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Process for producing block copolymer

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专利汇可以提供Process for producing block copolymer专利检索,专利查询,专利分析的服务。并且A self-curing block copolymer, which has improved elastomeric properties without being subjected to any special chemical or physical treatment, is obtained by a single-stage process which comprises subjecting coexistent conjugated diene and vinylsubstituted aromatic hydrocarbon to the action of a dilithium catalyst, and, after substantial completion of polymerization of the conjugated diene, adding a chelating bi- or tri-functiona Lewis base to continue polymerization of the vinyl substituted aromatic hydrocarbon. The block copolymer thus obtained has a high tensile strength and high elongation in the unvulcanized state and can be processed similarly to a thermoplastic resin by injection and extrusion techniques.,下面是Process for producing block copolymer专利的具体信息内容。

1. A PROCESS FOR PORDUCING A BLOCK COPOLYMER HAVING A MIDDLE COPOLYMER BLOCK COMPOSED PREDOMINANTLY OF UNITS OF CONJUGATED DIENE AND REMAINING UNITS OF A VINYL-SUBSTITUTED AROMATIC HYDROCARBON OF THE GENERAL FORMULA
2. A process according to claim 1, wherein the chelating tri-functional Lewis base is tris(dimethylamino)phosphine oxide or tris(diethylamino)phosphine oxide.
3. A process according to claim 1, wherein the chelating tri-functional Lewis base is tris(dimethylamino)phosphine oxide.
4. A process according to claim 1, wherein the vinyl-substituted aromatic hydrocarbon is styrene, 3-vinyltoluene, Alpha -methylstyrene, Alpha ,p-dimethylstyrene, 2,5-dimethyl- Alpha -methylstyrene or 1-vinylnaphthalene.
5. A process according to claim 1, wherein the vinyl-substituted aromatic hydrocarbon is Alpha -methylstyrene.
6. A process according to claim 1, wherein the conjugated diene is 1,3-butadiene, isoprene or 1,3-pentadiene.
7. A process according to claim 1, wherein the dilithium compound is a member selected from the group consisting of methylenedilithium, ethylenedilithium, trimethylenedilithium, tetramethylenedilithium, pentamethylenedilithium, hexamethylenedilithium, 1,4-dilithiobenzene, 1,5-dilithionaphthalene, 1,2-dilithio-1,2-diphenylethane, 1,2-dilithio-1,3diphenylpropane, 1,4-dilithio-1,1,4,4-tetraphenylbutane; addition compounds of metallic lithium with isoprene, styrene and Alpha -methylstyrene; and addition compounds of metallic lithium with naphthalene, anthracene and phenanthrene.
8. A process according to claim 1, wherein the ratio of the vinyl-substituted aromatic hydrocarbon component in the block copolymer is 5 to 50% by weight.
9. A process according to claim 1, wherein the polymerization is carried out in the solution phase using a solvent.
10. A process according to claim 9, wherein the solvent is at least one member selected from the group consisting of benzene, toluene, n-hexane, n-heptane and cyclohexane.
11. A process according to claim 1, wherein polymerization is carried out in bulk.
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