序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
141 METHOD FOR PRODUCING AN ENAMELLED STEEL SUBSTRATE EP09701092.0 2009-01-09 EP2238279A1 2010-10-13 LEVEAUX, Marc; GONZALEZ, Javier
The present invention is related to a method for producing an enamelled steel substrate, said method comprising the steps of: providing a steel substrate, applying to a surface of said steel substrate a solution comprising a solvent, a polymer precursor, and at least one metal or metal oxide, said metal or metal oxide being suitable for promoting the adhesion of an enamel layer to the surface of the steel substrate, curing said steel sheet, thereby removing said solvent, and forming an organic layer comprising said at least one metal or metal oxide, applying to said organic layer, an enamel layer, followed by a firing step, to obtain the enamelled steel substrate.
142 METHOD OF CONTROLLABLE MORPHOLOGY OF SELF-ASSEMBLED MONOLAYERS ON SUBSTRATES EP04761664 2004-08-17 EP1682284A4 2008-08-27 NIE HENG-YONG; WALZAK MARY JANE; MCINTYRE STEWART N
Method of controlling the morphology of self-assembled monolayers (SAMS) on substrates having hydrophilic surfaces. The hydrophilic surface is exposed to a fluid having a mixture of molecules which can self-assemble on the hydrophilic surface and hydrophobic molecules for a sufficient length of time so that the molecules which can self-assemble on the hydrophilic surface form a complete self-assembled monolayer. In a particular embodiment octadecylphosphonic acid (OPA) molecules have been self-assembled on oxidized substrates including but not limited to mica, silicon, sapphire, quartz and aluminum by spin-coating a solution containing the octadecylphosphonic acid (OPA) molecules and hydrophobic molecules such as chloroform or trichloroethylene under a controlled relative humidity. Control of the morphology of OPA SAMs is affected by adjusting humidity and the duration of spin-coating. Atomic force microscopy revealed that relative humidity has a profound influence on the morphology of the OPA SAMs formed. When sufficient molecules are applied either consecutively or separately, the final morphology will be a complete monolayer, regardless of the relative humidity.
143 Glass lining application method EP02008166.7 2002-04-15 EP1354978B9 2007-03-14 Iizawa, Yoshihiro; Shirasaki, Masahiro; Ono, Jyunji
144 METHOD FOR ACTIVATING SURFACE OF PARENT MATERIAL AND ITS ACTIVATING SYSTEM EP02796468 2002-11-06 EP1498512A4 2006-12-20 YOSHIDA HIDEO; SATO NOBUYOSHI; SAKO TAKESHI; SONE MASATO; ABE KENTARO; SAKON KIYOHITO
A method and a system for activating the surface of a parent material suitable for pretreatment in electrochemical treatment, e.g. electroplating, in which productivity can be enhanced while reducing the facility cost by performing degreasing and removal of an oxide film on the surface of the parent material simultaneously, efficiently and rationally using an inexpensive safety solution, and waste liquid can be reused and environmental contamination can be prevented by rationalizing waste liquid treatment. The method for activating the surface of a parent material is used for degreasing and removing an oxide film on the surface of a material to be treated. A solution for removing an oxide film having a specified acidity is prepared by dissolving pressurized carbon dioxide into a specified quantity of water.
145 METHOD OF CONTROLLABLE MORPHOLOGY OF SELF-ASSEMBLED MONOLAYERS ON SUBSTRATES EP04761664.4 2004-08-17 EP1682284A1 2006-07-26 NIE, Heng-Yong; WALZAK, Mary, Jane; MCINTYRE, Stewart, N.
Method of controlling the morphology of self-assembled monolayers (SAMS) on substrates having hydrophilic surfaces. The hydrophilic surface is exposed to a fluid having a mixture of molecules which can self-assemble on the hydrophilic surface and hydrophobic molecules for a sufficient length of time so that the molecules which can self-assemble on the hydrophilic surface form a complete self-assembled monolayer. In a particular embodiment octadecylphosphonic acid (OPA) molecules have been self-assembled on oxidized substrates including but not limited to mica, silicon, sapphire, quartz and aluminum by spin-coating a solution containing the octadecylphosphonic acid (OPA) molecules and hydrophobic molecules such as chloroform or trichloroethylene under a controlled relative humidity. Control of the morphology of OPA SAMs is affected by adjusting humidity and the duration of spin-coating. Atomic force microscopy revealed that relative humidity has a profound influence on the morphology of the OPA SAMs formed. When sufficient molecules are applied either consecutively or separately, the final morphology will be a complete monolayer, regardless of the relative humidity.
146 Glass lining application method EP02008166.7 2002-04-15 EP1354978B1 2006-06-07 Iizawa, Yoshihiro; Shirasaki, Masahiro; Ono, Jyunji
147 STEEL SHEET FOR PORCELAIN ENAMELING AND METHOD FOR PRODUCTION THEREOF, AND ENAMELED PRODUCT AND METHOD FOR PRODUCTION THEREOF EP01271460 2001-12-17 EP1347070A4 2004-08-04 SATO FUMIAKI; HAMADA TOSHIHIRA; ODA SHUZO; JONO YOSHIHIRO; HAYASHIDA TAKAHIRO; FUJIMOTO JUNICHI; KOMAI MASAO
A method for producing a steel sheet for porcelain enameling, wherein an aluminum killed steel sheet, a high oxygen steel sheet, a Ti-containing steel sheet, a Nb-containing steel sheet or a B-containing steel sheet which has a specific chemical composition including a low carbon content is plated with a Ni-Mo alloy and then is subjected to a heat treatment in a manner such that the surface of each steel sheet has specific ranges of contents of Ni, Mo and Fe; a steel sheet for porcelain enameling produced by the method; a method for producing an enameled product wherein the above steel sheet is coated with a cover coat enamel and then fired; and an enameled product produced by the method. The steel sheet for porcelain enameling exhibits excellent formability and also allows the achievement of excellent adhesiveness of porcelain enamel to a steel sheet and the production of an enamel layer free of a black point defect, with one time application of a cover coat enamel.
148 Procédé de préparation d'un objet en tôle d'acier émaillé en mode direct EP98400466.3 1998-02-27 EP0866147B1 2002-04-10 Cholet, Vincent; Vonner, Daniel
149 Emaillierbare Oxidschicht EP94810572.1 1994-09-30 EP0648863B2 2001-05-02 Paulet, Jean-François; Weber, Hermann
150 Aluminiumhaltiges Substrat für Emailbeschichtungen EP94810015.1 1994-01-14 EP0611834A1 1994-08-24 Paulet, Jean-François; Weber, Hermann

