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序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
121	Unsaturated compounds containing silane, electron donor and electron acceptor functionality	US10302574	2002-11-20	US20040097651A1	2004-05-20	Osama M. Musa
This invention relates to curable compounds or resins containing electron donor or acceptor functionality, carbon to carbon unsaturation, and silane functionality, having the structure. 1 in which E is an electron donor or electron acceptor functionality; Q is an oligomeric or polymeric group containing at least one carbon to carbon double bond, A is a hydrocarbyl group; and L is a linking group.
122	Process for the preparation of sbr rubbers with an improved processability and a lower rolling resistance	US10257395	2003-06-02	US20040006187A1	2004-01-08	Gian Tommaso Viola; Luca Soddu; Sabrina Isidori; Attilio Taccioli; Francesco Masi
Process for the production of statistic elastomeric conjugated diene-vinyl arene copolymers having a branched structure which comprises: (1) anionic copolymerization in solution of the conjugated diene and vinyl arene monomers, in the presence of randomizing agents and an initiator selected from the group of Lithium alkyls, the copolymerization being carried out until the almost total disappearance of the monomers; (2) addition to the solution of step (1) of a quantity of Lithium alkyl from 1 to 4 times the molar quantity of the Lithium alkyl of step (1); (3) addition to the polymeric solution of step (2) of a compound having the general formula RnullBr, the molar ratio between RnullBr and the total Lithium alkyl ranging from 0.6/1 to 1/1, preferably from 0.7/1 to 0.9/1, thus obtaining an elastomeric branched copolymer.
123	Process for reacting large hydrophobic molecules with small hydrophilic molecules	US10257809	2002-10-15	US20030224952A1	2003-12-04	Marvin B. Detar; John C. Smoggie; Richard M. Lange
A process for reacting relatively small hydrophilic carboxylic molecules with relatively large, hydrophobic hydrocarbon based molecules, said process comprising conducting the reacting in the presence of a sulfonic acid catalyst having solubilizing properties. In a preferred embodiment the large hydrophobic molecule comprises at least one member of the group consisting of (1) olefinically unsaturated hydrocarbons containing at least about 10 carbon atoms and (2) aliphatic hydrocarbyl group substituted hydroxy aromatic compounds wherein the aliphatic hydrocarbyl group contains at least 12 carbon atoms and the small hydrophilic molecule comprises a carboxylic reactant selected from the group consisting of compounds of the formula R3C(O)(R4)nC(O)OR5 wherein each of R3 and R5 is independently H or a hydrocarbyl group, R4 is a divalent hydrocarbylene group, and n is 0 or 1, and reactive sources thereof.
124	Process for crosslinking carboxylated nitrile rubber, hydrogenating carboxylated nitrile rubber, the crosslinked rubber and its' uses	US10266722	2002-10-08	US20030109642A1	2003-06-12	Janet N. Gamlin; Sharon X. Guo
A process has now been discovered that permits the simultaneous crosslinking and derivation of an, optionally hydrogenated, polymer whose backbone is composed of a conjugated diene, an unsaturated nitrile and an unsaturated carboxylic acid in the presence of a coupling/condensing agent. This permits the preparation of a novel polymeric material that is an optionally hydrogenated polymer of a conjugated diene, an unsaturated nitrile and a derived unsaturated acid. It has also been found that this novel polymeric material has unexpected and valuable properties.
125	Amino-terminated polybutadienes	US10300435	2002-11-20	US20030096916A1	2003-05-22	Herbert Shin-I Chao; John Schmidhauser; Alain Robert Drexler; Nan Tian
Improved amine-terminated polybutadienes (ATPBs) having one or two terminal groups of the formula nullCHRNH2 wherein R is C1-C20 alkyl, are prepared by aminating a secondary hydroxyl-terminated polybutadiene having no ether groups. The ATPBs may be hydrogenated or partially hydrogenated, either prior to or after the amination, to saturate or partially saturate the polymers. Preferred ATPBs are of the formula H2NCHR-(polybutadiene)-CHRNH2 wherein R is C1-C20 alkyl. Polyureas, polyurethanes, crosslinked epoxies, polyamides, and other derivatives with improved properties can be prepared from the ATPBs. The resultant derivatives are useful in liquid binders for braking systems, electric potting compositions, coatings, adhesives, sealants, and water proofing membranes, for example.
126	Dispersant and dispersant viscosity index improvers from selectively hydrogenated aryl-substituted olefin containing diene copolymers	US09201431	1998-11-30	US06248702B1	2001-06-19	Thomas S. Coolbaugh; Frederick C. Loveless; John E. Marlin, II; Demetreos N. Matthews
The invention provides dispersants and dispersant viscosity index improvers which include polymers of conjugated dienes which have been hydrogenated, functionalized, optionally modified, and post treated. The dispersant substances include a copolymer of two different conjugated dienes and an aryl-substituted olefin. The polymers are selectively hydrogenated to produce polymers which have highly controlled amounts of unsaturation, permitting highly selective functionalization. Also provided are lubricant fluids, such as mineral and synthetic oils, which have been modified in their dispersancy and/or viscometric properties by means of the dispersant substances of the invention. Also provided are methods of modifying the dispersancy and/or viscometric properties of lubricating fluids such as mineral and synthetic lubricating oils. The dispersant substances may also include a carrier fluid to provide dispersant concentrates.
