序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
1 一种的制备方法 CN201610109264.X 2016-02-26 CN105753341A 2016-07-13 程小伟; 杨永胜; 李早元; 张兴国; 郭小阳; 段艺; 李明; 刘健; 曹艳; 时宇
发明公开了一种的制备方法,依次包括以下步骤:将钙质原料、铝质原料、铁质原料、助熔剂及无乙醇按摩尔比为(24.5~30.9):(6~7.7)∶(6.1~15.7)∶1∶72.5进行混合和研磨,使原料的平均粒径≤5μm;将研磨后的原料进行干燥,对干燥后的原料进行压片处理,将压制的试片进行预烧结,冷却后进行气流粉碎,得到的粉体经高温煅烧后再进行骤冷即获得铁铝酸钙。本发明技术可靠、产率高、对原料的品质要求较低;制备的产品均匀度高、化学稳定性好、水化能强,适用于大规模工业生产,具有广阔的市场前景。
2 Spherical ionomer particles and production thereof US09508118 2000-06-14 US06447907B1 2002-09-10 Herbert Wolter; Carsten Gellermann
The invention relates to spherical or approximately spherical ionomer particles, comprising an inner area and an outer area which contains silicon ions. The cations of said outer area comprise a) at least one element which can occupy lattice sites of the silicon in silicate compounds, producing a negative excess of charge and b) at least one element which is selected from the elements of the first and second main groups and those that can appear in a divalent form and which can compensate for the negative excess of charge. Suitable methods for producing the inventive particles are all those methods for producing spherical or approximately spherical particles from a suspension dispersion, emulsion or similar and separating them from the surrounding solvent. Aerosol methods and especially, spray drying of suitable solutions, gels, sols or dispersions/suspensions can also be used. The inventive ionomer particles are especially suitable for use with acid-containing matrices as cements which can be used advantageously in dentistry for example.
3 Method for making improved ceramic cement compositions containing a dispersed seeded phase and a method and apparatus for producing seed crystals US09881509 2001-06-14 US06765153B2 2004-07-20 David M. Goodson
A method of controlling the physical properties of cement by adding a predetermined amount of a second phase to a first phase cementitious precursor. The second phase is added in the form of seed crystals having controlled sizes, shapes, and compositions. The seed crystals provide growth sites upon curing the cement for a second phase in the cement body. The curing is accelerated by the presence of the seed crystals. Control of the microstructure of the resulting cement body through controlled distribution and growth of the seed crystals enables the formation of a cement body having precisely controlled physical properties.
4 Method for making improved ceramic cement compositions containing a dispersed seeded phase and a method and appartatus for producing seed crystals US09881509 2001-06-14 US20030005860A1 2003-01-09 David M. Goodson
A method of controlling the physical properties of cement by adding a predetermined amount of a second phase to a first phase cementitious precursor. The second phase is added in the form of seed crystals having controlled sizes, shapes, and compositions. The seed crystals provide growth sites upon curing the cement for a second phase in the cement body. The curing is accelerated by the presence of the seed crystals. Control of the microstructure of the resulting cement body through controlled distribution and growth of the seed crystals enables the formation of a cement body having precisely controlled physical properties.
5 SPHÄRISCHE IONOMERPARTIKEL UND DEREN HERSTELLUNG EP99938322.7 1999-07-22 EP1114006B1 2002-10-09 WOLTER, Herbert; GELLERMANN, Carsten
The invention relates to spherical or approximately spherical ionomer particles, comprising an inner area and an outer area which contains silicon ions. The cations of said outer area comprise a) at least one element which can occupy lattice sites of the silicon in silicate compounds, producing a negative excess of charge and b) at least one element which is selected from the elements of the first and second main groups and those that can appear in a divalent form and which can compensate for the negative excess of charge. Suitable methods for producing the inventive particles are all those methods for producing spherical or approximately spherical particles from a suspension, dispersion, emulsion or similar and separating them from the surrounding solvent. Aerosol methods and especially, spray drying of suitable solutions, gels, sols or dispersions/suspensions can also be used. The inventive ionomer particles are especially suitable for use with acid-containing matrices as cements which can be used advantageously in dentistry for example.
6 Spherical hydraulic material and a method of manufacturing the same JP51722891 1991-11-01 JP3176919B2 2001-06-18 健一 服部; 悦郎 朝倉; 康弘 深田; 浩幸 藤澤
