Multilyer barrier coating and method to produce a multilayer barrier coating
专利汇可以提供Multilyer barrier coating and method to produce a multilayer barrier coating专利检索，专利查询，专利分析的服务。并且Examples of the present disclosure relate to an apparatus for providing a multilayer barrier coating and method for forming the same. The apparatus may comprise: at least a first layer and a third layer formed via a first process; and at least a second layer, between the first and third layers, formed via a second process different to the first process; wherein the first process is a Sol-Gel process. The apparatus may be used to encapsulate an object (not least for example an organic light-emitting display or photovoltaic cell) to provide barrier protection.，下面是Multilyer barrier coating and method to produce a multilayer barrier coating专利的具体信息内容。
Examples of the present disclosure relate to an apparatus and method for multilayer barrier coating. Some examples, though without prejudice to the foregoing, relate to a multilayer thin-film composite barrier coating for encapsulation of an object, not least for example a flexible substrate such as an organic light-emitting display (OLED) or photovoltaic cell.
Conventional barrier coatings are not always optimal. Previous coatings may not provide adequate barrier properties in thin-film form and/or may be too bulky and brittle for long term flexible use as a barrier coating for a flexible substrate, such as flexible OLEDs and flexible active-matrix OLEDs (AMOLEDs) which require a high degree of protection from moisture and oxygen penetration as well as maintaining such protection during long-term flexible use.
The listing or discussion of any prior-published document or any background in this specification should not necessarily be taken as an acknowledgement that the document or background is part of the state of the art or is common general knowledge. One or more aspects/examples of the present disclosure may or may not address one or more of the background issues.
The present invention is as set out in the independent claims.
According to at least some but not necessarily all examples of the disclosure there is provided an apparatus configured to provide a multilayer barrier coating for a surface, the apparatus comprising: at least a first layer and a third layer formed via a first process; and at least a second layer, between the first and third layers, formed via a second process different to the first process; wherein the first process is a Sol-Gel process.
According to at least some but not necessarily all examples of the disclosure there is provided a method comprising causing, at least in part, actions that result in: forming a first layer of a multilayer barrier coating on a substrate via a first process; forming a second layer of the multilayer barrier coating via a second process different to the first process; forming a third layer of the multilayer barrier coating via the first process, such that the second layer interposes the first and third layers; and wherein the first process is a Sol-Gel process.
According to at least some but not necessarily all examples of the disclosure there is provided a multilayer barrier coating fabricated by the above method.
According to at least some but not necessarily all examples of the disclosure there is provided a substrate, device or object (such as, for example, an Organic Light Emitting Diode or a Photovoltaic cell) at least partially encapsulated by the above multilayer barrier coating.
For a better understanding of various examples of the present disclosure that are useful for understanding the detailed description and certain embodiments of the invention, reference will now be made by way of example only to the accompanying drawings in which:
Figure 1 schematically illustrates an example of a multilayer barrier coating;Figure 2 schematically illustrates a further example of a multilayer barrier coating;Figure 3 schematically illustrates a yet further example of a multilayer barrier coating;Figure 4 schematically illustrates an object encapsulated by a multilayer barrier coating; andFigure 5 schematically illustrates an example of a method.
The Figures schematically illustrate an apparatus 100 configured to provide a multilayer barrier coating for a surface 201'. The apparatus 100 comprises:
- at least a first layer 101 and a third layer 103 formed via a first process; and
- at least a second layer 102, between the first and third layers, formed via a second process different to the first process;
- wherein the first process is a sol-gel process.
Without limiting the scope of the claims, an advantage of certain examples of the present disclosure may be to provide a multilayer thin-film composite structure for providing a barrier coating and encapsulation of an object such as, not least for example: an organic light emitting diode (OLED), photovoltaic (PV) cell, packaging (such as food packaging), a membrane or filter (such as a water treatment filter membrane). Examples may also be to provide a barrier coating for a flexible surface such as a: flexible substrate, laminate film, sheet or roll. Examples may also be used for encapsulating objects/articles that require a high degree of protection against contamination or for hygiene purposes, such as, not least for examples in the food industry or medical industry.
An advantage of certain examples of the present disclosure is that the first layer formed via the sol-gel process provides a hydrophilic primer layer for a subsequently deposited layer (which is formed by a process other than the sol-gel process). Such a hydrophilic primer layer aids the binding/attachment of the subsequently deposited layer, thereby enhancing the robustness of the subsequent layer. Moreover, the first layer provides a planarised/smooth surface onto which the subsequent layer may be deposited. Such a planarising/smoothing layer reduces surface roughness of the underlying surface by encapsulating surface defects so as to provide a smooth planarised surface better suited for forming a subsequent layer which enhances the robustness of the subsequent layer.
