序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
141 Adduct thermosetting surfacing film and method of forming the same US13288888 2011-11-03 US09725567B2 2017-08-08 Qiang Wang; Ito Akihiro; Paul Kyle; Augusto Arakaki; Catalina Gutierrez
In various embodiments, the invention provides an in-situ adduct formed by reacting liquid, solid, and/or semi-solid epoxy resins with a di-carboxylic acid functionalized polymer. The adducting process at least doubles the viscosity of the mixture. A hot melt thermosetting surfacing film and composite formed using the adduct are also disclosed. Methods of preparing and using are also disclosed.
142 INDUCTIVELY CURABLE COMPOSITION US15324738 2015-08-18 US20170198116A1 2017-07-13 Jung-Sheng Wu; Lijun Zu; Zeba Parkar
An inductively curable thermoset compositions comprising a thermoset resin and, dispersed therein, susceptor particles and surface modified silica particles is described.
143 METHODS, SYSTEMS AND APPARATUSES FOR CURING EPOXY-CONTAINING PREPREG COMPOSITE ASSEMBLY US14987988 2016-01-05 US20170190855A1 2017-07-06 Gwen M. Gross; Michael P. Thompson
Methods and systems and components made according to the methods and systems, are disclosed relating to improved curing methods for epoxy resin-containing composite prepreg materials, wherein the composite prepreg materials are exposed to a flow of ammonia-containing compounds to fully cure the composite prepreg materials at substantially ambient temperatures and pressures.
144 Fiber reinforced polymer composite with a hard interphase US14650138 2013-12-23 US09688891B2 2017-06-27 Felix N. Nguyen; Kenichi Yoshioka; Swezin Than Tun; Alfred P. Haro
A fiber reinforced polymer composition is provided comprising a fiber and an adhesive composition, wherein the adhesive composition comprises at least a thermosetting resin, a curing agent, and a hard interfacial material. When cured, the adhesive composition forms good bonds to the reinforcing fiber, and an interfacial region between the reinforcing fiber and the adhesive composition is formed which comprises the hard interfacial material. Additional embodiments include a prepreg and a method of manufacturing a composite article by curing the adhesive composition and the reinforcing fiber.
145 Process of manufacturing thickeners and the use of thus produced thickeners in high-viscosity epoxy resin formulations US15355447 2016-11-18 US09670339B1 2017-06-06 Klaus Dziwok; Helmut Coutelle; Robert G. Briell; Tyler Nash
The invention relates to the use of at least one mixed mineral organoclay rheology additive in a liquid composition comprising at least one epoxy resin, the additive comprises or consists of a quaternary alkyl-ammonium salt treated mineral clay mixture prepared by forming an aqueous hormite clay slurry (a), forming an aqueous smectite clay slurry (b), combining the aqueous hormite clay slurry (a) with the aqueous smectite clay slurry (b) to form a combined clay slurry (c), treating the combined clay slurry (c) with one or more quaternary alkyl-ammonium salts, and separating the produced quaternary alkyl-ammonium salt treated mineral clay mixture from the aqueous medium. The invention also relates to a process for producing a mixed mineral organoclay rheology additive and the use of the thus produced additive as a thickening agent in liquid compositions.
146 Epoxy resin formulation for large and thick composite structures US14431039 2013-03-26 US09670328B2 2017-06-06 Rahul Harshe; Ranjith Kottot; Anoop Anand; Makarand Joshi
In the present disclosure!, there is disclosed an epoxy resin formulation for the manufacturing of large and thick composite structures, said formulation comprising i) at least one epoxy resin in a weight proportion varying between 50 parts to 70 parts; (ii) at least one hardening agent in a weight proportion varying between 21 phr to 29 phr; (iii) at least one diluent in a weight proportion varying between 10 phr to 40 phr; and (iv) N,N′dimethylaminopropylamine as an accelerator in a weight proportion varying between 0.5 phr to 3.0 phr. The formulation is used in the manufacturing of large and thick composite structures by employing Vacuum Assisted Resin Transfer Molding Process.
147 Cycloaliphatic carbonates as reactive diluents in epoxy resins US15364801 2016-11-30 US20170081465A1 2017-03-23 Bruce L. Burton
Embodiments of the present invention disclose a method for limiting peak exotherm temperatures in epoxy systems comprising the step of: combining an amine hardener, an epoxy and a diluent to form an epoxy system, wherein the diluent is selected from the group consisting of: ethylene carbonate, propylene carbonate, butylene carbonate, delta-valerolactam, delta-valerolactone, gamma valerolactone, butyrolactam, beta butyrolactone, gamma butyrolactone, and combinations thereof.
