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序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
61	Dérivés de l'acide benzoique pour utilisation comme médicament et utilisation de ces dérivés comme agents conservateurs ou désinfectants	EP84401676.6	1984-08-16	EP0135433B1	1989-01-18	Demarne, Henri; Filhol, Robert; Mossé, Madeleine

62	Phenol derivatives, pharmaceutical compositions containing them and process for the preparation of these compounds and pharmaceutical compositions	EP86106126	1986-05-05	EP0202529A3	1988-08-03	Zimmer, Oswald, Dr.; Vollenberg, Werner, Dr.; Loschen, Gerriet, Dr.; Winter, Werner, Prof. Dr.; Kiesewetter, Erwin, Dr.; Seipp, Ulrich, Dr.

63	Dérivés de l'acide benzoique, procédé de préparation et application à titre de médicaments désinfectants ou de conservateurs	EP84401675.8	1984-08-16	EP0135432B1	1988-06-01	Demarne, Henri; Filhol, Robert; Mossé, Madeleine

64	Protease inhibitors	EP84105171.7	1984-05-08	EP0124905B1	1986-10-29	Müller, Richard August; Partis, Richard Allen

65	Processes for making hydroxymethylbenzoic acid compounds	US14581369	2014-12-23	US09328050B1	2016-05-03	Venkata Bharat Ram Boppana; Robert Thomas Hembre; Scott Donald Barnicki; Shane Kipley Kirk
This invention relates to hydrogenation processes for making hydroxymethylbenzoic acid compounds. More specifically, this invention relates to hydrogenation processes in the presence of tertiary amide solvent compounds, as well as compositions that can result from such processes. The invention thus provides processes for making hydroxymethylbenzoic acid compounds.
66	Diels-Alder reactions catalyzed by Lewis acid containing solids: renewable production of bio-plastics	US14282099	2014-05-20	US09108979B2	2015-08-18	Mark E. Davis; Joshua Pacheco
The present disclosure is related to silica-based Lewis acid catalysts, being essentially devoid of strong Brønsted acid character, and their ability to effect the [4+2] cycloaddition and dehydrative aromatization of dienes and dienophiles containing oxygenated substituents to form substituted benzene products. In some embodiments, the processes comprise contacting biomass-derived substrates with ethylene to form terephthalic acid and its derivatives.
67	DIELS-ALDER REACTIONS CATALYZED BY LEWIS ACID CONTAINING SOLIDS: RENEWABLE PRODUCTION OF BIO-PLASTICS	US14561351	2014-12-05	US20150141670A1	2015-05-21	MARK E. DAVIS; JOSHUA J. PACHECO
The present disclosure is related to silica-based Lewis acid catalysts, being essentially devoid of strong Brønsted acid character, and their ability to effect the [4+2] cycloaddition and dehydrative aromatization of dienes and dienophiles containing oxygenated substituents to form substituted benzene products. In some embodiments, the processes comprise contacting biomass-derived substrates with ethylene to form terephthalic acid and its derivatives.
68	DIELS-ALDER REACTIONS CATALYZED BY LEWIS ACID CONTAINING SOLIDS: RENEWABLE PRODUCTION OF BIO-PLASTICS	US14282099	2014-05-20	US20140364631A1	2014-12-11	MARK E. DAVIS; JOSHUA PACHECO
The present disclosure is related to silica-based Lewis acid catalysts, being essentially devoid of strong Brønsted acid character, and their ability to effect the [4+2] cycloaddition and dehydrative aromatization of dienes and dienophiles containing oxygenated substituents to form substituted benzene products. In some embodiments, the processes comprise contacting biomass-derived substrates with ethylene to form terephthalic acid and its derivatives.
69	Method for preparing tricyclic derivatives	US13381036	2010-06-29	US08742160B2	2014-06-03	Myung-Hwa Kim; In-Hae Ye; Jong-Hee Choi
