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序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
81	Lubricant composition	US825252	1977-08-17	US4147640A	1979-04-03	Gerald J. J. Jayne; David R. Woods; Joseph P. O'Brien
Lubricating oils having improved antioxidant and antiwear properties are obtained by adding a minor amount of a reaction product made by reacting an olefinic hydrocarbon containing about 6-18 carbon atoms and about 1-3 olefinic double bonds concurrently with sulfur and hydrogen sulfide to obtain a reaction intermediate and reacting this intermediate with additional olefin hydrocarbon which may be the same or different. Preferred olefinic hydrocarbons are dicyclopentadiene and alloocimene.
82	Novel sulfur-containing compositions	US240795	1972-04-03	US3953347A	1976-04-27	Emile Najib Habiby
Compositions suitable as replacements for sulfurized sperm oil as extreme pressure additives in lubricants are obtained by sulfurizing a mixture of at least one fatty acid ester (preferably an oil such as soybean oil), at least one C.sub.8 -.sub.36 aliphatic olefin (preferably an .alpha.-olefin), and, optionally, at least one fatty acid (preferably unsaturated).
83	Sulfurized diels-alder adducts and lubricants containing the same	US3498915D	1968-12-16	US3498915A	1970-03-03	COLEMAN LESTER E

84	Continuous process for preparation of organic sulfur compounds	US20588962	1962-06-28	US3257302A	1966-06-21	WARNER PAUL F

85	Toxic nitriles	US64147757	1957-02-21	US2919225A	1959-12-29	ALLEN HEININGER SAMUEL; BIRUM GAIL H

86	Process for the preparation of surface-active organic nitrosationsulfitation productsin the polyvalent metal salt form	US69757846	1946-09-17	US2510466A	1950-06-06	FESSLER WILLIAM A

87	Production of commercially pure mercaptans and disulfides	US60024545	1945-06-19	US2455656A	1948-12-07	CAULEY STEPHEN P

88	Manufacture of sulfur compounds	US50690443	1943-10-19	US2426648A	1947-09-02	SCHULZE WALTER A; CROUCH WILLIE W

89	Process for producing mercaptans from olefins and hydrogen sulfide	US49346343	1943-07-03	US2426646A	1947-09-02	SCHULZE WALTER A