148 RESIN COMPOSITION AND CURED PRODUCT THEREOF US15123020 2014-11-06 US20170066899A1 2017-03-09 Seiji NAKAJIMA; Yosuke TATSUNO; Mitsuo ITO; Satoshi HIRONO; Yuzo MORISAKI; Junji KAWAMOTO
The present invention provides a resin composition which can be cured in a short time without a heat load on an adherend and with which a cured product having stable quality can be obtained. The resin composition in accordance with the present invention contains (i) a bisphenol A epoxy resin, (ii) an encapsulated curing agent including a core that contains a curing agent and a shell that covers the core, (iii) a filler, and (iv) a color material.
149 COMPOSITES AND EPOXY RESINS BASED ON ARYL SUBSTITUTED COMPOUNDS US15336503 2016-10-27 US20170051119A1 2017-02-23 Larry Steven CORLEY; Robert Dale Farris; Carlton E. Ash
Compositions and methods for forming epoxy resin are provided, and compositions and methods for forming epoxy resin composites are provided. In one embodiment, a composite comprises an epoxy resin composition comprising an epoxy resin component comprising a glycidyl ether of an aryl substituted phenolic compound, a curing agent component, and a substrate. In one embodiment, a composite comprises an epoxy resin composition comprising an epoxy resin component and a curing agent component comprising an aryl substituted phenolic compound, and a substrate.
150 ELECTRONIC COMPONENT DEVICE PRODUCTION METHOD AND ELECTRONIC COMPONENT SEALING SHEET US15107203 2014-12-22 US20170040287A1 2017-02-09 Goji Shiga; Tsuyoshi Ishizaka; Kosuke Morita; Chie Iino
The electronic component device production method includes a step A of preparing a layered body comprising electronic components immobilized on a support body, a step B of preparing an electronic component sealing sheet, a step C of disposing the electronic component sealing sheet over the electronic components under conditions where the probe tack force of the electronic component sealing sheet is 5 gf or lower according to a probe tack test, a step D of rising the temperature of the electronic component sealing sheet until the probe tack of the electronic component sealing sheet is 10 gf or greater according to the probe tack test to immobilize temporarily the electronic component sealing sheet onto the electronic components, and a step E of embedding the electronic components in the electronic component sealing sheet to form a sealed body comprising the electronic components embedded in the electronic component sealing sheet.
151 Phosphorous containing compounds and process for synthesis US14932092 2015-11-04 US09546262B1 2017-01-17 An-Pang Tu; Szu-Fang Chen; Ping-Chieh Wang; Kuen-Yuan Hwang
The instant disclosure relates to phosphorus-containing compounds that can be used to form flame retardant phosphorus-containing resins, and also can serve as a hardener for a flame retardant epoxy resin compositions. In particular, the phosphorus-containing compounds are modified with acyloxy groups (—O—(C═O)—R), as shown below. Incorporation of the acyloxy groups results in resins that are water resistant and exhibit improved dielectric properties.
152 SIZING COMPOSITION FOR REINFORCING FIBRES AND APPLICATIONS THEREOF US15117756 2015-02-11 US20160355645A1 2016-12-08 Arnaud Martin; Brigitte Defoort; Xavier Coqueret
A sizing composition for reinforcing fibres is provided which makes it possible to improve the adhesion of these fibres with respect to an organic matrix that forms, with them, a part made of a composite material and that results from the chain transfer polymerization of a curable resin. The sizing composition includes a polybutadiene prepolymer comprising at least two epoxide functions, a cross-linking agent comprising at least two reactive functions, at least one of which is a thiol function; and a catalyst comprising at least one tertiary amine function. The sizing composition may be used in the following fields of use: aeronautical, aerospace, railway, naval and motor vehicle industries, for example, for the production of structural, engine, passenger compartment or body work parts; arms industry, for example, for the production of parts incorporated into the composition of missiles or missile launch tubes; sports and leisure goods industry, for example, for the production of goods intended for water sports and board sports.
153 FAST CURING HIGH GLASS TRANSITION TEMPERATURE EPOXY RESIN SYSTEM US15037498 2015-02-02 US20160347903A1 2016-12-01 Timothy A. Morley; Rainer Koeniger; Sergio Grunder; Nebojsa Jelic; Rolf Hueppi
A two-component curable epoxy resin system having an epoxy component containing a unique combination of two or more epoxy resins with at least one of the epoxy resins being an epoxy novolac type resin. The composite made from such resin system exhibits high glass transition temperature.
154 Composites and epoxy resins based on aryl substituted compounds US14275093 2014-05-12 US09499692B2 2016-11-22 Larry Steven Corley; Robert Dale Farris; Carlton E. Ash
Compositions and methods for forming epoxy resin are provided, and compositions and methods for forming epoxy resin composites are provided. In one embodiment, a composite comprises an epoxy resin composition comprising an epoxy resin component comprising a glycidyl ether of an aryl substituted phenolic compound, a curing agent component, and a substrate. In one embodiment, a composite comprises an epoxy resin composition comprising an epoxy resin component and a curing agent component comprising an aryl substituted phenolic compound, and a substrate.
