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序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
161 Structured bodies with siliceous binder US11189665 2005-07-26 US07572749B2 2009-08-11 Jean W. Beeckman; Glenn R. Sweeten; Arthur W. Chester; John P. McWilliams; Dominick N. Mazzone
The invention relates to the use of particulate silicone resins in the absence of added organic solvents with particulate inorganic materials to form structured bodies and in particular molecular sieve containing structured bodies. The silicone resin is used in the form of a particulate with an average particle size of less than 700 um. Upon calcining, the silicone resin is converted to silica which acts as a binder.
162 System and method for making carbon foam anodes US12008268 2008-01-08 US20090176130A1 2009-07-09 Randall J. Harris; Damian Wales
A system for making carbon foam anodes including a digestion vessel in communication with a coal feedstock unit for producing a digested coal; a mold having an interior for accepting the digested coal to produce an ungraphitized carbon foam anode having a desired shape; a pressure unit in communication with the mold for producing an increased pressure within the interior of said mold; a heating element in communication with the mold to provide heat to the mold sufficient to convert the digested coal into the ungraphitized carbon foam anode; and a graphitization oven for graphitizing the ungraphitized carbon foam anode to produce the carbon foam anode. The present invention further includes methods for making carbon foam anodes.
163 Porous Ceramic Materials US12114711 2008-05-02 US20090166214A1 2009-07-02 Tao T. Tao; Linda Bateman
The present invention relates to porous articles, including porous ceramic materials, which can be used in a variety of settings, but find particular use in connection with electrochemical devices such as fuel cells, as well as methods of their manufacture and use. The porous ceramic may have, in some aspects of the invention, an average pore size of between about 1 micrometer and about 300 micrometers, and in some cases, certain advantageous permeability characteristics with respect to species useful in certain types of electrochemical devices. In some cases, the ceramic may be sufficiently porous to allow gaseous molecules (e.g., air or oxygen, gaseous fuels, etc.) and/or liquids (e.g., water or liquid fuels) to be transported therethrough, and/or the ceramic may be substantially resistive or impermeable to a liquid such as a non-wetting liquid, for instance, a liquid metal such as liquid (molten) tin. Another aspect of the invention is generally directed to systems and methods of forming such porous ceramics. In one set of embodiments, a porous ceramic may be formed by impregnating a template (for example, an interconnected template, typically three-dimensional) with a ceramic precursor, causing the ceramic precursor to form a ceramic having an open channel structure, and removing the template. The ceramics of the present invention may find use in a wide variety of applications, including kiln furniture, filters, catalyst supports, fuel cells, carriers for absorbents, insulators, or separators (e.g., for a burner and a flame), and the ceramics may be useful at a broad range of temperatures. For example, a ceramic may be used to separate a fuel from an electrode in a fuel cell (for instance, by converting fuel molecules to produce reaction products), as the ceramic may be permeable to a gas and/or a liquid. Other aspects of the invention relate to kits involving such ceramics, methods of promoting the making or use of such ceramics, and the like.
164 Method of controlling swelling and shrinkage during synthesis of coke US10772920 2004-02-05 US07553470B2 2009-06-30 Alfred Stiller; Chong Chen
Methods of treating a carbon foam precursor to facilitate subsequent foaming of the material at low pressures, which may be on the order of about 0.5 to 1.5 atmospheres, are disclosed. In one embodiment, the carbon foam precursor is subjected to partial devolatilization under controlled conditions with subsequent foaming being effected at low pressure. The carbon foam precursor may be one of various forms of coal including raw coal, coal extract mesophase pitch, synthetic mesophase pitch or petroleum based pitch. The performing treatment of the carbon foam precursor may remove a portion of the internal blowing agent and may alter the fluidity of the carbon foam precursor matrix. In another embodiment, the precursor after being converted into a powder is subjected to oxidation prior to foaming. In another embodiment of the invention a high density carbonaceous material is produced by oxidizing a carbonaceous feedstock to remove from the feedstock volatile gases followed by solvent treatment to remove hydrocarbons thereby providing a carbonaceous feedstock which when coked will produce a material of higher density.
165 Method and apparatus associated with anisotropic shrink in sintered ceramic items US11788286 2007-04-19 US07551977B2 2009-06-23 M. Eric Schlienger; Nina Bergan French; Michael D. Baldwin; Michael Maguire; Paul Withey
A manufacturing method for producing ceramic item from a photocurable ceramic filled material by stereolithography. The method compensates for the anisotropic shrinkage of the item during firing to produce a dimensionally accurate item.
