序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
61 Acrylonitrile compound, production thereof and pest-controlling agent containing the same JP4895598 1998-02-12 JPH11158137A 1999-06-15 KOYANAGI TORU; NAKAMURA YUJI; MORITA MASAYUKI; SUGIMOTO KOJI; IKEDA TAKESHI; OGAWA MUNEKAZU
PROBLEM TO BE SOLVED: To obtain the subject new compound useful as an active ingredient for pest-controlling agents such as insecticides, acaricides and nematicides. SOLUTION: An acrylonitrile compound of formula I Q is a group of formula II-V [R3 groups are each a halogen, an alkyl which may be substituted, or the like; (m) is 0-5; (n) is 0-3; (q) is 0-4]; Y is C(R4 ) (R4 is H, a halogen, an alkyl or the like) or N; R1 is an alkyl, a haloalkyl, an alkoxyalkyl or the like; R2 is the same as R3 ; 1 is 1-4}, for example, β-(2-chlorophenyl)-β- isopropylcarbonyloxy-α-(2-thienyl)acrylonitrile. The compound of formula I may be obtained, for example, by allowing a compound of formula VI to react with a compound of the formula: R1 -X (X is a halogen). The compound of formula II is obtained by allowing a compound of formula VII to react with a compound of formula VIII (Z1 is an alkoxy).
62 The ▲ ii ▼ family method for producing a metal overbased sulfurized alkylphenol JP26518687 1987-10-20 JP2637117B2 1997-08-06 TOOMASU BUI RISUTON
63 Bisphenol ester derivative JP4669996 1996-02-08 JPH08277248A 1996-10-22 RITA PITERUU; BERUNAARU GIRUGU
PROBLEM TO BE SOLVED: To obtain a new bisphenol ester derivative useful as a stabilizer for organic materials. SOLUTION: A compound of formula I [A is a group of formula II (Y is O, methylene or the like; Z is N, CH or the like; R 5 is H, a 1-10C alkyl or the like; R 6 is H, a 1-4C alkyl or the like; R 7 is H or a 1-10C alkyl; R 8-R 10 are each independently H or a 1-4C alkyl) or the like; each R 1 is independently a 1-25C alkyl, a 2-24C alkenyl or the like; each R 2 is independently H, a 1-25C alkyl or the like; each R 3 is independently H or a 1-4C alkyl; R 4 is H or a 1-8C alkyl], such as a compound of formula III. The compound of formula I is obtained by subjecting a compound of formula IV and a compound of formula V to a thermal Diels-Alder reaction. COPYRIGHT: (C)1996,JPO
64 New delta-amino-gamma-hydroxy-omega-arylalkanoic acid amide JP9253295 1995-04-18 JPH0881430A 1996-03-26 RIHIYARUTO GUSHIYUKE; YURUGEN KURAUSU MAIBAUMU; BARUTAA SHIYURINKU; SUTEFUAN SHIYUTOUTSU; PASUKARU RIGORIEERU; YASUCHIKA YAMAGUCHI; NISHIMU KUROODO KOOHEN; PEETERU HERORUTO
PURPOSE: To obtain a new compound having renin-inhibiting activity and accordingly can be used as an active component of a hypotensive agent. CONSTITUTION: A compound of formula I (R 1 is H, OH, an alkoxy, a cycloalkoxy or the like; R 2 is H, an alkyl, a cycloalkyl, OH, an alkoxy, an aminoalkyl or the like; R 3 is an alkyl, an aminoalkyl, a cycloalkyl, an aryl, OH, an alkoxy or the like; R 4 is H, an alkyl, OH, an alkoxy or the like; X is methylene or hydroxymethylene; R 5 is an alkyl or a cycloalkyl; R 6 is amino; R 7 is an alkyl, an alkenyl, an arylalkyl or the like; R 8 is an alkyl, a cycloalkyl, an aminoalkyl, a heteroaryl or the like). For example, 2(R,S)-methyl-4(S)- hydroxy-5(S)-amino-7(S)-isopropyl-8-(p-t-butylphenyl)octanoic acid (N-butyl)amide hydrochloric acid salt. A compound in which at least one asymmetric carbon in the main chain has a stereochemical configuration expressed by formula II is preferable among the compounds of formula I. COPYRIGHT: (C)1996,JPO
