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序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
181 JPS5946497B2 - JP17018779 1979-12-26 JPS5946497B2 1984-11-13 UIRIAMU MONTOGOMERII HAARON; CHEN FUAN ROO
182 JPS5932453B2 - JP12593074 1974-10-30 JPS5932453B2 1984-08-09 MINAMI KUNIICHI; TAKAHASHI SHIGENOBU; FURIKADO KAZUAKI
183 JPS5858339B2 - JP14646875 1975-12-10 JPS5858339B2 1983-12-24 KARURO NERII; GIOACHIINO SHIPURIAANI
184 Novel molecular compound and its preparation JP13811882 1982-08-09 JPS5849394A 1983-03-23 IIDA TAKAO
NEW MATERIAL:An equimolar compound of an aromatic compound containing an active hydrogen atom and a quaternary phosphonium salt compound. EXAMPLE: The reaction product between bisphenol AF and triphenylbenzylphosphonium chloride. USE: A vulcanization accelerator for fluoroelastomers. PROCESS: An aromatic compound containing an active hydrogen atom, e.g. phenol, bisphenol A, 2, 2'-bis(4'-hydroxyphenyl)ketone or benzoic acid, is reacted with a quaternary phosphonium salt compound, e.g. tetraphenylphosphonium chloride or allyltriphenylphosphonium bromide, at a molar ratio of preferably 0.8W1.1 in a polar solvent, e.g. an alcohol, at 20W80°C for 1W4hr to give the aimed equimolar compound in high yield ≥90% as crystals. COPYRIGHT: (C)1983,JPO&Japio
185 JPS583754B2 - JP8855074 1974-07-31 JPS583754B2 1983-01-22 OOKAWA KATSUAKI; CHIKAISHI TSUTOMU; OMURA TAKASHI; KATSUKI HIROSHI; OKAMOTO AKINORI; KENMOCHI HIROTO
186 Cashew nut shell liquid treatment JP521081 1981-01-19 JPS57140736A 1982-08-31 JIYON HENRII POORU TAIMAN; MAHESHIYU SOMABUHAI PATERU; ANSONII PIITAA MANZARA
187 JPS576990B2 - JP8855174 1974-07-31 JPS576990B2 1982-02-08
188 Manufacture of 2,2'-dihydroxy-biphenyl derivative JP2929081 1981-02-28 JPS56135432A 1981-10-22 MIKAERU RASUBAAGAA
189 JPS5624920Y2 - JP14436976 1976-10-26 JPS5624920Y2 1981-06-11
190 Preparation of phenol JP8221679 1979-06-29 JPS567730A 1981-01-27 KAWAI YOSHIO; KIDA KOUICHI; IGARASHI HIDEO; TOKI TSUKASA; SUZUKI YOSHIHARU
PURPOSE: To prepare phenols in high yield, by the cleavage reaction of a mixture of an aromatic tert-hydroxyperoxide and an aromatic prim-hydroxyperoxide in a solvent composed of an aliphatic ketone and an aliphatic alcohol in the presence of an acid. CONSTITUTION: Phenols (e.g. p-cresol, p-isopropylphenol, etc.) are prepared by the cleavage reaction of an aromatic tertiary hydroperoxide (e.g. p-methylcumene hydroperoxide) and an aromatic primary hydroperoxide (e.g. p-isopropylbenzyl hydroperoxide) in the presence of an acid (e.g. sulfuric acid). The reaction is carried out in a mixed solvent composed of (A) 60W99pts.wt., pref. 70W95pts.wt. of an aliphatic ketone (e.g. acetone) and (B) 40W1pts.wt., pref. 30W5pts.wt. of an aliphatic alcohol (e.g. methanol). EFFECT: Methylbenzenes which are difficult to be oxidized to the corresponding hydroperoxides, can be converted to the hydroperoxides by oxidizing in the presence of cumene or cumene hydroperoxide. COPYRIGHT: (C)1981,JPO&Japio
191 Preparation of phenol JP101279 1979-01-11 JPS5594326A 1980-07-17 MATSUNAGA FUJINAO; NANBU HIROHIKO
