专利检索_ .其中至少有两个但不是所有的硅原子是与氧以外的原子键合专利检索_ .其中至少有两个但不是所有的硅原子是与氧以外的原子键合专利检索查询

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序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
141	Room temperature curable organopolysiloxanes	US36842773	1973-06-08	US3826782A	1974-07-30	LENGNICK G
THE INVENTION RELATES TO CURABLE ONE-COMPONENT ORGANOPOLYSILOXANES OBTAINED FROM THE REACTION OF A HYDROXYLTERMINATED ORGANOPOLYSILOXANE AND THE NOVEL DISILANE CROSS-LINKING AGENTS HAVING FUNCTIONAL GROUPS WHICH ARE HYDROLYZABLE IN AMBIENT MOISTURE.
142	Siloxane polymers for soil-repellent and soil-release textile finishes	US3716517D	1972-03-02	US3716517A	1973-02-13	PITTMAN A; WASLEY W
FLUOROCARBON SILANES ARE COPOLYMERIZED WITH SILANES WHICH CONTAIN TWO OR MORE ALKYLENEOXY GROUPS. THE COPOLYMERS ARE USEFUL FOR APPLICATION TO FIBROUS MATERIALS TO PROVIDE BOTH SOIL EPELLENCY AND SOIL RELEASABILITY.
143	Siloxane polymers for soil-repellent and soil release textile finishes	US3702859D	1971-07-09	US3702859A	1972-11-14	PITTMAN ALLEN G; WASLEY WILLIAM L
FLUOROCARBON SILANES ARE COPOLYMERIZED WITH SILANES WHICH CONTAIN TWO OR MORE ALKYLENEOXY GROUPS. THE COPOLYMERS ARE USEFUL FOR APPLICATION TO FIBROUS MATERIALS TO PROVIDE BOTH SOIL REPELLENCY AND SOIL RELEASABILITY.
144	Method of producing 1,3-bis (hydroxyaryl) tet raorganosiloxanes	US3697569D	1971-02-04	US3697569A	1972-10-10	MIRONOV VLADIMIR FLOROVICH; FEDOTOV NIKOLAI SEMENOVICH; KOZLIKOV VADIM LVOVICH
A method of producing 1,3 bis-(hydroxyaryl) tetraorganodisiloxanes of the general formula WHERE R is alkyl, CONSISTING IN THAT A DIORGANOHYDROSILYL HALOPHENOL ESTER IS REACTED WITH MAGNESIUM IN AN ORGANIC SOLVENT MEDIUM. Then the solvent is distilled off, the reaction mixture is heated to a temperature of 150-180C, is treated with a 10-15 percent solution of a mineral acid, thus isolating diorganohydroxilylsubstituted phenols of the general formula WHERE R is alkyl. The obtained compounds of the above-mentioned general formula are subjected to hydrolysis in the presence of a catalyst such as powdered copper, powdered nickel, powdered iron, an organic or inorganic base, hydroxide or alcoholate of alkali metals, or are subjected to alcoholysis in the presence of the above-said catalysts followed by hydrolysis. After that condensation of the diorganohydroxysilylphenols is effected under a vacuum at a temperature of 35-60C and a residual pressure of 1-2 mm Hg. The 1,3 bis-(hydroxyaryl) tetraorganodisiloxanes are used for synthesis of polymers having a high terminal stability.
145	Reaction products of silicon monoxide and organic halides and methods of making the same	US3660451D	1970-08-24	US3660451A	1972-05-02	SCHASCHEL ERICH T
ORGANO SILICON POLYMERS ARE PREPARED BY THE REACTION OF SILICON MONOXIDE AND AN ORGANIC MONOHALIDE SUCH AS 1-CHLORO-BUTANE TO PROVIDE A POLYMER THAT IS USEFUL AS A LUBRICANT, STOP-COCK GREASE AND AS A FILLER FOR CERAMIC AND PLASTIC COMPOSITIONS.
