序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
81 永固紫生产用三乙胺回收系统 CN202021864844.8 2020-08-31 CN212864612U 2021-04-02 王彬彬; 姚鹏飞; 李泽荣; 王聪; 张川; 杨志成; 吴声; 王忠群
本实用新型提供一种永固紫生产用三乙胺回收系统,属于永固紫生产技术领域。在永固紫粗品洗涤过滤器后端依次设置洗涤液缓存池、调槽及三乙胺蒸馏釜,在永固紫粗品洗涤过滤器内,经拉开粉和热水洗涤后,三乙胺盐酸盐溶解,并随滤液排出至洗涤液缓存池内。洗涤液缓存池内的滤液被送入调碱槽中,加入碱液,此时,三乙胺盐酸盐与被水解成三乙胺、氯化钠和水,水解液被排入三乙胺蒸馏釜中,减压蒸馏,分馏其中的三乙胺组分。通过永固紫生产用三乙胺回收系统,一方面,回收了永固紫生产废水中的三乙胺组分,实现资源化,另一方面,降低了废水的盐含量和COD值,降低了废水的处理难度,从而实现降本增效。
82 永固紫离心母液处理系统 CN202021864969.0 2020-08-31 CN212293390U 2021-01-05 王正贤; 王彬彬; 吴声; 孙涛; 宁亮; 李泽荣; 时春玲; 孙宝宁
本实用新型提供了一种永固紫离心母液处理系统,属于永固紫生产技术领域。依次设置邻二氯苯蒸馏釜、沉渣池、永固紫回收装置及永固紫精制装置,永固紫离心母液首先被送入邻二氯苯蒸馏釜中,蒸馏脱除邻二氯苯,釜底残渣则排入沉渣池中,冷却并静置分层。位于沉渣池底层的固体渣被送入沉渣打浆罐,加入邻二氯苯,控制温度,打浆,浆液被输送至第一永固紫过滤器中,滤饼为永固紫粗品,在第一永固紫过滤器中,加入邻二氯苯,对永固紫粗品洗涤。经过邻二氯苯洗涤的永固紫滤饼被送入汽蒸馏釜中,向水汽蒸馏釜中通入水蒸气,利用水汽蒸馏法,使邻二氯苯从永固紫中充分析出,从而有效地去除了永固紫中的邻二氯苯组分,降低永固紫中邻二氯苯的残留。(ESM)同样的发明创造已同日申请发明专利
83 永固紫精制系统 CN202021829619.0 2020-08-27 CN212293389U 2021-01-05 王正贤; 王彬彬; 宁亮; 李泽荣; 马飞; 孙涛; 汪国建; 吴声
本实用新型提供一种永固紫精制系统,属于永固紫生产技术领域。系统包括邻二氯苯洗涤离心机、汽蒸馏装置、水洗压滤装置及后处理装置,永固紫粗品首先在邻二氯苯洗涤离心机中,用邻二氯苯进行洗涤,去除永固紫粗品中溶解于邻二氯苯的物质。离心滤渣送入水汽蒸馏装置,加热水打浆,然后通入蒸气,一方面提供高温,使离心滤渣中的邻二氯苯与水共沸蒸馏,另一方面,蒸气提供一定的气提作用,使邻二氯苯从离心滤渣中充分析出,从而降低永固紫中邻二氯苯的残留。永固紫浆液被送入水洗压滤装置,进行压滤脱水,同时加热水进行热水洗涤,以去除三乙胺盐酸盐。经检测,经三次洗涤后,永固紫成品中的邻二氯苯残余量明显小于传统的拉开粉洗涤。(ESM)同样的发明创造已同日申请发明专利
84 一种高压反应釜 CN202123180059.8 2021-12-17 CN217042478U 2022-07-26 章国盛; 刘孙丽; 戴之杰
本实用新型公开了一种高压反应釜,包括加热箱,所述加热箱的一侧固定连接有支撑板,所述加热箱的内部设有釜体,所述釜体的顶端固定安装有釜盖,所述加热箱的内底壁开设有固定槽,所述固定槽的内底壁固定连接有加热器,所述釜体的外表面固定连接有隔热层,所述隔热层的内部固定镶嵌有加热丝,所述加热丝的外表面与釜体的外表面相接触,所述加热器的输出端贯穿隔热层并与加热丝的外表面固定连接,所述支撑板的上表面固定连接有壳体,所述壳体的内顶壁固定连接有气。本实用新型提高了釜体的加热速度,解决目前高压反应釜采用加热装置对釜体的底部进行加热速度较慢的问题,并且能够对釜体的内部进行加压,将会达到有效高压反应的效果。
85 用于永固紫烷基化硝化的反应系统 CN202021037452.4 2020-06-09 CN213060713U 2021-04-27 林大勇; 钱忠海; 付江堂; 何连成
一种用于永固紫烷基化硝化的反应系统,涉及化工设备技术领域,它包括原料储罐,原料储罐与烷基化釜连接,烷基化釜与蒸馏釜一连接,蒸馏釜一通过管路分别与冷凝器和静置分层槽一连接,冷凝器与静置分层槽二连接,静置分层槽二与烷基化釜连接,静置分层槽一通过管路分别与硝化釜和结晶分离器连接,结晶分离器与烷基化釜连接,硝化釜与中和罐连接,中和罐与离心机连接,离心机通过管路分别与离心洗涤机和蒸馏釜二连接,蒸馏釜二与冷凝分离器连接,冷凝分离器与硝化釜连接,离心洗涤机与产品储罐连接。本用于永固紫烷基化硝化的反应系统将原料合理烷基化硝化处理,最终得到纯度较高的硝化物,便于后续永固紫的提纯。
