| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 1 | 用于轮胎胎面的橡胶组合物及其制造方法 | CN02823072.8 | 2002-11-25 | CN1589293A | 2005-03-02 | P·罗贝尔; S·马蒂厄 |
| 本发明涉及一种可构成轮胎胎面的橡胶组合物，所述组合物至少含有：补强无机填料，在乳液中制得的沿着链含有羧酸官能团的二烯高弹体，其中由共轭二烯生成的单元的摩尔比率高于30％，和在所述补强无机填料和所述高弹体之间的含聚硫化烷氧基硅烷的粘合剂。该组合物中，所述高弹体可以通过下列步骤制得：在乳化溶液中，至少一个共轭二烯单体与可水解或可氧化生成羧酸的前体共聚单体进行自由基共聚合，以制得沿着链含有所述酸的前体官能团的中间二烯高弹体，然后将所述前体官能团水解或氧化以制得沿着链含有羧酸官能团的所述高弹体。 | ||||||
| 2 | 含硅烷的羧基封端的聚合物 | CN201480023457.2 | 2014-04-11 | CN105164163A | 2015-12-16 | 诺贝特·施泰因豪泽; 托马斯·格罗斯 |
| 本发明涉及端基官能化的聚合物，其中这些聚合物在聚合物链的末端具有式(I)的含硅烷的羧基基团，其中R1、R2是相同或不同的并且是H和烷基、烷氧基、环烷基、环烷氧基、芳基、芳氧基、烷芳基、烷芳氧基、芳烷基以及芳烷氧基部分，这些部分可以含有一个或多个杂原子，优选O、N、S或Si，R3、R4是相同或不同的并且是H和烷基、环烷基、芳基、烷芳基以及芳烷基部分，这些部分可以含有一个或多个杂原子，优选O、N、S或Si，并且A是二价有机部分，该二价有机部分除C和H之外可以含有一个或多个杂原子，优选O、N、S或Si。 | ||||||
| 3 | 具有良好加工行为的冷流降低的聚合物 | CN201480023445.X | 2014-04-11 | CN105143315A | 2015-12-09 | 诺贝特·施泰因豪泽; 托马斯·格罗斯 |
| 本发明涉及具有良好的加工行为的冷流降低的聚合物，这些在该聚合物链末端具有一个具有式(I)的含硅烷的羧基其中R1、R2是相同或不同的，并且是H、烷基、烷氧基、环烷基、环烷氧基、芳基、芳氧基、烷芳基、烷芳氧基、芳烷基或芳烷氧基，其可以包含一个或多个杂原子，优选O、N、S或Si，R3、R4是相同或不同的，并且是H、烷基、环烷基、芳基、烷芳基或芳烷基，其可以包含一个或多个杂原子，优选O、N、S或Si，A是一个二价有机基团，除了C和H之外，它可包含一个或多个杂原子，优选O、N、S或Si。 | ||||||
| 4 | 官能化聚合物 | CN200810167355.4 | 2008-10-22 | CN101418054A | 2009-04-29 | 燕远勇 |
| 一种官能化聚合物，其包括聚合物链，和通过包含一个或多个氨基甲酸酯基团的官能度与该链连接的端基。该官能化聚合物可通过使亲核试剂与具有末端异(硫代)氰酸酯官能度的聚合物反应提供，该具有末端异(硫代)氰酸酯官能度的聚合物又通过使末端活性聚合物与多异(硫代)氰酸酯反应提供。在所述工艺中，甚至可采用包含大量苯乙烯链节的聚合物。 | ||||||
| 5 | 马来酰亚胺封端橡胶和用所述马来酰亚胺封端橡胶制备的可固化组合物 | CN200480000956.6 | 2004-05-13 | CN1774451A | 2006-05-17 | 崔源文; 畑中和洋 |
| 本发明的一个目的在于提供一种具有优异的固化后韧性及优异的长期稳定性的可固化组合物以及一种用于所述可固化组合物的橡胶。通过一种可通过使分子两端具有氨基和/或亚氨基的橡胶与双马来酰亚胺化合物反应得到的分子两端具有马来酰亚胺结构的马来酰亚胺封端橡胶以及通过一种包含所述马来酰亚胺封端橡胶和树脂和/或不同于所述马来酰亚胺封端橡胶的橡胶的可固化组合物可以实现所述目的。 | ||||||
| 6 | 氢化共轭二烯聚合物的制造方法 | CN201480008770.9 | 2014-02-14 | CN104995214A | 2015-10-21 | 野坂直矢; 柴田昌宏; 丰田畅之; 阿部慈; 上田二朗 |
| 本发明提供一种氢化共轭二烯聚合物的制造方法，其可形成与填充剂混合时的分散性提高优异、混合后的滞后损耗减少优异、且与热塑性树脂等混合时的加工性优异、混合后的物性优异的聚合物合金。一种氢化共轭二烯聚合物的制造方法，其具有以下工序：在由具有式(x)和(y)中至少1种结构的胺化合物和碱金属化合物等金属化合物构成的聚合引发剂的存在下将共轭二烯化合物聚合而得到共轭二烯聚合物的工序，以及将上述共轭二烯聚合物加氢的工序。[式(x)、(y)中，R1为亚烃基，R1中的亚烃基只要不具有活性氢则可含有杂原子，A1为三烃基甲硅烷基，R2和R3为亚烃基，R2和R3中的亚烃基只要不具有活性氢则可含有杂原子，A2是如下的官能团：具有三烃基甲硅烷基，不具有活性氢，与R3键合的原子为N等]。 | ||||||
| 7 | 热致可逆交联接枝聚合物 | CN201180054241.9 | 2011-11-08 | CN103201294B | 2015-04-29 | 西尔维娅·哈德斯; 卢德维克·莱布勒; 伊利亚斯·伊利奥普洛斯; 朱利耶·普雷沃斯特 |
