序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
1 电极 CN200880116165.8 2008-11-14 CN101861412B 2013-04-24 M·洛斯沃尔; R·艾德文森-埃尔伯斯; K·海登斯泰德
发明涉及一种电极,其包含:a)包含M(n+1)AXn的电极基材,其中M为元素周期表第IIIB、IVB、VB、VIB或VIII族的金属或其组合,A为元素周期表第IIIA、IVA、VA或VIA族的元素或其组合,X为、氮或其组合,其中n为1、2或3;和b)在所述电极基材上沉积的电催化涂层,其选自如下的至少一种:b.1)包含ByC(1-y)Oz1Sz2的金属化物和/或金属硫化物,其中B为钌、铂、铑、钯、铱和钴中的至少一种,C为至少一种金属,y为0.4-0.9,0≤z1,z2≤2且z1+z2=2;b.2)包含BfCgDhEi的金属氧化物,其中B为钌、铂、铑、钯和钴中的至少一种,C为至少一种阀金属,D为铱,E为Mo和/或W,其中f为0-0.25或0.35-1,g为0-1,h为0-1,i为0-1,其中f+g+h+i=1;b.3)至少一种贵金属;b.4)任意包含-钼、铁-钨、铁-镍、钌-钼、钌-钨或其混合物的合金或混合物;b.5)至少一种纳米晶体材料。该电极用于电解池中以生产金属氯酸盐。
2 电极 CN201210204703.7 2008-11-14 CN102703921A 2012-10-03 M·洛斯沃尔; R·艾德文森-埃尔伯斯; K·海登斯泰德
发明涉及一种电极,其包含:a)包含M(n+1)AXn的电极基材,其中M为元素周期表第IIIB、IVB、VB、VIB或VIII族的金属或其组合,A为元素周期表第IIIA、IVA、VA或VIA族的元素或其组合,X为、氮或其组合,其中n为1、2或3;和b)在所述电极基材上沉积的电催化涂层,其选自如下的至少一种:b.1)包含ByC(1-y)Oz1Sz2的金属化物和/或金属硫化物,其中B为钌、铂、铑、钯、铱和钴中的至少一种,C为至少一种金属,y为0.4-0.9,0≤z1,z2≤2且z1+z2=2;b.2)包含BfCgDhEi的金属氧化物,其中B为钌、铂、铑、钯和钴中的至少一种,C为至少一种阀金属,D为铱,E为Mo和/或W,其中f为0-0.25或0.35-1,g为0-1,h为0-1,i为0-1,其中f+g+h+i=1;b.3)至少一种贵金属;b.4)任意包含-钼、铁-钨、铁-镍、钌-钼、钌-钨或其混合物的合金或混合物;b.5)至少一种纳米晶体材料。该电极用于电解池中以生产金属氯酸盐。
3 连续流电絮凝处理系统 CN201610584343.6 2012-05-03 CN106630034A 2017-05-10 薇薇安·罗宾森
一种连续流电絮凝处理系统。公开了用于从水中去除污染物的设备和方法。所述设备包括:一组电极,其包括第一电极、第二电极、第三电极和第四电极;一个或者多个隔片;至少一个支撑件;电源组件。所述方法包括:将上述一组电极基本上浸入水中;以及施加正电压和负电压。
4 用于净化硫化氢溶液的方法和设备 CN201080045561.3 2010-08-13 CN102695679A 2012-09-26 汉努·索米宁
发明涉及用于净化硫化氢溶液的方法和设备。待净化的水溶液穿过至少两个电解槽元件(2、3、4),这样的电解槽元件中的至少一个电解槽元件采用正电极,并且至少另一个电解槽元件采用正电极。电解槽元件的电流调节为使得装备有铝电极的电解槽元件产生氢化铝和硫酸铝,并且装备有铁电极的电解槽元件产生氢氧化铁。待净化的水溶液和在电解槽元件中获得的反应产物进入提取塔(7),并且电解时释放的氢用来使由反应产物构成的沉淀上升到用于絮状物(15)的提取塔(7)的顶部端部。净化水从提取塔排出,从而能够将硫化氢以硫酸铝的形式从水中提取到絮状物(15)中。
5 用于从藻类获得细胞内产物和细胞物质和碎片的系统、装置和方法及其衍生产品和使用方法 CN201080023861.1 2010-04-20 CN102449155A 2012-05-09 尼古拉斯·D·埃克尔百利; 迈克尔·菲利普·格林; 斯科特·亚历山大·弗拉瑟尔
发明提供了用于从性悬液中的藻类细胞收获至少一种细胞内产物(例如脂质、糖类、蛋白质等)和用于从含有藻类细胞的水性溶液收获破裂藻类细胞和碎片的物质的系统和方法,所述系统和方法利用了包括电路的装置。电路包括外部阳极结构(例如管)和用作阴极的内部结构(例如导电体),所述外部阳极结构为尺寸比所述外部阳极结构小的所述内部结构提供外壳。螺旋式表面、例如在性质上非常类似于枪筒中的“膛线”的由至少一个阳膛线分隔开的多个阴膛线,或者与两个结构(即外部管和内部导体)平行的电绝缘性隔离分隔物,提供了液体密封,并提供了阳极与阴极电路之间的分隔,其为相等的电分布所需,并能防止含藻类细胞的水性溶液的流动路径短路
6 电解处理工业的方法和装置 CN95103540.1 1995-03-25 CN1126178A 1996-07-10 维利·维特
发明涉及一用电解法来处理工业的方法,根据本发明,使废水通过输入直流电的电极,电极用直流电脉冲加以输入,废水流也以脉冲方式进行加速并以一升高的流速把废水强制地导向电极,这样提高了去除毒性物质的效率并且能耗降低,电极板寿命延长。
7 用于从藻类获得细胞内产物和细胞物质和碎片的系统、装置和方法及其衍生产品和使用方法 CN201080023861.1 2010-04-20 CN102449155B 2014-12-10 尼古拉斯·D·埃克尔百利; 迈克尔·菲利普·格林; 斯科特·亚历山大·弗拉瑟尔
发明提供了用于从性悬液中的藻类细胞收获至少一种细胞内产物(例如脂质、糖类、蛋白质等)和用于从含有藻类细胞的水性溶液收获破裂藻类细胞和碎片的物质的系统和方法,所述系统和方法利用了包括电路的装置。电路包括外部阳极结构(例如管)和用作阴极的内部结构(例如导电体),所述外部阳极结构为尺寸比所述外部阳极结构小的所述内部结构提供外壳。螺旋式表面、例如在性质上非常类似于枪筒中的“膛线”的由至少一个阳膛线分隔开的多个阴膛线,或者与两个结构(即外部管和内部导体)平行的电绝缘性隔离分隔物,提供了液体密封,并提供了阳极与阴极电路之间的分隔,其为相等的电分布所需,并能防止含藻类细胞的水性溶液的流动路径短路
8 用于净化硫化氢溶液的方法和设备 CN201080045561.3 2010-08-13 CN102695679B 2013-12-25 汉努·索米宁