146	Reaction products of silicon monoxide and aromatic compounds such as benzene and methods of making the same	US3660450D	1970-03-03	US3660450A	1972-05-02	TIMMS PETER L
AN ORGANO SILICON POLYMER IS PREPARED BY THE REACTION OF SILICON MONOXIDE AND AN AROMATIC COMPOUND SUCH AS BENZENE TO PROVIDE A POLYMER THAT IS USEFUL AS A LUBRICANT, AS AN INGREDIENT FOR A COATING COMPOSITION AND AS A FILLER FOR PLASTIC COMPOSITIONS.
147	Reaction products of silicon monoxide and acetylenes and methods of preparing the same	US3660449D	1970-03-03	US3660449A	1972-05-02	SCHASCHEL ERICH T
AN ORGANO SILICON POLYMER IS PREPARED BY THE REACTION OF SILICON MONOXIDE AND AN ORGANIC COMPOUND CONTAINING A TRIPLE BOND SUCH AS ACETYLENE TO PROVIDE A POLYMER THAT IS USEFUL AS A LUBRICANT, AS A COATING COMPOSITION INGREDIENT AND AS A FILLER FOR PLASTIC COMPOSITIONS.
148	Equilibrated organo-polysiloxane mixtures with terminal sulfuric acid groups and process for their preparation	US3655712D	1970-01-28	US3655712A	1972-04-11	ROSSMY GERD
A LINEAR EQUILIBRATED ORGAN-POLYSILOXANE MIXTURE HAVING TERMINAL SULFURIC ACID GROUPS OF THE GENERAL FORMULA HO3S-O-(SI(-R)2-O)N-SO3H WHEREIN N=2 TO 20 AND R IS HYDROCARBON WHICH MAY BE SUBSTITUTED BY A GROUP INERT IN RESPECT TO SULFURIC ACID. A PORTION OF THE HYDROCARBON GROUPS R MAY BE REPLACED BY THE GROUP -O-(SI(-R)2-O)N-SO3H THE APPLICATION ALSO DISCLOSES A PROCESS FOR THE PREPARATION OF SUCH EQUILIBRATED ORGANO-POLYSILOXANE MIXTURES WHICH ARE IN EQUILIBRIUM WITH SULFURIC ACID AND CYCLIC COMPOUNDS OF THE GENERAL FORMULA ((SI(-R)2-O)N-SO3)M WHEREIN R AND N HAVE THE ABOVE MEANING, M BEING 1-10. IF A PORTION OF THE R GROUPS OF FORMULA I IS REPLACED BY GROUPS OF FORMULA V, THEN TWO OF THE FORMULA V GROUPS MAY FORM THE GROUP -O-(SI(-R)2-O)N-SO3-(SI(-R)2-O)N- ON THAT SIDE OF THE EQUILIBRIUM WHICH CONTAINS THE FORMULA II COMPOUNDS AND THE FREE SULFURIC ACID. THE NOVEL MIXTURES ARE USEFUL AS EQUILIBRATION CATALYSTS FOR ORGANOPOLYSILOXANES. THEY MAY ALSO SUCCESSFULLY BE EMPLOYED AS IMPREGNATION AGENTS FOR IMPARTING VARIOUS MATERIALS SUCH AS GLASS, TEXTILES, AND THE LIKE WITH WATER REPELLENT CHARACTERISTICS.
149	Bis-silylphenyl carbonates	US3595974D	1969-05-21	US3595974A	1971-07-27	LLOYD NORMAN C; PEARCE CHRISTOPHER A; PATTISON IAN
BIS-SILYLPHENYLCARBONATES OF THE GENERAL FORMULA 1-((4-(R2-SI(-Q)-)PHENYL)-O-CO-O-),4-(R2-SI(-Q)-)BENZENE WHERE Q IS H, HALOGEN, ALKOXY, MONOVALENT HYDROCARBON RADICAL OR -OH, AND R IS ALKYL, ALKENYL OR ARYL RADICAL AND PREPARATION THEREOF BY REACTING THE CORRESPONDING SILYLATED PHENOLS WITH AN ESTER-FORMING DERIVATIVE OF CARBONIC ACID SUCH AS PHOSGENE AND CORRESPONDING POLYMERS AND COPOLYMERS PREPARED BY HYDROLYSIS OF Q GROUPS FROM THE SILICON ATOMS.
150	Branched organopolysiloxanes containing terminal hydroxy groups	US3488372D	1964-07-22	US3488372A	1970-01-06	ROSSMY GERD; WASSERMEYER JAKOB

