序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
61 Method for contact between fluids US37626673 1973-07-03 US3905900A 1975-09-16 GULYAS JAMES W; VYDRA CHARLES
Precipitation of solids from a liquid is effected in a confined contact zone by passing the liquid downwardly through a rising stream of hot gas. A number of light weight spheres are confined within and freely movable throughout the zone. The upper and lower limits of the zone are defined by partitions each composed of a horizontal foraminous divider and an imperforate wall. The imperforate wall extends upwardly and outwardly from the divider and terminates at a wall defining the side limit of the zone. The velocity of the rising gas is highest as it passes through the divider and decreases upwardly therefrom. The gas causes the spheres resting on the divider to move upwardly and outwardly until the gas velocity is no longer capable of keeping the spheres in suspension whereupon the spheres fall downwardly along the side wall and imperforate wall scouring solids precipitated thereon.
62 Removal of cobalt from nickel salt solutions US39328673 1973-08-31 US3903246A 1975-09-02 GANDON LOUIS; BOZEC CHRISTIAN; LENOBLE PHILIPPE
A compound for use as an oxidizing agent in an aqueous saline reaction medium, having a base of nickel salts which is a basic nickel III carbonate of the general formula:
63 Removal of cobalt from nickel salt solutions US29037772 1972-09-19 US3890243A 1975-06-17 GANDON LOUIS; BOZEC CHRISTIAN; LENOBLE PHILIPPE
A composition suitable for use as an oxidizing agent in an aqueous saline solution is disclosed comprising a major portion of a basic nickel III carbonate having the formula
64 Method of preparing hydrated nickel carbonate and the product thereof US31168163 1963-09-26 US3350167A 1967-10-31 MCMULLEN WARREN H; MOONEY THOMAS J; STODDARD JR WILLIAM B
65 炭酸ニッケルの製造方法 JP2014500208 2012-03-26 JP5886410B2 2016-03-16 ティアゴ、バレンティム、ベルニ; アントニオ、クラレティ、ペレイラ; フェリペ、イラリオ、ギマランイス
66 Production method of high-purity nickel sulfate, and method for removing impurity element from solution containing nickel JP2013012563 2013-01-25 JP2014144877A 2014-08-14 HIRAGORI SHINICHI; OZAKI KEICHI; KUDO TAKASHI
PROBLEM TO BE SOLVED: To provide a method for removing impurity elements for selectively removing magnesium from a solution containing nickel, and a production method for producing high-purity nickel sulfate using the method for removing impurity elements.SOLUTION: A production method of high purity nickel sulfate from a solution containing nickel is provided which includes a production process. In the production process,the solution containing nickel in the production process is subjected to an impurity elements removing process comprising: a hydroxylation process for adding an alkali of a hydroxide to the solution containing nickel in the production process, thereby forming hydroxide slurry; a carbonation process for adding an alkali carbonate to the hydroxide slurry, thereby forming a carbonate slurry and recovering a nickel component from the solution; a solid-liquid separation process of the obtained slurry; and a neutralization process for neutralizing a reacted solution obtained in the solid-liquid separation, thereby recovering impurity elements contained in a solution containing nickel in the production process.
67 METHOD FOR PRODUCING reaction agglomerated particles, a method of manufacturing a positive active material for lithium ion batteries, manufacturing equipment preparation and reaction agglomerated particles of a lithium ion battery JP2012139618 2012-06-21 JP5466732B2 2014-04-09 陽 銅谷; 秀徳 後藤
68 Complex carbonate and a method of manufacturing the same JP2008022628 2008-02-01 JP4968944B2 2012-07-04 泰裕 仲岡
The present invention provides a nickel atom-, manganese atom- and cobalt atom-containing composite carbonate that is high in specific surface area and large in tap density, and useful as a raw material for producing a lithium nickel manganese cobalt composite oxide to be used in a positive electrode active material for use in a lithium secondary battery, and provides a method for industrially advantageously producing the composite carbonate. The composite carbonate includes nickel atoms, manganese atoms and cobalt atoms, and has an average particle size of 5 μm or more and less than 20 μm, a BET specific surface area of 40 to 80 m2/g and a tap density of 1.7 g/ml or more.