86 一种用于永固紫RL生产的加氢环节搅拌装置 CN202121833782.9 2021-08-06 CN216172241U 2022-04-05 姚开春
本实用新型公开了一种用于永固紫RL生产的加氢环节搅拌装置,具体涉及搅拌装置技术领域,包括装置主体,所述装置主体的顶部和底部分别固定连通有进料管和出料管,所述装置主体内壁的顶部中心处转动连接有竖向转杆,所述竖向转杆的两侧外表面固定连接有对称的支杆和若干个搅拌杆,若干个所述搅拌杆远离竖向转杆的另一端固定连接有搅拌片。本实用新型能对物料进行有效地快速翻动搅拌,增强了内部物料的流动性和混合,使搅拌混料更均匀,结构简单,省时省力,提高了永固紫生产加工的效率效果,满足搅拌所需,还有效加快了排料出料速度,减少了内部残留,使出料更通畅,提高了工作效率。
87 低邻二氯苯残留的永固紫精制系统 CN202021865934.9 2020-08-31 CN212864629U 2021-04-02 吴声; 王正贤; 王彬彬; 姚鹏飞; 孙涛; 宁亮; 时春玲; 孙宝宁
本实用新型提供一种低邻二氯苯残留的永固紫精制系统,属于永固紫生产技术领域。设置洗涤装置及醇萃取装置,闭环反应完成后,生成的永固紫粗液首先被输送至第一永固紫过滤器中,滤饼依次用邻二氯苯、拉开粉及热水洗涤除杂。洗涤后,得到的滤饼中,大约还有8000mg/kg‑10000mg/kg的邻二氯苯残留。将洗涤后的滤饼投入浆化萃取釜中,通过醇进料管加入甲醇或乙醇,启动打浆搅拌器,充分打浆,使滤饼充分分散于甲醇或乙醇中,使邻二氯苯被甲醇或乙醇充分浸取。将浆化萃取釜中的浆液送入第二永固紫过滤器中,进行过滤,得到永固紫成品。经检测,经甲醇或乙醇萃取后,永固紫成品中的邻二氯苯残留量≤800mg/kg,极大程度地降低了永固紫成品中的邻二氯苯残留。
88 永固紫离心母液资源化处理系统 CN202021864911.6 2020-08-31 CN212864621U 2021-04-02 王彬彬; 孙涛; 宁亮; 李泽荣; 马飞; 王聪; 陈星; 张川
本实用新型提供一种永固紫离心母液资源化处理系统,属于永固紫生产技术领域。依次设置邻二氯苯蒸馏釜、沉渣池、永固紫打浆罐及永固紫过滤洗涤装置,永固紫离心母液首先被送入邻二氯苯蒸馏釜中,蒸馏并回收邻二氯苯。釜底残渣则排入沉渣池中,冷却静置分层。位于沉渣池底层的固体渣被送入永固紫打浆罐,加入邻二氯苯,控制温度,打浆。然后在永固紫过滤洗涤装置中,依次经过压滤、邻二氯苯洗涤、拉开粉洗涤与热洗涤,进行精制,回收永固紫。该永固紫离心母液资源化处理系统,资源化回收利用了永固紫离心母液中的邻二氯苯组分和永固紫组分,从而降低外排固体废弃物的总量,提高永固紫的单位产率。
89 永固紫还原及缩合闭环的连续反应系统 CN202021037060.8 2020-06-09 CN212476600U 2021-02-05 林大勇; 韩刚; 祝晶晶; 何连成
一种永固紫还原及缩合闭环的连续反应系统,涉及化工设备技术领域,它包括原料储罐,原料储罐与溶解釜连接,溶解釜与加氢釜连接,加氢釜与中转槽连接,中转槽与抽滤器一连接,抽滤器一分别与回收槽和分层槽一连接,分层槽一与脱机连接,脱水机分别与冷凝器一和缩合釜连接,冷凝器一与分层槽二连接,分层槽二与脱水机连接,缩合釜与闭环釜连接,闭环釜与抽滤器二连接,抽滤器二分别与蒸馏釜和离心洗涤机一连接,蒸馏釜与冷凝器二连接,冷凝器二与脱水机和加氢釜分别连接,离心洗涤机一与离心洗涤机二连接,离心洗涤机二与烘干器连接,烘干器与产品储罐连接。本永固紫还原及缩合闭环的连续反应系统提高了永固紫粗品的纯度。
90 智能学习机及其磁卡 CN94226626.9 1994-01-17 CN2198274Y 1995-05-24 顾谷频
本实用新型涉及一种智能学习机及其磁卡,学习机内设有磁卡通道,所用磁卡上配有图文,使用时放音与图文展示同步,与现有技术相比,具有操作简单,结构新颖的特点,既可作少年儿童中外文语言及其他学科学习的辅导用具,又可兼作中高级玩具,收到寓教于乐的良好效果。
91 METHOD FOR INDUCING TUMOR REGRESSION PCT/US2020/052278 2020-09-23 WO2021061818A1 2021-04-01 CINCOTTA, Anthony H.

