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序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
21	COMPOUNDS AND THE USE THEREOF IN METATHESIS REACTIONS	EP15720779.6	2015-04-09	EP3129365A1	2017-02-15	TOTH, Florian; FRÁTER, Georg; ONDI, Levente
The disclosure provides Group 6 complexes, which, in some embodiments, are useful for catalyzing olefin metathesis reactions. In some embodiments, the compounds are compounds of the following formula (I) wherein: M is a Group 6 metal atom; X is an oxygen atom, =N-R ⁵, =N-N(R ⁵)(R ^5') or =N-0-R ⁵, R ⁵ and R ^5' independently being various substituents, such as aryl or heteroaryl, each optionally substituted; n is 0 or 1; R ^z is a neutral ligand; R ¹ is hydrogen or an organic substituent; R ² is an aryl or heteroaryl group, each optionally substituted; R ³ is an anionic ligand; and R ⁴ is an anionic ligand, such as a pyrrolide, a pyrazolide, an imidazolide, an indolide, an azaindolide, or an indazolide, each optionally substituted.
22	METHOD OF CATALYTIC REACTION USING MICRO-REACTOR	EP05704332.5	2005-01-26	EP1726577B1	2012-11-14	KOBAYASHI, Shu; MORI, Yuichiro; KITAMORI, Takehiko; UENO, Masaharu; OKAMOTO, Kuniaki

23	FLUIDS HAVING PARTIALLY HYDROGENATED SUSBSTITUED STYRENE LINEAR DIMERS AND METHOD OF MAKING SAME	EP05788570.9	2005-08-17	EP1778607B1	2008-07-02	FORBUS, T.R., Jr.; HAGEMIESTER, Mark
A basestock that comprises a fully hydrogenated substituted styrene linear dimer; a partially hydrogenated mono-aromatic substituted styrene linear dimer; and a partially hydrogenated di-aromatic substituted styrene linear dimer. A process of producing a basestock that comprises reacting a feed stream that comprises substituted styrene, alcohol, and a dimerization catalyst, in the presence of a solvent, to form a crude slurry of dimerized substituted styrene; and partially hydrogenating the dimerized substituted styrene with hydrogen over a Group VIII catalyst to form a basestock that comprises a fully hydrogenated substituted styrene linear dimer and a partially hydrogenated substituted styrene linear dimer.
24	FLUIDS HAVING PARTIALLY HYDROGENATED SUSBSTITUED STYRENE LINEAR DIMERS AND METHOD OF MAKING SAME	EP05788570.9	2005-08-17	EP1778607A1	2007-05-02	FORBUS, T.R., Jr.; HAGEMIESTER, Mark
A basestock that comprises a fully hydrogenated substituted styrene linear dimer; a partially hydrogenated mono-aromatic substituted styrene linear dimer; and a partially hydrogenated di-aromatic substituted styrene linear dimer. A process of producing a basestock that comprises reacting a feed stream that comprises substituted styrene, alcohol, and a dimerization catalyst, in the presence of a solvent, to form a crude slurry of dimerized substituted styrene; and partially hydrogenating the dimerized substituted styrene with hydrogen over a Group VIII catalyst to form a basestock that comprises a fully hydrogenated substituted styrene linear dimer and a partially hydrogenated substituted styrene linear dimer.
25	P-CHIRAL PHOSPHOLANES AND PHOSPHOCYCLIC COMPOUNDS AND THEIR USE IN ASYMMETRIC CATALYTIC REACTIONS	EP02803182.1	2002-11-08	EP1451133A2	2004-09-01	ZHANG, Xumu; TANG, Wenjun
Chiral ligands and metal complexes based on such chiral ligands useful in asymmetric catalysis are disclosed. The metal complexes according to the present invention are useful as catalysts in asymmetric reactions, such as, hydrigenation, hydride transfer, allylic alkylation, hydrosilytation, hydroboration, hydrovinylation, hydroformylation, olefin metathesis, hydrocarboxylation, isomerization, cyclopropanation. Diels-Alder reaction, Heck reaction, isomerization, Aldol reaction, Michael addition; epoxidation, kinetic resolution and [m+n] cycloaddition. Processes for the preparation of the ligands are also described.
