101 |
초저 수준의 유기 황 화합물을 갖는 디젤 연료를 제조하기 위한 기상 산화적 탈황 및 수소화탈황을 통합한 표적화된 탈황 방법 및 장치 |
KR1020147024686 |
2013-01-30 |
KR1020150105905A |
2015-09-18 |
보우란,압데누어; 코서그루,오메르,리파; 이스마기로브,진퍼; 야스닉,스베트라나; 케르젠트세브,미크하일; 파르몬,발랜틴 |
탄화수소 공급물의 탈황은 표적 차단점 온도에서 공급물을 플래시 처리하여 2개의 분획을 얻음으로써 성취된다. 제1 분획은 표적 차단점 온도 이상에서 비등하는 내화성 유기 황 화합물을 함유한다. 표적 차단점 온도 미만에서 비등하는 제2 분획은 내화성 황-함유 화합물을 실질적으로 포함하지 않는다. 제2 분획은 온화한 조건 하에 조작되는 수소화탈황 반응 구역에서 수소화탈황 촉매와 접촉하여 유기 황 화합물의 분량을 초저 수준으로 감소시킨다. 제1 분획은 기상 촉매 산화 반응 구역에서 화학식 Cu
x Zn
1
-
x Al
2 O
4 를 갖는 산화 촉매 위에서 가스 산화제와 접촉하여 내화성 유기 황 화합물을 내지 SO
x 및 저황 탄화수소로 전환한다. 부산물 SO
x 는 이후 제거되어, 감소된 수준의 유기 황 화합물을 함유하는 스트림을 제조한다.
|
102 |
인-시튜 유기 과산화물 생산 및 산화성 이종원자 전환을 위한 통합 시스템 및 공정 |
KR1020147005202 |
2012-06-28 |
KR1020140049036A |
2014-04-24 |
알-샤흐라니,파르한,엠.; 코세오글루,오머레파; 보우렌,아브데노우어 |
산화 처리 공정, 예를 들어, 산화 탈황 또는 탈질소는 제공되며, 여기서 산화제는 본래의 액체 탄화수소 공급원료의 방향족-풍부 부분을 사용하여 인-시튜 생산된다. 상기 공정은 산화 처리 공정에서 과산화수소, 유기 과산화물 및 유기 하이드로퍼옥사이드와 같은 액체 산화제의 별도의 도입에 대한 필요를 감소 또는 대체한다.
|
103 |
석유 정제 방법 |
KR1020037006996 |
2001-11-30 |
KR100800286B1 |
2008-02-04 |
이노마타마코토; 후지무라야수시; 오카다츄요시; 이무라코조; 사사키하지미 |
The oil refining method according to the present invention comprises the fractional distillation process 1 for distilling and separating the feed oil into the distillate M1 and the residue M2; the hydrorefining process 2 wherein at least a part of the distillate M1 is refined by hydrogenation and desulfurized thereby to obtain the hydrorefined oil M3; the solvent deasphalting process 3 wherein the residue M2 is deasphalted with a solvent thereby to obtain the deasphalted oil M4 as an extract and asphaltene (pitch) M5 as the residue; the hydrodemetalizating/desulfurizing process 4 wherein at least a part of the deasphalted oil M4 is demetalized and desulfurized by hydrogenation thereby to obtain the HDMS refined oil M6; and the first mixing process 5 wherein a part of the HDMS refined oil M6 and at least a part of the hydrorefined oil M3 are mixed thereby to produce oil products. <IMAGE> |
104 |
Integrated process for converting crude oil to high value petrochemicals |
US18152941 |
2023-01-11 |
US11840672B2 |
2023-12-12 |
Ponoly Ramachandran Pradeep; Shahil Siddiqui; Vineeth Venu Nath; Darshankumar Manubhai Dave; Mainak Sarkar; Satyen Kumar Das; Madhusudan Sau; Sankara Sri Venkata Ramakumar |
The present invention relates to a process and system for complete conversion of crude oils by integrating Desalter unit, Atmospheric and vacuum column, high severity FCC process, Naphtha cracking process, residue slurry hydrocracking process, Delayed coking process, Selective mild hydrocracking aromatic production unit, Dehydrogenation units, Aromatic/olefin recovery section, gasifier unit along with syngas to olefins conversion section. |
105 |
An Integrated Process For Converting Crude Oil To High Value Petrochemicals |
US18152941 |
2023-01-11 |
US20230227738A1 |
2023-07-20 |
Ponoly Ramachandran PRADEEP; Shahil SIDDIQUI; Vineeth Venu NATH; Darshankumar Manubhai DAVE; Mainak SARKAR; Satyen Kumar DAS; Madhusudan SAU; Sankara Sri Venkata RAMAKUMAR |
The present invention relates to a process and system for complete conversion of crude oils by integrating Desalter unit, Atmospheric and vacuum column, high severity FCC process, Naphtha cracking process, residue slurry hydrocracking process, Delayed coking process, Selective mild hydrocracking aromatic production unit, Dehydrogenation units, Aromatic/olefin recovery section, gasifier unit along with syngas to olefins conversion section. |
106 |
PROCESS SCHEME FOR MAXIMUM HEAVY OIL CONVERSION WITH STAGE ASPHALTENE REJECTION |
US18069556 |
2022-12-21 |
US20230193145A1 |
2023-06-22 |