127	Selected deprotection of protected functional polymers	US09207226	1998-12-08	US06184309B2	2001-02-06	James A. Schwindeman; John F. Engel; Eric J. Granger; Conrad W. Kamienski; Roderic P. Quirk
A process for removing a protecting group from a polymer. Protected functional groups of a polymer may be deprotected by treating the polymer in the presence of an acid catalyst, including organic acids, mineral acids, heterogeneous acid systems, Lewis acids, and fluoride ion sources.
128	Fixed-bed Raney metal catalyst, its preparation and the hydrogenation of polymers using this catalyst	US951125	1997-10-15	US6121188A	2000-09-19	Boris Breitscheidel; Uwe Diehlmann; Thomas Ruhl; Sabine Weiguny
An activated fixed-bed Raney metal catalyst which is free of metal powder, has macropores and is based on an alloy of aluminum and at least one metal of subgroup VIII of the Periodic Table, contains more than 80% by volume, based on the total pores, of macropores and is used for the hydrogenation of low molecular weight and polymeric organic compounds.
129	Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers: Mannich reaction products	US102680	1998-06-23	US06034184A	2000-03-07	Thomas S. Coolbaugh; Frederick C. Loveless; John E. Marlin, II; Demetreos N. Matthews
The invention provides dispersants and dispersant viscosity index improvers which include polymers of conjugated dienes which have been hydrogenated, functionalized, optionally modified and post treated. The dispersant substances include a copolymer of two different conjugated dienes. The polymers are selectively hydrogenated to produce polymers which have highly controlled amounts of unsaturation, permitting highly selective functionalization. The polymers may be functionalized by a Mannich base condensation reaction. Also provided are lubricant fluids, such as mineral and synthetic oils, which have been modified in their dispersancy and/or viscometric properties by means of the dispersant substances of the invention. Also provided are methods of modifying the dispersancy and/or viscometric properties of lubricating fluids such as mineral and synthetic lubricating oils. The dispersant substances may also include a carrier fluid to provide dispersant concentrates.
130	Cyclic carbonyl containing polymers	US92150	1993-07-15	USRE35004E	1995-07-25	Stanley J. Brois
The present invention relates to novel polymers which are adducts of an unsaturated hydrocarbon, wherein the novel polymers are produced by contacting cyclic carbonyl monomers with an unsaturated hydrocarbon to form novel cyclic carbonyl polymers having an Mn of about 500 to about 10.sup.7.
131	Resin, process for preparing the same and compositon comprising the same	US284927	1994-08-02	US5432234A	1995-07-11	Masami Enomoto; Hitoshi Yuasa; Fumiaki Oshimi; Yutaka Otsuki
A novel hydroxyphenylated resin having excellent thermal stability, weather resistance, and electrical properties useful as a resin for a printed circuit board, a resin for sealing a semiconductor, an insulating materials, and the like; a process for preparing the resin; and curable epoxy composition comprising the same. Specifically, the present invention provides a novel resin containing a number of phenolic hydroxyl groups and having a high softening point and substantially no double bonds; and a process for preparing the same wherein a butadiene oligomer and a phenol compound are used as starting materials; and a curable epoxy resin composition comprising the same suitable for applications such as a sealing material.
132	Polymers containing repeating cycloketonic units, and method for obtaining them	US71517	1993-06-03	US5369187A	1994-11-29	Anna Sommazzi; Nicoletta Cardi; Fabio Garbassi; Chrissostomos Chatgilialoglu
Polymers having a very good combination of chemical, mechanical and process properties, and particularly useable either alone or as mixtures, as high-tenacity thermoplastic polymer and as elastomers or elastomeric modifiers, contain, randomly distributed along their chain, repeating cycloketonic structural units having the following general formula (I): ##STR1## wherein: A represents a tetravalent aliphatic or cycloaliphatic, substituted or non-substituted moiety containing a total number of from 4 to 50, preferably from 4 to 20, carbon atoms.Such polymers can be prepared by means of a process which comprises reacting, in a liquid media, a polydiene containing adjacent structural units derived from the 1,4-cis polymerization of conjugated dienes, with carbon monoxide, in the presence of free radical generating compounds and, optionally, a compound capable of acting as a hydrogen donor.
133	Resin, process for preparing the same, and composition comprising the same	US743367	1991-08-19	US5360870A	1994-11-01	Masami Enomoto; Hitoshi Yuasa; Fumiaki Oshimi; Yutaka Otsuki
A novel hydroxyphenylated resin having excellent thermal stability, weather resistance, and electrical properties useful as a resin for a printed circuit board, a resin for sealing a semiconductor, an insulating materials, and the like; a process for preparing the resin; and curable epoxy composition comprising the same. Specifically, the present invention provides a novel resin containing a number of phenolic hydroxyl groups and having a high softening point and substantially no double bonds; and a process for preparing the same wherein a butadiene oligomer and a phenol compound are used as starting materials; and a curable epoxy resin composition comprising the same suitable for applications such as a sealing material.