26	Compounds and the use thereof in metathesis reactions	US15303089	2015-04-09	US10106566B2	2018-10-23	Florian Toth; Georg Frater; Levente Ondi
The disclosure provides Group 6 complexes, which, in some embodiments, are useful for catalyzing olefin metathesis reactions. In some embodiments, the compounds are compounds of the following formula (I) wherein: M is a Group 6 metal atom; X is an oxygen atom, ═N—R5, ═N—N(R5)(R5′) or ═N—O—R5, R5 and R5′ independently being various substituents, such as aryl or heteroaryl, each optionally substituted; n is 0 or 1; Rz is a neutral ligand; R1 is hydrogen or an organic substituent; R2 is an aryl or heteroaryl group, each optionally substituted; R3 is an anionic ligand; and R4 is an anionic ligand, such as a pyrrolide, a pyrazolide, an imidazolide, an indolide, an azaindolide, or an indazolide, each optionally substituted.
27	TANDEM TRANSFER HYDROGENATION AND OLIGOMERIZATION FOR HYDROCARBON PRODUCTION	US15596255	2017-05-16	US20170320792A1	2017-11-09	David Leitch; Jay A. Labinger; John E. Bercaw; Yan Choi Lam
A method for coupling an alkane with an alkene using a hydrogen transfer catalyst and an alkene dimerization catalyst to form one or more higher molecular weight hydrocarbons.
28	Surfactant-enabled transition metal-catalyzed chemistry	US15167952	2016-05-27	US09656985B2	2017-05-23	Volker Berl
In one embodiment, the present application discloses mixtures comprising (a) water in an amount of at least 1% wt/wt of the mixture; (b) a transition metal catalyst; and (c) one or more solubilizing agents; and methods for using such mixtures for performing transition metal mediated bond formation reactions.
29	COMPOUNDS AND THE USE THEREOF IN METATHESIS REACTIONS	US15303089	2015-04-09	US20170037069A1	2017-02-09	Florian Toth; Georg Frater; Levente Ondi
The disclosure provides Group 6 complexes, which, in some embodiments, are useful for catalyzing olefin metathesis reactions. In some embodiments, the compounds are compounds of the following formula (I) wherein: M is a Group 6 metal atom; X is an oxygen atom, ═N—R5, ═N—N(R5)(R5′) or ═N—O—R5, R5 and R5′ independently being various substituents, such as aryl or heteroaryl, each optionally substituted; n is 0 or 1; Rz is a neutral ligand; R1 is hydrogen or an organic substituent; R2 is an aryl or heteroaryl group, each optionally substituted; R3 is an anionic ligand; and R4 is an anionic ligand, such as a pyrrolide, a pyrazolide, an imidazolide, an indolide, an azaindolide, or an indazolide, each optionally substituted.
30	Surfactant-Enabled Transition Metal-Catalyzed Chemistry	US15167952	2016-05-27	US20160347677A1	2016-12-01	Volker Berl
In one embodiment, the present application discloses mixtures comprising (a) water in an amount of at least 1% wt/wt of the mixture; (b) a transition metal catalyst; and (c) one or more solubilizing agents; and methods for using such mixtures for performing transition metal mediated bond formation reactions.
31	Compositions Comprising TPGS-750-M	US15167975	2016-05-27	US20160340332A1	2016-11-24	Volker Berl
In one embodiment, the present application discloses mixtures comprising (a) water in an amount of at least 1% wt/wt of the mixture; (b) a transition metal catalyst; and (c) one or more solubilizing agents; and methods for using such mixtures for performing transition metal mediated bond formation reactions.
32	Compounds for neutron radiation detectors and systems thereof	US13736898	2013-01-08	US08735843B2	2014-05-27	Stephen A. Payne; Wolfgang Stoeffl; Natalia P. Zaitseva; Nerine J. Cherepy; M. Leslie Carman
A material according to one embodiment exhibits an optical response signature for neutrons that is different than an optical response signature for gamma rays, said material exhibiting performance comparable to or superior to stilbene in terms of distinguishing neutrons from gamma rays, wherein the material is not stilbene, the material comprising a molecule selected from a group consisting of: two or more benzene rings, one or more benzene rings with a carboxylic acid group, one or more benzene rings with at least one double bound adjacent to said benzene ring, and one or more benzene rings for which at least one atom in the benzene ring is not carbon.