Methods for treating cancer and/or inducing tumor regression in mammals (e.g., humans) by increasing the metabolism of the mammal, administering a BA dye to the mammal, and thereafter exposing the tumor to actinic light for activation of the BA dye.

92 FLUORESCENT PROBES FOR MONOACYLGLYCEROL LIPASE (MAGL) PCT/EP2020/076345 2020-09-22 WO2021058443A1 2021-04-01 BENZ, Joerg; GAZZI, Thais; GOBBI, Luca; GRETHER, Uwe; HORNSPERGER, Benoit; KROLL, Carsten; KUHN, Bernd; MOSTINSKI, Yelena; NAZARE, Marc; O'HARA, Fionn; RICHTER, Hans

The invention provides fluorescent probes having the general formula (I) wherein X, Y, L and R1 to R4 are as described herein, compositions including the compounds, processes of manufacturing the compounds and methods of using the compounds. The compounds are useful as fluorescent probes for monoacylglycerol lipase (MAGL).

93 A CLEANED PHOTOCHROMIC DYE SUITABLE FOR USE ON HUMAN SKIN PCT/US2017/029403 2017-04-25 WO2017192309A1 2017-11-09 SANDERS, Clifton; IMEL, Courtland

An organic manufactured photochromic dye, and method of manufacture, that is free of carcinogens, non-mutagenic, non-toxic to human skin in any concentration, and suitable for application to, and absorbable by, human skin. The photochromic dye is suitable to be applied directly to human skin, and which dye is configured to indicate exposure to UV rays. The composition is configured to change color upon exposure to UVA, UVB and/or UVC rays. The composition can be used with other compositions, such as sunscreen, and be applied to human skin prior to application of the sunscreen, or, formulated with the sunscreen such that when the active ingredients of the sunscreen diminish, the photochromic dye will change color to generate a visual indicator of this condition.

94 DYE PCT/EP2017/050384 2017-01-10 WO2017121714A1 2017-07-20 BATCHELOR, Stephen, Norman; BURNHAM, Neil, Stephen

The present application provides a laundry treatment composition comprising a phenoxazine blue or violet dye and a surfactant, and a domestic method of treating a textile with an aqueous solution of said composition.

95 LAUNDRY CARE COMPOSITIONS PCT/US2015/029210 2015-05-05 WO2015171592A1 2015-11-12 BUTTERFIELD, Benjamin R.; TORRES, Eduardo; DEY, Sanjeev K.; HONG, Michael; QIN, Haihu; VALENTI, Dominick J.

A laundry care composition comprises a laundry care ingredient or adjunct and at least one compound that is capable of changing from a first color state (i.e., the initial color state in the composition) to a second color state that is perceptibly different from the first color state. A method for treating textile articles comprises the steps of: (a) providing a laundry care composition as described above; (b) adding the laundry care composition to a liquid medium; and (c) placing the textile articles in the liquid medium.

96 顔料分散組成物 PCT/JP2010/053518 2010-03-04 WO2010101210A1 2010-09-10 二宮 敏貴; 杉原 幸一; 鈴木 成一; 藤牧 一宏; 神田 博美

【課題】カラーフィルタとしたときに高いコントラスを発揮し、しかもカラーフィルタの成形工程における現像、ポストベーク、UV洗浄などといった処理を経ても表面の荒れを抑制ないし防止して良好な表示性能を実現し、かつ高い分散安定性を示す顔料分散組成物を提供する。 【解決手段】有機顔料微粒子と顔料吸着基を有する高分子化合物とを含有させた顔料分散組成物であって、前記有機顔料微粒子が、良溶媒に有機顔料を溶解した有機顔料溶液と、前記良溶媒と相溶性でありかつ前記有機顔料に対しては貧溶媒となる貧溶媒とを混合して析出させたビルドアップ顔料微粒子である顔料分散組成物。

