| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 81 | Calcium phosphate cements made from (TTCP) with surface whiskers and process for preparing same | US11133152 | 2005-05-19 | US20050274282A1 | 2005-12-15 | Jiin-Huey Lin; Chien-Ping Ju; Wen-Cheng Chen |
| A tetracalcium phosphate (TTCP) particle for use in preparing a fast-setting, bioresorbable calcium phosphate cement is disclosed. The TTCP particle has a basic calcium phosphate whiskers on a surface thereof; the basic calcium phosphate whiskers having a Ca/P molar ratio greater than 1.33, and having a length up to about 5000 nm and a width up to about 500 nm. The basic calcium phosphate whiskers are substantially free of a hydroxyapatite phase and mainly composed of TTCP phase. | ||||||
| 82 | Injectable calcium phosphate cements and the preparation and use thereof | US11129029 | 2005-05-13 | US20050271740A1 | 2005-12-08 | Jiin-Huey Lin; Chien-Ping Ju; Wen-Cheng Chen |
| A calcium phosphate cement suitable for use in dental and bone prosthesis is disclosed, which include calcium phosphate particles having a diameter of 0.05 to 100 microns, wherein said calcium phosphate particles on their surfaces have whiskers or fine crystals having a width ranging from 1 to 100 nm and a length ranging from 1 to 1000 nm. | ||||||
| 83 | Injectable calcium phosphate cements and the preparation and use thereof | US11129227 | 2005-05-13 | US20050268819A1 | 2005-12-08 | Jiin-Huey Lin; Chien-Ping Ju; Wen-Cheng Chen |
| A calcium phosphate cement suitable for use in dental and bone prosthesis is disclosed, which include calcium phosphate particles having a diameter of 0.05 to 100 microns, wherein said calcium phosphate particles on their surfaces have whiskers or fine crystals having a width ranging from 1 to 100 nm and a length ranging from 1 to 1000 nm. | ||||||
| 84 | Magnesium ammonium phosphate cement composition | US11104392 | 2005-04-11 | US20050246036A1 | 2005-11-03 | Michael Zimmermann |
| This invention relates to a cement, which comprises in its main phase of microcrystalline magnesium ammonium phosphate and nanoapatite after hardening and thus at the same time has considerable strength. The material is biologically degradable and is suitable for application in tooth cements, as bone replacement, as bone filler, as bone cement or as bone adhesive. | ||||||
| 85 | Process for rendering an ash inert, artificial pozzolana obtained by means of the said process | US11117297 | 2005-04-29 | US20050188904A1 | 2005-09-01 | Claude Criado; Fabrice Giraud; Jean-Emmanuel Aubert; Bernard Husson |
| Process for rendering inert an ash originating from the incineration of municipal waste, according to which the ash is subjected successively to treatment (19) with a water-soluble phosphate (20) in the presence of water, under conditions adjusted to crystallize hydroxyapatite and/or whitlockite, and to calcination (22). Artificial pozzolana, obtained by subjecting an ash originating from the incineration of municipal waste to such an inerting process. | ||||||
| 86 | Method of increasing working time of tetracalcium phosphate cement paste | US10940922 | 2004-09-14 | US20050069479A1 | 2005-03-31 | Jiin-Huey Lin; Chien-Ping Ju; Wen-Cheng Chen; Kuan-Liang Lin; I-Chang Wang |
| A method for increasing working time/setting time of monolithic tetracalcium phosphate (TTCP) cement paste formed by mixing a TTCP powder with an aqueous solution, which includes heating the TTCP powder, prior to the mixing, so that the TTCP powder is maintained at a temperature of 50-350° C. for a period of time which is greater than one minute, and that a TTCP cement paste formed by mixing the resulting heated TTCP powder with the aqueous solution has a prolonged working time in comparison with that formed by mixing TTCP powder that has not been subjected to such heating with the aqueous solution. | ||||||
| 87 | Fast-setting, fibrous, Portland cement-based building material | US10746111 | 2003-12-24 | US20040163573A1 | 2004-08-26 | Dennis Maq Crook; Siti M. Crook |
| A fast-setting, fibrous, Portland Cement-based building material is made by soaking wood chips in water to provide substantially saturated wood chips, combining the saturated wood chips with a slurry of Portland cement to provide a wood chip/cement slurry, mixing a slurry of monomagnesium phosphate (nullMOPnull) with the wood chip/cement slurry to provide a quick-setting MOP/wood chip/cement composition, and compressing the quick-setting MOP/wood chip/cement composition to make the fast-setting, fibrous, Portland Cement-based building material. The inventive composition combines the best properties of cement and wood, yet uses recycled materials to make an environmentally-friendly building material. | ||||||
| 88 | Magnesium-ammonium-phosphates cements, the production of the same and the use thereof | US10070670 | 2002-03-04 | US06692563B2 | 2004-02-17 | Michael Zimmermann |
| This invention relates to a cement, which consists in its main phase of microcrystalline magnesium ammonium phosphate and nanoapatite after hardening and thus at the same time has considerable strength. The material is biologically degradable and is suitable for application in tooth cements, as bone replacement, as bone filler, as bone cement or as bone adhesive. | ||||||
