序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
41 METHODS AND COMPOSITIONS USING CALCIUM CARBONATE AND STABILIZER US14828212 2015-08-17 US20150353422A1 2015-12-10 MIGUEL FERNANDEZ; IRVIN CHEN; PATRICIA TUNG LEE; MATTHEW GINDER-VOGEL
Provided herein are compositions, methods, and systems for a material containing metastable carbonate and stabilizer. Methods for making the compositions and using the compositions are also provided.
42 MOLTEN SALT SYNTHESIS FOR MANUFACTURE OF CEMENT PRECURSORS US14441708 2013-11-08 US20150299040A1 2015-10-22 Jonathan Blake NELSON
A method of manufacturing calcium silicates, calcium aluminates, calcium aluminosilicates and calcium ferrites and the products thereby derived utilizing molten-salt synthesis and/or molten-salt sintering. Molten-salt synthesis enables efficiently manufacture calcium silicate (Ca—SiO3), dicalcium silicate (Ca2SiO4), tricalcium disilicate (Ca3Si2O7) and related compounds such as calcium aluminate (CaAl2O4), Gehlenite (Ca2Al2—SiO7) and tetracalcium aluminoferrite (Ca4Al2Fe2OO10) at temperatures in the range of about 400-750° C. The composition of the synthesized product(s) can be varied by altering the ratio of the precursor compounds and by changing the molten-salt composition, whether used as a sintering flux or molten bath, resulting in the ability to manufacture calcium silicates and related compounds for a wide variety of uses, but most specifically as precursors to the manufacture of hydraulic cements or for use in hydraulic cements such as Portland cements and calcium aluminate and other cements.
43 METHODS AND COMPOSITIONS USING CALCIUM CARBONATE AND STABILIZER US14566304 2014-12-10 US20150096470A1 2015-04-09 MIGUEL FERNANDEZ; IRVIN CHEN; PATRICIA TUNG LEE; MATTHEW GINDER-VOGEL
Provided herein are compositions, methods, and systems for a material containing metastable carbonate and stabilizer. Methods for making the compositions and using the compositions are also provided.
44 Methods and compositions using calcium carbonate and stabilizer US13457156 2012-04-26 US08936773B2 2015-01-20 Miguel Fernandez; Irvin Chen; Patricia Tung Lee; Matthew Ginder-Vogel
Provided herein are compositions, methods, and systems for a material containing metastable carbonate and stabilizer. Methods for making the compositions and using the compositions are also provided.
45 Cementitious trim articles US12754567 2010-04-05 US08904732B2 2014-12-09 Hong Chen; Chongjun Jiang; Jong Min Keum; Caidian Luo; Shan Ren; Daniel Jose Suasnabar; Bryan Louis Walters
Described herein is a monolithic cementitious article with one or more pre-formed shaped regions. The shaped regions are generally channels that extend through a portion of the article or span the full article. The article includes one or more openings at least one of its ends. The article has a low apparent density with a high strength as well as high performance characteristics. The article when manufactured is suitable for use as a building product, such as siding, panel, trim, fascia, roofing, crown molding, decking, and fencing.
46 METHOD AND ADDITIVE FOR INCREASING EARLY STRENGTH US14238976 2012-07-16 US20140238274A1 2014-08-28 Frank Bullerjahn; Dirk Schmitt; Mohsen Ben Haha
The present invention relates to a method for accelerating the hardening of hydraulic or latent hydraulic binders, wherein ternesite and an aluminum component are added to the binder, and relates to an additive that increasing early strength for hydraulic or latent hydraulic binders that contain ternesite and a non-hydraulically reactive aluminum component, and relates to the use of an additive comprising ternesite and an aluminum component for the purpose of accelerating the hardening of hydraulic or latent hydraulic binders.
47 Sulfoaluminous clinker and method for preparing same US13141398 2010-01-28 US08268071B2 2012-09-18 Michel Pasquier; Laury Barnes-Davin; Guy Beauvent
The invention relates to a novel sulfoaluminous clinker, to a method for preparing said clinker, and to the use of said clinker for preparing a hydraulic binder and subsequently grout, concrete, or mortar.
48 Process to produce portland cement clinker and obtained clinker US11659372 2005-07-08 US08021478B2 2011-09-20 Homero Ramirez Tobías; Carlos Enrique Castillo Linton
A process for producing Portland cement clinker at low temperatures fixing the sulfur produced by burning high sulfur content coke fuel. The invention also describes a Portland cement clinker that includes new additional phases.
