序号 | 专利名 | 申请号 | 申请日 | 公开(公告)号 | 公开(公告)日 | 发明人 |
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141 | Phosphorylated cellulose ester membrane for use in separation or concentration of substances | US469281 | 1974-05-13 | US3962212A | 1976-06-08 | Takezo Sano; Takatoshi Shimomura |
A novel phosphorylated cellulose ester membrane containing 0.1 to 10 % of phosphorus and having a selective permeability. This permselective phosphorylated cellulose ester membrane consists essentially of a phosphorylated cellulose ester obtained by reacting a phosphorylating reagent such as phosphorus oxychloride with a lower aliphatic acid ester of cellulose, which has a reactive hydroxyl group, in an organic solvent, and then hydrolyzing the resulting ester. The membrane can be used widely in separating materials by processes such as reverse osmosis, ultrafiltration, dialysis, electrodialysis, and the like. | ||||||
142 | Preparation of an enzyme-cellulose complex | US513048 | 1974-10-08 | US3960666A | 1976-06-01 | Jean Paul Bourdeau; Jean Louis Seris; Rene Pornin |
Enzymes are fixed to cellulose containing 5 to 25% lignin to form an enzyme-cellulose complex by a process involving treating cellulose pieces with an alkaline solution to remove lignin on the surface of the pieces, treating the resultant cellulose pieces with a sulfochlorinating or a chlorinating agent in an excess of pyridine until sulfur and/or chlorine is combined with the cellulose, washing the sulfur and/or chlorine-containing cellulose pieces and treating the pieces with an aqueous enzyme solution to attach enzymes thereto. A very important application is preparation of a rennet-cellulose complex and using the complex for coagulating milk in making cheese. | ||||||
143 | Halogenated esters of phosphorus-containing acids (ii) | US38360073 | 1973-07-30 | US3888844A | 1975-06-10 | D ALELIO GAETANO F |
This invention deals with new phosphorus containing polymeric esters having pendent groups therein of the formula
OBTAINED BY THE REACTION OF A POLYMER HAVING AT LEAST 2 AND PREFERABLY AT LEAST 4 HYDROXY GROUPS THEREIN WITH A PHOSPHORUSHALOGEN COMPOUND OF THE FORMULA XP(O) (ORCX CXR'')2 wherein: R represents a divalent hydrocarbon radical containing 1-20 carbon atoms; R'' represents X, hydrogen or R''''; R'''' represents a monovalent hydrocarbon radical containing 1-20 carbon atoms; and X represents chlorine or bromine. Somewhat related polymers are also disclosed as derived by the reaction of WHEREIN Q'' is an organic moiety, n'' has a value of at least one, n'''' is one or two, R'''''' represents hydrogen or a monovalent hydrocarbon group of 1-20 carbon atoms, and the other symbols have the same meaning as defined above. Also disclosed are the reaction products of the phosphite compound HOP(ORCX CXR'')2 with an aldehyde and an organic nitrogen compound having one or two hydrogen atoms on the nitrogen, or with a compound having an ethylenic group therein. These new ester polymers and compounds are useful particularly as fire retardants, agricultural chemicals, fuel additives, plasticizers, monomers and intermediates for the synthesis of other useful derivatives. |
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144 | Organophosphorus modified cellulose nitrate | US7773970 | 1970-10-02 | US3808199A | 1974-04-30 | LIN K; RHEINECK A |
SOLUBLE ORGANOPHOSPHORUS DERIVATIVES OF CELLULOSE NITRATE PREPARED BY REACTION OF CELLULOSE NITRATE CONTAINING FREE HYDROXYL GROUPS WITH A MONO-FUNCTIONAL ORGANOPHOSPHORYL OR PHOSPHINYL CHLORIDE. THE MODIFIED POLYMERS HAVE MARKEDLY IMPROVED FIRE RESISTANCE, RETAIN SUBSTANTIALLY THE ORIGINAL NITROGEN CONTENT, ARE SOLUBLE IN MOST LACQUER SOLVENTS AND ARE CAPABLE OF FORMING DURABLE FILM AS DECORATIVE AND FUNCTIONAL COATINGS.
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145 | Phosphorylation of cellulosic material having free hydroxyl groups | US3565886D | 1969-09-12 | US3565886A | 1971-02-23 | CLERMONT LOUIS-PHILIPPE |
A METHOD FOR PHOSPHORYLATING CELLULOSIC MATERIAL SUCH AS CELLULOSE AND CELLULOSE DERIVATIVES PARTICULARLY THE ESTERS AND ETHERS BY REACTING THE CELLULOSIC MATERIAL WITH A SOLUTION OF PHOSPHORIS PENTOXIDE IN DIMETHYLFORMAMIDE. PHOSPHORYLATED CELLULOSE DERIVATIVES CONTAINING ABOUT 4 TO ABOUT 10% BY WT. BOUND PHOSPHORUS HAVE BEEN PREPARED.