| 89 | Tetracalcium phosphate (TTCP) having calcium phosphate whisker on surface | US10607023 | 2003-06-27 | US20040003757A1 | 2004-01-08 | Jiin-Huey Chern Lin; Chien-Ping Ju; Wen-Cheng Chen; Kuan-Liang Lin; I-Chang Wang |
| A tetracalcium phosphate (TTCP) particle for use in preparing a fast-setting, bioresorbable calcium phosphate cement is disclosed. The TTCP particle has a basic calcium phosphate whiskers or fine crystals on a surface thereof; the basic calcium phosphate whiskers or fine crystals having a Ca/P molar ratio greater than 1.33, and having a length up to about 5000 nm and a width up to about 500 nm. | ||||||
| 90 | Magnesium-ammonium-phosphates cements, the production of the same and the use thereof | US10070670 | 2002-03-04 | US20020166480A1 | 2002-11-14 | Michael Zimmerman |
| This invention relates to a cement, which consists in its main phase of microcrystalline magnesium ammonium phosphate and nanoapatite after hardening and thus at the same time has considerable strength. The material is biologically degradable and is suitable for application in tooth cements, as bone replacement, as bone filler, as bone cement or as bone adhesive. | ||||||
| 91 | Biocompatible cement containing reactive calcium phosphate nanoparticles and methods for making and using such cement | US09978601 | 2001-10-16 | US20020073894A1 | 2002-06-20 | Brian R. Genge; Licia Wu; Glenn R. Sauer; Roy E. Wuthier; Ronald Genge |
| A cement powder is disclosed that contains reactive tricalcium phosphate nanoparticles and other ingredients required to form a cementous material. Methods of making the reactive tricalcium phosphate nanoparticles, the cement powder, the cement paste, and cured cement are also provided, as are methods and articles for using the cement. | ||||||
| 92 | Fast-setting, fibrous, portland cement-based building material | US09767167 | 2001-01-22 | US20010045179A1 | 2001-11-29 | Dennis Maq Crook |
| A fast-setting, fibrous, Portland Cement-based building material is made by soaking wood chips in water to provide substantially saturated wood chips, combining the saturated wood chips with a slurry of Portland cement to provide a wood chip/cement slurry, mixing a slurry of monomagnesium phosphate (nullMOPnull) with the wood chip/cement slurry to provide a quick-setting MOP/wood chip/cement composition, and compressing the quick-setting MOP/wood chip/cement composition to make the fast-setting, fibrous, Portland Cement-based building material. The inventive composition combines the best properties of cement and wood, yet uses recycled materials to make an environmentally-friendly building material. | ||||||
| 93 | Reactive tricalcium phosphate compositions | US570237 | 1995-12-11 | US5683667A | 1997-11-04 | Mark Fulmer; Brent R. Constantz; Ira C. Ison; Bryan M. Barr |
| Methods for producing a room temperature stable, phase pure .alpha.-C.sub.3 P product, and compositions derived therefrom, are provided. In the subject method, a tricalcium phosphate source is heated to a temperature sufficient to convert substantially all of said tricalcium phosphate source to a substantially phase pure .alpha.-C.sub.3 P product. The temperature of the resultant product is rapidly cooled to a temperature below about 700.degree. C., resulting in a room temperature stable, reactive .alpha.-C.sub.3 P product. The resultant .alpha.-C.sub.3 P product may be milled to provide an .alpha.-C.sub.3 P composition which may find use in the preparation of calcium phosphate cements. | ||||||
| 94 | Storage stable calcium phosphate cements | US294325 | 1994-08-23 | US5496399A | 1996-03-05 | Ira C. Ison; Mark T. Fulmer; Bryan M. Barr; Brent R. Constantz |
| Two component, storage stable apatitic cement compositions, as well as methods for their production, are provided. The dry component of subject apatitic cements comprises basic calcium source particles at least partially coated with a partially neutralized acidic calcium phosphate. The dry component of subject compositions is prepared by combining basic calcium source particles with dissolved acidic phosphate in at least a partially aqueous medium, whereby the basic calcium source particles become partially coated with a partially neutralized acidic calcium phosphate. The reaction is terminated prior to completion of the reaction between the acidic phosphate and the basic calcium source by removing the available water from the reaction mixture. In a first mode, the subject cement may be produced by mechanically mixing an acidic phosphate source with basic calcium source particles in the presence of an aqueous solvent and stopping the reaction between the acid and base prior to completion. Alternatively, a phosphoric acid solution may be rapidly combined with a basic calcium phosphate particle slurry such that partially neutralized acidic calcium phosphate precipitates on the surface of the basic calcium phosphate particles. | ||||||
| 95 | Gunnable refractory | US3552984D | 1967-12-18 | US3552984A | 1971-01-05 | MARTINET JACQUES R; ALLEN JIM E |
| A GUNNABLE REFRACTORY COMPOSITION SHOWS GREATLY ENHANCED STICKING AND REDUCED REBOUND, ESPECIALLY WHEN GUNNED ONTO A HOT SURFACE, WHEN PLASTER OF PARIS IS USED AS PLASTICIZER IN THE COMPOSITION. A PREFERRED BOND TO ACHIEVE RAPID SETTING IS ONE CONTAINING BOTH MONOSODIUM DIHYDROGEN PHOSPHATE AND POTASSIUM TRIPOLYPHOSPHATE. A PREFERRED COMPOSITION ALSO CONTAINS HYDRATED LIME AND CARBON, FOR EXAMPLE IN THE FORM OF GRAPHITE.
