161 |
High compressive strength silica mortar and manufacturing method thereof |
US12055508 |
2008-03-26 |
US07682448B2 |
2010-03-23 |
Young Do Kim; Se Gu Son; Seung Yeob Hong; Soo Bok Jeong |
A high compressive strength silica mortar to be used for the installation of constructs such as building inside and outside walls, the road pavement, a slope and planting trees in the roof and manufacturing method thereof are provided. The high compressive strength silica mortar is formed of 30 to 60 wt % of silica, 40 to 70 wt % of blast furnace slag, and the 15 to 35 weight parts of polycondensation regulator for 100 weight parts of dry mortar powder of these silica and blast furnace slag, and is solidified by generating C—S—H, C-A-H, amorphous Geopolymeric Matrix{Al2O3.mSiO2.nM2O.xH2O(M=K,Na,Ca)} and Zeolite in the mortar. In particular, the high compressive strength silica mortar exhibits the compressive strength of 70.0 MPa or more by vibration forming and curing for 12˜48 hours at 25 to 80° C. before removal of form and aging for 28 days, and can save energies because a firing process is not required. Accordingly, the high compressive strength silica mortar has excellent properties compared with conventional cement concretes or polymer cements, and further shows high compressive strength in initial stage, which could not be generated in such products. |
162 |
Dry Mix Cement Composition, Methods and Systems Involving Same |
US12239335 |
2008-09-26 |
US20090071374A1 |
2009-03-19 |
Jan Stephanus Jakob Van Deventer; Dingwu Feng; Peter Duxson |
A dry mix cement composition including an alkaline multi-phase aluminosilicate material, wherein the alkaline multi-phase aluminosilicate material provides a source of alkaline and soluble silicate to the cement composition. |
163 |
Zeolite-containing drilling fluids |
US11544691 |
2006-10-09 |
US20070032388A1 |
2007-02-08 |
Donald Getzlaf; Karen Luke; Russell Fitzgerald |
Methods and compositions for wellbore treating fluids, especially drilling fluids, that comprise zeolite and a carrier fluid. |
164 |
Fluid loss additives for cement slurries |
US11545392 |
2006-10-10 |
US20070028811A1 |
2007-02-08 |
Karen Luke; Russell Fitzgerald; Robert Taylor; Keith Rispler; Glen Fyten |
Methods for cementing in a subterranean zone, which use a cement composition that includes zeolite, cementitious material, proportioned fluid loss control additives and a mixing fluid. Cement compositions containing proportioned fluid loss control additives, and methods of making cement compositions containing proportioned fluid loss control additives. |
165 |
Fluid loss additives for cement slurries |
US10816034 |
2004-04-01 |
US07140440B2 |
2006-11-28 |
Karen Luke; Russell M. Fitzgerald; Robert S. Taylor; Keith A. Rispler; Glen C. Fyten |
Methods for cementing in a subterranean zone, which use a cement composition that includes zeolite, cementitious material, proportioned fluid loss control additives and a mixing fluid. Cement compositions containing proportioned fluid loss control additives, and methods of making cement compositions containing proportioned fluid loss control additives. |
166 |
Zeolite compositions having enhanced compressive strength |
US11338576 |
2006-01-24 |
US20060148657A1 |
2006-07-06 |
Ashok Santra; Karen Luke |
Wellbore treating fluids that include zeolite, an activator, and an organic acid or salt thereof are provided. |
167 |
Zeolite compositions having enhanced compressive strength |
US10822459 |
2004-04-12 |
US20040188092A1 |
2004-09-30 |
Ashok
K.