166 HIGH TEMPERATURE REFRACTORY COATINGS FOR CERAMIC SUBSTRATES US11778692 2007-07-17 US20090130446A1 2009-05-21 Wayde R. Schmidt; Tania Bhatia; Xia Tang; David C. Jarmon; Owen B. Donahue
A composite article includes a substrate and a protective layer on the substrate. The protective layer includes a non-oxide ceramic matrix and a refractory phase within the non-oxide ceramic matrix.
167 Method Of Making The Porous Carbon Material And Porous Carbon Materials Produced By The Method US11628153 2005-05-31 US20090117094A1 2009-05-07 Jaan Leis; Mati Arulepp; Marko Latt; Helle Kuura
A method for making the microporous carbon with modified pore size distribution and advanced sorption behaviour. The carbon is derived from metal or metalloid carbides. The method employs the use of oxidant in reaction medium that during the carbide conversion into carbon widens small micropores, which otherwise would be hardly accessed by sorbing molecules or ions in practical applications. The microporous carbon obtained is free of impurities and possesses extremely narrow pore size distribution.
168 Organic, open cell foam materials, their carbonized derivatives, and methods for producing same US11281696 2005-11-16 US07521485B2 2009-04-21 Donald F Albert; Greg R Andrews; Joseph W Bruno
Organic, small pore area materials (“SPMs”) are provided comprising open cell foams in unlimited sizes and shapes. These SPMs exhibit minimal shrinkage and cracking. Processes for preparing SPMs are also provided that do not require supercritical extraction. These processes comprise sol-gel polymerization of a hydroxylated aromatic in the presence of at least one suitable electrophilic linking agent and at least one suitable solvent capable of strengthening the sol-gel. Also disclosed are the carbonized derivatives of the organic SPMs.
169 Method and Apparatus for Producing a Carbon Based Foam Article Having a Desired Thermal-Conductivity Gradient US11862325 2007-09-27 US20090087373A1 2009-04-02 James W. Klett; Christopher Stan Cameron
A carbon based foam article is made by heating the surface of a carbon foam block to a temperature above its graphitizing temperature, which is the temperature sufficient to graphitize the carbon foam. In one embodiment, the surface is heated with infrared pulses until heat is transferred from the surface into the core of the foam article such that the graphitizing temperature penetrates into the core to a desired depth below the surface. The graphitizing temperature is maintained for a time sufficient to substantially entirely graphitize the portion of the foam article from the surface to the desired depth below the surface. Thus, the foam article is an integral monolithic material that has a desired conductivity gradient with a relatively high thermal conductivity in the portion of the core that was graphitized and a relatively low thermal conductivity in the remaining portion of the foam article.
170 POROUS OBJECT BASED ON SILICON CARBIDE AND PROCESS FOR PRODUCING THE SAME US12194015 2008-08-19 US20090017283A1 2009-01-15 Takuya HIRAMATSU; Shinji KAWASAKI
Provided are a silicon carbide-based porous article comprising silicon carbide particles as an aggregate, metallic silicon and an aggregate derived from organometallic compound particles to form pores through volume shrinkage due to decomposition/conversion by heat treatment; and a method for producing the silicon carbide-based porous article, comprising, adding organometallic compound particles to form pores through volume shrinkage due to decomposition/conversion by heat treatment to a raw-material mixture containing silicon carbide particles and metallic silicon, then forming into an intended shape, calcinating and/or firing the resultant green body, forming pores through volume shrinkage due to decomposition/conversion of the organometallic compound particles, and the decomposed/converted substance of the organometallic compound particles being present as an aggregate in the porous article.
171 Electrically Gradated Carbon Foam US11964036 2007-12-25 US20080299378A1 2008-12-04 Jesse M. Blacker; Janusz W. Plucinski
Electrically gradated carbon foam materials that have changing or differing electrical properties through the thickness of the carbon foam material and methods for making these electrically gradated carbon foam materials are described herein. In some embodiments, the electrically gradated carbon foam materials exhibit increasing electrical resistivity through the thickness of the carbon foam material such that the electrical resistivity near a second surface of the carbon foam is at least 2 times greater than the electrical resistivity near a first surface of the carbon foam. These electrically gradated carbon foam materials may be used as radar absorbers, as well as in electromagnetic interference (EMI) shielding schemes.
