| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 101 | ELICITOR-DERIVED PEPTIDES AND USE THEREOF | US15989647 | 2018-05-25 | US20180362993A1 | 2018-12-20 | Zhongmin Wei; Gregory A. Zornetzer |
| Disclosed are non-hypersensitive response eliciting peptides and weak hypersensitive response eliciting peptides that induce active plant responses, and that exhibit improved solubility, stability, resistance to chemical degradation, or a combination of these properties. Use of these peptides or fusion polypeptides, compositions, recombinant host cells or DNA constructs encoding the same, for modulating plant biochemical signaling, imparting disease resistance to plants, enhancing plant growth, imparting tolerance to biotic stress, imparting tolerance and resistance to abiotic stress, imparting desiccation resistance to cuttings removed from ornamental plants, imparting post-harvest disease or post-harvest desiccation resistance to a fruit or vegetable, or enhancing the longevity of fruit or vegetable ripeness are also disclosed. | ||||||
| 102 | Preparation of arthropodicidal oxadiazines | US727607 | 1996-10-16 | US5869657A | 1999-02-09 | Gary David Annis; Stephen Frederick McCann; Rafael Shapiro |
| A method for making arthropodicidal oxadiazines and intermediates which are racemic or enantiomerically enriched at their chiral center, the method for making the oxadiazines comprising reaction of an intermediate selected from ##STR1## wherein: R.sup.1 is F, Cl, or C.sub.1 -C.sub.3 fluroalkoxy,R.sup.2 is C.sub.1 -C.sub.3 alkyl, andR.sup.4 is H or CO.sub.2 CH.sub.2 (C.sub.6 H.sub.5).as well as certain selected intermediates including those depicted above, and methods of making them. | ||||||
| 103 | 2,2-dialkylpentane 1,5-diisocyanates, 2,2-dialkylpentane 1,5-diurethanes and 2,2-dialkylpentane 1,5-dicarbamoyl chlorides, and their preparation and use | US383771 | 1995-02-03 | US5554787A | 1996-09-10 | Franz Merger; Andreas Otterbach; Tom Witzel; Hans Renz |
| Novel 2,2 -dialkylpentane-1,5-diisocyantes, 2,2-dialkylpentane-1,5-diurethanes and 2,2-dialkylpentane-1,5-dicarbamoyl chlorides of the formula ##STR1## where R.sup.1 and R.sup.2 are identical or different linear C.sub.1 -to C.sub.12 -alkyl, branched C.sub.3 - to C.sub.12 -alkyl, branched C.sub.2 - to C.sub.12 -alkenyl or branched C.sub.4 - to C.sub.12 -alkenyl,or R.sup.1 and R.sup.2 together are alkylene having from 4 to 7 carbon atoms, which is unsubstituted or substituted by from 1 to 5 C.sub.1 - to C.sub.4 -alkyl groups, and X is NCO, NH--CO.sub.2 R.sup.3, NHCO.sub.2 R.sup.4 or NHCOCl, where R.sup.3 and R.sup.4 are identical or different and are linear C.sub.1 - to C.sub.20 -alkyl, branched C.sub.3 - to C.sub.20 -alkyl or C.sub.5 - to C.sub.12 -cycloalkyl, are described. | ||||||
| 104 | Process for preparing N,N-substituted carbamoyl halides | US192322 | 1994-02-04 | US5380855A | 1995-01-10 | William D. McGhee; John J. Talley |
| A process for preparing N,N-substituted carbamoyl halides comprising (a) contacting carbon dioxide and a secondary amine in the presence of an aprotic organic solvent and a base selected from the group consisting of a phosphazene compound, an organic, nitrogenous base, mixtures of pyridine and a phosphazene compound or an organic, nitrogenous base, and mixtures thereof, to produce the corresponding ammonium carbamate salt, and (b) reacting the ammonium carbamate salt with a halide-containing electrophilic compound to produce the corresponding N,N-substituted carbamoyl halides. A second embodiment comprises recovering the ammonium carbamate salt of step (a) prior to reacting the ammonium carbamate salt with an halide-containing electrophilic compound in the presence of an aprotic organic solvent and a base selected from the group consisting of a phosphazene compound, an organic, nitrogenous base, mixtures of pyridine and a phosphazene compound or an organic, nitrogenous base, and mixtures thereof. | ||||||
| 105 | Process for the preparation of .beta.-halogeno-tert.-alkyl isocyanates | US862049 | 1992-04-02 | US5245076A | 1993-09-14 | Rudiger Schubart |
