序号 | 专利名 | 申请号 | 申请日 | 公开(公告)号 | 公开(公告)日 | 发明人 |
---|---|---|---|---|---|---|
161 | SYSTEM AND METHOD FOR OIL FUEL BURNING INTEGRATED COMBINED CYCLE POWER GENERATION | PCT/JP2000/007988 | 2000-11-13 | WO01036566A1 | 2001-05-25 | |
A light portion is extracted from feed oil by a separation system. The light portion is then subject to a hydrotreatment to obtain impurity-removed fuel oil which is stored in an intermediate tank. A residue of the feed oil after extraction of the light portion is gasified to obtain syngas (H2 gas + CO gas) which is used as basic fuel for power generation in a power generation system. The fuel oil is fed to the power generation system as auxiliary fuel for supplementing the power generation based on the syngas. The power generation system includes a plurality of gas turbines and generators. The number of the gas turbines to be driven by the fuel oil is controlled to adjust the power generation amount depending on demand. | ||||||
162 | COUNTERCURRENT DESULFURIZATION PROCESS FOR REFRACTORY ORGANOSULFUR HETEROCYCLES | PCT/US2000/023470 | 2000-08-25 | WO01016256A1 | 2001-03-08 | |
A process for the hydrodesulfurization (HDS) of the multiple condensed ring heterocyclic organosulfur compounds present in petroleum and chemical streams. The stream is passed through at least one reaction zone countercurrent to the flow of a hydrogen-containing treat gas, and through at least one sorbent zone. The reaction zone contains a bed of Group VIII metal-containing hydrodesulfurization catalyst and the sorbent zone contains a bed of hydrogen sulfide sorbent material. | ||||||
163 | POLISHED TURBINE FUEL | EP19215294.0 | 2016-10-18 | EP3656835A1 | 2020-05-27 | WOHAIBI, Mohammed; PRUITT, Tom F. |
Turbine fuel provided is suitable for large-scale land based turbines used by utilities for producing electricity and desalinated water, and for large mobile engines and turbines in marine and remote applications where only liquid fuels are available. Use results in less corrosion, ash formation and emissions (NOx, SOx, CO2 and noxious metals) than firing contaminated heavy crude, refinery residual oils or high sulfur fuel oils. Manufacture is by decontaminating crude oils, nonconventional crudes, and other highly contaminated liquids such as refinery residual oils and high sulfur fuel oil. Each fuel is produced as a single product of unit operations, not an ex-plant blend of various refinery products yet using an apparatus configuration less complex than conventional crude oil refining. These fuels can be fired by advanced high efficiency turbine systems of combined cycle power plants having hot flow paths and heat recovery steam generation systems susceptible to corrosion, which systems cannot otherwise use contaminated heavy crude or refinery residual oils. |
||||||
164 | APPARATUS INTEGRATING GAS PHASE OXIDATIVE DESULFURIZATION AND HYDRODESULFURIZATION TO PRODUCE DIESEL FUEL HAVING AN ULTRA-LOW LEVEL OF ORGANOSULFUR COMPOUNDS | EP16183658.0 | 2013-01-30 | EP3118281B1 | 2018-10-17 | ISMAGILOV, Zinfer; YASHNIK, Svetlana; KERZHENTSEV, Mikhail; PARMON, Valentin; BOURANE, Abdenour; KOSEOGLU, Omer Refa |
Desulfurization of hydrocarbon feeds is achieved by flashing the feed at a target cut point temperature to obtain two fractions. A first fraction contains refractory organosulfur compounds, which boils at or above the target cut point temperature. A second fraction boiling below the target cut point temperature is substantially free of refractory sulfur-containing compounds. The second fraction is contacted with a hydrodesulfurization catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level. The first fraction is contacted with gaseous oxidizing agent over an oxidation catalyst having a formula Cu x Zn 1-x Al 2 O 4 in a gas phase catalytic oxidation reaction zone to convert the refractory organosulfur compounds to SO x and low sulfur hydrocarbons. The by-product SO x is subsequently removed, producing a stream containing a reduced level of organosulfur compounds. | ||||||
165 | PRODUCTION OF LOW SULFUR GASOLINE | EP16738993.1 | 2016-07-06 | EP3325575A1 | 2018-05-30 | HARANDI, Mohsen, N.; GREELEY, John, P.; CHUBA, Michael, R.; LU, Bryan, C. |
