序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
1 甲苯和苯乙烯衍生的调聚物分布物及由其制备的溴化阻燃剂 CN200980146870.7 2009-11-30 CN102224122B 2014-09-03 小威廉·J·莱曼; 查尔斯·H·科利赫; 亚瑟·G·马克; 史蒂文·A·安德森; 乔纳森·P·麦卡尼; 王君左
发明涉及新的且有用的甲苯和苯乙烯衍生的调聚物分布物,所述分布物是用于制备溴化阻燃剂的期望的基质。
2 甲苯和苯乙烯衍生的调聚物分布物及由其制备的溴化阻燃剂 CN200980146870.7 2009-11-30 CN102224122A 2011-10-19 威廉·J·莱曼; 查尔斯·H·科利赫; 亚瑟·G·马克; 史蒂文·A·安德森; 乔纳森·P·麦卡尼; 王君左
发明涉及新的且有用的甲苯和苯乙烯衍生的调聚物分布物,所述分布物是用于制备溴化阻燃剂的期望的基质。
3 P-手性磷杂戊环和磷环化合物及其在不对称催化反应中的用途 CN200910137791.1 2002-11-08 CN101565435A 2009-10-28 张绪穆; 汤文军
发明公开了用于不对称催化的手性配体和基于此类手性配体的金属配合物。根据本发明的金属配合物可在不对称反应,例如氢化、氢负离子转移、加氢羧基化、氢化烷化、氢化、加氢乙烯基化、加氢甲酰基化、烯丙位烷基化、烯易位、异构化、环丙烷化、狄尔斯-阿德反应、Heck反应、醇缩合反应、迈克尔加成、环化、动学拆分和[m+n]环加成反应中用作催化剂。另外描述了所述配体的制备方法。
4 P- chiral phospholanes and phospho-cyclic compounds and their use in asymmetric catalysis JP2003543975 2002-11-08 JP2005509012A 2005-04-07 ウェンジュン・タン; シュームー・チャン
不斉触媒作用において有用なキラルリガンドおよびこのようなキラルリガンドを基にした金属錯体が開示されている。 本発明に従う金属錯体は、素化、水素化物移動、アリルアルキル化、ヒドロシリル化、ヒドロホウ素化、ヒドロビニル化、ヒドロホルミル化、オレフィンメタセシス、ヒドロカルボキシル化、異性化、シクロプロパン化、ディールス−アルダー反応、ヘック反応、異性化、アルドール反応、マイケル付加;エポキシ化、動学的分割および[m+n]付加環化のような不斉反応において触媒として有用である。 本リガンドの製造方法もまた記載されている。
5 Method of manufacturing a diphenylbutane JP20708090 1990-08-03 JP2760643B2 1998-06-04 MATANO KOICHI; ITO HIROSHI; KOKUBO MASAHIRO; NIWA TADASHI; UENO HIROSHI
6 Production of diphenylbutane JP20708090 1990-08-03 JPH0491040A 1992-03-24 MATANO KOUICHI; ITO HIROSHI; KOKUBO MASAHIRO; NIWA TADASHI; UENO HIROSHI
PURPOSE: To obtain the objective substance at one stage in high yield and economically in producing a diphenylbutane by reacting benzene with 1,3-butadiene by using reusable high silica mordenite as a catalyst. CONSTITUTION: Benzene is reacted with 1,3-butadiene in a molar ration of 30-150 in the presence of high silica mordenite catalyst at 100-200°C to produce diphenylbutane. The high silica mordenite is proton type mordenite having a molar ratio of silica/alumina of >10 and can be prepared by treating commercially available mordenite with an acid. For example, Na type commercially available modenite is subjected to ion exchange with 2N hydrochloric acid, washed, steamed, treatment with 12N hydrochloric acid at 90°C for 8 hours to extract Al, washed, dried and treated with steam to prepare high silica mordenite having a molar ratio of silica/alumina of 100-140. COPYRIGHT: (C)1992,JPO&Japio
7 Preparation of polycyclic aromatic hydrocarbon compound JP13120578 1978-10-25 JPS5557524A 1980-04-28 SHIMIZU ISOO; TSUJI OKITSUGU; MATSUZAKA EIICHI; SATOU ATSUSHI
PURPOSE: To obtain the title compound useful as plasticizers, lubricants, etc., in high selectivity in two steps, by dimerisation of styrenes in the presence of a novel and specific catalyst, and then by direct aralkylation of the unsaturated dimer thus formed with an aromatic hydrocarbon. CONSTITUTION: Styrene, α-metylstyrene, β-methylstyrene or vinyl-toluene is dimerized or CO dimerized in the presence of a catalyst of the formula RCF 2SO 3H [R is Cl, F, or C nF p, Cl 2n+1-p(n is 1W3; p is an integer 1W2n+1)], e.g., difluorochloromethanesulfonic acid, to form an unsaturated dimer which is directly to aralkylated give a polycyclic aromatic hydrocarbon compound with no need of removing the catalyst after the first reaction and of separating and purifying the dimer thus formed, so that the reaction is continuously possible under the same conditions, and more expensive raw materials are converted to the title compound in a high selectivity. USE: A raw material for high energy fuels. COPYRIGHT: (C)1980,JPO&Japio
