序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
1 氟代链烯基化合物的制备方法 CN92101341.8 1992-02-28 CN1057755C 2000-10-25 P·G·鲁明斯基
用于控制对农作物有害的线虫、昆虫和螨的氟代链烯基化合物及其控制方法。尤其是将极性化合物,例如3,4,4-三氟-3-丁烯-1-胺或3,4,4-三氟-3-丁烯酸用于内吸收控制害虫。还提供了制备3,4,4-三氟-3-丁烯-1-胺的新方法和中间体。
2 氟代链烯基化合物及其用作驱虫剂 CN98125774.7 1992-02-28 CN1269136A 2000-10-11 P·G·鲁明斯基
用于控制对农作物有害的线虫、昆虫和螨的氟代链烯基化合物及其控制方法。尤其是将极性化合物,例如3,4,4-三氟-3-丁烯-1-胺或3,4,4-三氟-3-丁烯酸用于内吸收控制害虫。还提供了制备3,4,4-三氟-3-丁烯-1-胺的新方法和中间体。
3 用于二烯的氢氰化和非共轭2-烷基-3-单烯烃腈的异构化的改进方法 CN96199151.8 1996-12-12 CN1205685A 1999-01-20 A·I·布雷克斯; T·福
一种二烯的氢氰化方法,采用了一种含有零价镍化合物和一些二配位磷化合物的催化剂,和一种通过采用这类催化剂来异构化2-烷基-3-单烯烃腈,生成直链腈的方法。
4 氟化链烯基化合物及其用作驱虫剂 CN92101341.8 1992-02-28 CN1064479A 1992-09-16 P·G·鲁明斯基
用于控制对农作物有害的线虫、昆虫和螨的氟代链烯基化合物及其控制方法。尤其是将极性化合物,例如3,4,4-三氟-3-丁烯-1-胺或3,4,4-三氟-3-丁烯酸用于内吸收控制害虫。还提供了制备3,4,4-三氟-3-丁烯-1-胺的新方法和中间体。
5 用于二烯的氢氰化和非共轭2-烷基-3-单烯烃腈的异构化的改进方法 CN96199151.8 1996-12-12 CN1090174C 2002-09-04 A·I·布雷克斯; T·福
一种二烯的氢氰化方法,采用了一种含有零价镍化合物和一些二配位磷化合物的催化剂,和一种通过采用这类催化剂来异构化2-烷基-3-单烯烃腈,生成直链腈的方法。
6 丙烯酰胺溶液的浓缩方法 CN97111697.0 1997-04-17 CN1090173C 2002-09-04 神原芳彦; 松村六雄; 梅野道明; 上原与志一; 朝生公一
发明公开了一种浓缩由丙烯腈合制得的丙烯酰胺水溶液或浓缩基本上不含丙烯腈的丙烯酰胺水溶液的方法。该方法使用了至少一部分与溶液接触的部分由含材料制成的浓缩设备。浓缩是在向设备中加入含气体的同时进行。使用本发明的方法,可以在丙烯酰胺水溶液的浓缩过程中,防止端聚物的生成、附着、沉积等,并且可以制备高质量的丙烯酰胺。
7 丙烯酰胺溶液的浓缩方法 CN97111697.0 1997-04-17 CN1170713A 1998-01-21 神原芳彦; 松村六雄; 梅野道明; 上原与志一; 朝生公一
发明公开了一种浓缩由丙烯腈合制得的丙烯酰胺水溶液或浓缩基本上不含丙烯腈的丙烯酰胺水溶液的方法。该方法使用了至少一部分与溶液接触的部分由含材料制成的浓缩设备。浓缩是在向设备中加入含气体的同时进行。使用本发明的方法,可以在丙烯酰胺水溶液的浓缩过程中,防止端聚物的生成、附着、沉积等,并且可以制备高质量的丙烯酰胺。
8 Fluoroalkenyl compounds and their use as pest repellents US443645 1995-05-18 US5623084A 1997-04-22 Peter G. Ruminski
Fluorinated alkene compounds useful for and methods of controlling nematodes, insects, and acarids that prey on agricultural crops. Polar compounds, for example, 3,4,4-trifluoro-3-butene-l-amine or 3,4,4-trifluoro-3-butenoic acid, are particularly useful for systemic control of pests. Novel method and intermediates for the preparation of 3,4,4-trifluoro-3-butene-1-amine are also provided.