Systems and methods are provided for producing naphtha boiling range fractions having a reduced or minimized amount of sulfur and an increased and/or desirable octane rating and suitable for incorporation into a naphtha fuel product. A naphtha boiling range feed can be separated to form a lower boiling portion and a higher boiling portion. The lower boiling portion, containing a substantial amount of olefins, can be exposed to an acidic catalyst without the need for providing added hydrogen in the reaction environment. Additionally, during the exposure of the lower boiling portion to the acidic catalyst, a stream of light olefins (such as C2-C4 olefins) can be introduced into the reaction environment. Adding such light olefins can enhance the C5+ yield and/or improve the removal of sulfur from thiophene and methyl-thiophene compounds in the naphtha feed. | ||||||
166 | TARGETED DESULFURIZATION PROCESS AND APPARATUS INTEGRATING GAS PHASE OXIDATIVE DESULFURIZATION AND HYDRODESULFURIZATION TO PRODUCE DIESEL FUEL HAVING AN ULTRA-LOW LEVEL OF ORGANOSULFUR COMPOUNDS | EP13705303.9 | 2013-01-30 | EP2823021B1 | 2016-09-28 | BOURANE, Abdennour; KOSEOGLU, Omer, Refa; ISMAGILOV, Zinfer; YASHNIK, Svetlana; KERZHENTSEV, Mikhail; PARMON, Valentin |
167 | TARGETED DESULFURIZATION PROCESS AND APPARATUS INTEGRATING GAS PHASE OXIDATIVE DESULFURIZATION AND HYDRODESULFURIZATION TO PRODUCE DIESEL FUEL HAVING AN ULTRA-LOW LEVEL OF ORGANOSULFUR COMPOUNDS | EP13705303.9 | 2013-01-30 | EP2823021A1 | 2015-01-14 | BOURANE, Abdennour; KOSEOGLU, Omer, Refa; ISMAGILOV, Zinfer; YASHNIK, Svetlana; KERZHENTSEV, Mikhail; PARMON, Valentin |
Desulfurization of hydrocarbon feeds is achieved by flashing the feed at a target cut point temperature to obtain two fractions. A first fraction contains refractory organosulfur compounds, which boils at or above the target cut point temperature. A second fraction boiling below the target cut point temperature is substantially free of refractory sulfur-containing compounds. The second fraction is contacted with a hydrodesulfurization catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level. The first fraction is contacted with gaseous oxidizing agent over an oxidation catalyst having a formula Cu xZn 1-xAL 2O 4 in a gas phase catalytic oxidation reaction zone to convert the refractory organosulfur compounds to SO x and low sulfur hydrocarbons. The by-product SO x is subsequently removed, producing a stream containing a reduced level of organosulfur compounds. | ||||||
168 | COUNTERCURRENT DESULFURIZATION PROCESS FOR REFRACTORY ORGANOSULFUR HETEROCYCLES | EP00957843 | 2000-08-25 | EP1240275A4 | 2003-05-28 | SCHORFHEIDE JAMES JOHN; ELLIS EDWARD STANLEY; TOUVELLE MICHELE SUE; GUPTA RAMESH |
A process for the hydrodesulfurization (HDS) of the multiple condensed ring heterocyclic organosulfur compounds present in petroleum and chemical streams. The stream is passed through at least one reaction zone countercurrent to the flow of a hydrogen-containing treat gas, and through at least one sorbent zone. The reaction zone contains a bed of Group VIII metal-containing hydrodesulfurization catalyst and the sorbent zone contains a bed of hydrogen sulfide sorbent material. | ||||||
169 | PROCESS OF REMOVING SULFUR COMPOUNDS FROM GASOLINE | EP00977214 | 2000-11-15 | EP1294826A4 | 2003-05-14 | LEE FU-MING; GENTRY JOSEPH C; WYTCHERLEY RANDI WRIGHT; CRETOIU LUCIA; SHYAMKUMAR CALAMBUR |
Sulfur compounds are removed from a hydrocarbon stream. In a preferred embodiment, a gasoline stream from a fluid catalytic cracker is extractively distilled in an extractive distillation column (C-201) to reject olefins to a raffinate stream and simultaneously extract sulfur compounds to an extract stream. | ||||||
170 | SYSTEM AND METHOD FOR OIL FUEL BURNING INTEGRATED COMBINED CYCLE POWER GENERATION | EP00974957.3 | 2000-11-13 | EP1230323A1 | 2002-08-14 | OKADA, Tsuyoshi; MASHIKO, Yoshinori; SASAKI, Tomoyoshi; INOMATA, Makoto |