| 本发明涉及一种接枝聚合物PG，所述接枝聚合物含有聚合物主链P和至少一个连接到所述聚合物主链P的侧接枝物G，接枝物G具有通式(1)：其中R1和R2彼此独立地代表直链或支链、不饱和或饱和的烃基，使得R1和R2基团的碳原子总数在2和110之间，X代表酰胺、酰胺基-酸、脲或氨基甲酸酯官能团，所述接枝物G通过硫原子连接到聚合物主链P。接枝聚合物PG是允许热致可逆交联的聚合物。接枝聚合物PG可用于许多领域如涂料、漆、热塑性塑料、胶粘剂、润滑剂、燃料、墨、水泥、建筑材料、橡胶和沥青。接枝聚合物PG尤其可用于热致可逆交联的沥青/聚合物组合物，因而可用于在沥青涂覆的材料的生产过程中降低涂覆、铺展和/或压制温度。——S——R1——X——R2(1)。 | ||||||
| 8 | 热致可逆交联接枝聚合物 | CN201180054241.9 | 2011-11-08 | CN103201294A | 2013-07-10 | 西尔维娅·哈德斯; 卢德维克·莱布勒; 伊利亚斯·伊利奥普洛斯; 朱利耶·普雷沃斯特 |
| 本发明涉及一种接枝聚合物PG，所述接枝聚合物含有聚合物主链P和至少一个连接到所述聚合物主链P的侧接枝物G，接枝物G具有通式(1)：其中R1和R2彼此独立地代表直链或支链、不饱和或饱和的烃基，使得R1和R2基团的碳原子总数在2和110之间，X代表酰胺、酰胺基-酸、脲或氨基甲酸酯官能团，所述接枝物G通过硫原子连接到聚合物主链P。接枝聚合物PG是允许热致可逆交联的聚合物。接枝聚合物PG可用于许多领域如涂料、漆、热塑性塑料、胶粘剂、润滑剂、燃料、墨、水泥、建筑材料、橡胶和沥青。接枝聚合物PG尤其可用于热致可逆交联的沥青/聚合物组合物，因而可用于在沥青涂覆的材料的生产过程中降低涂覆、铺展和/或压制温度。——S——R1——X——R2 (1)。 | ||||||
| 9 | 官能化聚合物 | CN200810167355.4 | 2008-10-22 | CN101418054B | 2012-08-15 | 燕远勇 |
| 一种官能化聚合物，其包括聚合物链，和通过包含一个或多个氨基甲酸酯基团的官能度与该链连接的端基。该官能化聚合物可通过使亲核试剂与具有末端异(硫代)氰酸酯官能度的聚合物反应提供，该具有末端异(硫代)氰酸酯官能度的聚合物又通过使末端活性聚合物与多异(硫代)氰酸酯反应提供。在所述工艺中，甚至可采用包含大量苯乙烯链节的聚合物。 | ||||||
| 10 | 用于轮胎胎面的橡胶组合物及其制造方法 | CN02823072.8 | 2002-11-25 | CN100475887C | 2009-04-08 | P·罗贝尔; S·马蒂厄 |
| 本发明涉及一种可构成轮胎胎面的橡胶组合物，所述组合物至少含有：-补强无机填料，-在乳液中制得的沿着链含有羧酸官能团的二烯高弹体，其中由共轭二烯生成的单元的摩尔比率高于30%，和-在所述补强无机填料和所述高弹体之间的含聚硫化烷氧基硅烷的粘合剂。该组合物中，所述高弹体可以通过下列步骤制得：-在乳化溶液中，至少一个共轭二烯单体与可水解或可氧化生成羧酸的前体共聚单体进行自由基共聚合，以制得沿着链含有所述酸的前体官能团的中间二烯高弹体，然后-将所述前体官能团水解或氧化以制得沿着链含有羧酸官能团的所述高弹体。 | ||||||
| 11 | 알릴붕산화를 통해 작용화된 탄성중합체의 제조 방법 | KR1020170087014 | 2017-07-10 | KR101920566B1 | 2018-11-20 | 플루크마가렛맥귀간; 슈네트만이니고고트커게난트; 라이흐트하네스; 멕킹스테판 |
| 본발명은제 1 단량체및 제 2 단량체를공중합하여공중합체 Y를형성하되, 제 1 단량체는 1,3-부타다이엔, 이소프렌및 스티렌으로이루어진군으로부터선택하고, 제 2 단량체는하기화학식 1 및 2의화합물로이루어진군으로부터선택하는단계; 및공중합체 Y를하기화학식 3의화합물인 Z와반응시켜작용화된탄성중합체를형성하는단계를 포함하는, 작용화된탄성중합체의제조방법에관한것이다: [화학식 1][화학식 2][상기식에서, B는붕소이고; O는산소이고; R및 R는독립적으로 1 내지 10개의탄소원자를함유하는선형또는분지형알킬기이고; R은수소, 또는 1 내지 10개의탄소원자를함유하는선형또는분지형알킬기이고; R는 1 내지 20개의탄소원자를함유하는선형또는분지형알칸다이일기, 또는가교방향족기이다] [화학식 3][상기식에서, R는페닐렌, 1 내지 10개의탄소원자를함유하는선형또는분지형알칸다이일기, 또는하나이상의페닐렌기 및 1 내지 10개의탄소원자를함유하는하나이상의선형또는분지형알칸다이일기의조합이고; Q는수소, 브롬, 또는질소, 산소, 인, 규소및 황으로이루어진군으로부터선택된하나이상의헤테로원자를포함하는작용기이다]. | ||||||
| 12 | 개질된 중합체의 제조시 실란올을 제거하는 방법 | KR1020117013383 | 2009-11-11 | KR1020110094056A | 2011-08-19 | 틸레스벤; 뵘요헨; 얀치노르베르트; 베른트크리스티아네 |
