序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
21 NICKEL COMPOSITIONS FOR PREPARING NICKEL METAL AND NICKEL COMPLEXES US12968373 2010-12-15 US20110311428A1 2011-12-22 John J. Ostermaier
Nickel compositions for use in manufacturing nickel metal compositions, and specifically to methods of making basic nickel carbonates used to produce nickel metal compositions are disclosed. By varying the molar ratios of carbonates and bicarbonates to nickel salts, the methods provide basic nickel carbonates that produce superior nickel-containing solids that react more effectively with phosphorous-containing ligands. The phosphorous containing ligands can be both monodentate and bidentate phosphorous-containing ligands.
22 COMPOSITE CARBONATE AND METHOD FOR PRODUCING THE SAME US13014855 2011-01-27 US20110114900A1 2011-05-19 Yasuhiro Nakaoka
The present invention provides a method for producing a nickel atom-, manganese atom- and cobalt atom-containing composite carbonate that is high in specific surface area and large in tap density, and useful as a raw material for producing a lithium nickel manganese cobalt composite oxide to be used in a positive electrode active material for use in a lithium secondary battery. The composite carbonate includes nickel atoms, manganese atoms and cobalt atoms, and has an average particle size of 5 μm or more and less than 20 μm, a BET specific surface area of 40 to 80 m2/g and a tap density of 1.7 g/ml or more.
23 Process for complete utilisation of olivine constituents US11630835 2005-06-06 US07763221B2 2010-07-27 Oddmund Wallevik; Tom Rames Jørgensen; Aage Aasheim; Birger Langseth
A novel process for complete utilization of olivine is based on purification of brine by oxidation and precipitation of iron and nickel compounds.
24 Process for Complete Utilisation of Olivine Constituents US11630835 2005-06-06 US20080075645A1 2008-03-27 Oddmund Wallevik; Tom Jorgensen; Aage Aasheim; Birger Langseth
A novel process for complete utilization of olivine is based on purification of brine by oxidation and precipitation of iron and nickel compound.
25 Method for producing fine spherical particles of carbonate or hydroxide of nickel, cobalt or copper US09463021 2000-03-22 US06197273B1 2001-03-06 Kazuhiko Nagano; Kazunobu Abe; Shigefumi Kamisaka; Kiyoshi Fukai; Tsutomu Hatanaka; Shinji Ohgama; Hiroshi Nakao; Minoru Yoneda; Hideto Mizutani
The invention provides a process for production of fine spherical particles of a carbonate or a hydroxide of nickel, cobalt or copper which comprises: dissolving a carbonate or a hydroxide of nickel, cobalt or copper having the general formula (I) M(CO3)x/2.(OH)y wherein M represents Ni, Co or Cu, and x and y are numerals satisfying the followings: 0≦x≦2, 0≦y≦2 and x+y=2, in aqueous ammonia, converting the resulting solution to a W/O emulsion containing droplets of the solution in a non-aqueous medium, and then removing volatile components including ammonia from within the droplets, thereby precipitating a basic carbonate or a hydroxide of a metal selected from nickel, cobalt and copperin the droplets. The fine spherical particles of a carbonate or a hydroxide of nickel, cobalt or copper obtained according to the process of the invention are especially useful as a precursor for the manufacture of uniform, fine spherical particles of nickel, copper or cobalt metal, as well as useful as themselves as a catalyst for use in organic synthesis, a carrier, a pigment, a filler or a glaze.
26 Enhanced cobalt recovery in the distillation of ammoniacal carbonate solutions of nickel and cobalt US37759873 1973-07-09 US3903245A 1975-09-02 WIEWIOROWSKI TADEUSZ KAROL; MILLER DAVID JAMES
In the straight distillation of aqueous ammoniacal carbonate solutions containing nickel and cobalt for the non-selective recovery of these metals as a mixed precipitate consisting mainly of basic nickel and cobalt carbonates, cobalt recoveries are significantly improved by carrying out the distillation in the presence of small amounts of sulfide ions.
27 Method for the production of high purity dense nickel oxide and the product thereof US38220864 1964-07-13 US3342547A 1967-09-19 ALEXANDER ILLIS; JOACHIM KOEHLER HANS; BRANDT BERNARDUS J
28 METHOD FOR PRODUCING HIGH-PURITY NICKEL SULFATE AND METHOD FOR REMOVING IMPURITY ELEMENT FROM SOLUTION CONTAINING NICKEL EP14742850 2014-01-20 EP2949626A4 2016-12-21 HEGURI SHIN-ICHI; OZAKI YOSHITOMO; KUDO KEIJI
Provided are an impurity-element removing method for selectively removing magnesium from a nickel-containing solution, and a method for producing high-purity nickel sulfate using the impurity-element removing method. The production method includes a production process in the production method of producing high-purity nickel sulfate from a nickel-containing solution, and the nickel-containing solution in the production process is subjected to an impurity-element removal treatment that includes: a hydroxylation step of adding an alkali hydroxide to the nickel-containing solution in the production process to form a hydroxylated slurry; a carbonation step of adding an alkali carbonate to the hydroxylated slurry to form a carbonated slurry, and recovering nickel component from the solution; a solid-liquid separation step for the slurry thus obtained; and a neutralization step of subjecting a solution after reaction obtained by solid-liquid separation to a neutralization, and recovering an impurity element included in the nickel-containing solution in the production process.