65 JPH07505631A - JP51762993 1993-03-31 JPH07505631A 1995-06-22
66 Alkene derivatives and their preparation JP3206986 1986-02-18 JPH0729964B2 1995-04-05 ハワード・タツカー; レスリー・リチヤード・ヒユーズ
67 Liquid crystal compound, liquid crystal composition containing the compound, liquid crystal element containing the composition and displaying method and display device using the element JP24357893 1993-09-06 JPH0776543A 1995-03-20 YAMADA YOKO; TAKIGUCHI TAKAO; IWAKI TAKASHI; TOKANOU GOUJI; NAKAMURA SHINICHI
PURPOSE:To provide a liquid crystal compound having quick response and high contrast and effective for decreasing the temperature dependency of the response speed. CONSTITUTION:A compound of the formula I [R1 and R2 are H, halogen, CN or 1-20C alkyl (one or more CH2 groups may be substituted with O, S, CO, CH=CH, etc., provided that hetero atoms are not adjacent to each other, or H atom may be substituted with F atom) ; at least one of R1 and R2 is group of the formula II ((m), (n), (p) and (q) are 1-15 and the sum is 518; Y1 is single bond, O, CO, COO, CidenticalC, etc.); A1 is A2, A2 X1 A3 Of A2-X1-A3 X2-A4; A2 to A4 are 1,4-phenylene, pyridine-2,5-diyl, pyrimidine-2,5-diyl, 1,4-cyclohexylene, etc.; X1 and X2 are single bond, COO, OCO, CH2O, CH2CH2, CH=CH, CidenticalC, etc.], e.g., 5-decyl-2-{4-(8, 8, 9, 9, 10, 10-heptafluoro-3, 6-dioxadecyloxy) phenyl}pyrimidine.
68 Liquid crystal compound, liquid crystal composition containing the compound, liquid crystal element containing the composition and displaying method and display device using the element JP24357693 1993-09-06 JPH0776542A 1995-03-20 IWAKI TAKASHI; TAKIGUCHI TAKAO; TOKANOU GOUJI; YAMADA YOKO; NAKAMURA SHINICHI; NAKAZAWA IKUO
PURPOSE:To provide a liquid crystal compound having quick response and effective for decreasing the temperature dependency of response speed. CONSTITUTION:A compound of the formula I [R1 and R2 are 1-18C straight or branched alkyl; one or non-adjacent two CH2 groups of the alkyl may be substituted with O, S, CO, COO or OCO and the H atom may be substituted with F; A1 is group of the formula II to the formula VIII (Z is O or S; Y1 and Y2 are H, F, Cl, Br, CH3, CN or CF3), etc.; A2 and A3 are group of the formula IX (Y3 and Y4 are same as Y1 and Y2); X1 is single bond, COO, OCO, CH2O, OCH2, CH2CH2 or CidenticalC], e.g. 2-[4-(4-hexylphenoxy)phenyl]-5- decylpyrimidine of the formula X. The compound can be synthesized by the process shown by the reaction formula.
69 Benzene derivative and liquid-crystalline medium JP9666894 1994-05-10 JPH06329573A 1994-11-29 ETSUKEHARUTO BARUTOMAN; HERUBERUTO PURAHA; ANDOREASU RUURU
A liquid-crystalline medium based on a mixture of polar compounds having positive dielectric anisotropy, comprising one or more compounds of the formula I <IMAGE> I in which R, A1,. A2, Z1, Z2, m, n, L1, L2 and L3 are as defined in claim 1.
