序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
141 Phosphorylated cellulose ester membrane for use in separation or concentration of substances US469281 1974-05-13 US3962212A 1976-06-08 Takezo Sano; Takatoshi Shimomura
A novel phosphorylated cellulose ester membrane containing 0.1 to 10 % of phosphorus and having a selective permeability. This permselective phosphorylated cellulose ester membrane consists essentially of a phosphorylated cellulose ester obtained by reacting a phosphorylating reagent such as phosphorus oxychloride with a lower aliphatic acid ester of cellulose, which has a reactive hydroxyl group, in an organic solvent, and then hydrolyzing the resulting ester. The membrane can be used widely in separating materials by processes such as reverse osmosis, ultrafiltration, dialysis, electrodialysis, and the like.
142 Preparation of an enzyme-cellulose complex US513048 1974-10-08 US3960666A 1976-06-01 Jean Paul Bourdeau; Jean Louis Seris; Rene Pornin
Enzymes are fixed to cellulose containing 5 to 25% lignin to form an enzyme-cellulose complex by a process involving treating cellulose pieces with an alkaline solution to remove lignin on the surface of the pieces, treating the resultant cellulose pieces with a sulfochlorinating or a chlorinating agent in an excess of pyridine until sulfur and/or chlorine is combined with the cellulose, washing the sulfur and/or chlorine-containing cellulose pieces and treating the pieces with an aqueous enzyme solution to attach enzymes thereto. A very important application is preparation of a rennet-cellulose complex and using the complex for coagulating milk in making cheese.
143 Halogenated esters of phosphorus-containing acids (ii) US38360073 1973-07-30 US3888844A 1975-06-10 D ALELIO GAETANO F
This invention deals with new phosphorus containing polymeric esters having pendent groups therein of the formula

OBTAINED BY THE REACTION OF A POLYMER HAVING AT LEAST 2 AND PREFERABLY AT LEAST 4 HYDROXY GROUPS THEREIN WITH A PHOSPHORUSHALOGEN COMPOUND OF THE FORMULA XP(O) (ORCX CXR'')2 wherein: R represents a divalent hydrocarbon radical containing 1-20 carbon atoms; R'' represents X, hydrogen or R''''; R'''' represents a monovalent hydrocarbon radical containing 1-20 carbon atoms; and X represents chlorine or bromine. Somewhat related polymers are also disclosed as derived by the reaction of

WHEREIN Q'' is an organic moiety, n'' has a value of at least one, n'''' is one or two, R'''''' represents hydrogen or a monovalent hydrocarbon group of 1-20 carbon atoms, and the other symbols have the same meaning as defined above. Also disclosed are the reaction products of the phosphite compound HOP(ORCX CXR'')2 with an aldehyde and an organic nitrogen compound having one or two hydrogen atoms on the nitrogen, or with a compound having an ethylenic group therein. These new ester polymers and compounds are useful particularly as fire retardants, agricultural chemicals, fuel additives, plasticizers, monomers and intermediates for the synthesis of other useful derivatives.
144 Organophosphorus modified cellulose nitrate US7773970 1970-10-02 US3808199A 1974-04-30 LIN K; RHEINECK A
SOLUBLE ORGANOPHOSPHORUS DERIVATIVES OF CELLULOSE NITRATE PREPARED BY REACTION OF CELLULOSE NITRATE CONTAINING FREE HYDROXYL GROUPS WITH A MONO-FUNCTIONAL ORGANOPHOSPHORYL OR PHOSPHINYL CHLORIDE. THE MODIFIED POLYMERS HAVE MARKEDLY IMPROVED FIRE RESISTANCE, RETAIN SUBSTANTIALLY THE ORIGINAL NITROGEN CONTENT, ARE SOLUBLE IN MOST LACQUER SOLVENTS AND ARE CAPABLE OF FORMING DURABLE FILM AS DECORATIVE AND FUNCTIONAL COATINGS.