29 PRODUCTION METHOD FOR REACTION-AGGLOMERATED PARTICLES, PRODUCTION METHOD FOR POSITIVE ELECTRODE ACTIVE MATERIAL FOR LITHIUM ION CELL, PRODUCTION METHOD FOR LITHIUM ION CELL, LITHIUM ION CELL, AND APPARATUS FOR PRODUCTION OF REACTION-AGGLOMERATED PARTICLES EP13807347 2013-02-15 EP2866284A4 2016-03-16 DOYA YO; GOTO HIDENORI
30 PROCESS FOR PRODUCTION OF NICKEL CARBONATE" EP12764036.5 2012-03-26 EP2688842A2 2014-01-29 BERNI, Tiago Valentim; PEREIRA, Antonio Clareti; GUIMARÃES, Felipe Hilario
Aspects of the present invention refers to a process for production of nickel carbonate including preparing a magnesium salt solution, contacting the solution with a stream of gaseous CO2, keeping pH between 4 and 10 and temperature between 0 and 100° C., during up to 5 hours to produce a first mixture, contacting the first mixture with a nickel sulphate solution to produce a second mixture, performing a separation of liquid and solid portions of the second mixture, and feeding the magnesium salt solution with the liquid portion. This process recycles the reagent used for producing nickel carbonate and yields a final product that is easy to handle and transport.
31 NICKEL COMPOSITIONS FOR PREPARING NICKEL METAL AND NICKEL COMPLEXES EP10838214.4 2010-12-15 EP2658651A1 2013-11-06 OSTERMAIER, John, J.
Nickel compositions for use in manufacturing nickel metal compositions, and specifically to methods of making basic nickel carbonates used to produce nickel metal compositions are disclosed. By varying the molar ratios of carbonates and bicarbonates to nickel salts, the methods provide basic nickel carbonates that produce superior nickel-containing solids that react more effectively with phosphorous-containing ligands. The phosphorous containing ligands can be both monodentate and bidentate phosphorous-containing ligands.
32 Method for producing high-purity nickel sulfate and method for removing impurity element from solution containing nickel US14653077 2014-01-20 US09567239B2 2017-02-14 Shin-ichi Heguri; Yoshitomo Ozaki; Keiji Kudo
Provided are an impurity-element removing method for selectively removing magnesium from a nickel-containing solution, and a method for producing high-purity nickel sulfate using the impurity-element removing method. The production method includes a production process in the production method of producing high-purity nickel sulfate from a nickel-containing solution, and the nickel-containing solution in the production process is subjected to an impurity-element removal treatment that includes: a hydroxylation step of adding an alkali hydroxide to the nickel-containing solution in the production process to form a hydroxylated slurry; a carbonation step of adding an alkali carbonate to the hydroxylated slurry to form a carbonated slurry, and recovering nickel component from the solution; a solid-liquid separation step for the slurry thus obtained; and a neutralization step of subjecting a solution after reaction obtained by solid-liquid separation to a neutralization, and recovering an impurity element included in the nickel-containing solution in the production process.
33 Method for producing size selected particles US14265638 2014-04-30 US09446967B2 2016-09-20 Gregory K. Krumdick; Young Ho Shin; Kaname Takeya
The invention provides a system for preparing specific sized particles, the system comprising a continuous stir tank reactor adapted to receive reactants; a centrifugal dispenser positioned downstream from the reactor and in fluid communication with the reactor; a particle separator positioned downstream of the dispenser; and a solution stream return conduit positioned between the separator and the reactor. Also provided is a method for preparing specific sized particles, the method comprising introducing reagent into a continuous stir reaction tank and allowing the reagents to react to produce product liquor containing particles; contacting the liquor particles with a centrifugal force for a time sufficient to generate particles of a predetermined size and morphology; and returning unused reagents and particles of a non-predetermined size to the tank.
