41 |
카르밤산 유도체의 제조방법 |
KR1019850000924 |
1985-02-15 |
KR1019850006929A |
1985-10-25 |
바르셀로제라흐; 세느쟝-피에르; 세니제라흐 |
내용 없음 |
42 |
Aspartate derivative and a method of manufacturing the same |
JP2006534006 |
2004-09-27 |
JP2007507507A |
2007-03-29 |
カルステン・ダニエルマイヤー; ダグラス・エイ・ウィックス; チャールズ・エイ・ガンビーノ; テレル・ディーン・ウェイト; ブライアン・ロング; リチャード・アール・ローズラー |
本発明は、新規なアスパルテート、その製造方法、これらのモノ及びポリアスパルテートの 2 成分ポリウレタン被覆組成物中のポリイソシアネート反応性成分としての使用、及びポリウレタンプレポリマー調製のためのその使用に関する。 |
43 |
Aryl - iminomethyl - a process for the preparation of carbamino acid ester |
JP2001551839 |
2001-01-11 |
JP2003523328A |
2003-08-05 |
ラルフ アンデルスケヴィッツ; ユッタ クレーバー; ロルフ シュミット; ライナー ソイカ; ロルフ バウアー; ライナー ハム; イェルク ブランデンブルク |
(57)【要約】 本発明は式(I) 【化1】 (式中、基R
1及びR
2は明細書及び特許請求の範囲に示された意味を有する)の化合物の製造方法に関するものであり、この方法は大規模で使用し得る。 |
44 |
New vinyl carbonate and vinyl carbamate contact lens material monomer |
JP11066490 |
1990-04-27 |
JP3274681B2 |
2002-04-15 |
イー.シーリェ デビット |
|
45 |
2- (1 ', 2', 4'-triazolyl-3'-oxymethylene) anilide, the manufacturing methods and uses |
JP50364796 |
1995-06-21 |
JPH10504809A |
1998-05-12 |
アマーマン,エーベルハルト; ケーニッヒ,ハルトマン; ゲツ,ノルベルト; ザウター,フーベルト; ミュラー,ベルント; レール,フランツ; ロレンツ,ギーゼラ |
(57)【要約】 下式(I) で表わされ、かつnが0、1、2、3または4を、Xが直接結合、酸素またはNR
aを、このR
aが水素、アルキル、アルケニル、アルキニル、シクロアルキル、シクロアルケニルを、R
1がニトロ、シアノ、ハロゲン、置換されていてもよい、アルキル、アルケニル、アルキニル、アルコキシ、アルケニルオキシまたはアルキニルオキシを、R
2が水素、ニトロ、シアノ、ハロゲン、アルキル、ハロゲンアルキル、アルコキシ、アルキルチオまたはアルコキシカルボニルを、R
3が置換されていてもよい、アルキル、アルケニル、アルキニル、シクロアルキル、ヘテロ環、アリールまたはヘテロアリールを、R
4が水素、置換されていてもよい、アルキル、アルケニル、アルキニル、シクロアルキル、シクロアルケニル、アルキルカルボニル、アルコキシカルボニルを、R
5が水素、アルキル、アルケニル、アルキニル、シクロアルキルまたはシクロアルケニルをそれぞれ意味する場合の2−(1′,2′,4′,−トリアゾリル−3′−オキシメチレン)−アニリド、その製造のための方法および中間生成物、ならびにその用途。 |
46 |
A fact that is tritiated 16-imino-17-aza manufacturing intermediate member of the steroid |
JP23447394 |
1994-09-05 |
JP2512389B2 |
1996-07-03 |
ARAN JUKEI; PIITAA FURANSHISU HANTO |
|
47 |
JPH06505484A - |
JP50742892 |
1992-03-05 |
JPH06505484A |
1994-06-23 |
|
|
48 |
JPH0560456B2 - |
JP16498685 |
1985-07-25 |
JPH0560456B2 |
1993-09-02 |
ASHOTSUKU KUMAA SHAAMA |
|
49 |
New vinyl carbonate and vinyl carbamate contact lens material monomer |
JP11066490 |
1990-04-27 |
JPH0372506A |
1991-03-27 |
DEBITSUTO II SHIIRIE |
PURPOSE: To obtain a copolymer useful for implements for living organism, especially a contact lens material, by polymerizing a prepolymer mixture containing a specified base monomer and a crosslinking agent.