155 Rapidly Curing Adhesives Using Encapsulated Catalyst and Focused Ultrasound US14667220 2015-03-24 US20160280867A1 2016-09-29 ANDREW P. NOWAK; GEOFFREY P. McKNIGHT; CARISSA A. PAJEL; SOPHIA S. YANG; THOMAS I BOUNDY; APRIL R. RODRIGUEZ; DARRIN M HANSEN; ALAIN A ADJORLOLO
Methods for making and curing resin-based adhesives are disclosed using encapsulated amine accelerators activated by providing ultrasonic energy.
156 CURABLE COMPOSITIONS US15032324 2014-12-02 US20160280846A1 2016-09-29 Krishnan Karunakaran; Marvin L. Dettloff; Nikhil K.E. Verghese; Ha Q. Pham
A dual cure system including at least two different and separate types of chemical reactions occurring as the process of the present invention proceeds including, for example, the following two reactions: (1) free radical polymerization of methacrylated or acrylated polyol; and (2) an epoxy-curing agent reaction. The dual cure system of the present invention advantageously provides a first cure reaction of methacrylated or acrylated polyol followed by a second epoxy-curing agent thermoset reaction to form a cured thermoset exhibiting an elongation property of greater than about 5%.
157 DEGRADABLE HYDRAZONE CURING AGENTS AND APPLICATIONS THEREOF US15024174 2014-09-24 US20160264718A1 2016-09-15 BING QIN; XIN LI; BO LIANG
This invention provides, among others, curing agents of Formulae (I) and (II), methods for preparing these curing agents, prepreg materials, degradable cross-linked polymers and reinforced composites made from these curing agents and epoxy resins, and methods for degrading and/or recycling the degradable polymers and reinforced composites.
158 IMPROVEMENTS IN OR RELATING TO FOAM FILLED HONEYCOMB STRUCTURES US15030618 2014-10-20 US20160243733A1 2016-08-25 Francis Meyer; Morgan Chene
Spherical heat foamable pellets (2) are used for reinforcing honeycomb structures (4). The pellets are preferably of average diameter from 0.5 mm to 0.9 mm and preferably at least 80% of the pellets have a diameter in this range. The pellets can form a free flowing stream which can be poured into the cells (5) of the honeycomb where they can be foamed by heating to form a reinforcing foam which can also bond the honeycomb structure to facing sheets. It is preferred that the pellets are based on a thermosetting resin and contain a curing agent that can cure the foamed resin to produce an integral rigid reinforcing foam within the cells of the honeycomb.
159 RESIN COMPOSITION, COPPER CLAD LAMINATE AND PRINTED CIRCUIT BOARD USING SAME US14411166 2013-08-23 US20160222204A1 2016-08-04 Rongtao WANG; Yu-Te Lin; Wenjun Tian; Ziqian Ma; Wenfeng Lv; Ningning Jia
The present invention provides a resin composition comprising: (A) 100 parts by weight of epoxy resin; (B) from 10 to 80 parts by weight of benzoxazine resin; (C) from 10 to 50 parts by weight of dicyclopentadiene phenol resin; and (D) from 0.5 to 5 parts by weight of amine hardener; wherein the resin composition is free of diallyl bisphenol A (DABPA).
160 EPOXY RESIN COMPOSITION, PREPREG, AND CARBON FIBER-REINFORCED COMPOSITE MATERIAL US14896865 2014-07-10 US20160152785A1 2016-06-02 Shizue UENO; Nobuyuki ARAI; Jun MISUMI; Hiroshi TAIKO
An epoxy resin composition including [A1] a hardener represented by Formula (1), and [B] an aromatic epoxy resin having tri- or higher functionality, wherein a carbon nuclear relaxation time T1C corresponding to a benzene ring carbon atom in the main backbone of Formula (1) assigned to 130 ppm in a solid-state 13C-NMR spectrum is 42 seconds or longer, and a prepreg and a carbon fiber-reinforced composite material obtained using the epoxy resin composition: wherein X represents any one selected from —CH2—, —O—, —CO—, —C(═O)O—, —S—, —SO2—, and —NHC(═O)—; n represents 1 to 5; and R1 to R6 each represent at least one selected from the group consisting of a hydrogen atom, an aliphatic hydrocarbon group having 1 to 4 carbon atoms, an alicyclic hydrocarbon group having 4 or less carbon atoms, and an a halogen atom, wherein when X is —C(═O)O— or —NHC(═O)—, X may be in either direction. Provided are an epoxy resin composition that provides a carbon fiber-reinforced composite material excellent in tensile strength and compression strength and suitable as a structural material, a prepreg, and a carbon fiber-reinforced composite material.
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