49 Cementitious Articles, Formulations, Methods Of Making And Uses US12754567 2010-04-05 US20100251632A1 2010-10-07 Hong Chen; Chongjun Jiang; Jong Min Keum; Caidian Luo; Shan Ren; Daniel Jose Suasnabar; Bryan Louis Walters
Described herein is a monolithic cementitious article with one or more pre-formed shaped regions. The shaped regions are generally channels that extend through a portion of the article or span the full article. The article includes one or more openings at least one of its ends. The article has a low apparent density with a high strength as well as high performance characteristics. The article when manufactured is suitable for use as a building product, such as siding, panel, trim, fascia, roofing, crown moulding, decking, and fencing.
50 Hydraulic binder having low CO2 emission level US11581292 2006-10-16 US07445668B2 2008-11-04 Denis Sommain
The invention relates to a hydraulic binder containing, in percentage by weight: from 1.1 to 9% of tricalcium aluminate from 1.5 to 13.5% of tetracalcium ferroaluminate from 0.5 to 1.5% of dodecacalcium heptaaluminate from 0.5 to 1.5% of tetracalcium trialuminate sulphate from 0 to 0.8% of dicalcium silicoaluminate from 5 to 70% of pozzolanic material(s) from 0 to 6% of calcium sulphate the remainder being composed of the non-aluminous constituents of at least one Portland-type clinker.It also relates to concretes or mortars prepared using a binder of this type.
51 High temperature cements US10595435 2004-10-26 US20070125271A1 2007-06-07 Veronique Barlet-Gouedard; Bruno Goffe
A method of designing a cement composition comprises determination of the temperature to which the composition will be exposed in situ; determination of a stable, thermodynamic equilibrium composition of a CaO—Al2O3—SiO2—H2O (CASH) mineral system in the [xonotlite/wollastonite]-grossulaire-anorthite or grossulaire-anorthite-quartz triangles of the Si—Ca—Al phase diagram with a possible contribution of iron and/or magnesium, analogous to the cement when set, at the determined temperature; determining proportions of cement and mineral oxides required to provide a mixture having the determined composition; and defining a series of particulate materials of predetermined particle sizes and densities, comprising cement and mineral oxides in the determined proportions.
52 High strength biological cement composition and using the same US11584132 2006-10-20 US20070098811A1 2007-05-03 Donghui Lu; Shuxin Zhou
A hydraulic cement for biomedical applications. The cement sets in-situ, hardening when exposed to water to produce nano-dispersed composite of calcium-silicate-hydrate gel mixed with hydroxyapatite. In comparison with prior cements, the composition provides high biocompatibility, high bioactivity and high biomechanical strength, due to the composite structure of the calcium silicate hydrate reinforced with co-precipitated particles of hydroxyapatite. Biocompatibility is also increased due to an absence of aluminum and magnesium in the composition. The cement is suitable for variety of applications, including dental implants, bone fixation, and bone repair.
53 Very early setting ultra-high strength cement US10886013 2004-07-06 US20050126443A1 2005-06-16 Hassan Kunbargi
Clinkered materials containing high concentrations of {(C,K,N,M)4(A,F,Mn,P,T,S)3(cl,{overscore (S)})} (crystal X), and {(C2S)3(C{overscore (S)})3 Ca(f,cl)2} or {(C2S)3(C{overscore (S)})3 Ca(f,cl)2} (crystal Y), and/or {C5S2{overscore (S)}) (crystal Z) directly from the kiln, rapidly hardening ultra-high early strength cement including these clinkered materials, methods for forming and using said compositions and the cements so produced are claimed. The methods include the steps of forming a mixture of raw material containing CaO, MgO, Al2O3, Fe2O3, TiO2, Mn2O3, SiO2, SO3, Na2O, K2O, P2O5 and F, respectively designated C, M, A, F, T, Mn, S, {overscore (S)}, N, K, P and f, and heating said mixture to an elevated temperature between 900° C. and 1,200° C.; before determining average amount of crystals X, Y, and Z. Final mixtures comprising these clinkers and hydraulic or portland type cement are made to produce cement compositions having crystal X concentrations of approximately 5% to 35% by weight, crystal Y concentrations of approximately 5% to 40% by weight, and/or crystal Z concentrations of approximately 5% to 40% by weight, with the remainder being hydraulic or portland type cement. The cements so produced are rapid hardening and exhibit high strengths ranging from 2,000 psi to 7,000 psi in one hour, 6,000 to 8,000 psi in one day and 9,000 to 12,000 psi in 28 days. They are sulfate and sea-water attack resistant and have low heats of hydration, minimal shrinkage, and high water impermeability. The methods claimed also results in significant reduction in gaseous emissions including SOx, NOx and COx.
