| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 161 | Use as amino acid derivatives and the pest control agent | JP50275496 | 1995-06-16 | JP3959108B2 | 2007-08-15 | カサー，カール; ザイツ，トマス; シユテルツアー，ウベ |
| 162 | Compound used for production of arthropodicidal oxadiazine | JP2006181231 | 2006-06-30 | JP2006273867A | 2006-10-12 | ANNIS GARY DAVID; MCCANN STEPHEN FREDERICK; SHAPIRO RAFAEL |
| PROBLEM TO BE SOLVED: To provide a compound used for the production of arthrooxadiazine which is racemic at a chiral center or rich in enantiomer. SOLUTION: The compound is expressed by formula (VII) (R 1 is F, Cl or a 1-3C fluoroalkoxy group; and R 2 is a 1-3C alkyl group). COPYRIGHT: (C)2007,JPO&INPIT | ||||||
| 163 | Their use as pyrazoline derivative and pesticides | JP2003515507 | 2002-07-08 | JP2005504748A | 2005-02-17 | エーアデレン，クリストフ; トウルベルク，アンドレアス; フツクス，ライナー; マオラー，フリツツ; レツクマン，ウード |
| 本発明は、式（Ｉ）（式中、Ｒ １ 、Ｒ ２ 、Ｒ ３及びＲ ４は、明細書に記載した意味を有する）の新規なピラゾリン誘導体、これらの物質を製造するための多数の方法、病害虫を防除するためのこれらの使用並びに新規な中間体生成物及びそれらの製造方法に関する。 | ||||||
| 164 | Poly perfluoro amino ether | JP10439189 | 1989-04-24 | JP3020510B2 | 2000-03-15 | ダリル、ディー、デスマトー; ワルテル、ナバリーニ |
| 165 | Use as amino acid derivatives and the pest control agent | JP50275496 | 1995-06-16 | JPH10502911A | 1998-03-17 | カサー，カール; ザイツ，トマス; シユテルツアー，ウベ |
| (57)【要約】 本発明は新規なアミノ酸誘導体、その製造方法並びにその有害生物防除剤、特に殺菌・殺カビ剤、及び従来、殺菌・殺カビ性の置換されたアミノ酸誘導体の製造に対する中間体生成物としての使用に関する。 | ||||||
| 166 | Production of joint policy Dar oxadiazinetrione | JP52766395 | 1995-04-17 | JPH09512533A | 1997-12-16 | ゲイリー・デイビツド アニス，; ラフアエル シヤピロ，; スチーブン・フレデリク マツキヤン， |
| (57)【要約】 それらのキラル中心においてラセミ又は鏡像異性体的に富んでいる関節 オキサジアジン及び中間体を作るための方法であって、（ＩＩ）又は（ＩＩａ） ［式中、Ｒ 1は、Ｆ、Ｃｌ又はＣ 1 〜Ｃ 3 −フルオロアルコキシであり、Ｒ 2は、Ｃ 1 〜Ｃ 3 −アルキルであり、そしてＲ 4は、Ｈ又はＣＯ 2 ＣＨ 2 （Ｃ 6 Ｈ 5 ）である］から選ばれた中間体の反応を含んで成る前記オキサジアジンを作るための方法、並びに上で述べたものを含むある種の選ばれた中間体、及びそれらを作る方法。 | ||||||
| 167 | JPH06510992A - | JP50574593 | 1992-09-10 | JPH06510992A | 1994-12-08 | |
| 168 | N-(1-arylalkyl)-n-(2-fluorocyclopropyl)carbamate derivative and production j thereof | JP33487791 | 1991-12-18 | JPH05163212A | 1993-06-29 | KAMATA MASAHIRO; HAYAKAWA ISAO; AKIBA TOSHIFUMI; TERAJIMA ATSURO; TAMURA OSAMU; KOBAYASHI YUKO; HASHIMOTO MASARU; KATO TADASHI; NAKATANI KAZUHIKO |
| PURPOSE: To produce (1R,2S)-2-fluorocyclopropylamine salt as an synthetic intermediate of quinolone derivatives used as an excellent antifungal, through a novel intermediate safely, inexpensively and readily. CONSTITUTION: N-[(1R)-arylalkyl]-N-(1R*, 2S*)-2-fluorocyclopropylcarbamate derivative of formula 7 (Ar is phenyl or naphthyl both of which may be optionally substituted) is subjected to dehydrative condensation reaction with acetaldehyde to give a compound of formula 6. The product is allowed to react with phosgene in the presence of a base to form N-(1-arylalkyl)-N-vinylcarbamic acid chloride derivative of formula 3, which is allowed to react with a compound of formula Y-OM (Y is alkyl bearing 1 to 3 aryl groups in the 1-position; M is alkali metal) to give a compound of formula 2. Then, monofluorocarbene is added to the product to give N-(1-arylalkyl)-N-[(1R*, 2S*)-2- fluorocyclopropyl]-carbamate derivative of formula 1. Then, the product is hydrogenolyzed into(1R*, 2S*)-2-fluorocyclopropylamine of formula 4. The compounds of formula 1 through formula 3 are novel. COPYRIGHT: (C)1993,JPO&Japio | ||||||
