| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 141 | Manufacture of liquid crystal having a Cf2o bond | JP2007101250 | 2007-04-09 | JP5037999B2 | 2012-10-03 | ピール キルシュ，; アンドレアス タウゲルベック，; デトレフ パウルート，; マティアス ブレメール， |
| 142 | Carbon - sulfur and carbon - poly -n- heterocyclic carbene transition metal complex for oxygen coupling reactions and n- heterocyclic carbene transition metal complex | JP2010506145 | 2008-05-02 | JP2010526063A | 2010-07-29 | ジャッキー ワイ． イン; ラン チャオ; ユゲン チャン |
| 炭素‐硫黄（CS）または炭素‐酸素（CO）カップリング反応のための方法を提供する。 これらの方法は、遷移金属と錯体を形成する複素環式カルベン配位子を含む遷移金属錯体の使用を含む。 ニッケルと錯体を形成する複素環式カルベン配位子を含む遷移金属錯体も提供する。 ニッケル複素環式カルベン錯体は、CSまたはC−Oカップリング反応に使用することができる。
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| 143 | Copper-catalyzed formation of carbon-heteroatom and carbon-carbon bonds | JP2008276608 | 2008-10-28 | JP2009149606A | 2009-07-09 | BUCHWALD STEPHEN L; KLAPARS ARTIS; ANTILLA JON C; JOB GABRIEL E; WOLTER MARTINA; KWONG FUK Y; NORDMANN GERO; HENNESSY EDWARD J |
| <P>PROBLEM TO BE SOLVED: To provide wide copper-catalyzed carbon-heteroatom and carbon-carbon bond-forming methods using the inexpensive copper as a catalyst. <P>SOLUTION: In certain embodiments, provided are copper-catalyzed methods of forming a carbon-nitrogen bond between the nitrogen atom of an amide or amine acyl hydrazide moiety and the activated carbon of an aryl, heteroaryl, or vinyl halide or sulfonate. In additional embodiments, provided are copper-catalyzed methods of forming a carbon-nitrogen bond between the nitrogen atom of a nitrogen-containing heteroaromatic, e.g., indole, pyrazole, and indazole, and the activated carbon of an aryl, heteroaryl, or vinyl halide or sulfonate. In certain embodiments, provided are copper-catalyzed methods of forming a carbon-oxygen bond between the oxygen atom of an alcohol and the activated carbon of an aryl, heteroaryl, or vinyl halide or sulfonate. Provided also are copper-catalyzed methods of forming a carbon-carbon bond between a reactant comprising a nucleophilic carbon atom, e.g., an enolate or malonate anion, and the activated carbon of an aryl, heteroaryl, or vinyl halide or sulfonate. <P>COPYRIGHT: (C)2009,JPO&INPIT | ||||||
| 144 | How to terrorism polymerizing a non-cyclic olefin | JP2003503574 | 2002-05-04 | JP4090052B2 | 2008-05-28 | ヴィーゼ クラウス−ディーター; レットガー ディルク; クライン ホルガー; ベラー マティアス; ヤックステル ラルフ |
| A process for the telomerization of non cyclic olefins (I) having at least two conjugated double bonds or mixtures containing olefins, with nucleophiles (II) comprises use of palladium carbene complexes. | ||||||
| 145 | Production of liquid crystal having cf2o bond | JP2007101250 | 2007-04-09 | JP2007262069A | 2007-10-11 | KIRSCH PEER; TAUGERBECK ANDREAS; PAULUTH DETLEF; BREMER MATTHIAS |
| <P>PROBLEM TO BE SOLVED: To provide a method by which a compound having at least one -CF<SB>2</SB>O- bridge in the molecule and useful as a liquid crystal compound is produced in a satisfactory rate of reaction in excellent yield. <P>SOLUTION: The compound having at least the one -CF<SB>2</SB>O- bridge in the molecule is formed by initially reacting a bis(alkylthio)carbenium salt with a compound containing at least one hydroxy group in the presence of a base and then, preferably in situ, oxidatively fluorinating the resultant compound with a fluorinating agent and an oxidizing agent. Thereby, the compound having at least the one -CF<SB>2</SB>O- bridge in the molecule is formed. <P>COPYRIGHT: (C)2008,JPO&INPIT | ||||||