172 NEGATIVE ELECTRODE ACTIVE MATERIAL FOR AN ELECTRICITY STORAGE DEVICE AND METHOD FOR MANUFACTURING THE SAME US11849023 2007-08-31 US20080220329A1 2008-09-11 Kenji Kojima; Nobuo Ando
To provide a negative electrode active material for an electricity storage device, which has considerably enhanced low-temperature characteristic, increased energy density, and increased output power. A negative electrode active material is made of a carbon composite containing carbon particles as a core and a fibrous carbon having a graphene structure, which is formed on the surfaces and/or the inside of the carbon particles, wherein the carbon composite has a volume of all mesopores within 0.005 to 1.0 cm3/g, and a volume of the mesopores each with a pore diameter ranging from 100 to 400 Å of not less than 25% of the volume of all mesopores.
173 Carbon Porous Body, Method of Manufacturing Carbon Porous Body, Adsorbent and Biomolecular Element US11883179 2006-01-25 US20080213557A1 2008-09-04 Ajayan Vinu; Katsuhiko Ariga; Masahiko Miyahara; Toshiyuki Mori
There are provided a carbon porous body having a larger pore capacity and a larger specific surface area that can advantageously diffuse the substance it adsorbs into the inside and a method of manufacturing such a carbon porous body. The method of manufacturing a carbon porous body is characterized by comprising a step of mixing a cage-shaped silica porous body and a carbon source, a step of heating the obtained mixture and a step of removing the cage-shaped silica porous body from the reaction product. The cage-shaped silica porous body contains a silica skeleton, a plurality of pores formed by the silica skeleton and a plurality of channels also formed by the silica skeleton to mutually link the plurality of pores. The plurality of pores are arranged three-dimensionally, regularly and symmetrically, the diameter d1 of the plurality of pores and the diameter d2 of the plurality of channels satisfy the relationship of d1>d2. The cage-shaped silica porous body and the carbon source are mixed so as to make the mol ratio (C/Si) of the silicon (Si) in the cage-shaped silica porous body and the carbon (C) in the carbon source satisfy the relationship of 0.8
174 Open-End Spinning Device with an Aerostatic Axial Bearing for a Spinning Rotor, an Aerostatic Axial Bearing and a Process for Manufacturing an Aerostatic Axial Bearing US11945496 2007-11-27 US20080124204A1 2008-05-29 Edmund Schuller; Manfred Knabel
An open-end spinning device (1) with a spinning rotor (2) whose shaft end (11) is supported by an aerostatic axial bearing (10) with an air gap (18) located between a bearing plate (17) of the axial bearing (10) and the shaft end (11). The aerostatic axial bearing (10) comprises a bearing plate (17) and a throttle device (19) made from a porous graphite material placed before the bearing plate (17). The throttle device (19) is an stamped pressed, tablet-shaped molding with largely homogenous porosity. In a process for manufacturing an aerostatic axial bearing (10) for a spinning rotor (2) of an open-end spinning device (1), a throttle device (19) made from a porous graphite material is placed before the axial bearing (10). The throttle device (19) is stamped pressed in a press tool as a tablet-shaped molding.
175 Method for preparing nanoporous carbons with enhanced mechanical strength and the nanoporous carbons prepared by the method US10325884 2002-12-23 US07326396B2 2008-02-05 Jong Sung Yu; Jin Gyu Lee; Seok Chang
The present invention relates to a method for preparing nanoporous carbons with enhanced mechanical strength and the nanoporous carbons prepared by the method, and more specifically, to a method for preparing a nanoporous carbon, comprising the steps of (i) synthesizing a mesoporous silica template not being subjected to any calcination process; (ii) incorporating a mixture of a monomer for addition polymerization and initiator, or a mixture of a monomer for condensation polymerization and acid catalyst into the as-synthesized mesoporous silica template, and reacting the mixture to obtain a polymer-silica composite; and (iii) carbonizing the polymer-silica composite at a high temperature to obtain a carbon-silica composite, from which the silica template is then removed using a solvent.According to the preparation method of the present invention, the nanoporous carbons having uniform size of mesopores, high surface area and high mechanical stability can be prepared at low preparation cost through a simplified preparation process. Therefore, the nanoporous carbons of the present invention can be used as catalysts, catalyst supports, separating agents, hydrogen reserving materials, adsorbents, membranes and membrane fillers in various application fields.