33	COBALT PHOSPHINE ALKYL COMPLEXES FOR THE ASYMMETRIC HYDROGENATION OF ALKENES	US13838835	2013-03-15	US20130281747A1	2013-10-24	Paul CHIRIK; Jordan M. Hoyt; Max R. Friedfeld
Disclosed herein are manganese, iron, nickel, or cobalt compounds having a bidentate ligand and the use of these compounds for the hydrogenation of alkenes, particularly the asymmetric hydrogenation of prochiral olefins.
34	Method of catalytic reaction using micro-reactor	US10587895	2005-01-26	US07663008B2	2010-02-16	Shu Kobayashi; Yuichiro Mori; Takehiko Kitamori; Masaharu Ueno; Kuniaki Okamoto
A method of catalytic reaction uses a micro-reactor (1) with a metal catalyst (5) or a metal complex catalyst (5) as a solid phase supported on the inner wall (4c) of a channel (4), a solution (7) dissolving a reactant as a liquid phase and hydrogen (9) as a gas phase are flown through the channel (4) in pipe flow state, and the reaction of the solution (7) and the gas (9) accelerated by the metal catalyst (5) or the metal complex catalyst (5) is conducted by three phase catalytic reaction of solid-liquid-gas phases. The metal catalyst (5) or the metal complex catalyst (5) is incorporated in a polymer, and hydrogenation reaction by three phase catalytic reductive reaction of a substance to be reduced can be conducted in short time at good yield. For hydrogenation reaction of unsaturated organics, the rate of reaction and yield are high when palladium catalyst is used, and carbonylation reaction can be conducted if carbon monoxide is used instead of hydrogen.
35	Method of catalytic reaction using micro-reactor	US10587895	2005-01-26	US20070161834A1	2007-07-12	Shu Kobayashi; Yuichiro Mori; Takehiko Kitamaori; Masaharu Ueno; Kuniaki Okamoto
A method of catalytic reaction uses a micro-reactor (1) with a metal catalyst (5) or a metal complex catalyst (5) as a solid phase supported on the inner wall (4c) of a channel (4), a solution (7) dissolving a reactant as a liquid phase and hydrogen (9) as a gas phase are flown through the channel (4) in pipe flow state, and the reaction of the solution (7) and the gas (9) accelerated by the metal catalyst (5) or the metal complex catalyst (5) is conducted by three phase catalytic reaction of solid-liquid-gas phases. The metal catalyst (5) or the metal complex catalyst (5) is incorporated in a polymer, and hydrogenation reaction by three phase catalytic reductive reaction of a substance to be reduced can be conducted in short time at good yield. For hydrogenation reaction of unsaturated organics, the rate of reaction and yield are high when palladium catalyst is used, and carbonylation reaction can be conducted if carbon monoxide is used instead of hydrogen.
36	Fluids having partially hydrogenated substituted styrene linear dimers and method of making same	US11205679	2005-08-17	US20060069212A1	2006-03-30	Mark Hagemeister; Thomas Forbus
A basestock that comprises a fully hydrogenated substituted styrene linear dimer; a partially hydrogenated mono-aromatic substituted styrene linear dimer; and a partially hydrogenated di-aromatic substituted styrene linear dimer. A process of producing a basestock that comprises reacting a feed stream that comprises substituted styrene, alcohol, and a dimerization catalyst, in the presence of a solvent, to form a crude slurry of dimerized substituted styrene; and partially hydrogenating the dimerized substituted styrene with hydrogen over a Group VIII catalyst to form a basestock that comprises a fully hydrogenated substituted styrene linear dimer and a partially hydrogenated substituted styrene linear dimer.