| 146 | Production method of aryl allyl ether | JP2004526169 | 2003-07-25 | JP2006501209A | 2006-01-12 | ジェイ． ボリアック，クリントン; ケー． リャオ，ツェン |
| A process for preparing an aryl allyl ether is disclosed comprising reacting (a) a phenolic compound with (b) an allyl acetate in the presence of (c) an allylation catalyst selected from a ruthenium or rare earth metal catalyst complex comprising at least one stable ligand containing a substituted aromatic-containing moiety, wherein the aromatic-containing ligand is cyclopentadienyl (Cp), pentamethylcyclopentadienyl (Cp*), indenyl (In), or 9-fluorenyl (F1), or a substituted olefinic-containing ligand, wherein the olefinic moiety is a cyclooctadienyl (COD) or butyldienyl moiety or substituted olefinic-containing ligands. A process for the preparation of an epoxy-containing compound is disclosed comprising epoxidizing the aryl allyl ether compound made according to this invention. | ||||||
| 147 | Method for synthesizing a cyclic fluorinated carboxylic acid ortho ester and the corresponding compound | JP2002537731 | 2001-10-01 | JP2004538244A | 2004-12-24 | キルシュ，ピール; タウゲルベック，アンドレアス |
| 本発明は、環状フッ素化カルボン酸オルトエステル合成のための以下のステップ、ａ）少なくとも１つのビス（アルキルチオ）カルベニウム塩と、少なくとも２つのヒドロキシル基を有する少なくとも１つの有機化合物を、少なくとも１つの塩基存在下で反応させ、ｂ）その後、好ましくはそのまま、得られたチオオルトエステルをフッ素化剤および酸化剤で、酸化的脱硫フッ素化させ、環状フッ素化カルボン酸オルトエステルを得る、ステップを含む方法に関する。 | ||||||
| 148 | Carbon - between hetero atoms and carbon - forming the copper of the carbon-carbon bond between as a catalyst | JP2002583366 | 2002-04-24 | JP2004536798A | 2004-12-09 | ジョン， シー． アンティラ，; マルチナ ウォルター，; アーティス カラパース，; フック， ワイ． クォン，; ガブリエル， イー． ジョブ，; ゲロ ノールマン，; スティーブン， エル． バックウォルド，; エドワード， ジェイ． ヘネシー， |
| The present invention provides a method represented by Scheme 1: wherein X represents I, Br, Cl, alkylsulfonate, or arylsulfonate; Z represents optionally substituted aryl, heteroaryl or alkenyl; catalyst comprises a copper atom or ion, and a ligand; base represents a Bronsted base; and R represents optionally substituted alkyl, cycloalkyl, aralkyl, heteroaralkyl, alkenylalkyl, or alkynylalkyl. | ||||||
| 149 | How to terrorism polymerizing a non-cyclic olefin | JP2003503574 | 2002-05-04 | JP2004534059A | 2004-11-11 | ヴィーゼ クラウス−ディーター; レットガー ディルク; クライン ホルガー; ベラー マティアス; ヤックステル ラルフ |
| A process for the telomerization of non cyclic olefins (I) having at least two conjugated double bonds or mixtures containing olefins, with nucleophiles (II) comprises use of palladium carbene complexes. | ||||||
| 150 | Liquid crystal compound | JP2002549618 | 2001-10-01 | JP2004525090A | 2004-08-19 | キルシュ，ピール; クラウゼ，ヨアヒム; クレメント，ダグマー; パウルート，デトレフ; ヘックマイヤー，ミヒャエル; ルェッセム，ゲオルク |
| 本発明は、式（Ｉ）
【化１】 式中、Ｒ １ 、Ｒ ２ 、Ａ １ 、Ａ ２ 、Ａ ３ 、Ａ ４ 、Ｚ １ 、Ｚ ２ 、ａ、ｂおよびｃは、請求項１中に示した定義を有する、 で表される液晶化合物に関する。 本発明はまた、少なくとも１種の式（Ｉ）で表される化合物を含む液晶媒体およびこのような液晶媒体を１種含む電気光学的ディスプレイに関する。 |
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| 151 | Manufacturing method of a compound having an Cf2o bridge | JP2002549611 | 2001-11-26 | JP2004515535A | 2004-05-27 | キルシュ，ピール; タウゲルベック，アンドレアス; ハーン，アレクサンダー |
| 分子当たりに、少なくとも１つの−ＣＦ
２ −Ｏ−ブリッジを有する化合物の調製方法であって、
ａ）酸を、少なくとも１種のケテンジチオケタールに付加し、 ｂ）得られるビス（アルキルチオ）カルベニウム塩を、塩基の存在下で、少なくとも１つの水酸基を有する少なくとも１種の化合物と反応させ、およびｃ）続いて、好ましくはその場で、得られるジチオオルトエステルに、フッ素化剤および酸化剤を用いて、酸化的フルオロ脱硫化を適用し、分子内当たりに、少なくとも１つの−ＣＦ ２ −Ｏ−ブリッジとの結合を達成する、前記方法に関する。 |