8 液晶性化合物、液晶組成物、液晶内包複合材料およびそれらをもちいた液晶表示素子 JP2017505008 2016-03-02 JPWO2016143634A1 2017-12-28 道子 澤田; 笹田 康幸; 康幸 笹田
所望の物性を維持しながら且つ他のバイメソゲン化合物や従来液晶表示素子へ用いられている液晶性化合物、液晶組成物、キラルドーパント、酸化防止剤や紫外線吸収剤を始めとする添加剤、重合性液晶化合物や対し高い溶解性を有するバイメソゲン化合物を提供する。式(1)で表される化合物、該化合物を含む液晶組成物、該液晶組成物から得られる液晶内包複合繊維および該液晶内包複合繊維から得られる液晶表示素子。式(1)において、MG1およびMG2はそれぞれ独立してメソゲン基であり;ZaおよびZbは独立して、例えば炭素数1〜4のアルキレンであり;Spは式(sp−1)で表されるアキラルな構造を有し、式(sp−1)において、αはそれぞれ独立して例えば炭素数1〜20の直鎖のアルキレンであり;Xは式(I)、式(II)または式(III)で表され式(I)においてRaは炭素数1〜10のアルキルであり;式(II)においてRbおよびRcは、それぞれ独立して、例えば炭素数1〜10のアルキルであり;式(III)においてQは例えば酸素原子である。
9 A telomer distribution derived from toluene and styrene, and then brominated flame retardants produced JP2011538715 2009-11-30 JP2012510538A 2012-05-10 アンダーソン,ステイーブン・エイ; コリシユ,チヤールズ・エイチ; マツカーニイ,ジヨナサン・ピー; マツク,アーサー・ジー; レイマン,ウイリアム・ジエイ,ジユニア; ワン,ジユンツオ
This invention relates to novel and useful toluene and styrene derived telomer distributions, such distributions being desirable substrates for the preparation of brominated flame retardants.
10 マイクロリアクターを用いた接触反応方法 JP2005517562 2005-01-26 JPWO2005073151A1 2007-09-13 小林 修; 修 小林; 雄一朗 森; 北森 武彦; 武彦 北森; 雅晴 上野; 訓明 岡本
流路(4)の内壁(4c)に固相となる金属触媒(5)又は金属錯体触媒(5)を担持したマイクロリアクター(1)を用いる接触反応方法であって、液相となる被反応物質を溶解した溶液(7)及び気相となる素(9)を、流路(4)にパイプフロー状態で流し、溶液(7)と気体(9)との反応を金属触媒(5)又は金属錯体触媒(5)により促進される固相−液相−気相の3相系接触反応で行う。金属触媒(5)又は金属錯体触媒(5)は高分子に取り込まれており、被還元物質の3相系接触還元反応による水素化反応を短時間で収率よく行うことができる。不飽和有機物の水素化反応には、パラジウム触媒を用いると反応時間が早く収率が高く、また、水素の代わりに一酸化水素を用いれば、カルボニル化反応とすることができる。
11 JPS6136497B2 - JP13120578 1978-10-25 JPS6136497B2 1986-08-19 SHIMIZU ISOO; TSUJI OKITSUGU; MATSUZAKA EIICHI; SATO ATSUSHI
12 BIMESOGENIC COMPOUNDS AND MESOGENIC MEDIA EP15784578.5 2015-10-23 EP3218446B1 2018-07-04 ADLEM, Kevin; PARRI, Owain Llyr; TUFFIN, Rachel; ARASI, Hassan; MACGREGOR, Thomas
to the use of bimesogenic compounds of formula I in liquid crystal media and particular to flexoelectric liquid crystal devices comprising a liquid crystal medium according to the present invention.
13 P-CHIRAL PHOSPHOLANES AND PHOSPHOCYCLIC COMPOUNDS AND THEIR USE IN ASYMMETRIC CATALYTIC REACTIONS EP02803182.1 2002-11-08 EP1451133B1 2017-10-25 ZHANG, Xumu; TANG, Wenjun
14 Method of reacting carboxylic acids EP03255348.9 2003-08-28 EP1398396B1 2007-04-04 Watts, Paul; Haswell, Stephen John
15 Method of reacting carboxylic acids EP03255348.9 2003-08-28 EP1398396A1 2004-03-17 Watts, Paul; Haswell, Stephen John

A carboxylic acid molecule (R COOH) is subjected to an electric field in a micro-reactor (11). The molecule decarboxyles to form a radical (R1). Two radicals (R') can dimerise to form the product (R - R). It is believed that the reaction occurs away from the electrodes used to apply the electric field (but may also occur at the electrode surfaces).