A light portion is extracted from feed oil by a separation system. The light portion is then subject to a hydrotreatment to obtain impurity-removed fuel oil which is stored in an intermediate tank. A residue of the feed oil after extraction of the light portion is gasified to obtain syngas (H2 gas + CO gas) which is used as basic fuel for power generation in a power generation system. The fuel oil is fed to the power generation system as auxiliary fuel for supplementing the power generation based on the syngas. The power generation system includes a plurality of gas turbines and generators. The number of the gas turbines to be driven by the fuel oil is controlled to adjust the power generation amount depending on demand. | ||||||
171 | Process for manufacturing lube base stocks | EP80303067.5 | 1980-09-03 | EP0028874B1 | 1983-07-27 | Graham, Ronald Irwin; Hicks, Edwin Arthur |
172 | Use of hot N-methyl-2-pyrrolidone (NMP) from solvent extraction operation to supply heat to strip H2S from NMP-scrubbing solution | EP79303056.0 | 1979-12-28 | EP0013177B1 | 1983-02-09 | Blume, John Herman; Bushnell, James Dyckman; Leighton, Milton Dale |
173 | Use of hot N-methyl-2-pyrrolidone (NMP) from solvent extraction operation to supply heat to strip H2S from NMP-scrubbing solution | EP79303056.0 | 1979-12-28 | EP0013177A1 | 1980-07-09 | Blume, John Herman; Bushnell, James Dyckman; Leighton, Milton Dale |
H2S is scrubbed (30) from a gas (32) by N-methyl pyrrolidone to form a scrubbed gas (34) and an HzS-rich NMP solution (36). The latter (36) is passed to a stripping zone (40) where it is stripped of H2S with a stripping gas (11) after first being heated to a stripping temperature by indirect heat exchange (in 26) with a combined stream (24,25) of stripped NMP solution (46) recovered from the stripping zone (40) and hot NMP (10) from a solvent extraction operation. Scrubbed gas (34) is used to strip NMP from hydrocarbons in the solvent extraction operation and is then used as the stripping gas (11) in the stripping zone (40). |
||||||
174 | PRODUCTION OF LOW SULFUR GASOLINE | PCT/US2016/041056 | 2016-07-06 | WO2017014947A1 | 2017-01-26 | HARANDI, Mohsen, N.; GREELEY, John, P.; CHUBA, Michael, R.; LU, Bryan, C. |
Systems and methods are provided for producing naphtha boiling range fractions having a reduced or minimized amount of sulfur and an increased and/or desirable octane rating and suitable for incorporation into a naphtha fuel product. A naphtha boiling range feed can be separated to form a lower boiling portion and a higher boiling portion. The lower boiling portion, containing a substantial amount of olefins, can be exposed to an acidic catalyst without the need for providing added hydrogen in the reaction environment. Additionally, during the exposure of the lower boiling portion to the acidic catalyst, a stream of light olefins (such as C2-C4 olefins) can be introduced into the reaction environment. Adding such light olefins can enhance the C5+ yield and/or improve the removal of sulfur from thiophene and methyl-thiophene compounds in the naphtha feed. |
||||||
175 | TARGETED DESULFURIZATION PROCESS AND APPARATUS INTEGRATING GAS PHASE OXIDATIVE DESULFURIZATION AND HYDRODESULFURIZATION TO PRODUCE DIESEL FUEL HAVING AN ULTRA-LOW LEVEL OF ORGANOSULFUR COMPOUNDS | PCT/US2013/023861 | 2013-01-30 | WO2014109777A1 | 2014-07-17 | BOURANE, Abdennour; KOSEOGLU, Omer, Refa; ISMAGILOV, Zinfer; YASHNIK, Svetlana; KERZHENTSEV, Mikhail; PARMON, Valentin |
Desulfurization of hydrocarbon feeds is achieved by flashing the feed at a target cut point temperature to obtain two fractions. A first fraction contains refractory organosulfur compounds, which boils at or above the target cut point temperature. A second fraction boiling below the target cut point temperature is substantially free of refractory sulfur-containing compounds. The second fraction is contacted with a hydrodesulfurization catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level. The first fraction is contacted with gaseous oxidizing agent over an oxidation catalyst having a formula CuxZn1-xAL2O4 in a gas phase catalytic oxidation reaction zone to convert the refractory organosulfur compounds to SOx and low sulfur hydrocarbons. The by-product SOx is subsequently removed, producing a stream containing a reduced level of organosulfur compounds. |