The subsequent (second) layer, formed via a non-sol-gel process, may be selected so as to provide a barrier layer which increases a permeate path length of the overall multilayer barrier coating. The barrier material and deposition process may be selected so as to provide a barrier against gas permeation, e.g. oxygen and water vapour. The third layer, which is formed via the sol-gel process, may provide both mechanical protection to the underlying second layer as well as may prevent leaching of the underlying second layer so as to provide a protective top coating, thereby providing a more robust second layer.
Advantageously, the interleaving of a non-sol-gel based layer between two sol-gel based layers provides a more robust non-sol-gel based layer which is better able to withstand repeated flexing. Moreover, each of the sol-gel layers themselves acts to increase a permeate path length of the overall multilayer barrier coating. Thus certain examples provide an improved barrier coating with enhanced barrier/penetration/permeation properties and resilience to flexing.
An example of an apparatus configured to provide a multilayer barrier coating for a surface will now be described with reference to the Figures. Similar reference numerals are used in the Figures to designate similar features. For clarity, all reference numerals are not necessarily displayed in all figures.
The first layer 101 is formed of a material which is deposited via a sol-gel process. The first layer may be provided on a surface (not shown in
The first layer 101 is applied to a surface 201' of the substrate 201. The substrate may be a flexible substrate (such as not least polyethylene naphthalate (PEN), Polyethylene terephthalate (PET) and polyimide based substrates) and/or a substrate onto which an object to be encapsulated is fabricated, such an object may comprise organic electronics such as an OLED or PV. The first layer helps reduce/avoid irregular peaks in the PEN substrate and provide a smooth primer layer for the subsequent second layer.
In the apparatus of
The third layer, in addition to providing diffusion control/increasing the permeate path length and providing a protective layer to the underlying second layer, also provides a planarization/smoothing layer to reduce surface roughness, encapsulating surface defects thereby providing a planarized surface better suited for forming the fourth layer on. Also, the third sol-gel layer provides a hydrophilic layer conducive for forming the fourth layer on.
In particular, in the apparatus 300 of
Advantageously, the multilayer basic unit structure of first to third layers 101-103 is reproducible on itself such that one can stack/repeat such a unit structure on top of one another. This can enable an easy and cost effective multilayer barrier to be fabricated with enhanced permeability/impenetrability properties or even having particular desired permeability/impenetrability properties by repeating the formation/application of the three layers.
It will be appreciated that for each of the apparatus 200 and the apparatus 300, yet further additional layers may be provided. For example yet further layers formed via a sol-gel process and via a non-sol-gel process. Since each sol-gel layer and each non sol-gel layer increases permeate path length of the multilayer structure, the addition of yet further sol-gel and non-sol-gel layers provides yet further diffusion control and yet further increase the permeate path length of the overall multilayer structure. Accordingly, additional sol-gel layers and additional non sol-gel layers may be provided so as to provide a requisite degree of diffusion control/permeate path lengths.
It is envisaged that examples of the present disclosure may enable the provision of low cost encapsulation especially when the multilayer structure is produced via a roll to roll process wherein additional layers of the multilayer structure can be stacked on top of one another by repeating the roll to roll process, or incorporating additional deposition steps in one continuous roll to roll process.
The object to be encapsulated and the multilayer barrier coating itself may be flexible as indicated by the arrow in
The object to be encapsulated may comprise an organic electronic circuit or device such as an organic light emitting diode. The object to be encapsulated may further or alternatively comprise a transistor-based circuit or a transistor array such as a metal-oxide transistor array. Furthermore, the apparatus may be included in a device such as an electronic device or a handheld supportable electronic device such that one or more components of the device or the entire device itself might be encapsulated by the multilayer barrier coating.
It is to be appreciated that
In certain examples, the apparatus may be embodied in a hand held portable electronic device, such as, mobile telephone, tablet, wearable computing device, a mobile terminal portable digital assistant (PDA), a pager, a mobile computer, a desktop computer, a television, a gaming device, a laptop computer, a camera, a video recorder, GPS device and in other types of electronic systems, which may readily employ examples of the present disclosure. Furthermore, devices may readily employ examples of the present disclosure regardless of their intent to provide mobility. Such electronic devices may additionally provide one or more audio/text/video communication functions (e.g. tele-communication, video-communication, and/or text transmission (Short Message Service (SMS)/ Multimedia Message Service (MMS)/emailing functions), interactive/non-interactive viewing functions (e.g. web-browsing, navigation, TV/program viewing functions), music recording/playing functions (e.g. Moving Picture Experts Group-1 Audio Layer 3 (MP3) or other format and/or (frequency modulation/amplitude modulation) radio broadcast recording/playing), downloading/sending of data functions, image capture function (e.g. using a (e.g. in-built) digital camera), and gaming functions.