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| 152 | Liquid crystal compound | JP2001303699 | 2001-09-28 | JP2002212144A | 2002-07-31 | KIRSCH PEER; HUBER FLORIAN; KRAUSE JOACHIM; HECKMEIER MICHAEL; PAULUTH DETLEF |
| PROBLEM TO BE SOLVED: To provide a liquid crystal compound that has no or small conventional defects, preferably has a large resistance and a low threshold voltage, particularly provide a medium for such matrix LCD, TN or STN display. SOLUTION: This invention provides a liquid crystal compound represented by general formula I exemplified by a compound represented by formula II and/or formula III (wherein R1 is a 1-10C straight chain alkyl group or a 2-10C alkenyl). | ||||||
| 153 | Production of alkene compound | JP2000151402 | 2000-05-23 | JP2001002614A | 2001-01-09 | AISCAR BAYETO JUAN JOSE; HENKELMANN JOCHEM DR; PREISS THOMAS DR; KNOCHEL PAUL; TZALIS DIMITRIOS; KORADIN CHRISTOPHER |
| PROBLEM TO BE SOLVED: To obtain an alkene compound in an improved and generally utilizable way by reacting an organic compound having at least one amino group, hydroxyl group and/or nitrile group with a compound having at least one acetylene group. SOLUTION: The objective compound of the formula R3-HC=CR2-R4 [wherein R2 and R3 are each H, NH2 or a (substituted) 1-20C hydrocarbon which may be interrupted by at least one nonadjacent heteroatom or may have at least one C-C double bond; R4 is R5R6N, R5R6C(Z) or R7O; R5 to R7 are each NH2 or a (substituted) 1-20C hydrocarbon which may be interrupted by at least one nonadjacent heteroatom or may have at least one C-C double bond; R7O is not a 1,2-aminoalkanol; and Z is CN or COOR (wherein R is H or a 1-6C alkyl)] is obtained by reacting (A) an alkene compound of the formula R4-H except 1,2-aminoalkanols with (B) a compound of the formula R2-C≡C-R3 in the presence of (C) CsOH.H2O as one kind of basic catalyst. COPYRIGHT: (C)2001,JPO | ||||||
| 154 | Sodium phosphate - or alkoxylation process catalyzed by potassium barium | JP34948291 | 1991-12-09 | JP3028432B2 | 2000-04-04 | ケース・ラトイエス; ルドルフ・ヤコブス・ウイーンガールデン |
| Alkylene oxide adducts of organic compounds having active hydrogen atoms are prepared by a process which comprises contacting and reacting an alkylene oxide reactant comprising one or more vicinal alkylene oxides with an active hydrogen containing reactant comprising one or more compounds having active hydrogen atoms in the presence of a catalytically effective amount of sodium barium phosphate or potassium barium phosphate. The product alkoxylates are known to be useful, for instance, as nonionic surfactants, wetting and emulsifying agents, solvents, and chemical intermediates. | ||||||
| 155 | JPH07506101A - | JP51875493 | 1993-04-23 | JPH07506101A | 1995-07-06 | |
| PCT No. PCT/AU93/00174 Sec. 371 Date Feb. 13, 1995 Sec. 102(e) Date Feb. 13, 1995 PCT Filed Apr. 23, 1993 PCT Pub. No. WO93/22266 PCT Pub. Date Nov. 11, 1993Active hydrogen containing organic compounds, for example alcohols, thiols, phenols, thiophenols, carboxylic acids, amides and amines, are alkoxylated, for example, ethoxylated, using catalysts comprising a salt of a Group IIa or Group Ia element and an oxyacid of at least one element chosen from Group IVb, Group Vb or Group VIb, for example, lanthanum titanate, barium titanium, barium strontium titanate, yttrium titanate, lanthanum zirconate, barium zirconate, lanthanum hafnate, barium strontium titanate zirconate and neodymium titanate. The catalyst provide narrow distribution of alkoxylation species and efficient reaction rates. | ||||||