Vinod Ramaseshan; Emad Al Subaie; Hector Infante; Jesse Williams; Rustam Ismagilov; Abdalaziz A. Al-Balawi; Ashok Kumar Choudhary |
Provided is a system to upgrade an input stream of a straight run vacuum residue or a cracked feedstock that includes a vacuum column, a hydrocracking unit, a high lift solvent deasphalting unit, a low lift solvent deasphalting unit, and a bitumen blowing unit or a pitch pelletizing unit, and optionally a hydrotreating reactor. The system and components thereof may pass a distillate and naphtha product, a light ends product, an asphaltene-lean heavy deasphalted oil stream, an asphaltene-rich pitch stream, a light deasphalted oil that is a lube base feed stock, a heavy oil stream, a bitumen and asphalt stream or a solid fuel. Further provided is a process, including introducing a straight run vacuum residue or a cracked feed stock into a system, and operating the system including a step of fractionating, a step of solvent stage deasphalting, and a step of hydrocracking. |
107 |
PROCESS FOR PRODUCTION OF NEEDLE COKE |
US17478692 |
2021-09-17 |
US20220089955A1 |
2022-03-24 |
Ponoly Ramachandran PRADEEP; Shivam Ashok DIXIT; Prantik MONDAL; Jitumoni BRAHMA; * RAJESH; Terapalli Hari Venkata Devi PRASAD; Satyen Kumar DAS; Madhusudan SAU; Gurpreet Singh KAPUR; Sankara Sri Venkata RAMAKUMAR |
High-quality graphite/needle grade coke is produced with reduced impurity levels and improved coefficient of thermal expansion using an integrated hydrotreatment, catalytic cracking and coking reaction sections, employing a combination of highly paraffinic hydrotreated VGO stream and aromatic CLO stream, which is thereafter processed in a delayed coking section. |
108 |
METHODS AND SYSTEMS OF STEAM STRIPPING A HYDROCRACKING FEEDSTOCK |
US16701983 |
2019-12-03 |
US20210163831A1 |
2021-06-03 |
Omer Refa Koseoglu |
A process for producing cracked hydrocarbons from a feedstock, which includes a top portion that boils below 375° C. and a bottom portion that boils above 375° C., may include stripping the feedstock in a stripper to isolate the top portion from the bottom portion, hydrocracking the bottom portion in one or more hydrocracking reactors to produce a hydrocracked effluent, separating the hydrocracked effluent in a separating unit to produce a light product stream, a distillate stream, and a heavy unconverted stream; and recycling the heavy unconverted stream to an earlier stage of the process. |
109 |
Polished turbine fuel |
US16780463 |
2020-02-03 |
US11015134B2 |
2021-05-25 |
Mohammed Wohaibi; Tom F. Pruitt |
Turbine fuel provided for large-scale land based turbines used by utilities for producing electricity and desalinated water, and for large mobile engines and turbines in marine and remote applications where only liquid fuels are available. Use results in less corrosion, ash formation and emissions (NOx, SOx, CO2 and noxious metals) than firing contaminated heavy crude, refinery residual oils or high sulfur fuel oils. Manufacture is by decontaminating crude oils, non-conventional crudes, and other highly contaminated feeds. Each fuel is produced as a single product of unit operations, not ex-plant blend of various refinery products, yet using an apparatus configuration less complex than conventional crude oil refining. These fuels can be fired by advanced high efficiency turbines of combined cycle power plants having hot flow paths and heat recovery steam generation systems susceptible to corrosion, which systems cannot otherwise risk contaminated heavy crudes or refinery residual oils feeds. |
110 |
Process for Upgrading Ultralight Crude Oil and Condensates |
US16552123 |
2019-08-27 |