The apparatus may be provided in a module. As used here 'module' refers to a unit or apparatus that excludes certain parts/components that would be added by an end manufacturer or a user. For example, the module may relate to a display module which is added to an electronic device.
Optionally, further layers may be applied to the first, second and third layers. The "A" branch of the method relates to forming a multi-layered structure having alternating layers of sol-gel derived material and non-sol-gel derived material. In block 504A, a fourth layer is applied over the third layer via a process other than the sol-gel process. Such a process may correspond to the same process that is used to form the second layer in block 502. In block 505A, a fifth layer is applied over the fourth layer via the sol-gel process. It will be appreciated that further additional layers, i.e. sixth, seventh and so on, may also be formed.
The "B" branch of the method 500 relates to forming a multi-layered structure having a stack/repetition of the basic unit structure of two layers of sol-gel derived material sandwiching a layer of a non-sol-gel derived material. In block 504B a fourth layer is applied via the sol-gel process followed by block 505B in which a fifth layer is applied which is formed via a differing process and in block 506B, a sixth layer is then provided formed via the sol-gel process. It will be appreciated that further additional basic unit structures may also be formed.
The flowchart of
The following tables provide results from coating trials which have been conducted by coating a PEN substrate with various differing coatings. Table 1 provides measured values of water vapour transmission rates (WVTR), whereas table 2 sets out measured values of oxygen transmission rates (OTR).
As will be apparent from these tables, coatings of examples of the present disclosure are highlighted which include the basic unit structure of the sandwiching of "non-sol-gel" layers between two sol-gel layers (e.g. Sol-Gel/ALD1 /Sol-Gel and Sol-Gel/ALD2/Sol-Gel) provides improved vapour and oxygen transmission rates.
The following is a discussion/overview of the sol-gel process.
The sol-gel process may involve the evolution of inorganic networks in a continuous liquid phase through the formation of colloidal suspension and following gelation of the sol. The sol-gel process can be used to manufacture various materials, including coatings, powders, monoliths, capsules, fibres or aerogels. Advantages of sol-gel thin films include the homogeneity and purity of the end-products formed at relatively low temperatures.
Metal or non-metal alkoxides may be used as monomers in a typical sol-gel synthesis for coatings. The sol-gel synthesis can be based on controlled hydrolysis and condensation reactions. Reaction 1 below represents the hydrolysis, where M may be a metal e.g.: silicon, zirconium or titanium and n is a number, e.g. four. Hydrolysis acts as a rapid initial reaction of sol-gel processes, where reactive alkoxide groups (-OR, where R is e.g. CH3, CH3CH2, CH3(CH2)2) react with water molecules to form hydroxyl groups (-OH). After the initiation of the reaction, the hydrolysed alkoxides may easily react with each other, forming dimers through the condensation reaction. Water or alcohol may be obtained as a by-product, depending on the reaction mechanism. The condensation reactions are described with Reactions 2 and 3.
M(OR)n + H2O -> M(OH)(OR)n-1+ROH (Reaction1)
M(OH)(OR)n-1 + M(OR)n -> (OR)n-1MOM(OR)n-1 + ROH (Reaction 2)
2M(OH)(OR)n-1 -> (OR)n-1MOM(OR)n-1 + H2O (Reaction 3)
The alkoxide monomers may have a different reactivity, which can be related to the partial charge of the metal or the non-metal alkoxide. The reactivity of the monomers in hydrolysis and condensation reactions can be accelerated or hindered by using catalysts or by increasing or decreasing the reaction temperature.
The sol-gel hybrid coating composition may typically be formed using components that are capable of producing cross-linked networks. These compositions include at least one curable component, i.e. a precursor, preferably selected from UV or thermally curable components. Particularly, such precursors may be selected from unsaturated organic compounds, metal alkoxides, metal salts, epoxy monomers and acid monomers, for example vinyl, acrylates, methacrylates, silanes and silicates, as well as their derivatives. Most suitably, the precursors may be selected from vinyl, acrylates, methacrylates and silicates, or their derivatives. Preferred derivatives are alkyl and alkoxyl derivatives.