Aluminiumhaltiges Substrat für Emailbeschichtungen, enthaltend wenigstens auf den Seiten der Emailbeschichtungen eine Oxidschicht, wobei das Substrat eine Oberflächenschicht aus Aluminium oder einer Aluminiumlegierung enthält und auf dieser Schicht eine porenhaltige Oxidschicht befindlich ist, wobei die Oxidschicht eine Dicke von mehr als 0,2 µm aufweist, der Porendurchmesser 0,03 bis 0,15 µm ist und das Verhältnis von Porentiefe zu Porendurchmesser von 2 bis 60 beträgt. Auf das Substrat wird eine Emailbeschichtung, beispielsweise in einer Dicke von 50 bis 200 µm, aufgebracht. Die emaillierten Substrate können als Aussenverkleidungen an Fahrzeugen oder Gebäuden eingesetzt werden, wobei die emailbeschichteten Substrate gegen Ausseneinflüsse hervorragend geschützt sind.

151 Process for improving the corrosion resistance of a ferrous metal body EP82300025.2 1982-01-05 EP0059023A1 1982-09-01 Drake, Cyril Francis

Ferrous metal surfaces are protected against corrosion by providing the metal (11) with a flash coating (12) of copper followed by coating the structure with a corrosion inhibiting layer wholly or partially comprising a water soluble glass. A plant for providing the coating treatment is also described.

152 METHOD FOR PROVIDING A CO- AND NI-FREE VITREOUS ENAMELLED METAL COATED STEEL SUBSTRATE AND A PRIMER COMPOSITION THEREFOR EP16745077.4 2016-07-20 EP3325416B1 2019-10-09 DE STRYCKER, Joost Remi Margueritte; LEVEAUX, Marc Henri André; KNOCKAERT, Pierre Claude Victor
153 SURFACE TREATMENT AGENT, ENAMEL STEEL AND PART COATED WITH SAME EP17812528.2 2017-05-24 EP3470549A1 2019-04-17 FANG, Wenqi; MA, Yuan; YANG, Jiayun; WANG, Shuangcheng

Disclosed in the present invention is a surface treatment agent for use on enamel steel or a part, an aqueous solution thereof comprising the following solid components in parts by mass: 15 to 55 parts of an aqueous polymer resin A; 32 to 58 parts of an organosilane coupling agent B having at least one epoxy functional group, wherein the ratio of parts by mass of the organosilane coupling agent B to the aqueous polymer resin A is 0.6 to 2.2; 0.2 to 3 parts of a polyol C containing at least three hydroxyl groups; 0.05 to 2 parts by mass of a molybdenum compound D, in terms of elemental molybdenum; 0.1 to 1 parts by mass of a phosphorus compound E, in terms of elemental phosphorus; 0.1 to 1 parts by mass of a zirconium compound F, in terms of elemental zirconium; and 0.5 to 8 parts of a metal salt or an organometallic compound G which promotes adhesion. The enamel steel coated with the surface treatment agent has excellent processability, and good resistance to various chemical media. The present invention effectively improves the surface adhesion between a ceramic glaze layer and a steel substrate, as well as the surface quality of a final enamel product.