34 METHOD OF MANUFACTURING REACTION AGGLOMERATED PARTICLES, METHOD OF MANUFACTURING CATHODE ACTIVE MATERIAL FOR LITHIUM ION BATTERY, METHOD OF MANUFACTURING LITHIUM ION BATTERY, LITHIUM ION BATTERY, AND DEVICE OF MANUFACTURING REACTION AGGLOMERATED PARTICLES US14409347 2013-02-15 US20150188133A1 2015-07-02 Yo Doya; Hidenori Goto
Liquid flow in a reaction processing vessel 10 is set to a spiral flow, a liquid A and B as an additional liquid containing an inorganic substance to be added is injected at a center-side position with respect to an inner surface of the reaction processing vessel 10 in a reaction field of the reaction processing vessel 10 so as to perform reaction processing.
35 Method of Manufacturing Metal Agglomerate, Method of Manufacturing Lithium Ion Battery Cathode Active Material, Method of Manufacturing Lithium Ion Battery, and Lithium Ion Battery US14373626 2012-12-21 US20150030522A1 2015-01-29 Yo Doya; Hidenori Goto
To obtain metal agglomerate having stable particle sizes and substantially spherical shapes, the method allows, by a circulation unit, a flow of a liquid containing metal to pass through a processing vessel and an external circulation path, and a part of the liquid from the processing vessel to be extracted to an outside in a substantially continuous manner so as to return to the processing vessel after it goes through the external circulation path, sets a flow velocity in the external circulation path to be 1 m/second or more, and injects at least a part of a liquid concentrate containing a reactant to be newly added into the external circulation path.
36 Decontamination of radioactive metals US14163593 2014-01-24 US08802041B1 2014-08-12 W. Novis Smith; David S. Eaker
There is provided a process for decontaminating and converting volumetrically contaminated radioactive metals, especially nickel, and recovering a decontaminated metal hydroxide or metal carbonate. The process includes the use of hydrogen peroxide to oxidize and remove nucleotides.
37 NICKEL METAL COMPOSITIONS AND NICKEL COMPLEXES DERIVED FROM BASIC NICKEL CARBONATES US12968341 2010-12-15 US20110196168A1 2011-08-11 JOHN J. OSTERMAIER
Nickel-metal-containing solids for use in manufacturing nickel metal complexes are disclosed. The nickel-metal-containing solids are made by reducing basic nickel carbonates. By varying the molar ratios of carbonates and bicarbonates to nickel salts, the methods provide basic nickel carbonates that produce superior nickel metal-containing solids that react more effectively with phosphorous-containing ligands. The phosphorous containing ligands can be both monodentate and bidentate phosphorous-containing ligands.
38 Composite carbonate and method for producing the same US12362918 2009-01-30 US07897069B2 2011-03-01 Yasuhiro Nakaoka
The present invention provides a nickel atom-, manganese atom- and cobalt atom-containing composite carbonate that is high in specific surface area and large in tap density, and useful as a raw material for producing a lithium nickel manganese cobalt composite oxide to be used in a positive electrode active material for use in a lithium secondary battery, and provides a method for industrially advantageously producing the composite carbonate. The composite carbonate includes nickel atoms, manganese atoms and cobalt atoms, and has an average particle size of 5 μm or more and less than 20 μm, a BET specific surface area of 40 to 80 m2/g and a tap density of 1.7 g/ml or more.
39 Cobalt encapseated nickel hydroxides and basic carbonates for battery electrodes US10635906 2003-08-07 US20040091414A1 2004-05-13 John Ernest Fittock; Cheryl Christine Lucas; Katherine Fiona Howison
A process for producing a cobalt III encapsulated nickel hydroxide or basic nickel carbonate product including the steps of: (i) providing an ammoniacal solution including cobalt ammine complexes and nickel II ammine compleses; (ii) progressively reducing the ammonia content to sequentially precipate the nickel as an hydroxide or basic carbonate; and (iii) further rudce the ammonia content to precipitate the majority of the cobalt as cobalt III oxide hydroxide; wherein the majority of cobalt III oxide hydroxide coats on the surface of the precipitate nickel hydroxide or basic nickel carbonate to form a coated particle.
40 Separation and recovery of metal alloys from superalloy scrap US380859 1982-05-21 US4442073A 1984-04-10 Douglas J. Robinson; Aniedi O. Ette
A method for recovering superalloy scrap is disclosed. The method involves oxidizing superalloy scrap in an aqueous acidic medium. The aqueous acidic medium has an oxidation potential sufficient to oxidize nonferrous additive superalloy elements to insoluble oxides thereof and to oxidize major superalloy constituents to aqueously soluble species. The insoluble solids from the aqueous solution are separated when the aqueous solution is extracted with an aqueously substantially insoluble tertiary amine to form an organic phase and an aqueous phase. The aqueous phase contains essentially nickel and chromium values. The organic phase is sequentially extracted with aqueous solutions which selectively solubilize individual metal value species to form individual aqueous solutions having substantially single metal value species therein. The metal value species solutions are processed to obtain substantially pure metals.
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