序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
41 Horifuruorukarubonirukagobutsunoseizohohonarabinikoreranokagobutsugunnochinojatsukannoshinkinakagobutsu JP14255281 1981-09-11 JPH0240652B2 1990-09-12 HANSU MIRAUERU; GYUNTERU JIIGEMUNTO; UERUNERU SHUERUTOFUEGERU
42 JPS6338388B2 - JP11745279 1979-09-14 JPS6338388B2 1988-07-29 URURITSUHI KUNTSUTSUE; HAINTSU UURITSUHI
43 JPS6230984B2 - JP12642279 1979-10-02 JPS6230984B2 1987-07-06 YAMAGUCHI HACHIRO
44 JPS6141349B2 - JP13784378 1978-11-10 JPS6141349B2 1986-09-13 HAYASHI AKIRA; AOKI YOSHIO; KITANO KYOZO; OOGOSHI TOSHIAKI
45 JPS6135981B2 - JP4840377 1977-04-28 JPS6135981B2 1986-08-15 KAWAKAMI AKIRA; AOKI YOSHIO
46 Compound having ionic structure, manufacture and manufactureof polymer JP15257485 1985-07-12 JPS6187649A 1986-05-06 GUNTAA HOFUARUTO; BORUFUGANGU RIHITAA; YOON GOOSENSU; BORUFUGANGU POTSUTSUN; KARURU HANSU ZUYURINGU; HANSU YOZEFU BUISHIYU; KURAUSU BARUTSU
47 Nitration process JP13655784 1984-07-03 JPS6115847A 1986-01-23 KAWAMURA KIYOSHI; SHIBUYA MASAYUKI; ISHIHAMA HIROSHI
PURPOSE:To produce a nitric acid ester, in high yield and purity, economically in an industrial scale, easily under mild condition, using a regenerable reagent, by reacting a sulfonic acid ester with an organic quaternary ammonium nitrate. CONSTITUTION:The objective compound of formula III can be produced by reacting (A) the sulfonic acid ester of formula II (R'SO2 is sulfonic acid residue) obtained by the conventional sulfonation process of an alcohol of formula I (R is organic residue) with (B) the organic quaternary ammonium nitrate of formula IV(Q<+> is organic quaternary ammonium residue), e.g. a quaternary alkyl (or substituted alkyl) ammonium nitrate or a nitrate of a strongly basic anion exchange resin having quaternary ammonium as an exchangeable group. The process can be applied to a compound which is difficult to be nitrated by conventional methods. When the process is applied to an optically active compound, a nitrate having inverted absolute configuration is prepared without causing racemization.
48 Manufacture of perfluoroacrylic acid ester JP14527784 1984-07-14 JPS60199857A 1985-10-09 POORU RAFUAERU RESUNITSUKU
49 Preparation of tertiary alcohol sulfuric ester salt JP13512780 1980-09-30 JPS5759853A 1982-04-10 YAMAGUCHI HACHIROU
PURPOSE: To obtain the titled compound in high yield economically and advantageously without troublesome operation, by reacting a tertiary alcohol with an amine adduct with sulfur trioxide as a sulfating agent under heating, cooling the reaction mixture, and adding a slightly soluble solvent to isolate the titled compound. CONSTITUTION: All the tertiary alcohols not only tertiary butanol are heated with an adduct of an amine, e.g. methylamine, cyclopropylamine, aniline or pyridine, of the formula R1R2R3N(R1, R2R3 are H, 1W10C alkyl or cycloalkyl; however, except when any one of R1, R2 and R3 is H) with sulfur trioxide, in an amount of equimolar with the tertiary alcohols at 0W120°C, and cooled to 0°C or below, and then a slightly soluble solvent, e.g. methanol or petroleum ether is added to deposit and isolate the aimed substance. The tertiary alcohols may be used in a large excess. COPYRIGHT: (C)1982,JPO&Japio
50 JPS5652897B2 - JP7367373 1973-07-02 JPS5652897B2 1981-12-15
51 Preparation of trialkylaluminum salt of mixed long-chain fatty acid-sulfuric acid anhydride JP12642279 1979-10-02 JPS5651446A 1981-05-09 YAMAGUCHI HACHIROU
PURPOSE: To obtain the titled compound in high purity and yield, by the reaction of a trialkylaluminum salt of a long-chain fatty acid with a trialkylamine-sulfur trioxide complex, in the presence of a solvent at a low temperature. CONSTITUTION: A trialkylaluminum salt of a long-chain fatty acid expressed by formula I (R is 11W17C alkyl; R' is 1W4C alkyl) is reacted with a trialkylamine- sulfur trioxide complex in the presence of a solvent, e.g. 1,2-dichloroethane, at a low temperature of -5 to 25°C, to give a trialkylaluminum salt of a mixed long- chain fatty acid-sulfuric acid anhydride expressed by formula III. The complex of formula II is obtained by the reaction of a trialkylamine with sulfur trioxide in a solvent. Lauric, myristic or palmitic acid may be cited as the long-chain fatty acid used in the compound expressed by formula I, and trimethyl- or triethylamine may be cited as the trialkylamine. COPYRIGHT: (C)1981,JPO&Japio
52 JPS5530704B2 - JP8906975 1975-07-21 JPS5530704B2 1980-08-13
53 Sulfonation process JP6205877 1977-05-27 JPS52144626A 1977-12-02 BAATON BURUTSUKUSU; RICHIYAADO JIEI BURUTSUKUSU
54 JPS5235647B1 - JP6094570 1970-07-11 JPS5235647B1 1977-09-10
55 Sufactant JP11909176 1976-10-04 JPS5235185A 1977-03-17 NAKAMURA SATOSHI; UMEMURA HITOSHI; YONEKURA MICHIMASA
PURPOSE: A fluorine-containing surfactant suitable for use as an ingredient of fireextinguishing aqueous film, in the production of emulsified products of fluorine dirivatives for oxygen carriers, and as finishing agent for textiles. COPYRIGHT: (C)1977,JPO&Japio
56 Method of sulfonation and its apparatus JP8906975 1975-07-21 JPS5214725A 1977-02-03 DEN KEI; MAJIMA KANJI; IMAMURA YOSHIYASU
PURPOSE: Process for sulfonating argamic compounds such as liquid alcoholic hydroxyl compounds with SO 3 gas, characterized in conducting the 1st step reaction in a plurality of tubular reactors set in parallel arrangement and the 2d step in a single tubular reactor, and apparatus for the same. COPYRIGHT: (C)1977,JPO&Japio
57 JPS5148767B2 - JP14202973 1973-12-17 JPS5148767B2 1976-12-22
58 JPS5091607A - JP14202973 1973-12-17 JPS5091607A 1975-07-22
59 JPS507561B1 - JP1829966 1966-03-26 JPS507561B1 1975-03-27
60 JPS5012022A - JP6033173 1973-05-31 JPS5012022A 1975-02-07
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