||||||
176 | HYDROTREATING OF AROMATIC-EXTRACTED HYDROCARBON STREAMS | PCT/US2012048463 | 2012-07-27 | WO2013019586A3 | 2013-07-11 | KOSEOGLU OMER REFA |
Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by first subjecting the entire feed to an extraction zone to separate an aromatic-rich fraction containing a substantial amount of the aromatic refractory and sterically hindered sulfur-containing compounds and an aromatic-lean fraction containing a substantial amount of the labile sulfur-containing compounds. The aromatic-rich fraction is contacted with isomerization catalyst, and the isomerized aromatic-rich fraction and the aromatic-lean fraction are combined and contacted with a hydrotreating catalyst in a hydrodesulfurization reaction zone operating under mild conditions to reduce the quantity of organosulfur compounds to an ultra-low level. | ||||||
177 | IMPROVED PROCESS FOR MANUFACTURE OF LIQUID FUEL COMPONENTS FROM RENEWABLE SOURCES | PCT/FI2012/050941 | 2012-10-02 | WO2013050653A1 | 2013-04-11 | LAAKKONEN, Marko; MYLLYOJA, Jukka; TOUKONIITTY, Blanka; HUJANEN, Mervi; SAASTAMOINEN, Ari; TOIVO, Alpo |
The present invention related to a method for producing liquid fuel components from renewable oil. In this method a fresh feedstock comprising saturated fatty acids is subjected to dilution by an organic lipophilic solvent. The solvent has a low phosphorus and metal impurity content, less than 5 ppm and less than 10 ppm, respectively. Dilution is performed before and/or during purification by at least one pretreatment process for removal of phosphorus and metal impurities. Subsequently, the resulting purified feedstock is fed into at least one post- treatment process suitable for producing liquid fuel components. |
||||||
178 | PROCESS FOR THE REFINING OF CRUDE OIL | PCT/EP2011068842 | 2011-10-27 | WO2012055957A3 | 2012-08-23 | RISPOLI GIACOMO FERNANDO; BELLUSSI GIUSEPPE |
A process for the refining of crude oil, comprising a separation unit of the crude oil, consisting of at least one atmospheric distillation unit for separating the various fractions, a unit for the conversion of the heavy fractions obtained, a unit for improving the quality of some of the fractions obtained by actions on the chemical composition of their constituents, and units for the removal of undesired components, characterized in that the heaviest fraction, the atmospheric distillation residue, is sent to the conversion unit comprising a hydroconversion reactor in slurry phase or of the ebullated bed type, into which hydrogen or a mixture of hydrogen and ¾S is introduced in the presence of a suitable nanodispersed hydrogenation catalyst. | ||||||
179 | CONVERSION METHOD COMPRISING DE-ASPHALTING AND RESIDUE CONVERSION | PCT/FR2009000815 | 2009-07-01 | WO2010004128A2 | 2010-01-14 | LENGLET ERIC; SARRAZIN PATRICK; PLUMAIL JEAN-CLAUDE; MOREL FREDERIC |
The invention relates to a method for converting a charge, said method comprising a step a) de-asphalting using charge solvent step b) hydrotreatment for the de-asphalted oil fraction and step c) hydroconversion of the fraction comprising the essential asphalts, preferably after addition for said fraction to a flux, for example a gas/oil cut. | ||||||
180 | PROCEDE DE CONVERSION COMPRENANT UNE VISCOREDUCTION DE RESIDU PUIS UN DESASPHALTAGE ET UNE HYDROCONVERSION | PCT/FR2009/000814 | 2009-07-01 | WO2010004127A3 | 2010-01-14 | LENGLET, Eric; SARRAZIN, Patrick; PLUMAIL, Jean-Claude; MOREL, Frédéric |
L'invention concerne un procédé comprenant au moins les étapes suivantes: une étape a de viscoréduction de tout ou partie de la charge, une étape b de desasphaltage au solvant de tout ou partie l'effluent de l'étape a, une étape c dliydroconversion de la fraction comprenant la majeure partie des asphaltènes issue de l'étape b, une étape d de fractionnement de l'huile desasphaltée obtenue à l'étape c et une étape e divydrotraitement du résidu desasphalté obtenu à l'issu de cette étape d de fractionnement. |