| The invention relates to a process for the preparation of known .beta.-halogeno-tert.-alkyl isocyanates of the formula ##STR1## in which X represents chlorine,Y represents hydrogen or chlorine,R.sub.1 represents in each case straight-chain or branched alkyl or halogenoalkyl andR.sub.2 represents in each case straight-chain or branched alkyl, halogenoalkyl or optionally halogen- and/or trifluoromethyl-substituted phenyl,where tert.-alkyl isocyanates of the formula (II) ##STR2## in which R.sub.1 and R.sub.2 have the meaning given above,are converted to the corresponding tert.-alkylcarbamoyl chlorides by means of hydrogen chloride gas, these are reacted with elemental chlorine under irradiation or in the presence of catalysts, and finally the .beta.-halogeno-tert.-alkyl isocyanates are liberated by dehydrohalogenation at elevated temperature. | ||||||
| 106 | Process for the preparation of carbamoyl chlorides derived from secondary amines | US851952 | 1986-04-14 | US4770820A | 1988-09-13 | Gunther Semler; Georg Schaeffer |
| Carbamoyl chlorides derived from secondary aliphatic amines having alkyl groups which are branched in the 1-position are prepared by passing phosgene at an elevated temperature into the corresponding, initially taken--if appropriate dissolved in an inert solvent--secondary aliphatic amines having alkyl groups which are branched in the 1-position.The reaction products are intermediates in various specialized fields, particularly in the plant protection sector. | ||||||
| 107 | N-(alpha-haloacyl)-N-hydrocarbyl carbamoyl halides | US786721 | 1985-10-15 | US4637901A | 1987-01-20 | Chennupati K. Rao; Sudershan K. Arora; Raman Grover; John A. Durden; Themistocles D. J. D'Silva |
| Novel N-(alpha-haloacyl)-N-hydrocarbyl carbamoyl halides and a process for their preparation are provided. The novel compounds are useful as intermediates in the preparation of insecticides. | ||||||
| 108 | Method for the preparation of 2-(trifluoromethyl)phenyl carbamic fluoride | US504636 | 1983-06-15 | US4466927A | 1984-08-21 | Henry C. Lin; Byron R. Cotter |
| A method for the preparation of a 2-(trifluoromethyl)phenyl carbamic fluoride comprises isomerizing N-(trifluoromethyl)-anthraniloyl fluoride in the presence of hydrogen fluoride to 2-(trifluoromethyl)phenyl carbamic fluoride. | ||||||
| 109 | Preparation of 1-monochloroethylcarbamyl chloride | US247984 | 1981-03-26 | US4411752A | 1983-10-25 | Karl-Heinz Koenig; Karl-Heinz Feuerherd |
| A process for the preparation of 1-monochloroethylcarbamyl chloride by chlorinating ethyl isocyanate or ethylcarbamyl chloride. The 1-chloroethylcarbamyl chloride obtainable according to the invention is an important starting material for the preparation of 1-chloroethyl isocyanate and vinyl isocyanate and accordingly a valuable starting material for the preparation of pest control agents, dyes, drugs, textile waterproofing agents, detergents, plastics, bleaching agents and adhesives, since the said isocyanates contain, in addition to a reactive isocyanate group, an activated double bond or an activated .alpha.-carbon atom. | ||||||
| 110 | Substituted carbamate intermediate | US899299 | 1978-04-24 | US4127605A | 1978-11-28 | James V. Hay |
| N,N'-[1,2-Ethanediylbis(thio)]bis[N-methylcarbamic fluoride] useful as an intermediate in preparation of insecticides. | ||||||
| 111 | Bis-halogen carbonyl anilines and process for the production | US447438 | 1974-03-01 | US3983172A | 1976-09-28 | Gerhard Buttner; Erich Klauke; Klaus Sasse |
| Bis-halogen carbonyl anilines useful in the production of herbicides having the formula ##SPC1##WhereinX is fluorine or chlorine,Y is fluorine, chlorine, fluorocarbonyl, or chlorocarbonyl,Z is halogen, nitro, cyano, lower alkyl sulfonyl or carbalkoxy,R is lower alkyl, alkoxy, thioalkyl, phenyl, naphthyl, lower perhalogen alkyl, perhalogen alkoxy or perhalogen alkylthio,a and b represent a number from 0 to 5, with the proviso that a plus b is at the most 5,Are prepared by reacting an aryl carbamic acid fluoride having the formula ##SPC2##WhereinZ, r, a, b are as defined above with an acylating agent having the formula ##EQU1## wherein X and Y are as defined above in the presence of a tertiary amine at a temperature in the range of from -20.degree. to +40.degree.C. | ||||||
| 112 | Production of carbamyl chlorides and bromides from corresponding n-(alpha-chloroalkyl or alpha-bromoalkyl) - carbamyl halides | US3489797D | 1968-03-20 | US3489797A | 1970-01-13 | KOENIG KARL-HEINZ; POMMER HORST |
| 113 | Alpha,beta-unsaturated isocyanates | US3468923D | 1962-05-23 | US3468923A | 1969-09-23 | KOENIG KARL-HEINZ; POMMER HORST |
