOF US14163682 2014-01-24 US20140142324A1 2014-05-22 Ayako KURAMOTO; Kuniaki OKAMOTO; Tsutomu WATAHIKI; Motoshige SUMINO
The present invention is directed to provide an efficient production method which is capable of not only obtaining a cyclic sulfonic acid ester (sultone) at low cost and in high yield, but also the sulfonic acid ester (sultone) stably even in a commercial scale. The present invention relates to a method for producing hydroxysultone comprising a first step where a diol having a specified structure and a thionyl halide are reacted to obtain a cyclic sulfite having a specified structure, and a second step where the cyclic sulfite is reacted with water or/and alcohol; a method for producing an unsaturated sultone having a specified structure comprising a third step where a hydroxylsultone having a specified structure is reacted with an acid halide or an acid anhydride to obtain an intermediate, subsequently the intermediate is treated with a base; as well as a cyclic sulfite having a specified structure.
153 CYCLIC SULFATE COMPOUND, NON-AQUEOUS ELECTROLYTE SOLUTION CONTAINING SAME, AND LITHIUM SECONDARY BATTERY US13820969 2011-10-21 US20130171514A1 2013-07-04 Shigeru Mio; Mitsuo Nakamura; Kaichiro Haruta; Hidenobu Nogi; Satoko Fujiyama; Takashi Hayashi; Hidetoshi Tsunoda
A non-aqueous electrolyte solution containing a cyclic sulfate compound represented by formula (I) is provided, wherein in formula (I), R1 represents a group represented by formula (II) or a group represented by formula (III); R2 represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, a group represented by formula (II), or a group represented by formula (III); and in formula (II), R3 represents a halogen atom, an alkyl group having from 1 to 6 carbon atoms, a halogenated alkyl group having from 1 to 6 carbon atoms, an alkoxy group having from 1 to 6 carbon atoms, or a group represented by formula (IV).
154 ACTINIC-RAY-SENSITIVE OR RADIATION-SENSITIVE RESIN COMPOSITION, AND RESIST FILM USING THE SAME, PATTERN FORMING METHOD, ELECTRONIC DEVICE MANUFACTURING METHOD, AND ELECTRONIC DEVICE, EACH USING THE SAME US13614797 2012-09-13 US20130078433A1 2013-03-28 Kaoru IWATO; Hidenori TAKAHASHI; Michihiro SHIRAKAWA
Provided are an actinic-ray-sensitive or a radiation-sensitive resin composition with greater residual film ratio and capable of suppressing pattern collapse and an occurrence of bridge defects after development, and a resist film, a pattern forming method, an electronic device manufacturing method, and an electronic device, each using the same. An actinic-ray-sensitive or radiation-sensitive resin composition includes a resin (P) having a repeating unit (a) represented by following General Formula (I), a compound (B) represented by any of following General Formulae (B-1) to (B-3), and a solvent, in General Formula (I), R0 represents a hydrogen atom or a methyl group, and R1, R2 and R3 each independently represent a straight chain or branched alkyl group.
155 POLYUNSATURATED FATTY ACID MONOGLYCERIDES, DERIVATIVES, AND USES THEREOF US13666002 2012-11-01 US20130059911A1 2013-03-07 Samuel FORTIN
There are provided various polyunsaturated fatty acid monoglycerides and derivatives thereof. These compounds can be useful as cancer chemopreventive agents, cancer treating agent, inhibiting tumor growth or cell proliferation, reducing tumor growth or as radioenhencers for radiotherapy of cancer.
156 Polyunsaturated fatty acid monoglycerides, derivatives, and uses thereof US12534439 2009-08-03 US08119690B2 2012-02-21 Samuel Fortin
There are provided various polyunsaturated fatty acid monoglycerides and derivatives thereof. These compounds can be useful as cancer chemopreventive agents, cancer treating agent, inhibiting tumor growth or cell proliferation, reducing tumor growth or as radioenhencers for radiotherapy of cancer.
157 ORGANIC CATALYST WITH ENHANCED ENZYME COMPATIBILITY US13195233 2011-08-01 US20110283463A1 2011-11-24 Gregory Scot MIRACLE; George Douglas Hiler, II; Rebecca Massie Grey; Mark Robert Sivik; Ludwig Voelkel; Frank Dietsche; Christian Bittner
This invention relates to cleaning compositions comprising organic catalysts having enhanced enzyme compatibility and processes for making and using such cleaning compositions.
158 Process for preparation of 13,14-dihydro-PGF2 alpha derivatives US11874218 2007-10-18 US07897793B2 2011-03-01 Jacek Martynow; Julita Szyc; Wieslaw Szelejewski; Osman Achmatowicz; Andrzej Kutner; Krzysztof Wiśniewski; Jerzy Winiarski; Oliwia Zegrocka-Stendel; Piotr Golebiewski
The invention relates to a process for the preparation of 13,14-dihydro-PGF2α derivatives of R or S configuration at carbon 15, represented by the general formula (I), wherein the identity of the substituents is defined in the description. Compounds of the formula (I) are valuable biologically-active substances or intermediates in the preparation thereof. The invention especially relates to the process for preparation of 13,14-dihydro-15(R)-17-substituted-18,19,20-trinor-PGF2α, i.e., latanoprost.
159 CYCLIC SULFONIUM SALT, METHOD FOR PRODUCTION OF CYCLIC SULFONIUM SALT, AND GLYCOSIDASE INHIBITOR US12522111 2008-01-04 US20100063302A1 2010-03-11 Osamu Muraoka; Genzoh Tanabe
Disclosed are: kotalanol which has an inhibitory activity on a glucosidase; a method for producing kotalanol or a cyclic sulfonium salt which is an analogue to kotalanol by an organic synthesis technique; a cyclic sulfonium salt produced by the method; a glucosidase inhibitor comprising the compound; an anti-diabetic agent or an anti-diabetic food comprising the glucosidase inhibitor. A sulfonium compound including kotalanol can be produced by coupling a thio-sugar synthesized from D-xylose (e.g., a compound having a cyclic structure composed of 4 carbon atoms and one sulfur atom, such as 1,4-dideoxy-1,4-epithio-D-arabinitol) with a heptitol cyclic sulfate ester having a protected hydroxyl group and synthesized from a pentose (D-xylose, D-ribose, D-arabinose, D-lyxose, L-xylose, L-ribose, L-arabinose or L-lyxose) to produce a cyclic sulfonium salt having a protected hydroxyl group, and then deprotecting the hydroxyl group.
160 ORGANIC CATALYST WITH ENHANCED ENZYME COMPATIBLITY US12468907 2009-05-20 US20090222999A1 2009-09-10 Gregory Scot Miracle; George Douglas Hiler, II; Rebecca Massie Grey; Mark Robert Sivik; Ludwig Voelkel; Frank Dietsche; Christian Bittner
This invention relates to cleaning compositions comprising organic catalysts having enhanced enzyme compatibility and processes for making and using such cleaning compositions.
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