To provide a coating that strongly attaches to a substrate, preferably by covalent attachment or by strong physical interaction, one can use coating components that have reactive covalent-bond-forming end-groups (in addition to the cross-linking groups), such as alkoxide groups, or end-groups that bind to the functional groups of the substrate surface using hydrogen bonds or van der Waals forces, such as silane end-groups or double or triple bonds, preferred ones may be silane groups. These may bind particularly to hydroxyl groups on the substrate surface.
Examples of suitable sol-gel formulations or precursors for a sol-gel composition for forming a coating layer via the sol-gel process include but are not limited to:
The sol-gel coating composition may be applied onto a substrate's surface in the form of a sol-gel, which may be formed, for example, by dispersing the precursors of the coating composition in any common solvent, such as water or an organic solvent, preferably water or an alcohol or a mixture thereof, most suitably a mixture of water and an alcohol. Such a mixture (sol-gel liquid) is typically prepared by mixing the solvents into a water content of ≤50 vol%. The optional alcohol is particularly selected from lower alcohols, including methanol, ethanol, n-propanol and isopropanol.
When using a solvent in forming the sol-gel, the obtained sol-gel can have any solids content between 5-95 percent by weight w-%, preferably between 20-50 w-%. However, it is possible to use also particularly high solids contents, such as contents of 50-95 w-%, or even 75-95 w-%, since the curing step or the optional separate drying step(s) will cause evaporation of any excess solvent.
The application of the coating composition on the substrate may be carried out using any appropriate technique, for example using spray or spin coating, more preferably with the coating composition in a sol-gel form. The sol-gel may be formed, for example, as described above.
The curing may be, in turn, carried out using thermal or UV curing. Further, it can be operated at atmospheric temperature and pressure. The curing causes the precursor component(s) of the coating composition to react and solidify, but causes also drying of the coating composition.
However, it is preferred to carry out at least one drying step, particularly two or more drying steps, prior to the curing. Suitable alternatives for the drying step are any drying procedures based on evaporation, such as air drying and drying by IR or UV radiation. Most suitably, at least two separate drying steps (in addition to the curing step) are carried out, which generally utilize two or more different techniques, such as air drying and IR drying. The drying temperature depends on the applied technique. Preferably, a low temperature (i.e. close to room temperature) is selected, such as a temperature within the range of 25-100 °C.
The thickness of the thus obtained final cured coating derived via the sol-gel process is adjustable, but is preferably within the range of 100 nm to 5 µm. The previously described advantages of a sol-gel derived layer can be obtained even with thin coatings, the thicknesses are particularly adjusted to be within the range of 100 to 1000 nm, most suitably 300 to 900 nm.
The examples of the present disclosure and the accompanying claims may be suitably combined in any manner apparent to one of ordinary skill in the art.
Features described in the preceding description may be used in combinations other than the combinations explicitly described.
Although functions have been described with reference to certain features, those functions may be performable by other features whether described or not.
Although features have been described with reference to certain examples, those features may also be present in other examples whether described or not.
Although various examples of the present disclosure have been described in the preceding paragraphs with reference to various examples, it should be appreciated that modifications to the examples given can be made without departing from the scope of the invention as set out in the claims.
The term 'comprise' is used in this document with an inclusive not an exclusive meaning. That is any reference to X comprising Y indicates that X may comprise only one Y or may comprise more than one Y. If it is intended to use 'comprise' with an exclusive meaning then it will be made clear in the context by referring to "comprising only one ..." or by using "consisting".
In this description, reference has been made to forming first, second, third layers and so on. It should be appreciated that each consecutive layer may be directly applied to the previous layer. However in certain examples it should also be appreciated that any number or combination of intervening layers could be provided and may exist between the first, and second layer or the second and third layer and so on (including no intervening layers).
In this description, reference has been made to various examples. The description of features or functions in relation to an example indicates that those features or functions are present in that example. The use of the term 'example' or 'for example' or 'may' in the text denotes, whether explicitly stated or not, that such features or functions are present in at least the described example, whether described as an example or not, and that they can be, but are not necessarily, present in some or all other examples. Thus 'example', 'for example' or 'may' refers to a particular instance in a class of examples. A property of the instance can be a property of only that instance or a property of the class or a property of a sub-class of the class that includes some but not all of the instances in the class.
Whilst endeavouring in the foregoing specification to draw attention to those features of examples of the present disclosure believed to be of particular importance it should be understood that the applicant claims protection in respect of any patentable feature or combination of features hereinbefore referred to and/or shown in the drawings whether or not particular emphasis has been placed thereon.
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