70 JPH06507603A - JP50549392 1992-03-04 JPH06507603A 1994-09-01
71 JPS6234754B2 - JP15750477 1977-12-28 JPS6234754B2 1987-07-28 DONARUDO EDOGAA BARUDASU; EDOWAADO ERUBIN DEBUSU
72 Novel sulfur-containing phenol, manufacture and organic material composition containing same as stabilizer JP19470485 1985-09-03 JPS6169755A 1986-04-10 SAMUERU EBANSU
73 Substituted diphenyl ether, manufacture and herbicide as major component thereof JP8570282 1982-05-22 JPS5810540A 1983-01-21 KOUUCHIYANGU RIYUU; MAIKERU JIEI BURAUN
74 PROCESS FOR MAKING AN OVERBASED, SULFURIZED SALT OF AN ALKYLATED HYDROXY-AROMATIC COMPOUND PCT/US2010056554 2010-11-12 WO2011066115A3 2011-09-29 SINQUIN GILLES P; BUCKLEY THOMAS FRANCIS III; CISSON CHARLES MICHAEL
An overbased, sulfurized salt of at least one alkylated hydroxyaromatic compound, wherein the alkyl substituent of the hydroxyaromatic compound is a residue of at least one isomerized olefin having from about 15 to about 99 wt. % branching is disclosed. The overbased, sulfurized salt of at least one alkylated hydroxyaromatic compound is produced by the process comprising: (a) alkylating at least one hydroxyaromatic compound with at least one isomerized olefin having from about 15 to about 99 wt. % branching obtained by isomerizing at least one normal alpha olefin having from about 10 to about 40 carbon atoms, to provide at least one alkylated hydroxyaromatic compound; (b) neutralizing and sulfurizing the alkylated hydroxyaromatic compound in any order to provide at least one neutralized, sulfurized alkylated hydroxyaromatic compound; and (c) overbasing the at least one neutralized, sulfurized alkylated hydroxyaromatic compound.
75 PROCESS FOR MAKING AN OVERBASED, SULFURIZED SALT OF AN ALKYLATED HYDROXY-AROMATIC COMPOUND PCT/US2010/056554 2010-11-12 WO2011066115A2 2011-06-03 SINQUIN, Gilles, P.; BUCKLEY, Thomas, Francis, III; CISSON, Charles, Michael

An overbased, sulfurized salt of at least one alkylated hydroxyaromatic compound, wherein the alkyl substituent of the hydroxyaromatic compound is a residue of at least one isomerized olefin having from about 15 to about 99 wt. % branching is disclosed. The overbased, sulfurized salt of at least one alkylated hydroxyaromatic compound is produced by the process comprising: (a) alkylating at least one hydroxyaromatic compound with at least one isomerized olefin having from about 15 to about 99 wt. % branching obtained by isomerizing at least one normal alpha olefin having from about 10 to about 40 carbon atoms, to provide at least one alkylated hydroxyaromatic compound; (b) neutralizing and sulfurizing the alkylated hydroxyaromatic compound in any order to provide at least one neutralized, sulfurized alkylated hydroxyaromatic compound; and (c) overbasing the at least one neutralized, sulfurized alkylated hydroxyaromatic compound.

76 4-((PHENOXYALKYL)THIO)-PHENOXYACETIC ACIDS AND ANALOGS PCT/US2005033137 2005-09-14 WO2006032023A2 2006-03-23 DEANGELIS ALAN; DEMAREST KEITH T; KUO GEE-HONG; PELTON PATRICIA; WANG AIHUA; ZHANG RUI
The invention features 4-((phenoxyalkyl)thio)-phenoxyacetic acids and analogs, compositions containing them, and methods of using them as PPAR modulators to treat or inhibit the progression of, for example, dyslipidemia.