Santra; Karen
Luke |
Zeolite compositions having enhanced compressive strength and methods therefor are provided. In particular, methods and compositions for wellbore treating fluids, especially settable spotting fluids having enhanced compressive strength are provided. |
168 |
Method for obtaining a geopolymeric binder allowing to stabilize,
solidify and consolidate toxic or waste materials |
US855633 |
1992-05-01 |
US5539140A |
1996-07-23 |
Joseph Davidovits |
The method of the invention provides a geopolymeric binder in powder, used for the ultra rapid treatment of materials, soils or mining tailings, containing toxic wastes. Said geopolymeric binder has a setting time equal to or greater than 30 minutes at a temperature of 20.degree. C. and a hardening rate such as to provide compression strengths (Sc) equal to or greater than 15 MPa, after only 4 hours at 20.degree. C., when tested in accordance with the standards applied to hydraulic binder mortars having a binder/sand ratio equal to 0.38 and a water/binder ratio between 0.22 and 0.27. The preparation method includes the following three reactive constituents:a) an alumino-silicate oxide (Si.sub.2 O.sub.5, Al.sub.2 O.sub.2) in which the Al cation is in (IV-V) coordination as determined by MAS-NMR analytical spectroscopy for .sup.27 Al;b) a disilicate of sodium and/or potassium (Na.sub.2.K.sub.2)(H.sub.3 SiO.sub.4).sub.2 ;c) a silicate of calciumwhere the molar ratios between the three reactive constituents being equal to or between ##EQU1## where Ca.sup.++ designates the calcium ion belonging to a weakly basic silicate of calcium whose atomic ratio Ca/Si is lower than 1. |
169 |
Tectoaluminosilicate cement and a process for its manufacture |
US855014 |
1992-06-09 |
US5372640A |
1994-12-13 |
Wolfgang Schwarz; Andre Lerat |
A tectoaluminosilicate cement which consists of K, Ca and aluminosilicates plus, optionally, Li, Na and Mg, contains: a phyllosilicate dehydroxylated at a temperature between 500.degree. and 900.degree. C., reactive amorphous silica, reactive calcium silicate glass or reactive calcium aluminosilicate glass with a Ca:Si ratio of .gtoreq.1 and alkali silicate with the total formula: a(M.sub.2 O) * x(SiO.sub.2) * y(H.sub.2 O) in which M=Li, Na or K, a=0-4, x=0-5 and y=3-20, the overall Si:Al ratio being .gtoreq.1. The tectoaluminosilicate cement preferably alkali hydroxide. The dehydroxylated phyllosilicate is a metakaolin giving tectosilicate structures. The reactive amorphous silica is a dealuminated phyllosilicate, a fly ash dealuminated with mineral acids, where applicable, a fine-grained crystalline form of SiO.sub.2 contained in calcinated clays, a silicic acid gel, thermally activated by alkali-activated aluminosilicate, obtained by sintering an aluminosilicate with alkali carbonate at a temperture between 800.degree. and 1,200.degree. C., the alkali and aluminosilicate components being mixed in the ratio 1:6 to 1:1, and/or microsilica ("silica fume"). The alkali metal activator may be prepared in situ from the dealuminated phyllosilicate and/or from the silicic acid gel in the presence of the alkali hydroxide. A bonding matrix obtained from the tectoaluminosilicate cement by reacting with water in the ratio 3:1 to 6:1 consists essentially of the formula: (Li, Na).sub.0-7 K.sub.1-6 Mg.sub.1-0 Ca.sub.3-0 [Al.sub.4 Si.sub.6-14 O.sub.21-36 ].(0-15H.sub.2 O). |
170 |
Method for obtaining a geopolymeric binder allowing to stabilize,
solidify and consolidate toxic or waste materials |
US90950 |
1993-07-13 |
US5349118A |
1994-09-20 |
Joseph Davidovits |