145 Phosphorylation of cellulosic material having free hydroxyl groups US3565886D 1969-09-12 US3565886A 1971-02-23 CLERMONT LOUIS-PHILIPPE
A METHOD FOR PHOSPHORYLATING CELLULOSIC MATERIAL SUCH AS CELLULOSE AND CELLULOSE DERIVATIVES PARTICULARLY THE ESTERS AND ETHERS BY REACTING THE CELLULOSIC MATERIAL WITH A SOLUTION OF PHOSPHORIS PENTOXIDE IN DIMETHYLFORMAMIDE. PHOSPHORYLATED CELLULOSE DERIVATIVES CONTAINING ABOUT 4 TO ABOUT 10% BY WT. BOUND PHOSPHORUS HAVE BEEN PREPARED.
146 Cellulose microspherical product US3501419D 1966-12-12 US3501419A 1970-03-17 BRIDGEFORD DOUGLAS J
147 High wet strength webs impregnated with polymeric alcohol US3429735D 1967-04-10 US3429735A 1969-02-25 BRIDGEFORD DOUGLAS J
148 Carbonate esters of flavorants US63527767 1967-02-23 US3419543A 1968-12-31 MOLD JAMES D; KALLIANOS ANDREW G; SHELBURNE FRANK A
149 After-glow suppressing cellulose derivatives US63150856 1956-12-31 US2990233A 1961-06-27 EUGENE PACSU; SCHWENKER JR ROBERT F
150 Preparation of cellulose phosphates US26467752 1952-01-02 US2759924A 1956-08-21 TOUEY GEORGE P
151 Pentaerythrityl phosphoric acid esters of cellulose and processes of making the same US15805650 1950-04-25 US2592544A 1952-04-15 DAUL GEORGE C; REID JOHN D
152 Carbohydrate derivative and process of making the same US70589834 1934-01-09 US2016299A 1935-10-08 FERDINAND SCHULZE
153 Production of cellulose phosphates US54404131 1931-06-12 US1896725A 1933-02-07 TANNER WELLINGTON L
154 繊維状セルロース含有物、繊維状セルロース含有液状組成物及び成形体 JP2018248484 2018-12-28 JP6978403B2 2021-12-08 轟 雄右
155 繊維状セルロース含有組成物、その製造方法、及び膜 JP2018209307 2018-11-07 JP6954257B2 2021-10-27 水上 萌; 伏見 速雄; 砂川 寛一
156 架橋性ミクロフィブリル化セルロースを含む性接着剤 JP2020568959 2019-06-11 JP2021527153A 2021-10-11 クンハ、ジゼラ; レンネマルク、レナ
本発明は、リン酸化MFCである架橋性ミクロフィブリル化セルロース(MFC)を含む性接着剤、および前記接着剤を使用して複数の表面を一緒に接着する方法に関する。
157 セルロース繊維の成形体及びその製造方法 JP2020064649 2020-03-31 JP2021161565A 2021-10-11 三好 隆裕; 今井 貴章
【課題】引張定荷重伸びが向上したセルロース繊維の成形体、及びその製造方法を提供する。
【解決手段】上記課題は、セルロース繊維を主成分とし、前記セルロース繊維がパルプ、セルロース微細繊維(A)及びセルロース微細繊維(B)を含み、セルロース微細繊維の平均繊維径は、前記セルロース微細繊維(B)が前記セルロース微細繊維(A)よりも大であり、前記セルロース微細繊維(A)の平均繊維径が1〜20nmであり、前記セルロース微細繊維(A)に対する前記セルロース微細繊維(B)の配合比が、4〜197である、ことを特徴とするセルロース繊維の成形体及びその製造方法によって解決される。
【選択図】図2
158 繊維状セルロース、繊維状セルロース含有物及び成形体 JP2020067530 2020-04-03 JP2021161353A 2021-10-11 趙 孟晨
【課題】本発明は、純吸水性及び塩水吸水性に優れた繊維状セルロースを提供することを課題とする。
【解決手段】本発明は、亜リン酸基又は亜リン酸基に由来する置換基を有する繊維状セルロースであって、所定のシート形成方法でシートを形成し、所定の測定方法で吸液速度を算出した場合、シートの吸液速度が0.30mm/s以上となる、繊維状セルロースに関する。
【選択図】なし
159 セルロース微細繊維含有物及びその製造方法 JP2018170669 2018-09-12 JP6920260B2 2021-08-18 松末 一紘
160 繊維状セルロース含有物 JP2016165640 2016-08-26 JP6859629B2 2021-04-14 尾崎 拓里; 水上 萌; 韓 金▲丹彡▼
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