151	Fluorinated organosilicon compounds	US3458554D	1965-06-16	US3458554A	1969-07-29	HALUSKA LOREN A

152	Silicon- and nitrogen-containing fourmembered ring compounds and process for preparing	US60078166	1966-12-12	US3414584A	1968-12-03	WALTER FINK

153	Carbonyl-containing organosilicon materials	US59111766	1966-11-01	US3410822A	1968-11-12	WILKUS EDWARD V; ABE BERGER
The invention comprises carbonyl-containing silanes and siloxanes of formula (I) and copolymers and homopolymers derived therefrom. The homopolymers consist essentially of units of the formula (II) and the copolymers consist of 0.01 to 99.99 mole per cent of units of Formula (II) combined with 99.99 to 0.01 mole per cent of units of formula In the above formulae R is a monovalent halogenated or unhalogenated hydrocarbon radical or a cyanoalkyl radical, R1 is a divalent halogenated or unhalogenated hydrocarbon radical, A is hydrogen, an R radical, a halogen atom or an alkoxy radical, Z is an arylene radical, a divalent aryl ether radical of the type -Ar-O-Q-where Ar is an arylene radical and Q is a hydrocarbon radical, a divalent five-membered heterocyclic aromatic radical having a Group VIa element as the hetero atom, or a substituted derivative thereof, Y is or an alkylene radical, a is 0 or 1, b is 2 or 3, c is 0, 1 or 2 and d is 1, 2 or 3. The compounds of Formula (I) are prepared by acylating an aryl nucleus, including the above defined heterocycles, with a silyl acid halide of formula where X is a halogen atom. If these monoacylated compounds contain a methylene group alpha to the aryl nucleus, they may be converted to the diacylated compounds by oxidation of the methylene group. Alternatively the diacylated compound may be prepared by reducing the carbonyl group of a monoacylated compound to a methylene group with a metal hydride e.g. LiACH4 in the presence of aluminium diboride, acylating the product to produce a carbonyl group attached to the aryl nucleus and then oxidizing the methylene group back to a carbonyl group. Polymers and copolymers may be prepared by hydrolysing these compounds or cohydrolysing them with an organo halo silane. Examples describe the preparation of p(trimethysilylethyl) trimethylsilylbutyrylbenzene, a homopolymer of the formula a copolymer comprising about 5 mole per cent of units derived from this combined with about 95 mole per cent of dimethylsiloxy units, and a vulcanizing composition prepared by mixing the homopolymer of Example 2, ethyl polysilicate and dibutyl tin dilaurate.
154	Curing catalyst system for si-h additions	US42085764	1964-12-18	US3385876A	1968-05-28	NIELSEN JOHN M

155	Moisture curable polysiloxane phosphate composition	US65059167	1967-07-03	US3385822A	1968-05-28	BROWN JR EDGAR D

156	Method of polymerizing siloxanes and silcarbanes in emulsion	US36835264	1964-05-18	US3360491A	1967-12-26	AXON GORDON L

157	Silylorganocyclopentadienylmetalcarbonyls and process therefor	US28352663	1963-05-27	US3329695A	1967-07-04	WILKUS EDWARD V; ABE BERGER

158	Organosilicon compounds	US27768163	1963-05-03	US3313837A	1967-04-11	GERD ROSSMY; GOTZ KOERNER

159	Random siloxane copolymers containing phenylene and phenyl ether chain linkages	US14162261	1961-09-29	US3287310A	1966-11-22	OMIETANSKI GEORGE M

160	Organosilicon compounds, methods of preparation and use	US25174163	1963-01-16	US3278484A	1966-10-11	TESORO GIULIANA C
1,054,282. Coatings. J. P. STEVENS & CO. Inc. Jan. 16 1964 [Jan. 16, 1963], No. 2017/64. Heading B2E. [Also in Divisions C3 and D1] Glass fibre, yarn or fabric is coated with amino-mercapto silicon compounds of the formula: A'A"A"'Si-X-NR'-CH 2 CH 2 SH and siloxanes and disulphides derived therefrom, prior to adhesion to vulcanisable materials, e.g. rubber, or resins such as epoxy resins, unsaturated polyester resins or phenolic resins, where A', A" and A"' are hydrolysable groups X is -CH 2 - or a divalent organic radical, R' is H or a substituted or unsubstituted aliphatic. The Examples describe the coating of glass fabric by (14) and (15) aqueous acetic and xylene/ acetic acid solutions of (EtO) 3 Si(CH 2 )NHCH 2 SH the product being cured by heating; in (16) a similar compound is used.

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