CONSTITUTION: This copolymer is formed by polymerizing a prepolymer mixture containing 1-99 wt.% base monomer represented by the formula (x is a divalent radical comprising -O-, -S- or -NR
3-; R
1 is an organic group; R
2 is -H or -CH
3; R
3 is -H or a monovalent alkyl; and b is 0 or 1) and 0.1-20 wt.% crosslinking agent. Examples of the base monomer used include 2-hydroxyethyl vinyl carbonate, 2-hydroxyethyl vinyl carbamate, and 3-(2-pyrrolidinon-1-yl)propyl vinyl carbonate. Examples of the crosslinking agent used include propargyl vinyl carbamate, 1-bis-(vinyloxycarbonyloxy)ethane, and α,ω-bis-(vinyloxycarbonyl) triethylene glycol.
COPYRIGHT: (C)1991,JPO |
50 |
Adhesion promoter |
JP15499590 |
1990-06-13 |
JPH0348690A |
1991-03-01 |
JIYOBANNI PARINERO; FUBERUTO SHIMON; RORUFU MIYUURUHAUPUTO |
NEW MATERIAL: A compound of formula I [wherein R
1 is 2-3C alkylene; R
2 is H, substitutable 1-6C alkyl or 1-6C alkyl substituted with OH, CN, Si (OR
3)
3-qR
4
q (wherein R
3 is 1-4C alkyl, 2R
3 join to form 1-4C alkylene, etc.; R
4 is 1-4C alkyl or phenyl; q is 0-2) or 2-6C alkenyl; E is a group of formula II (wherein R
5 is H or 1-4C alkyl; R
6 is H and R
5 and R
6 join to form 4-8C alkylene); A is a group of formula III (wherein r is 1-3); p is 0 or 1; Y is O or S; T is a group of IV, etc.; m>1].
EXAMPLE: A compound of formula of formula V.
USE: An adhesion promoter, an adhesive, and a sealant containing the same.
PREPARATION: Successively, a first silane and an aminal of formula IV or an imine-amine VII and then, a second silane are added and reacted in the presence of a catalyst such as triethylamine at 30-140°C.
COPYRIGHT: (C)1991,JPO |
51 |
JPS628424B2 - |
JP3201177 |
1977-03-23 |
JPS628424B2 |
1987-02-23 |
RUISU RAFUON |
|
52 |
JPS627182B2 - |
JP1639078 |
1978-02-14 |
JPS627182B2 |
1987-02-16 |
RUI RAFUON |
|
53 |
Acetoacetylation of aromatic compound |
JP2427486 |
1986-02-07 |
JPS61183244A |
1986-08-15 |
MISHIERU KUROSHIYUMOORU; MISHIERU GEI |
|
54 |
Novel perfluorodialkylcarbamoyl fluoride and preparation thereof |
JP24279284 |
1984-11-16 |
JPS61122260A |
1986-06-10 |
ABE TAKASHI; HAYASHI EIJI |
NEW MATERIAL:The compound of formula I (n is 1W5; m is 2W5).
EXAMPLE: Perfluoro(N,N-diethylcarbamoyl fluoride).
USE: Useful as a synthetic intermediate for fluorine-containing products (e.g. agricultural chemicals, pharmaceuticals, dyes, surfactants, etc.).
PREPARATION: The compound of formula I can be prepared by reacting the perfluoroaliphatic tert-amine of formula II with fuming sulfuric acid in the presence or absence of a catalyst under heating. The compound of formula II is e.g. perfluoro(N,N-diethyl-methylamine), etc., and can be obtained easily by the electrolytic fluorination of the corresponding aliphatic tert-amine. The reaction is carried out preferably at a fuming sulfuric acid concentration of 10W60% and a reaction temperature of 100W180°C.
COPYRIGHT: (C)1986,JPO&Japio |
55 |
Concentrating method of heavy carbon |
JP18273684 |
1984-09-03 |
JPS6161621A |
1986-03-29 |
KITAMOTO ASAFUMI; TAKESHITA KENJI |
PURPOSE: To separate and obtain easily C-13 utilizable for a tracer, etc. by carrying out an carbon isotope-exchange reaction between carbamic acid, formed from amine and carbon dioxide, and carbon dioxide.