176 BIPHASIC NANOPOROUS VITREOUS CARBON MATERIAL AND METHOD OF MAKING THE SAME US11627940 2007-01-26 US20070275863A1 2007-11-29 Christopher Whitmarsh
A biphasic nanoporous vitreous carbon material with a cementitious morphology characterized by presence of non-round porosity, having superior hardness and tribological properties, as useful for high wear-force applications. The biphasic nanoporous vitreous carbon material is produced by firing, under inert atmosphere, of particulate vitrified carbon in a composition containing (i) a precursor resin that is curable and pyrolyzable to form vitreous carbon and, optionally, (ii) addition of one or more of the following: solid lubricant, such as graphite, boron nitride, or molybdenum disulfide; a heat-resistant fiber reinforcement, such as copper, bronze, iron alloy, graphite, alumina, silica, or silicon carbide; or one or more substances to improve electrical conductivity, such as dendritic copper powder, copper “felt” or graphite flake, to produce a superior vitreous carbon that is useful alone or as a continuous phase in reinforced composites, in relation to conventional glassy carbon materials.
177 Porous mullite bodies and methods of forming them US11799414 2007-05-01 US20070203315A1 2007-08-30 Chandan Saha; Sharon Allen; Chan Han; Robert Nilsson; Arthur Prunier; Aleksander Pyzik; Sten Wallin; Robin Ziebarth; Timothy Gallagher
A porous mullite composition is made by forming a mixture of one or more precursor compounds having the elements present in mullite (e.g., clay, alumina, silica) and a property enhancing compound. The property enhancing compound is a compound having an element selected from the group consisting of Mg, Ca, Fe, Na, K, Ce, Pr, Nd, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb, Lu, B, Y, Sc, La and combination thereof. The mixture is shaped and to form a porous green shape which is heated under an atmosphere having a fluorine containing gas to a temperature sufficient to form a mullite composition comprised substantially of acicular mullite grains that are essentially chemically bound.
178 HIGH STRENGTH POLYCRYSTALLINE CERAMIC SPHERES US11612194 2006-12-18 US20070154268A1 2007-07-05 Andrew Barron; Kimberly Defriend
A method for making hollow spheres of alumina or aluminate comprises: coating polymeric beads with an aqueous solution of an alumoxane, drying the beads so as to form an alumoxane coating on the beads; heating the beads to a first temperature that is sufficient to convert the alumoxane coating to an amorphous alumina or aluminate coating and is not sufficient to decompose the polymeric beads; dissolving the polymeric bead in a solvent; removing the dissolved polymer from the amorphous alumina or aluminate coating; and heating the amorphous alumina or aluminate coating to a second temperature that is sufficient to form a hollow ceramic sphere of desired porosity and strength. The hollow spheres can be used as proppants or can be incorporated in porous membranes.
179 Micelle-containing organic polymer, organic polymer porous material and porous carbon material US10516533 2003-06-03 US20070149627A1 2007-06-28 Shiyou Guan; Fumikazu Araki
The invention provides a micelle-containing organic polymer which comprises at least one peak in its X-ray diffraction pattern, at least one pair of the diffraction angle (2θ) and the lattice spacing (d) of said peak satisfying the relation (1) given below: 2θ=2 sin−1(λ/2d)   (1) (in the formula, λ represents the wavelength (nm) of the characteristic X-ray Kα1) and d being at least one value within the range of not less than 0.8 nm to not more than 150 nm. The invention also provides an organic polymer porous material or a porous carbon material which comprises the total volume of pores having diameters within the range of ±40% of the pore diameter Dmax showing a maximum peak in a pore diameter distribution curve is not smaller than 50% by volume based on the total pores volume.
180 Aerogel and metallic compositions US11585578 2006-10-24 US20070142222A1 2007-06-21 Can Erkey; Hiroaki Hara
Metallic aerogel compositions comprising an aerogel, e.g., RF or carbon aerogel, having metallic particles dispersed on its surface are disclosed. The aerogel compositions can have a uniform distribution of small metallic particles, e.g., 1 nanometer average particle diameter. Also disclosed are processes for making the aerogel compositions comprising contacting an aerogel with a supercritical fluid containing a metallic compound. The aerogel compositions are useful, for example in the manufacture of fuel cell electrodes.
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