7 Production of spherical cement particle JP13149189 1989-05-26 JPH02311338A 1990-12-26 SUZUKI NOBUO; TANAKA ISAO; TAKE TAKAO; KOISHI MASUMI; HONDA HIROTAKA
PURPOSE:To enable production of the subject cement excellent in fluidity, having high strength and capable of providing a cement concrete having high durability by crushing cement clinker fine-particles and forming spherical particles using the impact method in a high-speed air flow. CONSTITUTION:Raw fine-particle cement in a hopper is supplied to a ring-impact chamber 7 from a shoot 13 of a machine for impact in high-speed air flow and scattered by rotating the chamber 7 using rotation of a rotary plate 4 and blades 5 attached thereto. During the abovementioned process, the cement fine-particles are forced to collide with a triangular channel on the surface of a ring-stator 8 and with the blades 5 while rotating. The cement fine-particles are then introduced into a circulating pipe 12 from one end opening of the pipe 12 opening to the chamber 7, circulated and subsequently introduced the chamber 7 from the other end opening again. The abovementioned rotational collision is continued till the cement particles are formed into a required sphere followed by taking-out of the resultant spherical cement particles from a shoot 11.
8 Production process of ground cement JP33211199 1999-11-22 JP2001151542A 2001-06-05 YAMAMOTO YOZO; YAMAMOTO KATSUMI; SUEMATSU TADASHI; YANAGAWA YASUSHI
PROBLEM TO BE SOLVED: To provide a cement grinding process, highly durable ready-mixed concrete and a ground cement production process and in particular, to provide a cement grinding technique which enables efficient grinding of cement into ground cement whose particles have roundness and minuter particle size, by using, as a raw material cement, cement conventionally available as a commercial product, mixing the raw material cement with a processing material and agitating the resulting mixture. SOLUTION: This production process comprises mixing raw material cement with a processing material (such as clinker, limestone or crushed stone) having particle size larger than the average particle size of the raw material cement. COPYRIGHT: (C)2001,JPO
9 Device for producing spherical hydraulic substance JP9406192 1992-04-14 JPH05294687A 1993-11-09 HATTORI KENICHI; ASAKURA ETSURO
PURPOSE: To obtain the spherical hydraulic substance useful for producing highly strong moldings by spraying and cooling the melted hydraulic substance. CONSTITUTION: A cement raw material is melted in a melting oven 1 and subsequently transferred into a holding oven 3. The holding oven 3 has a nozzle 4 thereunder. The melted product 2 is sprayed into a tank 5 through the nozzle together with a high pressure gas charged from a high pressure gas bomb 8 or compressor. In the tank, the sprayed melted product is cooled into a spherical or powdery cement due to its surface tension during the process, and the cement is recovered in powder tanks 7 through a cyclone 6. A vacuum method or a centrifugal method except the gas atomization method is adopted. A cement raw material such as lime stone, clay, silica, slag, bauxite or iron raw material, a proper combination of coal ash, incineration ash, etc., or a hydraulic substance such as a cement or a cement clinker or their mixture is employed as the raw material. The diameter, particle distribution and crystallinity of the spherical particles are controlled by changing the surface tension, particle size, spraying condition and cooling condition of the melted substance. COPYRIGHT: (C)1993,JPO&Japio
10 Spherical powder JP2000385041 2000-12-19 JP2002187749A 2002-07-05 TAKADA MINORI; HOSHINO SEIICHI; MATSUURA SHIGERU
PROBLEM TO BE SOLVED: To provide a spherical powder capable of easily being produced and of being used as a hydraulic powder. SOLUTION: This spherical powder consists essentially of CaO and Al2O3 as chemical component and is produced by heating and fusing a CaO raw material and an Al2O3 raw material, and thereafter, blowing the resulting fused material by high-pressure air or the like, to scatter the material, wherein preferably, the spherical powder contains 30-60 wt.% CaO and 40-70 wt.% Al2O3 in terms of the total content of CaO and Al2O3.
11 Method for producing a composite type spherical cement JP13149189 1989-05-26 JP2832201B2 1998-12-09 SUZUKI NOBUO; TANAKA ISAO; TAKE TAKAO; KOISHI MASUMI; PPONDA HIROTAKA
12 Cement and production thereof and concrete made therefrom EP91300059.2 1991-01-04 EP0437324A3 1993-03-10 Suzuki, Nobuo; Tanaka, Isao; Takeshi, Takao