134	Hydroesterification of polymerized conjugated dienes	US569680	1990-08-20	US4980422A	1990-12-25	Carl L. Willis
Polymerized 1,3-butadiene, including styrenic block copolymers, are functionalized with both carboxylic ester groups and ketone linking groups by reaction with carbon monoxide and an alcohol. Such conjugated diene polymers can be reacted in the presence of a catalyst composition that includes a cobalt compound and an amine ligand. The functionalized 1,3-butadiene polymers may be hydrogenated with a nickel/aluminum catalyst which removes olefinically unsaturated carbon-carbon bonds without substantially hydrogenating the ketone linking groups and carboxylic ester groups.
135	Carboxylated syndiotactic 1,2-polybutadiene	US461955	1990-01-08	US4960834A	1990-10-02	Lawson G. Wideman
Syndiotactic 1,2-polybutadiene can be blended with various rubbers in order to improve the properties thereof. For instance, syndiotactic 1,2-polybutadiene can be blended with rubbers utilized in making tire treads in order to improve the heat build-up and wear characteristics of tires. The interaction and adhesion between syndiotactic 1,2-polybutadiene and rubbers can be improved by carboxylating the syndiotactic 1,2-polybutadiene. The presence of carboxylic acid groups on the syndiotactic 1,2-polybutadiene also greatly improves interaction with fillers commonly utilized in rubber compounding, such as carbon black. This invention discloses a process whereby syndiotactic 1,2-polybutadiene can be easily and inexpensively carboxylated. This invention more specifically discloses a method for preparing carboxylated syndiotactic 1,2-polybutadiene which comprises: (1) reacting syndiotactic 1,2-polybutadiene with hydrogen and carbon monoxide in an organic medium to produce formyl syndiotactic 1,2-polybutadiene, wherein the syndiotactic 1,2-polybutadiene is in the form of small particles having a particle size of less than about 250 microns which are suspended in the organic medium; and (2) reacting the formyl syndiotactic 1,2-polybutadiene with oxygen to produce the carboxylated syndiotactic 1,2-polybutadiene.
136	Enhancing cure rates of rubber	US249489	1988-09-26	US4914157A	1990-04-03	Lawson G. Wideman; Thomas J. Botzman; George Jalics
There is disclosed a process for enhancing the rate of cure of a sulfur vulcanizable rubber. Addition of a hydroformylated rubber to a sulfur vulcanizable rubber enhances the rate of cure and concomitantly improves the rubber/filler interaction of the vulcanized rubber.
137	Method for improving rubbers	US844550	1986-03-27	US4704427A	1987-11-03	Shizuo Kitahara; Fujito Nakakawaji
A method for improving the physical properties of a rubber having --C(CH.sub.3).dbd.C-- type unsaturated bonds, characterized by subjecting said rubber to two reactions consisting of a modification reaction by Lewis acid and a carboxylation reaction in any desired order.
138	Process for the preparation of an azidosulphonylbenzoic acid	US819953	1986-01-21	US4666631A	1987-05-19	Anne C. Udding
The invention relates to a process for the preparation of an azidosulphonylbenzoic acid which comprises reacting a water-soluble salt of a chlorosulphonylbenzoic acid with hydrazine (N.sub.2 H.sub.4) in an aqueous medium, reacting the obtained hydrazinosulphonylbenzoic acid salt with nitrous acid in the same aqueous medium, acidifying the resulting aqueous solution comprising the azidosulphonylbenzoic acid salt, to precipitate the azidosulphonylbenzoic acid and separating the azidosulphonylbenzoic acid. The process is a one-pot process, which differs from a known process in that the intermediate, being the hydrazinosulphonylbenzoic acid salt, is not isolated.
139	Method of treating diene rubber with amino- and hydroxy aryl compounds	US549032	1983-11-07	US4499243A	1985-02-12	Charles P. Rader
Treatment of diene rubber with a compound of the formula ##STR1## wherein X and Y are --OH or --NH.sub.2 and R and R' are hydrogen, --OH, NH.sub.2 or non-reactive substituents is performed at temperatures above 130.degree. C. Rubber compositions treated in this manner exhibit increased green strength, decreased plasticity, and, when vulcanized, decreased hysteresis.
140	Method for rubber treatment	US374451	1982-05-03	US4410656A	1983-10-18	Aubert Y. Coran; Charles P. Rader; Chester D. Trivette, Jr.
The method of masticating diene rubber in the presence of maleic acid or maleic anhydride together with sulfur or an organic sulfur compound capable of generating a thiyl radical is shown.Improved tack, green strength or both are realized in the treated diene rubber.

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