37	Aryl-substituted acyclic enediyne compounds	US10847667	2004-05-18	US20050004212A1	2005-01-06	Ming-Jung Wu; Chi-Fong Lin
This invention provides aryl-substituted acyclic enediyne compounds of formula (I): or a pharmaceutically acceptable salt or solvate thereof, wherein R1═R2═H; or R1 and R2 together form a moiety represented by the formula R3 represents a substituted or unsubstituted alkyl having 4-30 carbon atoms, or a substituted or unsubstituted aryl group having 3-30 carbon atoms; and R represents a substituted or unsubstituted aryl group having 3-30 carbon atoms; with the proviso that R3 is not butyl, pentyl, tetrahydropyranyloxymethyl, tetrahydropyranyloxypropyl or phenyl when R1═R2═H and R4 is o-cyanophenyl,; and with the proviso that R3 is not butyl when R1═R2═H and R4 is phenyl. The compounds of formula (I) are found to have inhibitory activities against topoisomerase I or act as a S phase or G2/M phase blocker.
38	Process for preparation of substituted aromatic compound employing friedel-crafts reaction using a reusable basic anionic clay catalyst	US10187183	2002-07-01	US06525226B2	2003-02-25	Vasant Ram chandra Choudhary; Suman Kumar Jana
A process for Friedel-Crafts type liquid-phase alkylation or acylation of an aromatic compound using a hydrotalcite-type basic anionic clay catalyst represented by a formula: [(M2+)1−x(M3+)x(OH)2]x+[Ay−]x/y q H2O where M2+ is a divalent cation selected from Mg2+, Zn2+, Ni2+, Co2+, Mn2+, Cu2+ or a mixture thereof, M3+ is a trivalent cation selected from Ga3+, In3+ Al3+, Fe3+ Cr3+ or a mixture thereof; x is a mole fraction of trivalent cations in the range of about 0.05 to about 0.5; O is oxygen; H is hydrogen; Ay− is an anion; y minus is an anionic negative charge having a value of 1 minus or 2 minus; and q is a number of water molecules, as the water of hydration; and involving following steps: i. pretreating said catalyst by contacting it with a halogen containing compound in the presence or absence of a non-aqueous solvent and optionally washing the pretreated catalyst with non-aqueous solvent or liquid aromatic compound to be alkylated or acylated; and then ii. contacting a liquid reaction mixture comprising said aromatic compound and said alkylating or acylating agent in the presence or absence of a non-aqueous solvent with the catalyst obtained from step (i) in a stirred batch reactor fitted with a reflux condenser under vigorous stirring, in the presence or absence of an inert gas bubbling through the reaction mixture, at effective reaction conditions; iii. cooling the reaction mixture to a temperature about 30° C., removing said catalyst from the reaction mixture by filtration and then separating the reaction products from the reaction mixture, and optionally washing the used catalyst by non-aqueous solvent; and if desired, iv. reusing the used catalyst directly with or without drying for the subsequent reaction batch avoiding step (i), is disclosed.
39	Method for preparing polycyclic aromatic hydrocarbons	US85979	1979-10-18	US4254292A	1981-03-03	Isoo Shimizu; Okitsugu Tsuji; Eiichi Matsuzaka; Atsushi Sato
A method for preparing polycyclic aromatic hydrocarbons with excellent yield and selectivity but without the formation of cyclic dimers and other undesirable by-products. In the method of the present invention, styrene, .alpha.-methylstyrene, .beta.-methylstyrene and/or vinyltoluene is dimerized and/or codimerized to produce unsaturated dimer and/or codimer in the first step reaction and said unsaturated dimer and/or codimer is caused to react with an aromatic hydrocarbon or hydrocarbons in the second step reaction, and both the first and second step reactions are carried out in the presence of a catalyst which is represented by the general formula: RCF.sub.2 SO.sub.3 H, in which the symbol R is Cl, F or C.sub.n F.sub.p CL.sub.2n+1-p, wherein n is an integer from 1 to 3 and p is also an integer from 1 to 2n+1.
40	Preparation of aromatic hydrocarbons	US3787512D	1971-03-10	US3787512A	1974-01-22	NELSON G
PROCESS FOR ALKYLATING AN AROMATIC HYDROCARBON BY REACTING A HALOALKANE WITH EITHER BENZENE OR AN ALKYL BENZENE AND CONDUCTING THE REACTION IN THE PRESENCE OF AN ALKYLALUMINUM HALIDE CATALYST WITHOUT DELIBERATELY ADDING HEAT TO ELEVATE THE TEMPERATURE OF THE REACTION.

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