Spherical cement particles are produced by (a) grinding cement clinker particles by a high speed impact treatment in apparatus of Fig. 1 wherein the particles are rotated and scattered by blades on a rotating plate and multiply impacted until (Fig. 6) the particles are spherical, or (b) by mechanochemical surface fusion.

The sphered cement may be encapsulated (Fig. 3) by attaching fine cement powder, silica-fume or other powder to its surface.

These sphered particles preferably have at least 60 wt% thereof of diameter 3.9 to 30 µm.

Before the particles have been completely sphered, the powder formed therefrom can be attached (Fig. 5) to fill the recesses in the particles, thus rounding them.

Alternatively (Fig. 4), silica fume particles are coated with ultrafine particles of cement clinker.

Cement mortar is made from the cements, or low-hydration concrete using the sphered cement, aggregate and water in a proportion of 1:2.5 to 8.0:0.17 to 0.75. The resultant cured concrete is of high strength.

13 SPHERICAL HYDRAULIC SUBSTANCE AND PRODUCTION THEREOF EP91918995.1 1991-11-01 EP0513367A1 1992-11-19 HATTORI, Ken-ichi; ASAKURA, Etsuro, Mitsubishi Materials Corporation; FUKUTA, Yasuhiro, Mitsubishi Materials Corporation; FUJISAWA, Hiroyuki, Mitsubishi Materials Corp.

A spherical hydraulic substance comprising a hydraulic powder based on CaO, SiO₂, Al₂O₃ and Fe₂O₃, wherein at least the surface of the powder is melted for smoothening and then cooled and the powder has a particle diameter of 500 µm or less and a means circularity of 0.7 or above. This substance is produced either by melting the starting material mainly comprising the above oxides, followed by splashing to effect cooling for solidification, or melting at least the surface of the hydraulic substance, followed by cooling for solidification. Alternatively it is produced by mixing a hot substance such as iron making slag in a state molten or heated above 500°C with a dried, calcined, sintered or molten starting material based on at least one oxide selected among CaO, SiO₂, Al₂O₃ and Fe₂O₃ and splashing the molten mixture to effect cooling for solidification. Since this substance is a minute spherical particle having a smooth surface and a shape close to a true sphere, it is remarkably excellent in fluidity and strength when kneaded with water.

14 Cement and production thereof and concrete made therefrom EP91300059.2 1991-01-04 EP0437324A2 1991-07-17 Suzuki, Nobuo; Tanaka, Isao; Takeshi, Takao

Spherical cement particles are produced by (a) grinding cement clinker particles by a high speed impact treatment in apparatus of Fig. 1 wherein the particles are rotated and scattered by blades on a rotating plate and multiply impacted until (Fig. 6) the particles are spherical, or (b) by mechanochemical surface fusion.

The sphered cement may be encapsulated (Fig. 3) by attaching fine cement powder, silica-fume or other powder to its surface.

These sphered particles preferably have at least 60 wt% thereof of diameter 3.9 to 30 µm.

Before the particles have been completely sphered, the powder formed therefrom can be attached (Fig. 5) to fill the recesses in the particles, thus rounding them.

Alternatively (Fig. 4), silica fume particles are coated with ultrafine particles of cement clinker.

Cement mortar is made from the cements, or low-hydration concrete using the sphered cement, aggregate and water in a proportion of 1:2.5 to 8.0:0.17 to 0.75. The resultant cured concrete is of high strength.