| 본 발명은 (a) 공액 디엔 및 방향족 알파-올레핀을 중합된 형태로 포함하는 개질된 인터폴리머 또는 (b) 공액 디엔을 중합된 형태로 포함하는 개질된 중합체로부터 선택되는 중합체의 제조방법의 제공에 관한 것으로, 상기 방법은 하나 이상의 중합 반응기에서 하나 이상의 용매의 존재하에 하나 이상의 공액 디엔 단량체를 포함하는 단량체들을 중합시켜 중합체를 형성하는 단계, 임의로, 하나 이상의 커플링제를 사용하여 중합체 쇄들의 단편을 커플링시키는 단계, 하나 이상의 반응기에서 하나 이상의 용매의 존재하에 하나 이상의 개질제로 상기 중합체를 개질시켜, 개질된 중합체 용액을 형성하는 단계; 임의로, 상기 개질된 중합체 용액을 하나 이상의 양성자 공여 화합물과 접촉시키는 단계; 상기 개질된 중합체 용액을 물과 접촉시키는 단계; 상기 하나 이상의 용매를 제거하는 단계; 실란올과 반응하고/하거나 이것을 흡수할 하나 이상의 물질과 상기 제거된 용매를 접촉시켜 정제된 용매를 형성하는 단계, 상기 정제된 용매를 상기 하나 이상의 중합 반응기로 반송시켜 재순환시키거나 저장 용기로 재순환시키는 단계를 적어도 포함한다. | ||||||
| 13 | 수소화 중합체의 제조 방법 | KR1020057000994 | 2003-07-09 | KR1020050030952A | 2005-03-31 | 벨트조한네스빌헬무스; 드리에센마르코마르쿠스마테우스; 반블리이트게르하르트 |
| This invention relates to a process for the preparation of a hydrogenated polymer comprising the steps of hydrogenation of at least one carbon-carbon double bond of an unsaturated polymer in latex in the presence of hydrazine, an oxidizing compound and a catalyst, followed by separation of the hydrogenated polymer from the latex. After the separation of the hydrogenerated polymer from the latex a mixing step is carried out in which the hydrogenated polymer is first mixed with an amine group containing compound and next the hydrogenated polymer is mixed with a compound that is capable of reacting with an amine. The invention also relates to the hydrogenated polymer. The invention further relates to the use of this polymer in a compounds to make an article by shaping and vulcanisation. | ||||||
| 14 | 절연 유리의 봉함제 조성물 | KR1019830002601 | 1983-06-11 | KR1019840004935A | 1984-10-31 | 브루스이.스트리터-2 |
| 내용없음 | ||||||
| 15 | MOISTURE-CURABLE SILYLATED POLYMERS FOR FAST MOISTURE CURING COMPOSITIONS | PCT/US2006044677 | 2006-11-16 | WO2007061846A3 | 2007-11-08 | LIM THOMAS FAY-OY; CHU HSIEN-KUN |
| The present invention relates to a method of preparing moisture-curable silylated polymers by reacting amino- or carboxy-containing polymers with methylenehydrocarbyloxysilanes, and to the compositions formed thereby. In particular, the inventive compositions possess fast moisture-curable capabilities. Illustrative of the compositions of the present invention are those including a polymer of Formula (I). | ||||||