9 Method of concentrated aqueous acrylamide solution JP9533296 1996-04-17 JP3708212B2 2005-10-19 与志一 上原; 公一 朝生; 六雄 松村; 道明 梅野; 芳彦 神原
10 Improved method of isomerization of hydrocyanation and non-conjugated 2-alkyl-3-monoalkenenitriles of diolefin JP52368997 1996-12-12 JP2925746B2 1999-07-28 BUREIKUSU AN AIRISA; FUU TOOMASU
11 Improved method of isomerization of hydrocyanation and non-conjugated 2-alkyl-3-monoalkenenitriles of diolefin JP52368997 1996-12-12 JPH11501672A 1999-02-09 フー,トーマス; ブレイクス,アン,アイリサ
(57)【要約】 ゼロ価のニッケル化合物と特定の二座リン化合物との組み合わせを含有する触媒を用いるジオレフィンのヒドロシアン化方法、およびそのような触媒を用いることによる2−アルキル−3−モノアルケンニトリルを異性化して直鎖状のニトリルを形成するための方法。
12 Method for concentration of acrylamide aqueous solution JP9533296 1996-04-17 JPH09278727A 1997-10-28 MATSUMURA MUTSUO; UMENO MICHIAKI; UEHARA YOSHIICHI; ASAO KOICHI; KANBARA YOSHIHIKO
PROBLEM TO BE SOLVED: To concentrate an acrylamide aqueous solution good in polymerizability without the generation of a popcorn polymer, capable of obtaining a product with a high degree of polymerization and good solubility in water by putting a copper material on a portion contacting to a solution, of an apparatus for concentration. SOLUTION: When synthesizing acrylamide B through hydration of acrylonitrile A, in a process to concentrate to a preferred concentration of an aqueous solution of the compound B by isolating the unreacted compound A and an excess quantity of water from a synthesizing reactional solution, or in a process to concentrate a dilute acrylamide aqueous solution virtually not including the compound A to a preferred concentration, at least a part of members forming a contact part with the solution of an apparatus for the concentration is made of a copper material and concentration is conducted by introducing oxygen gas into the apparatus at the time of the concentration. It is preferable that a concentration of copper ions in the solution fed into the concentration process is in the range of 0∼100ppm based on the quantity of the compound B. COPYRIGHT: (C)1997,JPO
13 JPH06505485A - JP50755992 1992-02-27 JPH06505485A 1994-06-23
14 Hidorajinno seizochunierareru goseiyoekino shorihoho JP9032575 1975-07-25 JPS5137896A 1976-03-30 KURUTO BIRUHERUMU AIHENHOTSUFU; RAINHARUTO SHURIIBUSU; HERUMAN BURANDORU; HAINRITSUHI KOONEN
In the production of hydrazine wherein aqueous ammonia is oxidized in the presence of a ketone to form an aqueous solution containing at least one of a hydrazone and a ketazine along with ammonia, the hydrazone and ketazine are concentrated and the hydrazone and ketazine are subsequently hydrolyzed to hydrazine and ketone, the improvement which comprises effecting the concentration of the hydrazone and ketazine by extracting the aqueous solution with a substantially water-immiscible organic solvent whereby the hydrazone and ketazine preferentially enter the water-immiscible solvent, and separating the water-immiscible solvent extract from the aqueous solution. The organic solvent is preferably a higher alcohol, a chlorinated hydrocarbon, benzene or a substitution product thereof. The organic solvent extract, in one or more stages, and optionally with addition of ketone, can be re-extracted with water, hydrolyzed with aqueous acid or subjected to distillation to separate the hydrazine values from the organic solvent.
15 Concentration method of aqueous acrylamide solution US834983 1997-04-07 US5922912A 1999-07-13 Yoshihiko Kambara; Mutsuo Matsumura; Michiaki Umeno; Yoshikazu Uehara; Koichi Asao
A method is disclosed for the concentration of an aqueous acrylamide solution prepared by hydration of acrylonitrile or an aqueous acrylamide solution substantially free of acrylonitrile. The method makes use of a concentration apparatus at least a part of whose solution-contacting section is made of a copper-containing material. The concentration is conducted while introducing an oxygen-containing gas into the apparatus. Use of this method can prevent formation, adhering, accumulation and the like of popcorn polymers inside the concentration apparatus upon concentration of the aqueous acrylamide solution, and can also produce high-quality acrylamide.
16 Fluoroalkenyl compounds and their use as pest repellents US763802 1996-12-11 US5693865A 1997-12-02 Peter Gerrard Ruminski
Fluorinated alkene compounds useful for and methods of controlling nematodes, insects, and acarids that prey on agricultural crops. Polar compounds, for example, 3,4,4-trifluoro-3-butene-1-amine or 3,4,4-trifluoro-3-butenoic acid, are particularly useful for systemic control of pests. Novel method and intermediates for the preparation of 3,4,4-trifluoro-3-butene-1-amine are also provided.
17 Fluoroalkenyl compounds and their use as pest repellents US321952 1994-10-12 US5457134A 1995-10-10 Peter G. Ruminski
Fluorinated alkene compounds useful for and methods of controlling nematodes, insects, and acarids that prey on agricultural crops. Polar compounds, for example, 3,4,4-trifluoro-3-butene-1-amine or 3,4,4-trifluoro-3-butenoic acid, are particularly useful for systemic control of pests. Novel method and intermediates for the preparation of 3,4,4-trifluoro-3-butene-1-amine are also provided.
18 Fluoroalkenyl compounds and their use as pest repellents US701517 1996-08-22 US5714517A 1998-02-03 Peter Gerrard Ruminski
Fluorinated alkene compounds useful for and methods of controlling nematodes, insects, and acarids that prey on agricultural crops. Polar compounds, for example, 3,4,4-trifluoro-3-butene-1-amine or 3,4,4-trifluoro-3-butenoic acid, are particularly useful for systemic control of pests. Novel method and intermediates for the preparation of 3,4,4-trifluoro-3-butene-1-amine are also provided.
19 Process for hydrocyanation of diolefins and isomerization of nonconjugated 2 alkyl-3-monoalkenenitriles US577355 1995-12-22 US5693843A 1997-12-02 Anne Irisa Breikss; Thomas Foo
Described herein is a process for the hydrocyanation of diolefins by employing a catalyst comprising the combination of a zero-valent nickel compound and certain bidentate phosphorus compounds, and a process for isomerizing 2-alkyl-3-monoalkenenitrile to form linear nitriles by the use of such catalyst.
20 Fluoroalkenyl compounds and their use as pest repellents US401635 1995-03-08 US5561162A 1996-10-01 Peter G. Ruminski
Fluorinated alkene compounds useful for and methods of controlling nematodes, insects, and acarids that prey on agricultural crops. Polar compounds, for example, 3,4,4-trifluoro-3-butene-1-amine or 3,4,4-trifluoro-3-butenoic acid, are particularly useful for systemic control of pests. Novel method and intermediates for the preparation of 3,4,4-trifluoro-3-butene-1-amine are also provided.
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