The present invention relates to a method for preparing a tricyclic derivative, and more particularly, to a method for preparing a tricyclic derivative intermediate with high yield and purity, the method including: introducing a hydroxy group by esterifying and substituting 2-fluoroisophthalic acid compound; introducing a piperidyl group; introducing a hydroxy group through reduction reaction; and then hydrolyzing the resultant compound, and to a method for preparing the tricyclic derivative using said intermediate. According to the method of the present invention, it is possible to provide a tricyclic derivative and an intermediate thereof with high productivity and economic feasibility as well as high purity and yield, by purifying a compound using re-crystallization unlike typical methods of using column chromatography. In addition, the method of the present invention can be usefully used for industrial mass production because sodium borohydride or lithium aluminum hydride with low risk of a fire is used unlike typical methods of using lithium borohydride which is not industrially applicable due to high risk of a fire.
70	Catalyst, Use Thereof and Process of Hydrogenating Aryl Aldehydes	US13496070	2010-09-20	US20120178964A1	2012-07-12	Philip O. Nubel; Thomas M. Bartos; Sameer Talreja; Stephen P. Brugge
This invention provides a catalyst and the use thereof and a process for hydrogenating carboxyaryl aldehydes with selectivity to hydroxyalkylaryl monocarboxylic acids. The catalyst comprises iridium.
71	Fluorine-containing dicarboxylic acids and their novel polymer compounds	US12174414	2008-07-16	US08003749B2	2011-08-23	Satoru Narizuka; Yuji Hagiwara; Masashi Nagamori; Kazuhiro Yamanaka
Disclosed is a fluorine-containing dicarboxylic acid represented by formula (1), wherein n represents an integer of 1-4, and the two carboxylic groups are not adjacent to each other on the aromatic ring. It is possible to obtain a linear polymer compound by reacting the fluorine-containing dicarboxylic acid with a comonomer (e.g., diaminodiol). By thermal cyclization, this linear polymer compound can be converted into another polymer compound having superior characteristics.
72	NEW 2-(ALPHA-HYDROXYPENTYL) BENZOATES, THEIR PREPARATIONS AND THEIR USES	US12468929	2009-05-20	US20090227809A1	2009-09-10	Jinghua YANG; Xiaoliang WANG; Zhibin XU; Ying PENG
The invention relates to new synthetic 2-(α-hydroxypentyl) benzoates, their preparation and pharmaceutical compositions containing such salts as active ingredients. The invention also relates to the use of the compounds for preventing and treating cardioischemia, cerebroischemia and cardiac or cerebral arterial occlusion (obstruction), etc.
73	PROCESS FOR THE SYNTHESIS OF PEPTIDES CONTAINING A 4-HYDROXY-PROLINE SUBSTRUCTURE	US12197657	2008-08-25	US20080312456A1	2008-12-18	Bernhard Wietfeld; Walter Prikoszovich; Bernhard Erb; Werner Pachinger
The present invention relates to processes for preparing peptides and to intermediates involved in such processes, e.g. a process for preparing a compound of formula VIII wherein R12 and R13 are as defined herein.
74	Process for the synthesis of peptides containing a 4-hydroxy-proline substructure	US11839565	2007-08-16	US07449587B2	2008-11-11	Bernhard Wietfeld; Walter Prikoszovich; Bernhard Erb; Werner Pachinger
The present invention relates to processes for preparing peptides and to intermediates involved in such processes, e.g. a process for preparing a compound of formula VIII wherein R12 and R13 are as defined herein.
75	PROCESS FOR THE SYNTHESIS OF HYDROXY AROMATIC ACIDS	US12056346	2008-03-27	US20080182962A1	2008-07-31	Joachim C. RITTER
Hydroxy aromatic acids are produced in high yields and high purity (>95%) from halogenated aromatic acids in a reaction mixture containing a copper source and a ligand that coordinates to copper.
76	Process for the synthesis of hydroxy aromatic acids	US11604942	2006-11-28	US07378547B1	2008-05-27	Joachim C. Ritter
Hydroxy aromatic acids are produced in high yields and high purity (>95%) from halogenated aromatic acids in a reaction mixture containing a copper source and a ligand that coordinates to copper.