| 16 | CONJUGATED DIENE-BASED POLYMER AND METHOD FOR PRODUCING SAME, POLYMER COMPOSITION, CROSSLINKED POLYMER, AND TIRE | US15747932 | 2016-07-27 | US20180223008A1 | 2018-08-09 | Mitsunori INOUE; Takumi ADACHI; Kenji YANAGIBASHI; Ryoji TANAKA |
| A conjugated diene-based polymer comprising a structural unit derived from a conjugated diene compound and having, at a terminal of the polymer, at least one nitrogen-containing group represented by formula (1) is used. In formula (1), R1 is a hydrocarbyl group, and the symbol “*” is a bonding site. | ||||||
| 17 | Rubber Composition for Tires and Pneumatic Tire | US15507216 | 2015-08-24 | US20170283519A1 | 2017-10-05 | Yusuke Iizuka; Hiroki Sugimoto; Makoto Ashiura |
| A rubber composition for tires of the present technology contains a diene rubber, silica, a silane coupling agent, a fatty acid metal salt, and a predetermined alkyltrialkoxysilane; the diene rubber containing 60 mass % or greater of a modified conjugated diene rubber and 30 mass % or greater of a particular conjugated diene rubber which corresponds to a part or all of the modified conjugated diene rubber; an average glass transition temperature of the diene rubber being from −45 to −20° C.; the particular conjugated diene rubber being a conjugated diene rubber produced by a particular production method and having predetermined ranges of aromatic vinyl unit content, vinyl bond content, and weight average molecular weight. | ||||||
| 18 | Stabilization of polymers that contain a hydrolyzable functionality | US13911503 | 2013-06-06 | US09546237B2 | 2017-01-17 | Christine M. Rademacher; Terrence E. Hogan; Jessica C. Kurasch |
| A process for treating a polymer having a hydrolyzable functionality, the process comprising: (i.) providing a polymer having hydrolyzable functionality; (ii.) introducing an alkoxysilane to the polymer, where the alkoxysilane is defined by the formula I where R2 is a hydrocarbyl group, R3, R4, and R5 are each independently a hydrocarbyl group or a hydrocarbyloxy group; and (iii.) introducing a silane having a hydrolyzable functionality, where the silane is defined by the formula II where χ is a hydrolyzable group that forms an acidic species upon hydrolysis, where R6, R7, and R8 are each independently a halogen atom, a hydrocarbyl group, a hydrocarboxylate group, or a hydrocarbyloxy group. | ||||||