15 SPHÄRISCHE IONOMERPARTIKEL UND DEREN HERSTELLUNG EP99938322.7 1999-07-22 EP1114006A1 2001-07-11 WOLTER, Herbert; GELLERMANN, Carsten
The invention relates to spherical or approximately spherical ionomer particles, comprising an inner area and an outer area which contains silicon ions. The cations of said outer area comprise a) at least one element which can occupy lattice sites of the silicon in silicate compounds, producing a negative excess of charge and b) at least one element which is selected from the elements of the first and second main groups and those that can appear in a divalent form and which can compensate for the negative excess of charge. Suitable methods for producing the inventive particles are all those methods for producing spherical or approximately spherical particles from a suspension, dispersion, emulsion or similar and separating them from the surrounding solvent. Aerosol methods and especially, spray drying of suitable solutions, gels, sols or dispersions/suspensions can also be used. The inventive ionomer particles are especially suitable for use with acid-containing matrices as cements which can be used advantageously in dentistry for example.
16 SPHERICAL HYDRAULIC SUBSTANCE AND PRODUCTION THEREOF EP91918995.1 1991-11-01 EP0513367B1 1996-06-12 HATTORI, Ken-ichi; ASAKURA, Etsuro, Mitsubishi Materials Corporation; FUKUTA, Yasuhiro, Mitsubishi Materials Corporation; FUJISAWA, Hiroyuki, Mitsubishi Materials Corp.
A spherical hydraulic substance comprising a hydraulic powder based on CaO, SiO2, Al2O3 and Fe2O3, wherein at least the surface of the powder is melted for smoothening and then cooled and the powder has a particle diameter of 500 νm or less and a means circularity of 0.7 or above. This substance is produced either by melting the starting material mainly comprising the above oxides, followed by splashing to effect cooling for solidification, or melting at least the surface of the hydraulic substance, followed by cooling for solidification. Alternatively it is produced by mixing a hot substance such as iron making slag in a state molten or heated above 500 °C with a dried, calcined, sintered or molten starting material based on at least one oxide selected among CaO, SiO2, Al2O3 and Fe2O3 and splashing the molten mixture to effect cooling for solidification. Since this substance is a minute spherical particle having a smooth surface and a shape close to a true sphere, it is remarkably excellent in fluidity and strength when kneaded with water.
17 APPARATUS FOR PRODUCING SPHERICAL HYDRAULIC MATERIAL EP93908081 1993-04-13 EP0593779A4 1996-06-05 HATTORI KENICHI; ASAKURA ETSURO
An apparatus for producing a spherical hydraulic material comprises a melting furnace (1) for melting raw materials of a hydraulic material and/or the hydraulic material, fine granulation means for finely granulating the molten material (2) such as a nozzle (4) or a high speed rotary member, a chamber (5) for accepting the finely granulated material, cooling it and converting it into spherical fine powder, and means (6, 7) for recovering the spherical fine powder. When the material molten in the melting furnace enters the chamber and is finely granulated, the molten material is immediately formed into a complete sphere because its surface tension is relatively great, and is cooled and recovered as the spherical fine powder. The resulting spherical hydraulic material is highly fluidized by a small amount of water, and turns to a molded article having high strength and high durability, and moreover, having an excellent dimensional accuracy. Spherical hydraulic material which is approximately in the form of a complete sphere, is extremely smooth on the particle surface and exhibits high fluidity can be obtained by using this apparatus. This hydraulic material can be produced without limiting the blend ratio of the starting components, and various ashes of an incinerator can be utilized as the hydraulic material. Moreover, maintenance becomes easy.
18 APPARATUS FOR PRODUCING SPHERICAL HYDRAULIC MATERIAL EP93908081.8 1993-04-13 EP0593779A1 1994-04-27 HATTORI, Kenichi; ASAKURA, Etsuro, Cement Lab, Mitsubishi

An apparatus for producing a spherical hydraulic material comprises a melting furnace (1) for melting raw materials of a hydraulic material and/or the hydraulic material, fine granulation means for finely granulating the molten material (2) such as a nozzle (4) or a high speed rotary member, a chamber (5) for accepting the finely granulated material, cooling it and converting it into spherical fine powder, and means (6, 7) for recovering the spherical fine powder. When the material molten in the melting furnace enters the chamber and is finely granulated, the molten material is immediately formed into a complete sphere because its surface tension is relatively great, and is cooled and recovered as the spherical fine powder. The resulting spherical hydraulic material is highly fluidized by a small amount of water, and turns to a molded article having high strength and high durability, and moreover, having an excellent dimensional accuracy. Spherical hydraulic material which is approximately in the form of a complete sphere, is extremely smooth on the particle surface and exhibits high fluidity can be obtained by using this apparatus. This hydraulic material can be produced without limiting the blend ratio of the starting components, and various ashes of an incinerator can be utilized as the hydraulic material. Moreover, maintenance becomes easy.

19 EP0513367A4 - EP91918995 1991-11-01 EP0513367A4 1994-03-23 HATTORI, KEN-ICHI; ASAKURA, ETSURO, MITSUBISHI MATERIALS CORPORATION; FUKUTA, YASUHIRO, MITSUBISHI MATERIALS CORPORATION; FUJISAWA, HIROYUKI, MITSUBISHI MATERIALS CORP.
QQ群二维码
意见反馈