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| 96 | Basic refractory compositions for intermediate temperature zones | US45346965 | 1965-05-05 | US3285758A | 1966-11-15 | LIMES ROBERT W; DAVID PONZANI |
| 97 | HYDRAULIC CEMENTS, METHODS AND PRODUCTS | PCT/IB2009055042 | 2009-11-12 | WO2010055483A3 | 2010-09-30 | ENGQVIST HAAKAN; ABERG JONAS |
| Non-aqueous hydraulic cement compositions comprise a non-aqueous mixture of a powder composition and a non-aqueous water-miscible liquid. In one embodiment, powder composition is a Brushite or Monetite-forming calcium phosphate powder composition. In another embodiment, the powder composition comprises porous ß-tricalcium phosphate (ß-TCP) granules and at least one additional calcium phosphate powder. In another embodiment, the powder composition comprises calcium silicate powder. In a further embodiment, the powder composition comprises calcium aluminate powder. In another embodiment, the powder composition is a cement composition and comprises nanopowders having a grain size of less than 1 micron. Hardened cements are formed from such hydraulic cement compositions, and methods of producing hardened cements, kits, and articles of manufacture employ such hydraulic cement compositions. | ||||||
| 98 | CALCIUM PHOSPHATE CEMENT COMPOSITION | EP13720218.0 | 2013-04-22 | EP2988789B1 | 2018-05-09 | DÖBELIN, Nicola; TIAINEN, Hanna; BOHNER, Marc |
| A calcium phosphate cement composition that includes the following two components: A) one or several calcium phosphate powders suspended in an aqueous solution including inhibitor cations inhibiting a reaction of the calcium phosphate powders with water, the inhibitor cations being selected from Mg2+, Sr2+ and Ba2+ at a concentration greater than 0.01 M; and B) an aqueous solution including Ca2+ cations at a concentration greater than 0.1 M. This calcium phosphate cement compositions can be safely stored for years yet still retain its full reactivity when mixed. | ||||||
| 99 | CALCIUM PHOSPHATE PARTICLES AND HYDRAULIC CEMENTS BASED THEREON | EP08733826.5 | 2008-05-02 | EP2271585B1 | 2018-03-07 | BOHNER, Marc |
| Calcium phosphate particles having A) a specific surface area (SSA) larger than 0.1 m2/g; B) a mean diameter smaller than 5 mm; C) a Ca/P molar ratio superior to 0.95; and wherein D) said particles have been subjected as a last processing step to a heat treatment at a temperature superior to 400° C. for a period of time such that the specific surface area (SSA) of said particles after the heat treatment is not decreased by more than 10% compared to the SSA before said heat treatment. | ||||||
| 100 | STRUVITE-K AND SYNGENITE COMPOSITION FOR USE IN BUILDING MATERIALS | EP14790451.0 | 2014-10-14 | EP3057921A1 | 2016-08-24 | HAUBER, Robert, J.; BOYDSTON, Gerald, D.; FRAILEY, Nathan; LAMBERET, Severine; PATTARKINE, Gaurav, V.; CHERIAN, Isaac, K.; CENTURIONE, Sergio; GHOSH, Anirban |
| A composition and process for manufacture thereof used in hybrid inventive building materials comprising Syngenite (K 2Ca(SO 4) 2.H 2O) and Struvite-K (KMgPO 4.6H 2O). Starting constituents include magnesium oxide (MgO), monopotassium phosphate (MKP) and stucco (calcium sulfate hemihydrate), mixed in predetermined ratios, cause reactions to proceed through multiple phases, which reactions variously are proceeding simultaneously and in parallel. Variables, e.g., water temperature, pH, mixing times and rates, have been found to affect resultant reaction products. Preferred ratios of chemical constituents and manufacturing parameters, including predetermined weight percent and specified ratios of Struvite-K and Syngenite are provided for building products used for specified purposes. Reactions are optimized in stoichiometry and additives to reduce the combined heat of formation to non-destructive levels. Various additives help control and guide reactions. Building products, such as board panels, include the resultant composition. A significant amount of the composition is disposed adjacent a building panel face. | ||||||
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