| 19 | Method for producing modified conjugated diene rubber, modified conjugated diene rubber, and rubber composition | US13991005 | 2011-11-28 | US08980987B2 | 2015-03-17 | Ryouji Tanaka; Naoya Nosaka |
| This invention relates to a method for producing a modified conjugated diene rubber wherein the method involves: (a) a step in which a conjugated diene polymer having an alkali metal or alkaline earth metal active end and obtained by polymerizing a conjugated diene compound or by polymerizing a conjugated diene compound with an aromatic vinyl compounds is reacted with a first alkoxysilane compound which has an alkoxysilyl group having two or more alkoxy groups and has a group protected by a protecting group wherein deprotection is possible to obtain a modified conjugated-diene polymer having an alkoxysilyl group; and (b) a step in which the modified conjugated-diene polymer is reacted with a second alkoxysilane compound which has an alkoxysilyl group. | ||||||
| 20 | Liquid polymer | US12263504 | 2008-11-02 | US08030397B2 | 2011-10-04 | Michael Joseph Rachita; Vanessa Marika Guscoff; Lawson Gibson Wideman |
| This invention discloses a process for manufacturing an elastomeric article by liquid injection molding, said process comprising the steps of: (I) heating a curable composition comprised of (1) a liquid polymer comprised of repeat units that are derived from a conjugated diolefin monomer, wherein said liquid polymer has a weight average molecular weight which is within the range of 5,000 to 100,000, and wherein the liquid polymer is functionalized with an amine moiety, (2) a carbonyl inhibited platinum catalyst, and (3) a tetrakis(dialkyl siloxy) silane crosslinking agent, to a temperature which is within the range of 30° C. to 100° C.; (II) injecting the heated curable composition into a mold at a temperature which is within the range of 100° C. to 210° C. to produce the elastomeric article; and (III) removing the elastomeric article from the mold. | ||||||
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