US20210062100A1 |
2021-03-04 |
Michael F. Milam; Gerry Obluda |
A method comprising the steps of feeding condensate to a splitter unit; directing the resulting naphtha product to a naphtha hydrotreater and the resulting diesel product to a diesel hydrotreater; directing ULSD product from the diesel hydrotreater to ULSD storage and naphtha product from the diesel hydrotreater to the naphtha hydrotreater; directing treated naphtha product from the naphtha hydrotreater to a naphtha splitter; isomerizing the light naphtha product and reforming the heavy naphtha product; sending the isomerate and the reformate to a gasoline separator; directing the products to storage. |
111 |
SYSTEM FOR CONVERSION OF CRUDE OIL TO PETROCHEMICALS AND FUEL PRODUCTS INTEGRATING VACUUM RESIDUE HYDROPROCESSING |
US16555799 |
2019-08-29 |
US20200123456A1 |
2020-04-23 |
Mohammed Saeed AL-GHAMDI; Bader BaHammam; Naif AL OSAIMI; Sami BARNAWI |
Process scheme configurations are disclosed that enable conversion of crude oil feeds with several processing units in an integrated manner into petrochemicals. The designs utilize minimum capital expenditures to prepare suitable feedstocks for the steam cracker complex. The integrated process for converting crude oil to petrochemical products including olefins and aromatics, and fuel products, includes mixed feed steam cracking and gas oil steam cracking. Feeds to the mixed feed steam cracker include one or more naphtha fractions from hydroprocessing zones within the battery limits, including vacuum residue hydrocracking, within the battery limits, recycle streams from the C3 and C4 olefins recovery steps, and raffinate from a pyrolysis gasoline aromatics extraction zone within the battery limits. Feeds to the gas oil steam cracker include gas oil range intermediates from the vacuum gas oil hydroprocessing zone and the vacuum residue hydrocracking zone. |
112 |
Catalytic gasoline desulfurization method having also an olefin selective removal function |
US16343679 |
2017-05-16 |
US10619111B2 |
2020-04-14 |
Tianzhen Hao; Xuhui Gao |
The present invention provides a catalytic gasoline desulfurization method having also an olefin selective removal function, which comprises: when a catalytic gasoline is pre-hydrotreated, cutting into a light fraction, a middle fraction and a heavy fraction; performing liquid-liquid extraction desulfurization treatment on the middle fraction to produce a sulfur-poor oil and a rich solvent containing sulfur-rich oil; the light fraction back-extracting the rich solvent, using C5 olefin therein to replace a macromolecular acyclic olefin in the sulfur-rich oil, so as to gather together C5 iso-olefins, cycloolefins, aromatic hydrocarbons and sulfides in the sulfur-rich oil; performing hydrogenation, olefin-reduction and desulfurization treatment on the heavy fraction together with the sulfur-rich oil removed from the back-extracted rich solvent to saturate the olefin therein; and finally, preparing together with the sulfur-poor oil to produce a full range gasoline. The sulfur-content of the catalytic gasoline produced by the method of the present invention can be reduced to 10 ppm or less, the olefin content of the catalytic gasoline can be reduced to 22%, the olefin is saturated by up to 8 percentage, and the RON loss of the full range gasoline is 1.5 or less, so that while reducing the olefin content of the catalytic gasoline, it ensures the less octane number loss, thereby satisfying the olefin-reduction requirements upgraded in the gasoline National VI Standard for ethanol-gasoline supply area enterprises. |
113 |
Method for deep desulfurization of gasoline |