97 SACCHARIDE SENSING MOLECULES HAVING ENHANCED FLUORESCENT PROPERTIES PCT/US0110541 2001-03-30 WO0174968A8 2001-12-20 SATCHER JOE H JR; LANE STEPHEN M; DARROW CHRISTOPHER B; CARY DOUGLAS R; TRAN JOE ANH
The present invention provides formulae for fluorescent compounds that have a number of properties which make them uniquely suited for use in sensors of analytes such as saccharides. The advantageous fluorescent properties include favorable excitation wavelengths, emission wavelengths, fluorescence lifetimes, and photostability. Additional advantageous properties include enhanced aqueous solubility, as well as temperature and pH sensitivity. The compound comprises an aryl or a substituted phenyl boronic acid that acts as a substrate recognition component, a fluorescent switch component, and a fluorophore. Fluorescent compounds are described that are excited at wavelengths greater than 400 nm and emit at wavelengths greater than 450 nm, which is advantageous for optical transmission through skin. The fluorophore is typically selected from transition metal-ligand complexes and thiazone, oxazine, oxazone, or oxazine-one as well as anthracene compounds. The fluorescent compound can be immobilized in a glucose permeable biocompatible polymer matrix that is implantable below the skin.
98 PHOTOCHROMIC SPIRO(INDOLINE)NAPHTHOXAZINES PCT/IL2001/000317 2001-04-05 WO01077112A2 2001-10-18
A photochromic compound for incorporation into plastic articles, particularly into a plastic lens, is selected from a spiro(indoline)naphtho(2,1-b) (1,4)oxazine and a spiro(indoline)naphtho(1,2-b)(1,4)oxazine containing a group selected from: (a) -CH2-CnF2n+1 at the nitrogen atom in the 1-position on the indoline part of the molecule, wherein n is an integer of 1 to 6; (b) -COOR at the 3-position on the indoline part of the molecule, wherein R is (i) C1-C6 alkyl optionally substituted by fluoro, C1-C4 alkoxy or fluoroalkoxy, C1-C4 alkylcarbonyloxy, C2-C4 alkenylcarbonyloxy, C3-C6 cycloalkyl or aryl; (ii) C2-C6 alkenyl with a terminal double bond; (iii) C3-C6 cycloalkyl optionally substituted by fluoro; or (iv) aryl; (c) an -OCF3 group on the benzene ring of the indoline part of the molecule; (d) an aryl(dialkyl)methyl group of the formula -C(aryl)(CnH2n+1)(CmH2m+1), wherein n and m are integers from 1 to 5, linked to one of the benzene rings of the naphthoxazine part of the molecule; and (e) any combination of (a), (b), (c) and/or (d).
99 OXYALKYLENE-SUBSTITUTED AMINOPHENOL INTERMEDIATE PCT/US2000/002677 2000-02-02 WO00051967A1 2000-09-08
This invention relates to very specific oxyalkylene-substituted aminophenol compounds as intermediates for the production of poly(oxyalkylene)-substituted xanthene (or other type) colorants. Such an inventive intermediate compound is produced in a single step by reacting an oxyalkylene oxide having from 3 to 12 carbon atoms (branched or unbranched), glycidol, or a glycidyl directly with aminophenol without the use of a catalyst and at a relatively low temperature. Propylene oxide and m-aminophenol are the preferred reactants. The propylene oxide selectively reacts with the amine group on the m-aminophenol without propoxylating the phenolic hydroxyl group. Such a specific method thus does not require extra time- and cost- consuming steps of protecting the phenolic hydroxyl group from attack. After production, this intermediate may be reacted with suitable compounds to ultimately form any number of different colorants, including xanthenes, oxazines, coumarins, and the like. The resultant oxypropylene groups may subsequently be reacted with electrophile compounds to produce any number of different colorants. Resultant colorants produced through the reaction of the inventive intermediate are also contemplated within this invention.
100 PHOTOCHROMIC OPHTHALMIC LENS PCT/US1999/016308 1999-07-19 WO00007040A1 2000-02-10
A photochromic ophthalmic lens and a process for its preparation are disclosed. The lens comprises a substantially transparent substrate having a lenticular shape and, at least one film adhering to at least one surface of said substrate. The film contains a resinous blend of polycarbonate resin, and polycaprolactone and an effective amount of a photochromic dye selected preferably from a group consisting of spiropyrans, benzopyrans, naphthopyrans, spiroxazines, fulgides and fulgimides. In an additional embodiment the film contains a copoly(carbonate-lactone) block or random copolymer.
QQ群二维码
意见反馈