The method of the invention provides a geopolymeric binder in powder, used for the ultra rapid treatment of materials, soils or mining tailings, containing toxic wastes. The geopolymeric binder has a setting time equal to or greater than 30 minutes at a temperature of 20.degree. C. and a hardening rate such as to provide compression strengths (Sc) equal to or greater than 15 MPa, after only 4 hours at 20.degree. C., when tested in accordance with the standards applied to hydraulic binder mortars having a binder/sand ratio equal to 0.38 and a water/binder ratio between 0.22 and 0.27. The preparation method includes the following three reactive constituents:a) an alumino-silicate oxide (Si.sub.2 O.sub.5,Al.sub.2 O.sub.2) in which the Al cation is in (IV-V) coordination as determined by MAS-NMR analytical spectroscopy for .sup.27 Al;b) a disilicate of sodium and/or potassium (Na.sub.2,K.sub.2)(H.sub.3 SiO.sub.4).sub.2 ;c) a silicate of calcium where the molar ratios between the three reactive constituents being equal to or between ##EQU1## where Ca.sup.++ designates the calcium ion belonging to a weakly basic silicate of calcium whose atomic ratio Ca/Si is lower than 1. |
171 |
Blast pipe for metallurgical processes having refractory coated surfaces |
US193453 |
1988-04-29 |
US4901983A |
1990-02-20 |
Arne Larsson |
A high-temperature resistant blast pipe is primarily intended for delivering gas, such as oxygen, and, when appropriate, solid material to metallurgical processes, and incorporates a layer of refractory material comprising a refractory mixture of solid particles and an alkali-silicate based binder.The blast pipe is characterized in particular in that the major constituent of the binder is of the type polymerized alkali silicate. |
172 |
Mineral binder and compositions employing the same |
US708689 |
1985-03-06 |
US4642137A |
1987-02-10 |
Richard F. Heitzmann; Mark Fitzgerald; James L. Sawyer |
A binder composition for Portland cement is disclosed, said composition including 100 parts by weight metakaolin and, based upon said metakaolin, from 20 to 70 parts by weight slag; from 85 to 130 parts by weight of at least 1 material selected from the class consisting of fly ash, calcined shale, and calcined clay; from 70 to 215 parts by weight finely divided silica, preferably amorphous silica; and from 55 to 145 parts by weight of a mixture of potassium silicate and potassium hydroxide, wherein at least 55 parts by weight is potassium silicate. The binder composition can be mixed with Portland cement or with a combination of Portland cement and fly ash to provide a composition curable to a material having a high early strength and a high ultimate strength. |
173 |
Synthetic mineral polymer compound of the silicoaluminates family and
preparation process |
US377204 |
1982-04-29 |
US4472199A |
1984-09-18 |
Joseph Davidovits |
A mineral polymer of the silicoaluminate family has a composition expressed in terms of oxides as follows:yK.sub.2 O:Al.sub.2 O.sub.3 :xSiO.sub.2 :w H.sub.2 Owhere, in the fully hydrated form, "w" is a value at the most equal to 4, "x" is a value in the range of about 4.0 to about 4.2, and "y" is a value in the range of about 1.3 to about 1.52. These mineral polymers are solid solutions which comprise one phase of a potassium polysilicate having the formula:(y-1)K.sub.2 O:(x-2)SiO.sub.2 :(w-1)H.sub.2 Oand one phase of a potassium polysialate polymer having the following formula: ##STR1## where "n" is the degree of condensation of the polymer. |
174 |
HYALOCLASTITE, SIDEROMELANE OR TACHYLITE POZZOLAN, CEMENT AND CONCRETE USING SAME AND METHOD OF MAKING AND USING SAME |
US16049399 |
2018-07-30 |
US20180339943A1 |
2018-11-29 |
Romeo Ilarian Ciuperca |
The invention comprises a composition comprising a natural pozzolan selected from hyaloclastite, sideromelane or tachylite, wherein the natural pozzolan has a volume-based mean particle size of less than or equal to 40 μm. The invention also comprises a cementitious material comprising a hydraulic cement and a natural pozzolan selected from hyaloclastite, sideromelane, tachylite or combination or mixtures thereof, wherein the natural pozzolan has a volume-based mean particle size of less than or equal to approximately 40 μm. The invention further comprises a cementitious-based material comprising aggregate, a cementitious material comprising a hydraulic cement and a natural pozzolan selected from hyaloclastite, sideromelane, tachylite or combination or mixtures thereof, wherein the natural pozzolan has a volume-based mean particle size of less than or equal to approximately 40 μm and water sufficient to hydrate the cementitious material. A method of using the composition of the present invention is also disclosed. |