US14929247 |
2015-10-30 |
US09683183B2 |
2017-06-20 |
Liang Zhao; Jinsen Gao; Chunming Xu; Tianzhen Hao; Xiaona Han |
The present invention provides a method for deep desulfurization of gasoline. The method includes steps of: cutting a gasoline feedstock into light, medium, and heavy gasoline fractions; the medium gasoline fraction being subjected to adsorption desulfurization to obtain a desulfurized medium gasoline fraction; the heavy gasoline fraction being subjected to selective hydrodesulfurization to obtain a desulfurized heavy gasoline fraction; mixing the light gasoline fraction with the desulfurized medium gasoline fraction and the desulfurized heavy gasoline fraction to obtain a desulfurized gasoline, where, a cutting temperature of the light and the medium gasoline fractions is 35-60° C., a cutting temperature of the medium and the heavy gasoline fractions is 70-130° C. The method according to the present invention not only can realize deep desulfurization of gasoline, but also has a less loss of octane number. |
114 |
Naphtha cracking |
US14271399 |
2014-05-06 |
US09328299B2 |
2016-05-03 |
Gregory A. Funk; Mary Jo Wier |
A process for increasing the yields of light olefins and the yields of aromatics from a hydrocarbon stream is presented. The process includes a first separation to direct the light components that are not reformable to a cracking unit, with the remainder passed to a second separation unit. The second separation unit extracts normal components from the hydrocarbon stream to pass to the cracking unit. The resulting hydrocarbon stream with reduced light ends and reduced normals is passed to a reforming unit. |
115 |
Methods and Systems for Combined Oxidative and Hydrotreatment of Hydrocarbon Fuel |
US14417091 |
2013-07-23 |
US20150210949A1 |
2015-07-30 |
Roger Kai Lott; Kamalul Arifin Yusof |
A method for combined reductive and oxidative treatment of liquid hydrocarbon feedstock to form upgraded liquid fuel having increased cetane number and reduced sulfur content. The yield of upgraded liquid fuel having a given cetane number is higher than processes than only increase cetane number by oxidative treatment. The feedstock can be initially hydrotreated to reduce sulfur content followed by oxidative treatment to increase cetane number. A first portion of a hydrotreated intermediate stream can be oxidatively treated to yield high cetane number blending stock, which is combined with a second portion of the hydrotreated intermediate stream to yield upgraded liquid fuel having increased cetane number and reduced sulfur content. Combining hydrotreatment with oxidative treatment facilitated by high energy cavitation maximizes yield and fuel quality. |
116 |
TARGETED DESULFURIZATION PROCESS AND APPARATUS INTEGRATING GAS PHASE OXIDATIVE DESULFURIZATION AND HYDRODESULFURIZATION TO PRODUCE DIESEL FUEL HAVING AN ULTRA-LOW LEVEL OF ORGANOSULFUR COMPOUNDS |
US13741101 |
2013-01-14 |
US20140197074A1 |
2014-07-17 |
Abdennour Bourane; Omer Refa Koseoglu; Zinfer Ismagilov; Svetlana Yashnik; Mikhail Kerzhentsev; Valentin Parmon |
Desulfurization of hydrocarbon feeds is achieved by flashing the feed at a target cut point temperature to obtain two fractions. A first fraction contains refractory organosulfur compounds, which boils at or above the target cut point temperature. A second fraction boiling below the target cut point temperature is substantially free of refractory sulfur-containing compounds. The second fraction is contacted with a hydrodesulfurization catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level. The first fraction is contacted with gaseous oxidizing agent over an oxidation catalyst having a formula CuxZn1-xAl2O4 in a gas phase catalytic oxidation reaction zone to convert the refractory organosulfur compounds to SOx and low sulfur hydrocarbons. The by-product SOx is subsequently removed, producing a stream containing a reduced level of organo sulfur compounds. |