CONSTITUTION: An amine consisting of di-normal-butylamine is allowed to react with carbon dioxide in the presence of an org. solvent consisting of normal hexane, etc. under pressure and/or at 0°C to form carbamic acid. And by obtaining carbamic acid and carbon dioxide, a carbon isotope-exchange reaction is carried out between carbon dioxide and carbamic acid to concentrate C-13. Namely, a solvent contg. a mixture of amine and carbon dioxide is continuously supplied into a reaction tower to form carbamic acid, and a carbon isotope- exchange reaction is continuously carried out by the contact of carbamic acid with carbon dioxide. Consequently, C-13 is concentrated in carbon dioxide at the bottom part of the tower. Meanwhile, C-12 is concentrated in carbon dioxide rising up to the top part of the tower.
COPYRIGHT: (C)1986,JPO&Japio |
56 |
JPS617186B2 - |
JP564679 |
1979-01-23 |
JPS617186B2 |
1986-03-04 |
MANFUREETO RENTE; GERUHARUTO DANKERUTO |
|
57 |
Manufacture of n-chlorocarbonyl-isocyanide dichloride |
JP21530684 |
1984-10-16 |
JPS60105656A |
1985-06-11 |
HERUMAN HAAGEMAN; MANFUREETO RENTE; FURITSUTSU DERINGU; KARURU HAINRITSUHI MOORUMAN |
|
58 |
Glycerol derivative, production thereof and pharmaceutical containing said derivative |
JP21251483 |
1983-11-14 |
JPS60105650A |
1985-06-11 |
ARAI YOSHINOBU; HAMANAKA NOBUYUKI; MIYAMOTO TSUMORU |
NEW MATERIAL:A compound of I [A is O or carbonyloxy; R
1 is 6W22C alkyl or 2W5C alkyl substituted by phenyl; R
2 is OH, amino, azido, 1W20C alkyl, etc.; R
3 is a group of -N(R
6)
2 (R
6 is 1W8C alkyl, etc.), etc.; m and n are 0 or integers 1W6, m+n is >1].
EXAMPLE: (2RS)-1-O-Hexadecyl-3-O-{4-[( N,N,N-trimethylammonio )butyl]phenyl} glycerol mesylate.
USE: An inhibitor for blood platelet agglutination, antiasthmatic, antiallergic, anti- inflammatory, hypotensive and antitumor agents.
PREPARATION: A compound of formula II (R
2a is OH, azido, 1W20C alkyl, etc.) is reacted with a compound of formula III (Q is halogen, alkylsulfonyloxy, etc.) in the presence of a base at room temperature W100°C, and if necessary the resultant product is alkylated and subjected to the salt conversion reaction to afford the aimed compound of formula I .
COPYRIGHT: (C)1985,JPO&Japio |
59 |
JPS6021133B2 - |
JP14351976 |
1976-12-01 |
JPS6021133B2 |
1985-05-25 |
SUAMI TETSUO; OGAWA SEIICHIRO |
|
60 |
Production of aminopropane derivative |
JP3590683 |
1983-03-07 |
JPS59161336A |
1984-09-12 |
OSHIMA IWAO; YAMASHITA MITSUO |
PURPOSE: An azetidine which is readily available from azetidinone and hydrolan is used as a starting substance to be subjected to reductive fission to produce the titled compound which is used as a medicine or its intermediate simply through a shortened process.
CONSTITUTION: An azetdine of formula I (Ar is aromatic radical; R
1 is H, alkyl, aromatic, ester, carboxyl, hydroxyl, alkoxy; R
2, R
3 are H, alkyl, alkoxy; X is hydroxyl, alkoxy, aryloxy, carbamoyl, acyloxy, amino), such as 1-cyclohexyl-2- phenyl-3-benzyloxyazetidine is subjected to reductive fission to give the objective compound of formula II (Ar' is Ar, R
1' is R
1; Y is X) such as l-cyclohexylamino-3-phenyl-2-propanol. The reductive fission is effected by using hydrogen in the presence of a palladium catalyst or using lithium or sodium in liquid ammonia.
COPYRIGHT: (C)1984,JPO&Japio |