154 PROCESS FOR THE PRODUCTION OF ENAMELLED STEEL SHEET OR PART EP08860540.7 2008-10-23 EP2229468A1 2010-09-22 LEVEAUX, Marc; DUPREZ, Lode; GONZÁLEZ JIMÉNEZ, Javier; GOUSSELOT, Philippe
The invention relates to a steel sheet or part whose composition is suitable for enamelling, and which is coated with a coating consisting of a matrix of polymer in which particles of non-oxide ceramic are homogeneously dispersed. It also relates to the use of this coated steel sheet or part for producing an enamelled steel sheet or part, and to a process for producing an enamelled steel sheet or part allowing a decrease of firing temperature and time compared with conventional firing temperatures and times.
155 Process for the production of enamelled steel sheet or part EP07291521.8 2007-12-13 EP2071056A1 2009-06-17 Leveaux, Marc; Duprez, Lode; Gonzalez, Jiménez Javier; Gousselot, Philippe

The invention relates to a steel sheet or part whose composition is suitable for enamelling, and which is coated with a coating consisting of a matrix of polymer in which particles of non-oxide ceramic are homogeneously dispersed. It also relates to the use of this coated steel sheet or part for producing an enamelled steel sheet or part, and to a process for producing an enamelled steel sheet or part allowing a decrease of firing temperature and time compared with conventional firing temperatures and times.

156 WORKS FOR ENAMELING AND ENAMELED PRODUCTS EP07792817.4 2007-08-15 EP2065482A1 2009-06-03 MURAKAMI, Hidekuni; NISHIMURA, Satoshi

The present invention provides a product for enameling and an enameled product that achieve adhesion, bubble/black spot defect resistance and fishscale resistance, even when preprocessing and ground coating are omitted, which product comprise a steel sheet having on the surface thereof an oxide film of 0.10 µm to 400 µm thickness comprising oxides of components of the steel sheet, which steel sheet comprises, in mass%, C: 0.0001% to 0.040%, Si: 0.0001% to 0.50%, Mn: 0.001% to 2.00%, P: 0.0001% to 0.10%, S: 0.0001% to 0.060%, Al: 0.0001% to 0.10%, N: 0.0001% to 0.015%, and O: 0.0001% to 0.070%, further comprises one or more of Ni:0.01% to 2.00%, Co: 0.0005% to 2.00%, Cr: 0.001% to 2.00%, Cu: 0.01% to 2.00%, Mo: 0.0001% to 2.00%, and Ti: 0.0005% to 0.50%, where Ni + Co + Cr/2 + Cu + Mo + Ti: 0.010% to 8.0%, the balance being Fe and unavoidable impurities.

157 Method for surface treatment EP98300245.2 1998-01-14 EP0853141B1 2005-07-06 Uchiyama, Akira
158 Verfahren und Vorrichtung zur Emaillierung der Oberfläche eines Stahlkörpers EP00250102.1 2000-03-28 EP1052310A3 2004-08-11 Knäpper, Klaus; Wenzel, Edda; Twardy, Frank

Um zur Emaillierung der Oberfläche eines Stahlkörpers, insbesondere einer Rohraußenoberfläche, durch Direktemaillierung, eine hohe Lebensdauer des Stahlkörpers in hochkorrosiven Umgebungen sowie eine einfache Herstellung der Emaillierung zu ermöglichen, wird vorgeschlagen,

daß zu emaillierende Oberflächenbereiche des Stahlkörpers einer Randentkohlung unterzogen werden, worauf mindestens eine Schicht aus Direktemail aufgebracht wird.

159 Glass lining application method EP02008166.7 2002-04-15 EP1354978A1 2003-10-22 Iizawa, Yoshihiro; Shirasaki, Masahiro; Ono, Jyunji

A new glass lining application method enables stable, uniform glass lining layers to be applied to large glass-lined instruments composed of a stainless base material, the method including forming a thermal spray treatment layer by applying a thermal spray treatment to a surface of a stainless base material using a thermal spray material selected from a group composed of a stainless material identical to the base material, Ni metal, Cr metal, Fe metal, Co metal, Ni-Cr alloys, and Fe-Cr alloys, then forming a glass lining layer on the thermal spray treatment layer by means of a glass lining heat treatment using a ground coat and a cover coat, a surface roughness Rz of the thermal spray treatment layer being within a range from 5 to 100 µm, and an open pore diameter being within a range from 3 to 60 µm.

160 PROCEDE DE FABRICATION D'UNE PIECE METALLIQUE EMAILLEE SANS OPERATION DE DEGRAISSAGE EP01907806.2 2001-02-15 EP1255878A2 2002-11-13 DELMOTTE, Christophe; LEGROS, Philippe; MALOT, Thierry; NICOLETTI, Patrick
The invention concerns a method which consists in: providing a protective treatment against corrosion to the initial sheet metal using an aqueous emulsion containing colloids based on acrylic and/or methacrylic polymer; a step which consists in applying a coat of liquid enamelling composition comprising an enamel frit capable of being vitrified; a baking step adapted to vitrify said frit. The invention is characterised in that said method does not comprise a step for degreasing said surface subsequent to the protective treatment. The invention provides the advantages of improved adherence of the enamel and a simpler process.
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