| 114 | Vapor phase process for the production of dimethylcarbamyl chloride from phosgene and trimethyl amine | US31872652 | 1952-11-04 | US2698343A | 1954-12-28 | EBERHARD STEIN; OTTO BAYER |
| 115 | Reaction accelerator and method of producing urethane compound, thiourethane compound, amide compound, or urea compound using same | US14906759 | 2014-07-22 | US09656952B2 | 2017-05-23 | Katsutoshi Ono; Tomomitsu Kato |
| A reaction accelerator is provided which is used in a reaction of a compound including an isocyanate group that is not directly bonded to an aromatic ring in a molecule with a compound including an active hydrogen-containing group and is formed of a compound including a halogenated carbamoyl group. A production method is provided which includes reacting a compound including an isocyanate group that is not directly bonded to an aromatic ring in a molecule with a compound including an active hydrogen-containing group to produce a urethane compound, a thiourethane compound, an amide compound or a urea compound, in which the reaction is performed in the presence of the reaction accelerator. | ||||||
| 116 | Process for the halogenation, nitration and fluorination of aromatic derivatives | US134539 | 1987-12-15 | US4876376A | 1989-10-24 | Michael Desbois; Camille Disdier |
| A process for the halogenation (bromination or chlorination)/nitration/fluorination of aromatic derivatives substituted by at least one group containing a halogenoalkyl unit. The aromatic derivative is reacted with a halogen and a nitrating agent in liquid hydrofluoric acid. The products obtained are useful as intermediates for the synthesis of compounds having a plant-protecting or pharmaceutical activity. | ||||||
| 117 | Method of preparation of novel 2-(alkoxymethyl)-pentane-1,5-diisocyanates, 2-(alkoxymethyl)-pentane-1,5-diurethanes, and 2-(alkoxymethyl)-pentane-1,5-dicarbamic acid chlorides and their uses | US97505 | 1987-09-16 | US4748226A | 1988-05-31 | Franz Merger; Wolfgang Schwarz |
| This invention relates to novel 2-(alkoxymethyl) pentane-1,5-diisocyanates, 2-(alkoxymethyl)-pentane-1,5-diurethanes, and 2-(alkoxymethyl)-pentane 1,5-dicarbamic acid chlorides having the structure: ##STR1## in which R is a straight chain or branched C.sub.1 -C.sub.20 -alkyl radical, a straight chain or branched C.sub.2 -C.sub.20 -alkenyl radical, a straight chain or branched C.sub.3 -C.sub.20 -oxaalkyl radical, an optionally substituted C.sub.5 -C.sub.12 -cycloalkyl radical, or an optionally substituted C.sub.7 -C.sub.20 -aralkyl radical and X is a --NCO--, --NH--CO.sub.2 R.sup.1 --, --NHCO.sub.2 R.sup.2 -- OR - NHCOCl-group whereby R.sup.1 and R.sup.2 can be the same or different and are a straight chain or branched C.sub.1 -C.sub.20 -alkyl radical or a C.sub.5 -C.sub.12 cycloalkyl radical, as well as a process for their preparation. The 2-(alkoxymethyl)-pentane-1,5-diurethanes or 2- (alkoxymethyl)-pentane-1,5-dicarbamic acid chlorides are suited for the preparation of 2-(alkoxymethyl)-pentane-1,5-diisocyanates, which in turn are used for the preparation of plastics using the polyisocyanate addition polymerization process. | ||||||
| 118 | Halogenated tertiary alkyl isocyanates and their preparation | US185404 | 1980-09-08 | US4344891A | 1982-08-17 | Karl-Heinz Koenig; Volker Schwendemann; Karl-Heinz Feuerherd |
| Halogenated tertiary alkyl isocyanates and a process for their preparation by reacting a tertiary alkyl isocyanate with halogen, sulfuryl chloride and/or sulfuryl bromide.The halogenated tertiary alkyl isocyanates prepared by the process of the invention are valuable starting materials for the preparation of pest control agents, fatliquoring agents, drugs, flameproofing agents, lubricating oils, synthetic resins and slip agents. | ||||||
| 119 | N-[4-(Tert-butyl)phenylsulfenyl]-N-alkylcarbamoyl fluoride compounds | US81376 | 1979-10-03 | US4304735A | 1981-12-08 | John A. Durden, Jr. |
| N-[4-(tert-butyl)phenylsulfenyl]-N-alkylcarbamoyl fluoride compounds are useful as intermediates in the preparation of pesticidally active carbamoyloxime compounds. | ||||||
| 120 | Sulfinyl-bis carbamoyl fluorides | US87078 | 1979-10-22 | US4255353A | 1981-03-10 | Anthony D. Wolf |
| Sulfinyl-bis carbamoyl fluorides, such as N,N'-sulfinylbis[N-methylcarbamoyl fluoride], useful as intermediates in the preparation of insecticides. | ||||||
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