69 Cobalt (iii) encapsulating the nickel hydroxide and basic carbonate for a battery electrode JP2002563547 2002-02-07 JP2004523067A 2004-07-29 ハウィソン、キャサリン、フィオナ; フィットック、ジョン、アーネスト; ルーカス、チェリル、クリスティーン
(i)コバルトアンミン錯体及びニッケルIIアンミン錯体を含むアンモニア性溶液を調製する工程、(ii)累進的にアンモニア含有量を減少させて、酸化物又は塩基性炭酸塩としてニッケルを経時的に沈殿させる工程、及び、(iii)さらにアンモニア含有量を減少させて、酸化コバルトIII水酸化物としてコバルトの大部分を沈殿させる工程を含み、ここで、酸化コバルトIII水酸化物の大部分は、沈殿物ニッケル水酸化物又は塩基性ニッケル炭酸塩の表面上を被覆して被覆粒子を形成する、コバルトIIIカプセル化されたニッケル水酸化物又は塩基性ニッケル炭酸塩生成物の生成方法。
【選択図】図1
70 Method of manufacturing nickel carbonate JP30946887 1987-12-09 JPH0753582B2 1995-06-07 光昭 木村; 武彦 猪股; 洋一 高沢
71 Production of nickel carbonate or nickel oxide JP32859288 1988-12-26 JPH02172829A 1990-07-04 HASHIMOTO TAKAO; YAMANAKA SHIZUO; SHINJO AKIO; KISHINO SHIZUO
PURPOSE: To produce high purity nickel carbonate for plating at low cost by allowing NaOH solution to absorb CO 2 to produce Na 2CO 3 solution and neutralizing this solution with refined NiSO 4. CONSTITUTION: The NaOH solution is allowed to absorb CO 2 gas in an absorption tower packed with packing to produce Na 2CO 3. Refined NiSO 4 is added to produce NiCO 3, which is then filtered, washed with water and dried to obtain high purity NiCO 3. Further, high purity NiO can be obtained by decomposing the NiCO 3 by heat. COPYRIGHT: (C)1990,JPO&Japio
72 Production of plating carbonate JP32859588 1988-12-26 JPH02172819A 1990-07-04 HASHIMOTO TAKAO; YAMANAKA SHIZUO; KASAI TATSUYUKI; SATO MASANORI
PURPOSE: To reduce the cost by recovering the gaseous CO 2 generated when ZnCO 3 or NiCO 3 is dissolved in an acidic liq., and using the recovered CO 2 as the extractant or neutralizer at the time of obtaining NaCO 3 or NiCO 3. CONSTITUTION: The material contg. Zn or Ni supplied to a dissolver 1A is dissolved in a liq. solvent supplied from a liq. solvent tank 2, the soln. is introduced into an ion-exchange tank 3 through dissolvers 1B and 1C, and metallic Zn or Ni is added. The soln. is then passed through a precipitation tank 4, a precision filter 7, a dissolver 8, ammonium distillation tanks 9A-9C, crystallization towers 10A and 10B, a collection tank 11, and a filter 12 to obtain ZnCO 3 or NiCO 3. The ZnCO 3 or NiCO 3 is supplied to a dissolver 13, and dissolved in an acidic liq. The generated gaseous CO 2 is returned to an absorption tank 14, and absorbed in the aq. ammonia or NaOH recovered in the distillation tanks 9A-9C. The obtained (NH 4) 2CO 3 or Na 2CO 3 is led to the liq. solvent tank 2. COPYRIGHT: (C)1990,JPO&Japio
73 Production of nickel carbonate JP30946887 1987-12-09 JPH01153534A 1989-06-15 TAKAZAWA YOICHI; KIMURA MITSUAKI; INOMATA TAKEHIKO
PURPOSE: To obtain NiCO 3 useful as semiconductor devices readily and stably by adding an alkalizing agent of carbonate to a specific solution to give NiCO 3 precipitate and washing the precipitate with water, adding NaClO to remove a NH 4 compound. CONSTITUTION: NiSO 4 containing 0.3W0.5wt.% NH 3 is dissolved in water under heating with steam to give an aqueous solution of NiSO 4 (A). Then an alkalizing agent is added to component A to give NiCO 3 precipitate (B). Then water is added to the component B, which is stirred about 30min and sufficiently washed with water by decantations of two or more times to remove NH 3 attached to the component B. Then NaClO is continuously added to the prepared component B from which NH 3 is removed under control of ORP (oxidation-reduction potential) until ORP becomes equilibrium approximately at 600mV and the component B is treated until the grade of NH 3 in NiCO 3 becomes ≤0.05wt.% of product standard to give the component B from which NH 3 is highly removed. NaClO is removed from the component B by washing with water to produce NiCO 3. COPYRIGHT: (C)1989,JPO&Japio