发明涉及用于净化硫化氢溶液的方法和设备。待净化的水溶液穿过至少两个电解槽元件(2、3、4),这样的电解槽元件中的至少一个电解槽元件采用正电极,并且至少另一个电解槽元件采用正电极。电解槽元件的电流调节为使得装备有铝电极的电解槽元件产生氢化铝和硫酸铝,并且装备有铁电极的电解槽元件产生氢氧化铁。待净化的水溶液和在电解槽元件中获得的反应产物进入提取塔(7),并且电解时释放的氢用来使由反应产物构成的沉淀上升到用于絮状物(15)的提取塔(7)的顶部端部。净化水从提取塔排出,从而能够将硫化氢以硫酸铝的形式从水中提取到絮状物(15)中。
9 电极 CN200880116165.8 2008-11-14 CN101861412A 2010-10-13 M·洛斯沃尔; R·艾德文森-埃尔伯斯; K·海登斯泰德
发明涉及一种电极,其包含:a)包含M(n+1)AXn的电极基材,其中M为元素周期表第IIIB、IVB、VB、VIB或VIII族的金属或其组合,A为元素周期表第IIIA、IVA、VA或VIA族的元素或其组合,X为、氮或其组合,其中n为1、2或3;和b)在所述电极基材上沉积的电催化涂层,其选自如下的至少一种:b.1)包含ByC(1-y)Oz1Sz2的金属化物和/或金属硫化物,其中B为钌、铂、铑、钯、铱和钴中的至少一种,C为至少一种金属,y为0.4-0.9,0≤z1,z2≤2且z1+z2=2;b.2)包含BfCgDhEi的金属氧化物,其中B为钌、铂、铑、钯和钴中的至少一种,C为至少一种阀金属,D为铱,E为Mo和/或W,其中f为0-0.25或0.35-1,g为0-1,h为0-1,i为0-1,其中f+g+h+i=1;b.3)至少一种贵金属;b.4)任意包含-钼、铁-钨、铁-镍、钌-钼、钌-钨或其混合物的合金或混合物;b.5)至少一种纳米晶体材料。该电极用于电解池中以生产金属氯酸盐。
10 アルカリ金属塩素酸塩の製造方法 JP2010533587 2008-11-14 JP5680417B2 2015-03-04 ロスバル,マグナス; エドヴィンソン−アルバース,ロルフ; ヘデンステッド,クリストファー
11 Systems for obtaining intracellular product from algal and cell clumps and debris, apparatus and method, and derivative and using the JP2012507316 2010-04-20 JP5284536B2 2013-09-11 エックルベリー,ニコラス,ディー.; グリーン,マイケル,フィリップ; フレイザー,スコット,アレキサンダー
Systems and methods for harvesting at least one intracellular product (e.g., lipids, carbohydrates, proteins, etc.) from algae cells in aqueous suspension and for harvesting a mass of ruptured algae cells and debris from an aqueous solution containing algae cells make use of an apparatus that includes an electrical circuit. The electrical circuit includes an outer anode structure (e.g., tube) which provides containment for an inner structure (e.g., electrical conductor) having lesser dimensions than the outer anode structure, the inner structure serving as a cathode. A spiraling surface, such as a plurality of grooves separated by at least one land, much as in the nature of "rifling" in the barrel of a gun, or alternatively, an electrically insulative, isolator spacer in parallel to both structures (e.g., the outer tube and internal conductor) provides a liquid seal and provides spacing between the anode and cathode circuits which is required for equal electrical distribution and to prevent short circuiting of the flow path for the aqueous solution containing algae cells.
12 Measurement and adjustment method of electrochemical potential in the slurry JP24178085 1985-10-30 JPH0762664B2 1995-07-05 オラビ ヘイマラ セツポ; ビルホ ランタプスカ セツポ
The invention relates to a method for measuring and adjusting electrochemical potential and/or component content in the process of treating valuable materials, when the valuable materials should be recovered either together or separately by aid of the values of the recovery range defined on the basis of electrochemical potential and component control. According to the invention, the measuring of electrochemical potential and/or component content is carried out by means of at least one electrode (4, 5), advantageously by means of a mineral electrode, so that in order to regulate the physicochemical state of the electrode and/or to remove the coating layer formed on the electrode surface and in order to protect the electrode, onto the electrode there is switched a supply voltage differing from the electrochemical balance potential of the electrode, which supply voltage is switched off before starting the measuring operation.