54 Rapid hardening, ultra-high early strength portland-type cement compositions, novel clinkers and methods for their manufacture which reduce harmful gaseous emissions US09907867 2001-07-18 US06758896B2 2004-07-06 Hassan Kunbargi
Clinkered materials containing high concentrations of {(C,K,N,M)4 (A,F,Mn,P,T,S)3 Cl,{overscore (S)})}(crystal X), and {C2S)3(C{overscore (S)})3Ca(f,Cl)2} or C9S3{overscore (S)}3Ca(f,cl)2 crystal Y), and/or {C5S2{overscore (S)}) (crystal Z) directly from the kiln, rapidly hardening ultra-high early strength cement including these clinkered materials, methods for forming and using said compositions and the cements so produced are claimed. The methods include the steps of forming a mixture of raw material containing CaO, MgO, Al2O3, Fe2O3, TiO2, Mn2O5, SiO2, SO3, Na2O, K2O, P2O5 and F, respectively designated C, M, A, F, T, Mn, S, {overscore (S)}, N, K, P and f, and heating said mixture to an elevated temperature between 900° C. and 1,200° C.; before determining average amount of crystals X, Y, and Z. Final mixtures comprising these clinkers and hydraulic or portland type cement are made to produce cement compositions having crystal X concentrations of approximately 5% to 35% by weight, crystal Y concentrations of approximately 5% to 40% by weight, and/or crystal Z concentrations of approximately 5% to 40% by weight, with the remainder being hydraulic or portland type cement. The cements so produced are rapid hardening and exhibit high strengths ranging from 2,000 psi to 7,000 psi in one hour, 6,000 to 8,000 psi in one day and 9,000 to 12,000 psi in 28 days. They are sulfate and sea-water attack resistant and have low heats of hydration, minimal shrinkage, and high water impermeability. The methods claimed also results in significant reduction in gaseous emissions including SOx, NOx and COx.
55 Rapid hardening, ultra-high early strength portland-type cement compositions, novel clinkers and methods for their manufacture which reduce harmful gaseous emissions US09716577 2000-11-20 US06406534B1 2002-06-18 Hassan Kunbargi
Clinkered materials containing high concentrations of {(C,K,N,M)4 (A,F,Mn,P,T,S)3 Cl,{overscore (S)})}(crystal X), and {C2S)3 (C{overscore (S)})3Ca(f,Cl)2} or C9S3{overscore (S)}3Ca(f,cl)2 (crystal Y), and/or {C5S2{overscore (S)}) (crystal Z) directly from the kiln, rapidly hardening ultra-high early strength cement including these clinkered materials, methods for forming and using said compositions and the cements so produced are claimed. The methods include the steps of forming a mixture of raw material containing CaO, MgO, Al2O3, Fe2O3, TiO2, Mn2O5, SiO2, SO3, Na2O, K2O, P2O5 and F, respectively designated C, M, A, F, T, Mn, S, {overscore (S)}, N, K, P and f, and heating said mixture to an elevated temperature between 900° C. and 1,200° C.; before determining average amount of crystals X, Y, and Z. Final mixtures comprising these clinkers and hydraulic or portland type cement are made to produce cement compositions having crystal X concentrations of approximately 5% to 35% by weight, crystal Y concentrations of approximately 5% to 40% by weight, and/or crystal Z concentrations of approximately 5% to 40% by weight, with the remainder being hydraulic or portland type cement. The cements so produced are rapid hardening and exhibit high strengths ranging from 2,000 psi to 7,000 psi in one hour, 6,000 to 8,000 psi in one day and 9,000 to 12,000 psi in 28 days. They are sulfate and seawater attack resistant and have low heats of hydration, minimal shrinkage, and high water impermeability. The methods claimed also results in significant reduction in gaseous emissions including SOx, NOx and COx.