| 169 | N-bisarylmethyl-n-(2-fluorocyclopropyl)-carbamate derivative and production thereof | JP13782891 | 1991-06-10 | JPH04360861A | 1992-12-14 | TERAJIMA ATSURO; TAMURA OSAMU; KOBAYASHI YUKO; HASHIMOTO MASARU; KATO TADASHI; NAKATANI KAZUHIKO; KAMATA MASAHIRO; HAYAKAWA ISAO |
| PURPOSE: To obtain the new title compound useful as a intermediate for producing (1R*,2R*)-2-fluorocyclopylamine of raw material for producing a quinolone derivative which is an excellent antimicrobial agent. CONSTITUTION: A N-bisarylmethyl-N-[(1R*,2S*)-2-fluorocyclopropyl]-carbamate derivative expressed by formula I (X 1 to X 6 are H, Cl, Br, 1-5C alkyl or 1-5C alkoxy; Y is mono-, di- or triarylmethyl, 4-10C triarylmethyl or 4-10C trialkylmethyl), e.g. 1,1-dimethylethyl N-[(1R*,2S*)-2fluorocyclopropyl]-N- dipheylmethycarbamate. The compound expressed by formula I is obtained by using a compound expressed by formula 6 as a starting material and passing through a compound expressed by formula 5, a compound expressed by formula 4, a new compound expressed by formula 3 and a new compound expressed by formula 2. (1R*,2S*)-2-Fluorocyclopylamine expressed by formula 7 is obtained from the compound expressed by formula 1. COPYRIGHT: (C)1992,JPO&Japio | ||||||
| 170 | Production of difunctional stilbene compound containing at lest one z-configulated stilbene group, novel difunctional stilbene compound containing at lest one z-confugulated stilbene group and use of the stilbene compound for production of polymer | JP8143690 | 1990-03-30 | JPH02290828A | 1990-11-30 | DEIITAA ARURUTO; AKUSERU BADAA; FUORUKAA ETSUKUHARUTO |
| PURPOSE: To obtain the subject compounds including novel compounds by reacting a specified compound as a starting material with an acetylene, converting the product with a base, reacting the covered product with a specified compound in the presence of Pd catalyst and base and reducing the final product with H 2 or the like. CONSTITUTION: A compound of formula I [A is a chemical bond or the like; D is COOR 1 (R 1 is H or the like), COR 1 or the like; and X is Br or I] is reacted with an acetylene of formula II [R 4 is formula III (R 5 and R 6 are each a 1-4C alkyl) or the like] in the presence of a Pd catalyst and a base, and the product is converted into a compound of formula IV by treatment with a base. This is reacted with a compound of formula V (D 1=D; p 1=p; and A 1=A), the product is reduced with H 2 or the like in the presence of a catalyst to form a compound of formula VI, and D and D' are converted into Z and Y (Z and Y are each COOR 1, COR 1 or the like) to obtain the objective compounds of formula VII (B is formula VIII; B 1 is formula IV; and l,q, a' and n are each equal to p) including novel compounds useful for the production of polymers. COPYRIGHT: (C)1990,JPO | ||||||