PURPOSE: To prepare a highly pure phenol compound from the hydroperoxide of an isopropylaromatic compound in high recovery ratio, by pretreating the thermal decomposition product of the hydroperoxide with a polyhydric alcohol or its ether to eliminate the by-products and thereafter recycling the product to the distillation system. CONSTITUTION: A process for the preparation of a phenol compound, comprising acid-decomposition of the hydroperoxide of an isopropylaromatic compound, distillation separation of the useful components, e.g. acetone, a phenol compound, etc., from the product, thermal decomposition of the distillation residue, and recyling of the produced crude phenol compound to the distillation separation process, wherein said crude phenol compound is preliminarily contacted with a polyhydric alcohol or its ether, e.g. ethylene glycol or a polyalkylene glycol, pref. the latter (pref. containing 10W50wt% of water), to form double layers, and the product is recycled to the distillation separation process after removing the hydrocarbon layer from the double layers. COPYRIGHT: (C)1980,JPO&Japio
192 Fuenooruruiofukumu haisuino shoriho JP8855174 1974-07-31 JPS5116757A 1976-02-10 OOKAWA KATSUAKI; CHIKAISHI TSUTOMU; OMURA TAKASHI; KATSUKI HIROSHI; OKAMOTO AKINORI; KENMOCHI HIROTO
193 JPS50139551A - JP4592074 1974-04-25 JPS50139551A 1975-11-07
194 2,6-di-tert-butylphenols JP2007118315 2007-04-27 JP2007246534A 2007-09-27 REIFFENRATH VOLKER; KRAUSE JOACHIM
<P>PROBLEM TO BE SOLVED: To provide new antioxidants in which preparation is easy, cost is low, handling and composition are easy, and which are effective at low concentration. <P>SOLUTION: 2,6-Di-tert-butylphenols are represented by formula I in which R, A<SP>1</SP>, A<SP>2</SP>, Z<SP>1</SP>, Z<SP>2</SP>, m and n have special definitions. These compounds are used as antioxidants or stabilizers. <P>COPYRIGHT: (C)2007,JPO&INPIT
195 Method for producing a phenolic resin binder JP11486792 1992-05-07 JP3581716B2 2004-10-27 キャスリーン・エイチ・コベントリー; デイヴィッド・エイ・セガル
196 Process for producing an alcohol and / or aldehyde from olefin JP50651698 1997-07-14 JP2001500110A 2001-01-09 シュヴァプ,ペーター; パシーロ,ロッコ; ヘーン,アルトゥル
(57)【要約】 アルコール及び/又はアルデヒドが、化学式(I)、XX 1 LL 1 Ru=CR 12 (I)で表され、かつ、R 1とR 2とは、原子又はヘテロ原子を有するか又は有しないC−有機の基であり、XとX 1とは、無関係に陰イオン性の配位子であり、またLとL 1とは、無関係に中性の電子供与性配位子である触媒上で、オレフィンと分子中少なくとも1個の二重結合を有し、かつ、少なくとも1個の水酸基が、C=C二重結合に関してアリル位に存在するアルコールとの交差メタセシスにより、更に続けて任意に水素化及び/又は異性化を行うことにより製造された。
197 1α, 26- dihydroxy -D- homo - vitamin D3 JP28392496 1996-10-25 JP3059108B2 2000-07-04 フェルナンド・シュナイダー
198 Method for producing alcohol JP28136891 1991-10-28 JP2925812B2 1999-07-28 HATSUTORI YASUYUKI; MORI ATSUTO; SHIMONAKA JUJI; TSUKADA KYOSHI
199 2,4-dimethyl--6-s- alkylphenols JP17253690 1990-06-29 JP2923674B2 1999-07-26 RITA PITSUTERODO; HOORU DAPUSU
200 Analytical method for phenol JP20428997 1997-07-30 JPH1151919A 1999-02-26 TOYAMA KENJI; ISOMOTO TOSHITAKA
PROBLEM TO BE SOLVED: To make a high-efficiency, high-accuracy analysis requiring an easy operation and not altering phenol by feeding a polar organic solvent aqueous solution with a specific concentration to a column in advance before it is concentrated. SOLUTION: When phenol is to be analyzed by an octadecyl silica gel-filled chromatographic column (ODS-filled column) by this analytical method for phenol, a polar organic solvent aqueous solution with a specific concentration specified according to the hydrophobic index is fed to the column in advance before a sample containing phenol is fed. The recovery percentage of an analytical object after fractionation by the ODS-filled column is sharply improved as compared with the conventional method, e.g. the level of about 95-100% can be sufficiently maintained against the reference quantity before the solution is fed to the ODS-filled column. The reason for the occurrence of this effect is considered that the column feature is changed to the state favorable to the concentration of phenol and phenol can be efficiently concentrated.
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