77 NOVEL THIO-AMINOTETRALIN COMPOUNDS USEFUL IN PAIN MANAGEMENT PCT/SE1999/002401 1999-12-17 WO00037438A1 2000-06-29
The present invention relates to novel thio-aminotetralin compounds of formula (I) wherein Z, X, R1, R2, R3, R4, R5, and R6 are defined herein. The compounds are useful in pain management.
78 COMPOUNDS COMPRISING POLYENE CHAIN STRUCTURE AND PROCESSES FOR PREPARING THE SAME PCT/KR1999/000648 1999-10-28 WO00027810A1 2000-05-18
The present invention provides valuable intermediates which can be used in the synthesis of a compound having polyene chain structure, processes for preparing the same, and a process for preparing beta -carotene by using said intermediates. The process for preparing beta -carotene (Chemical Formula 3) or a compound having polyene chain structure, is characterized in that the polyene chain structure is formed by applying Ramberg-Bäcklund reaction to a diallylic sulfone obtained by the oxidation of diallylic sulfide. Further, the present invention provides retinyl sulfide which was synthesized by the coupling of diallylic sulfide with the corresponding Wittig salt.
79 Process for making Group II metal overbased sulfurized alkylphenols US10672721 2003-09-26 US20050070451A1 2005-03-31 Robert Wollenberg; Steven Lockett
The present invention is directed to a novel process for making Group II metal overbased sulfurized alkylphenols, which process uses alkylene carbonate as both a source of carbon dioxide and alkylene glycol. In particular, under the reaction conditions using ethylene carbonate, carbonation time is reduced to about one quarter the time taught in the prior art to make Group II metal overbased sulfurized alkylphenol compositions. The present invention is also directed to a detergent-dispersant additive composition comprising a Group II metal overbased sulfurized alkylphenols, wherein the Group II metal overbased sulfurized alkylphenols have a reduced color as measured by ASTM Test No. D 6045 and an increased hydrolytic stability as measured by a modified ASTM Test No. 2619. The present invention is also directed to a process using ethylene carbonate or alkyl-substituted ethylene carbonate and water for delivering in situ equimolar quantities of ethylene glycol and carbon dioxide for use as reactants in chemical reactions.
80 Process for preparing solutions of alkali metal salts of functionalized alcohols US10704808 2003-11-12 US20040097759A1 2004-05-20 Johannes Ruwwe; Klaus Stadtmueller
Alkali metal salt of formula (I): MOYXR1 (I), and its solution can be prepared in high yields, particularly high space-time yields, and with high purities by reacting an alcohol of the formula (Ia): HOYXR1 (Ia), in a solvent mixture with an alkali metal salt of formula (II): MOR2 (II), or by reacting the alcohol (Ia) in a solvent mixture with an alkali metal hydroxide. Part of the liberated alcohol of formula (IIa): HOR2 (IIa) or a part of the liberated water is distilled from the solvent mixture, initially, without addition of an entrainer. Subsequently, a remainder of the liberated alcohol of formula (IIa) or the liberated water is distilled from the solvent mixture with the aid of at least one organic solvent as entrainer. In formula (I) and in formula (II), M is Li, Na, K, Rb or Cs. In formula (I) and in formula (Ia): Y is (C1-C8)-alkylene, X is O, S or NR1, and R1 is H, (C1-C8)-alkyl, (C2-C8)-alkenyl, (C2-C8)-alkynyl, (C3-C8)-cycloalkyl, (C6-C18)-aryl, (C7-C19)-aralkyl, (C3-C18)-heteroaryl, (C4-C19)-heteroaralkyl, ((C1-C8)-alkyl)1-3-(C3-C8)-cycloalkyl, ((C1-C8)-alkyl)1-3-(C6-C18)-aryl or ((C1-C8)-alkyl)1-3-(C3-C18)-heteoraryl. In formula (II) and in formula (IIa), R2 is methyl, ethyl, propyl, isopropyl, sec-butyl, isobutyl or tert-butyl.
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