56 Rapid hardening, ultra-high early strength Portland-type cement compositions, novel clinkers and methods for their manufacture which reduce harmful gaseous emissions US301370 1999-04-16 US6113684A 2000-09-05 Hassan Kunbargi
Clinkered materials containing high concentrations of {(C,K,N,M).sub.4 (A,F,Mn,P,T,S).sub.3 Cl,S)}(crystal X), and {C.sub.2 S).sub.3 (CS).sub.3 C(f,Cl)} or C.sub.10 S.sub.3 S.sub.3 (f,cl) (crystal Y), and/or {C.sub.5 S.sub.2 S) (crystal Z) directly from the kiln, rapidly hardening ultra-high early strength cement including these clinkered materials, methods for forming and using said compositions and the cements so produced are claimed. The methods include the steps of forming a mixture of raw material containing CaO, MgO, Al.sub.2 O.sub.3, Fe.sub.2 O.sub.3, TiO.sub.2, Mn.sub.2 O.sub.5, SiO.sub.2, SO.sub.3, Na.sub.2 O, K.sub.2 O, P.sub.2 O.sub.5 and F, respectively designated C, M, A, F, T, Mn, S, S, N, K, P and f, and heating said mixture to an elevated temperature between 900.degree. C. and 1,200.degree. C.; before determining average amount of crystals X, Y, and Z. Final mixtures comprising these clinkers and hydraulic or portland type cement are made to produce cement compositions having crystal X concentrations of approximately 5% to 35% by weight, crystal Y concentrations of approximately 5% to 40% by weight, and/or crystal Z concentrations of approximately 5% to 40% by weight, with the remainder being hydraulic or portland type cement. The cements so produced are rapid hardening and exhibit high strengths ranging from 2,000 psi to 7,000 psi in one hour, 6,000 to 8,000 psi in one day and 9,000 to 12,000 psi in 28 days. They are sulfate and sea-water attack resistant and have low heats of hydration, minimal shrinkage, and high water impermeability. The methods claimed also results in significant reduction in gaseous emissions including SO.sub.x, NO.sub.x and CO.sub.x.
57 Interground white blended cement US790958 1997-01-29 US6033468A 2000-03-07 Timothy S. Folks; Patrick M. Hill; Frank T. Sheets, III; Richard F. Ball; Joseph R. Sisneros; Jesus Uribe; Curtis W. Forrester
A composition comprises anhydrous alumino-silicate, diatomaceous earth, and/or other natural pozzolans, white clinker, and white gypsum interground together and in a ratio by weight of 5-20% anhydrous alumino-silicate, diatomaceous earth, and/or other natural pozzolans, 3-7% gypsum, and 73-92% white clinker.
58 Cement containing activated belite US246806 1994-05-20 US5509962A 1996-04-23 Fulvio J. Tang
An article of manufacture and method of manufacture of a cement product composition. A cementitious clinker consisting essentially of an alpha belite and a ferrite phase having a composition of about 0.04-0.13 moles Na.sub.2 O, 0.03-0.07 moles K.sub.2 O, 0.09-0.18 moles Fe.sub.2 O.sub.3, and 2.8 moles dicalcium silicate.
59 Tectoaluminosilicate cement and a process for its manufacture US855014 1992-06-09 US5372640A 1994-12-13 Wolfgang Schwarz; Andre Lerat
A tectoaluminosilicate cement which consists of K, Ca and aluminosilicates plus, optionally, Li, Na and Mg, contains: a phyllosilicate dehydroxylated at a temperature between 500.degree. and 900.degree. C., reactive amorphous silica, reactive calcium silicate glass or reactive calcium aluminosilicate glass with a Ca:Si ratio of .gtoreq.1 and alkali silicate with the total formula: a(M.sub.2 O) * x(SiO.sub.2) * y(H.sub.2 O) in which M=Li, Na or K, a=0-4, x=0-5 and y=3-20, the overall Si:Al ratio being .gtoreq.1. The tectoaluminosilicate cement preferably alkali hydroxide. The dehydroxylated phyllosilicate is a metakaolin giving tectosilicate structures. The reactive amorphous silica is a dealuminated phyllosilicate, a fly ash dealuminated with mineral acids, where applicable, a fine-grained crystalline form of SiO.sub.2 contained in calcinated clays, a silicic acid gel, thermally activated by alkali-activated aluminosilicate, obtained by sintering an aluminosilicate with alkali carbonate at a temperture between 800.degree. and 1,200.degree. C., the alkali and aluminosilicate components being mixed in the ratio 1:6 to 1:1, and/or microsilica ("silica fume"). The alkali metal activator may be prepared in situ from the dealuminated phyllosilicate and/or from the silicic acid gel in the presence of the alkali hydroxide. A bonding matrix obtained from the tectoaluminosilicate cement by reacting with water in the ratio 3:1 to 6:1 consists essentially of the formula: (Li, Na).sub.0-7 K.sub.1-6 Mg.sub.1-0 Ca.sub.3-0 [Al.sub.4 Si.sub.6-14 O.sub.21-36 ].(0-15H.sub.2 O).
60 Time setting clay cement and method of correcting lost circulation US28312952 1952-04-18 US2861636A 1958-11-25 MESSENGER JOSEPH U
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