77	NOVEL PHENOL DERIVATIVES AND ANTITRYPANOSOMA PREVENTIVE/THERAPEUTIC AGENT COMPRISING THE SAME AS ACTIVE INGREDIENT	US10575653	2004-10-18	US20070208078A1	2007-09-06	Hiroyuki Saimoto; Yoshihiro Shigemasa; Kiyoshi Kita; Yoshisada Yabu; Tomoyoshi Hosokawa; Masaichi Yamamoto
A compound represented by formula (I): [wherein, for example, X is a hydrogen atom or a halogen atom; R1 is a hydrogen atom; R2 is a hydrogen atom or a C1-4 alkyl group; R3 is —CHO or —COOH; and R4 is —CH═CH—(CH2)p—CH3 (wherein p is an integer of 1 to 12), —CH(OH)—(CH2)q—CH3 (wherein q is an integer of 1 to 13), —CH(OH)—CH2—CH(CH3)—(CH2)2—CH═C(CH3)2, —CH═CH—CH(CH3)—(CH2)3—CH(CH3)2, —(CH2)2—CH(CH3)—(CH2)3—CH(CH3)2 or —(CH2)8—CH3], an optical isomer thereof and a pharmaceutically acceptable salt thereof. These compounds have antitrypanosoma activity, and accordingly are useful as drugs for preventing or treating the diseases caused by trypanosoma.
78	2-(&agr;-Hydroxypently) benzoate and its preparation and use	US10512792	2002-05-09	US20050288263A1	2005-12-29	Jinghua Yang; Xiaoliang Wang; Zhibin Xu; Ying Peng
The invention relates to new synthetic 2-(α-hydroxypentyl) benzoates, their preparation and pharmaceutical compositions containing such salts as active ingredients. The invention also relates to the use of the compounds for preventing and treating cardioischemia, cerebroischemia and cardiac or cerebral arterial occlusion (obstruction), etc.
79	Producing method of (hydroxyalkyl) alicyclic carboxylic acids and intermediates for producing the same and producing method of such intermediates	US09541609	2000-04-03	US06444843B1	2002-09-03	Yuuichi Satoh; Jun Tatsumi; Toshiya Iida
(Acyloxyalkyl)aromatic carboxylic acids are produced by partial oxidation of alkyl substituted aromatic compounds which are represented by the following General Formula (1) CHR1R2—Ar—(R3)n (1) (where Ar is an aromatic ring of two or greater valency, R1 is a hydrogen atom or alkyl group having a carbon number of 1 to 3, R2 is a hydrogen atom, alkyl group having a carbon number of 1 to 3, or —OCOR5 group, R3 is an alkyl group having a carbon number of 1 to 4, —COOH group, —CHO group, —CH2R4 group, or —COOR group, n is an integer of 1 to 5, R4 is a halogen atom, —OH group, or —OCOR5 group, and R5 is an alkyl group having a carbon number of 1 to 4), and carboxylic acids in the presence of oxygen using a catalyst including an element which belongs to Group VIII of the periodic table. (Hydroxyalkyl)alicyclic carboxylic acids are produced by carrying out hydrogenation and hydrolysis using the (acyloxyalkyl)carboxylic acids as a starting material.
80	Phenol derivatives, pharmaceutical compositions containing these compounds and processes for the preparation of these compounds and compositions	US218981	1988-07-14	US4959391A	1990-09-25	Oswald K. Zimmer; Werner P. Vollenberg; Gerriet K. H. Loschen; Werner Winter; Erwin O. Kiesewetter; Ulrich G. P. Seippl
Phenol derivatives of the formula ##STR1## wherein A and B have the same or different meanings and each represent one of the groups --C.tbd.C--, cis--CH.dbd.CH-- or trans--CH.dbd.CH--, R.sub.1 is hydrogen, an optionally substituted alkyl or phenyl group or a cycloalkyl group, R.sub.2 is hydrogen, methyl or ethyl, R.sub.3 represents hydrogen, acetyl or propionyl, R.sub.4 has the same meaning as R.sub.3 or represents an alkyl group, R.sub.5 is a carboxylic or a hydroxy group or a functional derivative of such groups or R.sub.5 is a nitrile group and R.sub.6 is hydrogen, an alkyl group or the group OR.sub.4 which specifically inhibit 5-lipoxygenase and are useful in pharmaceutical compositions for prophylaxis and treatment of diseases due to the action of leukotrienes. The compounds are prepared by reacting suitable acetylene compounds or metal derivatives thereof with alkyl or aryl halides or by means of Wittig reactions optionally followed by transforming the member R.sub.5 into another carboxylic acid derivative. By hydrogenation A and B may be varied within the scope of the definition.

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