13 CONTINUOUS FLOW ELECTROFLOCCULATION WATER TREATMENT SYSTEM US14814530 2015-07-31 US20160016828A1 2016-01-21 Vivian Robinson
A method is disclosed in which water is pumped continuously into one end of a container, the pollutants are captured and floated to the surface, the treated and cleaned water flows out the other end and the floated pollutants are removed. In one embodiment, the system consists of at least one container that has a set of electrically active plates and a mechanism for capturing and removing the pollutants that are floated to the surface by the electrically active plates. Multiple containers can be connected in series and used for similar or separate purposes to remove the pollutants. In another embodiment, the single container is partitioned into a multiple of chambers. Each chamber can be used for a similar or separate purpose, which purpose depends upon the application. In both embodiments, the primary reaction consists of electroflocculation, in which a low voltage is applied across a set of metal plates. This liberates metal ions and gas bubbles. The metal ions capture the pollutants and the gas bubbles float them to the surface. The whole process is done in a manner in which the floated pollutants form a stable layer on the surface of the flowing water. Different sets of metal plates can be used in separate chambers to remove different pollutants. The voltage to the plates is controlled in such a manner as to provide a known charge dose to the water as it passes through the apparatus at a Known rate. This is controlled by monitoring and controlling both the rate at which the water flows and the rate at which the electric charge is imparted through the water. In operation water is pumped into the first chamber where it is treated with the first set of plates. It can then flow into a second chamber, with a barrier mechanism that limits the surface floe from flowing with it. This process can be repeated in other chambers until the water is adequately treated with different sets of plates. The water can then flow into additional chambers in which much of the residual floe and bubbles floats to the surface. Each chamber has a wall over which the floe can flow into a drain mechanism, and a mechanism for getting the floe to flow over the wall. In this manner these continuous flow electroflocculation water treatment systems operate like a membrane free filter or a chemical free dissolved air flotation system.