117 |
Process for the valorization of a charge of hydrocarbons and for reducing the vapour pressure of said charge |
US10653426 |
2003-09-03 |
US20050101821A1 |
2005-05-12 |
Patrick Briot; Vincent Coupard; Alain Forestiere; Eric Llido; Thierry Poussereau |
A process is described for the valorization of a charge of hydrocarbons and for reducing the vapour pressure of said charge, comprising three steps: a step a) consisting of separating said charge of hydrocarbons into a fraction (O1) comprising essentially compounds containing 5 carbon atoms, including at least 2% by weight of pentenes, a step b) consisting of placing said fraction (O1) in contact with a cut of hydrocarbons (O2) at least partly comprising hydrocarbons having a number of carbon atoms between 6 and 10, including at least 2% by weight of olefins, and a step c) consisting of separating the effluents originating from step b) into a gasoline cut (α) the upper distillation point of which is less than 100° C. and a kerosene cut (β) having a distillation range between 100° C. and 300° C. |
118 |
Process for desulphurizing gasoline by adsorption |
US10898173 |
2004-07-26 |
US20050092655A1 |
2005-05-05 |
Alexandre Nicolaos; Florent Picard |
The invention concerns a process for desulphurizing gasoline comprising a step for fractionating said gasoline under conditions in which a light fraction comprising the lightest thiophene compounds such as thiophene or methylthiophenes and a heavy fraction concentrating the heaviest aromatic sulphur-containing compounds are obtained. Said heavy fraction is treated by hydrodesulphurization, while the light fraction is brought into contact with a solid adsorbant to eliminate at least a portion of said light thiophene compounds. |
119 |
Process for the simultaneous treatment and fractionation of light
naphtha hydrocarbon streams |
US150573 |
1998-09-10 |
US6083378A |
2000-07-04 |
Gary R. Gildert; Willibrord A. Groten; Hugh M. Putman |
A process for concurrently fractionating and hydrotreating of a full range naphtha stream. The full boiling range naphtha stream is subjected to simultaneous hydrodesulfurization and splitting into a light boiling range naphtha and a heavy boiling range naphtha. The two boiling range naphthas are treated separately according to the amount of sulfur in each cut and the end use of each fraction. |
120 |
Hydrocarbon upgrading process |
US925001 |
1992-08-05 |
US5413698A |
1995-05-09 |
David L. Fletcher; Mohsen N. Harandi; Michael S. Sarli; Stuart S. Shih |
Low sulfur gasoline of relatively high octane number is produced from a catalytically cracked, sulfur-containing naphtha by hydrodesulfurization followed by treatment in a second step over a a first catalyst zone comprising a large pore size zeolite material and a second catalyst zone comprising an intermediate pore size material. Preferably, the large pore size material is zeolite beta and the intermediate pore size material is ZSM-5. The treatment in the second step restores the octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product with an octane number comparable to that of the feed naphtha. In favorable cases, using feeds of extended end point such as heavy naphthas with 95 percent points above about 380.degree. F. (about 193.degree. C.), improvements in both product octane and yield relative to the feed may be obtained. |