| 156 | Preparation of difluoromethoxyarene and difluoromethylthioarene | JP12802994 | 1994-05-19 | JPH06340567A | 1994-12-13 | KURAUSUUHERUMUUTO MIYURAA |
| PURPOSE: To provide a new method for preparation of difluoromethoxyarene and difluoromethyothioarene. CONSTITUTION: When hydroxyarene or mercaptoarene of formula I [Ar is optionally substd. aryl; Q is oxygen or sulfur] is reacted with chlorodifluoromethane in the presence of alkali, the reaction is carried out in the presence of a phase transfer catalyst based on tetrasubstd. ammonium salt or phosphonium salt and of a solvent selected from aliphat. or non-aliphat. hydrocarbons, arom. hydrocarbons and alkyl ethers, to obtain difluoromethoxyarene or difluoromethylthioarene of formula II [Ar and Q are the same as in formula I]. COPYRIGHT: (C)1994,JPO | ||||||
| 157 | JPH06505954A - | JP50671792 | 1992-03-26 | JPH06505954A | 1994-07-07 | |
| PCT No. PCT/EP92/00675 Sec. 371 Date Oct. 4, 1993 Sec. 102(e) Date Oct. 4, 1993 PCT Filed Mar. 26, 1992 PCT Pub. No. WO92/17405 PCT Pub. Date Oct. 15, 1992Hydrophobicized double-layer hydroxide compounds may be produced if double-layer hydroxide compounds of the general formula (I): [M(II)1-xM(III)x(OH)2] Ax.n H2O, in which M(II) is a divalent metal cation, M(III) is a trivalent metal cation, A is an equivalent of a monobasic and/or multibasic inorganic acid, x is a number from 0.2 to 0.5 and n is a number from 0 to 10, are reacted at elevated temperature and under autogenous pressure with at least one carboxylic acid or its salt and the reaction product is then dried. The hydrophobicized double-layer hydroxide compounds obtained by this process are suitable as catalysts for the alkoxylation of compounds with active hydrogen atoms or of fatty acid esters. | ||||||
| 158 | JPS5312501B2 - | JP2713577 | 1977-03-14 | JPS5312501B2 | 1978-05-01 | |
| 159 | JPS4925243B1 - | JP186467 | 1967-01-11 | JPS4925243B1 | 1974-06-28 | |
| 1,130,822. Derivatives of tetrafluoroethylene oligomers. IMPERIAL CHEMICAL INDUSTRIES Ltd. 19 Dec., 1966 [12 Jan., 1966], No. 1425/66. Heading C2C. [Also in Divisions B2, C3 and D1] Novel derivatives of tetrafluoroethylene oligomers having the formula RfR where Rf is the residue of an oligomer (C 2 F 4 ) n , where n is an integer greater than 3, after removal of fluorine therefrom, and R is the residue of at least one alkali metal derivative of an organic compound, in which the alkali metal is attached to oxygen or carbon, after removal of the alkali metal therefrom, are obtained (1) by reacting the oligomers with the appropriate alkali metal derivatives, (2) by reacting the oligomers with the corresponding hydroxy derivatives in the presence of an organic base, or (3) by interconversion from other compounds of the above formula, e.g. by ester hydrolysis or esterification. Some of the compounds have surfaceactive properties and some have oil or waterrepellent properties. Those compounds containing a vinyl group may be polymerized to polymers having oil or water-repellent properties. | ||||||
| 160 | 비-사이클릭 올레핀의 텔로머화 방법 | KR1020037016073 | 2002-05-04 | KR100855517B1 | 2008-09-02 | 룃트커디르크; 벨러맛티아스; 악크슈텔랄프; 클라인홀거; 비제클라우스-디터 |
| 본 발명은 팔라듐-카르벤 착물을 촉매로서 사용하는, 친핵체(II)에 의한 2개 이상의 공액 이중 결합을 갖는 비-사이클릭 올레핀(I) 또는 이러한 올레핀을 포함하는 혼합물의 텔로머화 방법을 제공한다. 비-사이클릭 올레핀, 팔라듐-카르벤 착물, 텔로머화, 친핵체 | ||||||
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