14 Flock separating apparatus US280140 1999-03-26 US6086732A 2000-07-11 Hannu L. Suominen
A flock separating apparatus, has an electrolytic cell (2) fitted with iron electrodes and a separating tank (3), wherein the flock is carried upwards by a hydrogen gas produced in electrolysis. The separating tank (3) has a substantially vertical pipe having a length which is at least 10 times, preferably at least 15-20 times more than its diameter.
15 Flock separating apparatus US836849 1997-05-19 US5888359A 1999-03-30 Hannu L. Suominen
A flock separating apparatus, has an electrolytic cell (2) fitted with iron electrode and a separating tank (3), wherein the flock is carried upwards by a hydrogen gas produced in electrolysis. The separating tank (3) has a substantially vertical pipe having a length which is at least 10 times, preferably at least 15-20 times more than its diameter.
16 Method and apparatus for removing impurities from liquids US817690 1986-01-10 US4623436A 1986-11-18 Yoshio Umehara
In a method and apparatus for removing impurities from a liquid, the liquid containing impurities is supplied to an electrolytic bath at a pressure higher than atmospheric pressure. Electrolysis is performed by applying a voltage to electrodes consisting of a metal which easily dissolves upon electrolysis. The liquid is then exposed to atmospheric pressure, and is treated in a flotation separation tank. Fine bubbles formed during the treatment of the liquid in the flotation separation tank attach to the impurities flocculated in the liquid by electrolysis. The flotation separation of the flocculated impurities is performed very efficiently, and high-purity water can be recovered.The apparatus comprises an electrolytic bath consisting of a pressure vessel, in which electrodes of a metal which easily dissolves upon electrolysis are housed, and a constant current source for applying a voltage to said electrodes so as to obtain a predetermined current density in a liquid contained in said electrolytic bath, wherein impurities in the liquid are caused to flocculate by a hydroxide of the metal.
17 Apparatus for electrochemical purification of contaminated liquids US366444 1982-04-07 US4414091A 1983-11-08 Alexandr A. Axenko; Miron M. Nazarian; Vladimir A. Kolyada; Arkady R. Mataev; Ljudmila F. Shamsha
An apparatus comprises a settling chamber with outlet pipes to discharge purified liquid and sludge and an electrocoagulation chamber installed in the settling chamber and communicating with the latter. The electrocoagulation chamber has an inlet pipe to feed contaminated liquid, an inlet pipe to feed electrolyte, and a system of soluble electrodes disposed below the inlet pipe to feed contaminated liquid. Apertures are provided in the walls of the electrocoagulation chamber along the perimeter thereof below the liquid level in the settling chamber, the apertures receiving the nozzles of injectors which transfer a part of foam from the electrocoagulation chamber to the settling chamber.
18 Flotation process for purification of waste water US180977 1980-08-25 US4311595A 1982-01-19 Elias Julke
In a flotation method for purification of industrial or municipal waste water, in which the waste water comes in contact with electrodes having an electrical potential capable of electrolytically decomposing a portion of the waste water, thereby creating an ascending stream of gas bubbles, the waste water is mixed before or during the electrolytic decomposition with wettable particles of polymer material which are practically insoluble in water and have an absolute density of 1.3 g/cm.sup.3 at the most. Polymeric materials, especially polyalkane fibrids, are suitable for use as particles. This process makes it possible to purify oil-containing waste water by electroflotation without forming an oil film on the electrodes.
19 Electrolytic flotation apparatus US790807 1977-04-25 US4101409A 1978-07-18 Eric Paul Austin
A method for treating a liquid wherein the liquid to be treated is caused to flow through a tank equipped with at least one electrode assembly in the base thereof for the generation of gas bubbles by electrolytic action, whereby suspended materials, usually but not necessarily solids, in the liquid are carried to the surface of the tank by said bubbles to form a layer of thickened material, characterised by the step of dissolving air under pressure into the liquid before it is caused to flow through said tank, whereby the amount of gas available for flotation purposes exceeds that available from the electrolytic action alone.
20 Water treatment apparatus US618047 1975-09-30 US4075076A 1978-02-21 Kurt Xylander
In a process for purifying an aqueous liquid by flotation of suspended solids with gas bubbles produced by electrolysis between at least one pair of electrodes, at least one of said electrodes, preferably in the form of an endless belt or band, is transported in or through said liquid while said electrolysis and flotation are taking place. Bridging and fouling of the electrodes are thereby minimised.
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