16 TOLUENE AND STYRENE DERIVED TELOMER DISTRIBUTIONS AND BROMINATED FLAME RETARDANTS PRODUCED THEREFROM EP09764669.9 2009-11-30 EP2370383A2 2011-10-05 LAYMAN, William, J.; KOLICH, Charles, H.; MACK, Arthur, G.; ANDERSON, Steven, A.; MCCARNEY, Jonathan, P.; WANG, Junzuo
This invention relates to novel and useful toluene and styrene derived telomer distributions, such distributions being desirable substrates for the preparation of brominated flame retardants.
17 METHOD OF CATALYTIC REACTION USING MICRO-REACTOR EP05704332 2005-01-26 EP1726577A4 2009-03-04 KOBAYASHI SHU; MORI YUICHIRO; KITAMORI TAKEHIKO; UENO MASAHARU; OKAMOTO KUNIAKI
A method of a catalytic reaction using a micro-reactor (1) composed of an inner wall (4c) of a flow channel (4) and a metal catalyst (5) or a metal complex catalyst (5) carried on the wall as a solid phase, wherein a solution (7) containing a material to be reacted dissolved therein as a liquid phase and hydrogen (9) as a gas phase are allowed to flow in the state of a pipe flow in the flow channel (4), and a reaction of the solution (7) with the gas (9) is carried out as a solid-liquid-gas three phase catalytic reaction promoted by the metal catalyst (5) or the metal complex catalyst (5). The metal catalyst (5) or the metal complex catalyst (5) is present together with a polymer and a hydrogenation reaction of a material to be reduced by a three phase catalytic reduction can be carried out in a short time in good yield. A hydrogenation reaction of an unsaturated organic material can be completed in a less reaction time in improved yield, by the use of a palladium catalyst, and the use of carbon monoxide in place of hydrogen can effect a carbonylation.
18 METHOD OF CATALYTIC REACTION USING MICRO-REACTOR EP05704332.5 2005-01-26 EP1726577A1 2006-11-29 KOBAYASHI, Shu; MORI, Yuichiro; KITAMORI, Takehiko; UENO, Masaharu; OKAMOTO, Kuniaki

A method of catalytic reaction uses a micro-reactor (1) with a metal catalyst (5) or a metal complex catalyst (5) as a solid phase supported on the inner wall (4c) of a channel (4), a solution (7) dissolving a reactant as a liquid phase and hydrogen (9) as a gas phase are flown through the channel (4) in pipe flow state, and the reaction of the solution (7) and the gas (9) accelerated by the metal catalyst (5) or the metal complex catalyst (5) is conducted by three phase catalytic reaction of solid - liquid - gas phases. The metal catalyst (5) or the metal complex catalyst (5) is incorporated in a polymer, and hydrogenation reaction by three phase catalytic reductive reaction of a substance to be reduced can be conducted in short time at good yield. For hydrogenation reaction of unsaturated organics, the rate of reaction and yield are high when palladium catalyst is used, and carbonylation reaction can be conducted if carbon monoxide is used instead of hydrogen.

19 P-CHIRAL PHOSPHOLANES AND PHOSPHOCYCLIC COMPOUNDS AND THEIR USE IN ASYMMETRIC CATALYTIC REACTIONS EP02803182 2002-11-08 EP1451133A4 2006-07-19 ZHANG XUMU; TANG WENJUN
Chiral ligands and metal complexes based on such chiral ligands useful in asymmetric catalysis are disclosed. The metal complexes according to the present invention are useful as catalysts in asymmetric reactions, such as, hydrigenation, hydride transfer, allylic alkylation, hydrosilytation, hydroboration, hydrovinylation, hydroformylation, olefin metathesis, hydrocarboxylation, isomerization, cyclopropanation. Diels-Alder reaction, Heck reaction, isomerization, Aldol reaction, Michael addition; epoxidation, kinetic resolution and [m+n] cycloaddition. Processes for the preparation of the ligands are also described.
20 BIMESOGENIC COMPOUNDS AND MESOGENIC MEDIA EP15784578.5 2015-10-23 EP3218446A1 2017-09-20 ADLEM, Kevin; PARRI, Owain Llyr; TUFFIN, Rachel; ARASI, Hassan; MACGREGOR, Thomas
to the use of bimesogenic compounds of formula I in liquid crystal media and particular to flexoelectric liquid crystal devices comprising a liquid crystal medium according to the present invention.
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