175 |
Hyaloclastite pozzolan, hyaloclastite based cement, hyaloclastite based concrete and method of making and using same |
US15853804 |
2017-12-24 |
US10065886B1 |
2018-09-04 |
Romeo Ilarian Ciuperca |
The invention comprises a composition comprising hyaloclastite having a volume-based mean particle size of less than or equal to 40 μm. The invention also comprises a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 μm. The invention further comprises a cementitious-based material comprising aggregate, a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 μm and water sufficient to hydrate the cementitious material. A method of using the composition of the present invention is also disclosed. |
176 |
ULTRA-HIGH STRENGTH HOT-PRESSED GEOPOLYMERIC COMPOSITION AND PRODUCTION METHOD THEREOF |
US15964734 |
2018-04-27 |
US20180244572A1 |
2018-08-30 |
Navid Ranjbar |
A hot-pressed geopolymeric composition and producing method for making the ultra-high strength geopolymer are disclosed. The hot-pressed geopolymeric composition may include at least one aluminosilicate source and at least one alkali activator and optionally any kind of fillers. The ultra-high strength geopolymer with various densities can be produced by applying low hot-pressing pressure in a short time. |
177 |
Hyaloclastite pozzolan, hyaloclastite based cement, hyaloclastite based concrete and method of making and using same |
US15817458 |
2017-11-20 |
US10047006B1 |
2018-08-14 |
Romeo Ilarian Ciuperca |
The invention comprises a composition comprising hyaloclastite having a volume-based mean particle size of less than or equal to 40 μm. The invention also comprises a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 μm. The invention further comprises a cementitious-based material comprising aggregate, a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 μm and water sufficient to hydrate the cementitious material. A method of using the composition of the present invention is also disclosed. |
178 |
Dimensionally stable geopolymer composition and method |
US13842100 |
2013-03-15 |
US09890082B2 |
2018-02-13 |
Ashish Dubey |
A method for making geopolymer cementitious binder compositions for cementitious products such as concrete, precast construction elements and panels, mortar, patching materials for road repairs and other repair materials, and the like is disclosed. The geopolymer cementitious compositions of some embodiments are made by mixing a synergistic mixture of thermally activated aluminosilicate mineral, calcium sulfoaluminate cement, a calcium sulfate and a chemical activator with water. |
179 |
PARTICULATE COMPOSITIONS FOR THE FORMATION OF GEOPOLYMERS, THEIR USE AND METHODS FOR FORMING GEOPOLYMERS THEREWITH, AND GEOPOLYMERS OBTAINED THEREFROM |
US15553691 |
2016-02-29 |
US20180022646A1 |
2018-01-25 |
Alexandre AUTEF |
The present invention relates to dry particulate composition for forming a geopolymer, comprising an alkali metal hydroxide, an alkali metal silicate, and an aluminosilicate. The invention further relates to methods for forming geopolymers and geopolymers formed according to said methods or using the said dry particulate compositions. |
180 |
Tailored geopolymer composite binders for cement and concrete applications |
US14960770 |
2015-12-07 |
US09834479B2 |
2017-12-05 |
Weiliang Gong; Werner Lutze; Ian Pegg |
A geopolymer composite binder is provided herein, the composite binder including (i) at least one fly ash material having less than or equal to 15 wt % of calcium oxide; (ii) at least one gelation enhancer; and (iii) at least one hardening enhancer having a different composition from a composition of the at least one fly ash material. |