| 171 | JPS6327338B2 - | JP15511582 | 1982-09-08 | JPS6327338B2 | 1988-06-02 | HASHIMOTO KOJI; MYAUCHI MASAYOSHI; KANEKO TAKASHI |
| 172 | Novel alpha-substituted acetophenone oxime derivative and herbicide containing said derivative as active component | JP8029685 | 1985-04-17 | JPS61238772A | 1986-10-24 | HAYASHI YOSHIHARU; MISUMI TERUYUKI |
| NEW MATERIAL:The compound of formula I {R 1 is H, ≥2C lower alkyl, lower alkynyl, acyl, group of formula IV [n is 1 or 2; R 3 is H or methyl; R 4 is OR 5 (R 5 is H, lower alkyl, alkali metal, etc.), etc.]; R 2 is H, lower alkyl, halogen, lower alkenyl, etc.}. EXAMPLE: 5-(2'-Chloro-4'-trifluoromethylphenoxy)-2-nitro-α-hydroxy-acetophenone oxime. USE: Herbicide capable of selectively killing the weeds in the field of crops such as soybean, cotton, corn,wheat, rice, etc., at an extremely low rate of application. PREPARATION: The objective compound of e.g. formula Ia can be produced according to the reaction formula by dehydrating the hydroxylamine hydrochloride of formula III (Z is halogen) in a solvent such as alcohol in the presence of an anhydrous organic acid salt such as anhydrous sodium acetate and an acid acceptor such as triethylamine by conventional method. COPYRIGHT: (C)1986,JPO&Japio | ||||||
| 173 | JPS6034536B2 - | JP15949177 | 1977-12-29 | JPS6034536B2 | 1985-08-09 | CHOMARU ISAO |
| 174 | N-(alpha-haloacyl)-n-hydrocarbylcarbamoyl halide and manufacture | JP19409284 | 1984-09-18 | JPS6087253A | 1985-05-16 | CHIENNIYUPATEI KOTESUWARA RAO; SUYUUDERUSHIYAN KUMAARU ARORA; RAAMAN GUROOBAA; JIYON APURINGU DAADEN; TEMISUTOKURESU DAMASHIEENO JIY |
| 175 | JPS5754503B2 - | JP11685774 | 1974-10-12 | JPS5754503B2 | 1982-11-18 | |
| 176 | JPS5735714B2 - | JP13853773 | 1973-12-11 | JPS5735714B2 | 1982-07-30 | |
| 177 | Biscarbamyl fluoride and its manufacture | JP4915479 | 1979-04-23 | JPS54144316A | 1979-11-10 | JIEEMUSU BORUNEI HAI |
| 178 | 4-2-(4-methylphenyl)ethoxylphenyl isocyanate and its preparation | JP1931278 | 1978-02-21 | JPS54112841A | 1979-09-04 | FUJITA FUMIO; KISHIDA HIROSHI; ITAYA NOBUSHIGE; TAKEMOTO KAZUKI |
| NEW MATERIAL:4-[2-(4-Methylphenyl)ethoxy]phenyl isocyanate of formula I. USE: An intermediate for preparing substituted phenylurea derivatives having a herbicidal activity. PROCESS: An aniline, e.g. 4-[2-(4-methylphenyl)ethoxy]aniline, of formula II is added to phosgene or diphosgene (P) dissolved in a solvent, e.g. benzene or toluene, inert to (P) at -20W30°C and slowly heated to 50W140°C for 1W10 hr to give the objective compound of formula I. The starting compound of formula II can be obtained by reducing the reaction product, prepared from the compound of formula III and the compound of formula IV in the presence of a base. COPYRIGHT: (C)1979,JPO&Japio | ||||||
| 179 | Process for manufacturing nnvinyllnn alkylcarbamic acid chloride | JP200877 | 1977-01-13 | JPS5287120A | 1977-07-20 | KAARUHAINTSU KEENITSUHI; KURISUCHIYAN RAITERU; DEIITORITSUHI MANGORUTO |
| 180 | JPS5133094B2 - | JP8992171 | 1971-11-12 | JPS5133094B2 | 1976-09-17 | |
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