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146 | Cellulose microspherical product | US3501419D | 1966-12-12 | US3501419A | 1970-03-17 | BRIDGEFORD DOUGLAS J |
147 | High wet strength webs impregnated with polymeric alcohol | US3429735D | 1967-04-10 | US3429735A | 1969-02-25 | BRIDGEFORD DOUGLAS J |
148 | Carbonate esters of flavorants | US63527767 | 1967-02-23 | US3419543A | 1968-12-31 | MOLD JAMES D; KALLIANOS ANDREW G; SHELBURNE FRANK A |
149 | After-glow suppressing cellulose derivatives | US63150856 | 1956-12-31 | US2990233A | 1961-06-27 | EUGENE PACSU; SCHWENKER JR ROBERT F |
150 | Preparation of cellulose phosphates | US26467752 | 1952-01-02 | US2759924A | 1956-08-21 | TOUEY GEORGE P |
151 | Pentaerythrityl phosphoric acid esters of cellulose and processes of making the same | US15805650 | 1950-04-25 | US2592544A | 1952-04-15 | DAUL GEORGE C; REID JOHN D |
152 | Carbohydrate derivative and process of making the same | US70589834 | 1934-01-09 | US2016299A | 1935-10-08 | FERDINAND SCHULZE |
153 | Production of cellulose phosphates | US54404131 | 1931-06-12 | US1896725A | 1933-02-07 | TANNER WELLINGTON L |
154 | 繊維状セルロース含有物、繊維状セルロース含有液状組成物及び成形体 | JP2018248484 | 2018-12-28 | JP6978403B2 | 2021-12-08 | 轟 雄右 |
155 | 繊維状セルロース含有組成物、その製造方法、及び膜 | JP2018209307 | 2018-11-07 | JP6954257B2 | 2021-10-27 | 水上 萌; 伏見 速雄; 砂川 寛一 |
156 | 架橋性ミクロフィブリル化セルロースを含む水性接着剤 | JP2020568959 | 2019-06-11 | JP2021527153A | 2021-10-11 | クンハ、ジゼラ; レンネマルク、レナ |
本発明は、リン酸化MFCである架橋性ミクロフィブリル化セルロース(MFC)を含む水性接着剤、および前記接着剤を使用して複数の表面を一緒に接着する方法に関する。 | ||||||
157 | セルロース繊維の成形体及びその製造方法 | JP2020064649 | 2020-03-31 | JP2021161565A | 2021-10-11 | 三好 隆裕; 今井 貴章 |
【課題】引張定荷重伸びが向上したセルロース繊維の成形体、及びその製造方法を提供する。 【解決手段】上記課題は、セルロース繊維を主成分とし、前記セルロース繊維がパルプ、セルロース微細繊維(A)及びセルロース微細繊維(B)を含み、セルロース微細繊維の平均繊維径は、前記セルロース微細繊維(B)が前記セルロース微細繊維(A)よりも大であり、前記セルロース微細繊維(A)の平均繊維径が1〜20nmであり、前記セルロース微細繊維(A)に対する前記セルロース微細繊維(B)の配合比が、4〜197である、ことを特徴とするセルロース繊維の成形体及びその製造方法によって解決される。 【選択図】図2 |
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158 | 繊維状セルロース、繊維状セルロース含有物及び成形体 | JP2020067530 | 2020-04-03 | JP2021161353A | 2021-10-11 | 趙 孟晨 |
【課題】本発明は、純水吸水性及び塩水吸水性に優れた繊維状セルロースを提供することを課題とする。 【解決手段】本発明は、亜リン酸基又は亜リン酸基に由来する置換基を有する繊維状セルロースであって、所定のシート形成方法でシートを形成し、所定の測定方法で吸液速度を算出した場合、シートの吸液速度が0.30mm/s以上となる、繊維状セルロースに関する。 【選択図】なし |
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159 | セルロース微細繊維含有物及びその製造方法 | JP2018170669 | 2018-09-12 | JP6920260B2 | 2021-08-18 | 松末 一紘 |
160 | 繊維状セルロース含有物 | JP2016165640 | 2016-08-26 | JP6859629B2 | 2021-04-14 | 尾崎 拓里; 水上 萌; 韓 金▲丹彡▼ |