90	Sulphurization process	US35887640	1940-09-28	US2289437A	1942-07-14	KNOWLES EDWIN C; MCCOY FREDERIC C

91	CONVERSION OF ALKANES TO ORGANOSELENIUMS AND ORGANOTELLURIUMS	EP14833997	2014-08-06	EP3030635A4	2016-07-27	PERIANA ROY A; KONNICK MICHAEL M; HASHIGUCHI BRIAN G
The invention provides processes and materials for the efficient and costeffective functionalization of alkanes and heteroalkanes, comprising contacting the alkane or heteroalkane and a soft oxidizing electrophile comprising Se(VI) or Te(VI), in an acidic medium, optionally further comprising an aprotic medium, which can be carried out at a temperature of less than 300 C. Isolation of the alkylselenium or alkyltellurium intermediate allows the subsequent conversion to products not necessarily compatible with the initial reaction conditions, such as amines, stannanes, organosulfur compounds, acyls, halocarbons, and olefins.
92	A thionation process and a thionating agent	EP13175186.9	2012-02-03	EP2650274A3	2013-12-18	Pettersson, Birgitta; Hasimbegovic, Vedran; Svensson, Per H.; Bergman, Jan
A thionating agent which is crystalline P₂S₅·2 C₅H₅N.
93	A THIONATION PROCESS AND A THIONATING AGENT	EP12702531.0	2012-02-03	EP2569263B1	2013-11-13	PETTERSSON, Birgitta; HASIMBEGOVIC, Vedran; SVENSSON, Per, H.; BERGMAN, Jan
A process for transforming a group >C=O (I) in a compound into a group >C=S (II) or into a tautomeric form of group (II) in a reaction giving a thionated reaction product, by use of crystalline P 2 S 5 ·2 C 5 H 5 N as a thionating agent. A thionating agent which is crystalline P 2 S 5 ·2 C 5 H 5 N.
94	A THIONATION PROCESS AND A THIONATING AGENT	EP12702531.0	2012-02-03	EP2569263A1	2013-03-20	PETTERSSON, Birgitta; HASIMBEGOVIC, Vedran; SVENSSON, Per, H.; BERGMAN, Jan
A process for transforming a group >C=O (I) in a compound into a group >C=S (II) or into a tautomeric form of group (II) in a reaction giving a thionated reaction product, by use of crystalline P 2 S 5 ·2 C 5 H 5 N as a thionating agent. A thionating agent which is crystalline P 2 S 5 ·2 C 5 H 5 N.
95	PROCEDE ET REACTIF DE SULFONYLATION UTILES POUR LA SYNTHESE DE SULFANILIDE PERHALOGENE	EP99954061.0	1999-11-04	EP1127036A1	2001-08-29	DESMURS, Jean-Roger; MILLET, André; PEVERE, Virginie
The invention concerns a method and a reagent useful for the synthesis of perhalogenated sulphanilide on the carbon borne by the sulphur atom of the sulphanilide function. Said perfluoroalkane sulphonylation method is characterised in that it comprises a step which consists in contacting a nucleophile whereof the nucleophilic atom is a nitrogen, with a reagent comprising by successive or simultaneous addition a heavy sulphonyl halide, advantageously sulphonyl chloride, and an organic base comprising a metalloid atom having resonance with a π bond, and the organic part of said sulphonyl is perhalogenated, advantageously perfluorinated, on the carbon borne by the sulphur. The invention is applicable to intermediate synthesis for organic chemistry.
96	Dielectric material	EP99117043.2	1999-08-30	EP0983979A1	2000-03-08	Sato, Motohiko, C/O NGK SPARK PLUG CO., LTD.; Yokoi, Hitoshi, C/O NGK SPARK PLUG CO., LTD.; Ohbayshi, Kazushige, C/O NGK SPARK PLUG CO., LTD.
Disclosed is a dielectric material comprising: a main ingredient having a composition represented by xBaO-yRE₂O₃-zTiO₂, wherein RE represents at least one rare earth element, and $x+y+z=100 mol%$ ; at least one alkali metal oxide; and an ingredient derived from an oxygen supplying agent which releases oxygen on heating.
97	Flüssige Antioxidantien als Stabilisatoren	EP94810528.3	1994-09-13	EP0644195A1	1995-03-22	Evans, Samuel Dr.; Dubs, Paul Dr.; Camenzind, Hugo Dr.
Es werden Produkte beschrieben, erhältlich durch Umsetzung der Komponenten a), b), c) und d), wobei die Komponente a) eine Verbindung der Formel I oder ein Gemisch von Verbindungen der Formel I, die Komponente b) eine Verbindung der Formel II oder ein Gemisch von Verbindungen der Formel II, die Komponente c) eine Verbindung der Formel III oder ein Gemisch von Verbindungen der Formel III, und die Komponente d) eine Verbindung der Formel IV oder ein Gemisch von Verbindungen der Formel IV sind, worin die allgemeinen Symbole wie in Anspruch 1 definiert sind, wobei die Verbindung der Formel I beispielsweise Pentaerythrit, Thiodiethylenglykol, 1,4-Butandiol, 1,2-Propandiol, Diethylenglykol, Triethylenglykol, Diethanolamin oder Glycerin bedeutet, die Verbindung der Formel II beispielsweise Sonnenblumen-Oel oder Kokosfett darstellt, die Verbindung der Formel III beispielsweise 3-(3',5'-Di-tert-butyl-4'-hydroxyphenyl)propionsäuremethylester bedeutet und die Verbindung der Formel IV beispielsweise Schwefel oder Dithiophosphorsäurediisopropylester darstellt. Die genannten Produkte sind als flüssige Antioxidantien in Polymeren und Schmiermitteln einsetzbar.
98	Verfahren zur Hydrosulfinierung von Olefinen	EP94113209.4	1994-08-24	EP0641755A1	1995-03-08	Herwig, Jürgen Kurt-Walter, DCh.; Keim, Wilhelm, Prof. Dr.
Verfahren zur Herstellung von Olefinen durch Verwendung eines Palladiumkatalysators bei einer Temperatur oberhalb der Ceiling-Temperatur des SO₂-Olefin-Copolymersystems zur Synthese von Sulfin- und Sulfonsäurederivaten.
99	Thiation process	EP86111221.7	1986-08-13	EP0212569B1	1991-05-22	Lilje, Kenneth Carl

100	Thiation process	EP86111221	1986-08-13	EP0212569A3	1988-06-01	Lilje, Kenneth Carl
The carbonyl group of an amide is thiated to the corresponding thiono group by reacting the amide with phosphorus pentasulfide in the presence of an alkali metal bicarbonate and a hydrocarbon diluent. In preferred embodiments of the invention, the amide is an aromatic amide, and the diluent is an inert hydrocarbon having a boiling point in the range of 50-l50°C.

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