74 JPS5324037B2 - JP10103173 1973-09-07 JPS5324037B2 1978-07-18
1437192 Precipitation of metal carbonates INTERNATIONAL NICKEL CO OF CANADA Ltd 10 Sept 1973 [11 Sept 1972] 42445/73 Heading C1A The preparation of a precipitate of the carbonate or basic carbonate of Ni, Co, Cu or Zn is carried out by mixing a stream of an aqueous solution of a water-soluble salt of Ni, Co, Cu or Zn substantially continuously in an agitated reaction zone at 40-60‹ C. and at pH 7À4- 7À8 with a stream of an aqueous solution of an alkali metal carbonate plus optionally alkali metal hydroxide or bicarbonate and the resulting precipitate is recovered, the amount of alkali metal carbonate and hydroxide or bicarbonate, expressed as alkali metal, being that required to use up any free acid in the salt solution and additionally 100-127% of the theoretical stoichiometrie amount required to precipitate the pure normal carbonate. It is preferred to use the sulphate salts of Ni, Co, Cu or Zn and to carry out the precipitation with aeration at 45-55‹ C., the product being easily filterable and highly reactive.
75 好ましい形態を有する不純物含有カソード材料及び不純物含有金属炭酸塩から調製するための方法 JP2017518496 2015-09-30 JP2017536654A 2017-12-07 イェンス・パウルセン; ホンピョオ・ホン; ジンドゥ・オ
リチウムイオンバッテリーにおいて活性正電極材料として使用可能なリチウム金属(M)酸化物粉末を製造するための炭酸塩前駆体化合物であって、Mが、20〜90モル%のNi、10〜70モル%のMn、及び10〜40モル%のCoを含み、前駆体が、ナトリウム及び硫黄不純物を更に含み、ナトリウム対硫黄のモル比(Na/S)が、0.4
76 The method of manufacturing high purity nickel sulfate, and the impurity element removal method from a solution containing nickel JP2013012563 2013-01-25 JP5598778B2 2014-10-01 伸一 平郡; 佳智 尾崎; 敬司 工藤
77 Production method of reactive agglomerated particle, production method of cathode active substance for lithium-ion battery, production method of lithium-ion battery, and production apparatus of reactive agglomerated particle JP2012139618 2012-06-21 JP2014004496A 2014-01-16 DOTANI AKIRA; GOTO HIDENORI
PROBLEM TO BE SOLVED: To provide a production method in which a metallic agglomerated particle, that is expected to have high performance as a cathode active substance and has small particle size and a narrow particle size distribution, can be mass-produced in a small-sized facility.SOLUTION: A whirling current is generated in a reaction processor 10 as a liquid current and additional liquids A, B, each of which contains an inorganic substance to be added, are injected in a reaction field in the reaction processor 10 at the center position parted from the inside surface of the reaction processor 10 to perform reaction processing. The liquid in the reaction processor is circulated and a return liquid of the circulation liquid is injected into the reaction processor to generate the whirling current.
78 Nickel, method for producing a cobalt or copper carbonate or hydroxide of fine spherical particles JP35418898 1998-12-14 JP4174887B2 2008-11-05 日六士 中尾; 信治 大釜; 一允 安倍; 英人 水谷; 一彦 永野; 清志 深井; 勉 畑中; 成文 神坂; 稔 米田
79 Method for producing nickel carbonate or nickel oxide JP32859288 1988-12-26 JPH0637308B2 1994-05-18 静雄 山中; 静夫 岸野; 昭夫 新城; 孝夫 橋本
80 JPH0544411B2 - JP32859588 1988-12-26 JPH0544411B2 1993-07-06 HASHIMOTO TAKAO; YAMANAKA SHIZUO; KASAI TATSUYUKI; SATO MASANORI
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