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序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
61	Enzymatic method for textile dyeing	US10375495	2003-02-27	US06805718B2	2004-10-19	Martin Barfoed; Ole Kirk; Sonja Salmon
The present invention relates to methods of dyeing a material which involve contacting the material with a dyeing system which comprises: (a) a mixture of (i) an aromatic diamine and (ii) one or more of a naphthol and an aminonaphthalene and (b) an oxidation system comprising (i) a hydrogen peroxide source and an enzyme exhibiting peroxidase activity or (ii) an enzyme exibiting oxidase activity on one or more of the compounds of mixture (a). The material may be a fabric, yarn, fiber, garment or film made of fur, hide, leather, silk or wool, or made of cationic polysaccharide, cotton, diacetate, flax, linen, lyocel, polyacrylic, synthetic polyamide, polyester, ramie, rayon, triacetate, or viscose.
62	Method for preparing the reactive tinting compound and the tinted contact lens	US10620783	2003-07-15	US20040012757A1	2004-01-22	Shinn-Gwo Hong
A method for preparing the tinted contact lens with the covalently bonded novel reactive tinting compound is disclosed. The reactive tinting compound with mono vinyl functionality is prepared by reacting the reactive dye with a hydrophilic monomer containing both pendent hydroxyl and vinyl groups under an alkaline condition. The water soluble reactive dyes containing either difluoro-chloropyrimidine or null-sulphatoethylsulphone reactive groups are used for synthesis of the reactive tinting dye. The lens forming materials is photo-polymerized in the presence of the reactive tinting compound to prepare a tinted contact lens. The reactive tinting compound is copolymerized with the lens forming monomers in a single photo-polymerization step that required no subsequently alkaline soaking or developing step as used in the prior art. In addition, the covalently bonded dye is stable and durable in the lens and does not fade or leach out after multiple high-pressure thermal sterilization.
63	Dyeing process and dyes	US952170	1998-01-30	US5976197A	1999-11-02	Michael Gordon Hutchings; Colin Michael Brennan; Neil Anthony Tallant; Andrew Paul Shawcross; Prakash Patel; Warren James Ebenezer
A process for defining a substrate is provided. The process comprises applying to the substrate a water soluble dye having at least two electrophilic groups and a nucleophilic agent having a molecular weight below 600 and at least one group selected from aliphatic primary amino groups and secondary amino groups.
64	Enzymatic method for overdyeing warp dyed denim textiles	US901548	1997-07-28	US5925148A	1999-07-20	Martin Barfoed; Ole Kirk
The present invention relates to methods of overdyeing a warp dyed denim textile, comprising treating the textile in an aqueous dye liquor with a dye system which comprises an effective amount of (a) one or more mono-, di- or polycyclic aromatic or heteroaromatic compounds and (b) (i) a hydrogen peroxide source and at least one enzyme exhibiting peroxidase activity and/or (ii) at least one enzyme exhibiting oxidase activity on the one or more aromatic or heteroaromatic compounds.
65	Tinting hydrogel materials with vat dyes	US446559	1995-05-19	US5534038A	1996-07-09	John M. Evans
Disclosed are processes for tinting hydrogel materials, such as contact lenses, by dissolving a leuco sulfate ester of a vat dye in an compatible monomer solution, adding an oxidizing initiator to the monomer solution, and oxidizing and polymerizing the monomer solution and dye in the same solution. In one aspect, the oxidation and polymerization are conducted simultaneously whereas in another embodiment, the oxidation of the soluble leuco sulfate ester of a vat dye to the insoluble vat dye and polymerization are conducted sequentially in the same reaction medium.
66	Stabilized composition of p-quinonedihaloimine compound	US3499721D	1966-08-17	US3499721A	1970-03-10	SUGIYAMA HIROSHI; KURIYAMA RYOZO; MATUMOTO OTOHEI; IMADA KUNIHIKO; MATSUSHITA YOSHIO

67	Stabilized coloring compositions and methods of making and using same	US45688754	1954-09-17	US2755202A	1956-07-17	JEAN BAION WALTER; OTTO STALLMANN

68	메탈릭사와 폴리에스테르사를 원료로 이용한 편직물의 염색 방법 및 이러한 방법으로 제조된 편직물	KR1020110118196	2011-11-14	KR101145879B1	2012-05-15	우정하; 김선진; 조성현
본 발명은 메탈릭사와 폴리에스테르사를 원료로 이용한 편직물의 염색 방법 및 이러한 방법으로 제조된 편직물에 관한 것으로, 자세하게는 메탈릭사 및 400~600kg/mm ² 의 탄성율과 30 ~ 40%의 신장도를 갖는 상압 염색 폴리에스테르사를 원료로 사용하여 편직물을 직조하는 직조단계; 염료를 물에 분산시킨 염료용액을 투입하여 염욕을 제조하는 염욕제조단계; 상기 직조된 편직물을 상기 제조된 염욕에 투입하여, 염욕의 온도를 35 ~ 45℃에서부터 1.2 ~ 1.5℃/분의 속도로 30 ~ 50분간 높이고, 상기 승온된 염욕을 90 ~ 100℃에서 15 ~ 25분간 유지하여 상기 편직물을 염착하는 단계; 및 상기 염착된 편직물을 수세하는 단계;를 포함하는 염색된 편직물의 제조방법에 대한 것이다. 이렇게 제조된 염색된 편직물은 20% ~ 30%의 광반사 감소율을 갖는다.
69	실험실용 저욕비 고온 염색기	KR1020070076194	2007-07-30	KR100876103B1	2008-12-29	정연국
A low bath ratio high temperature dyeing machine for a laboratory is provided to get high efficiency of dyeing by operating for fabric and dyes up and down in the port which is installed to be inclined to top and bottom. A low bath ratio high temperature dyeing machine for the laboratory comprises: a container(3); the dyes container fixture(2) and the dyeing feeding machinism(5) by the pump(4) at one side of bottom of the main body(1); the left-right operation machinism(6) moving the driving part left and right by a motor, a gear box or link at one side of the upper main body; the driving part(8) which is installed the slewing gear operating by the motor and the gear box; the operating part which is rotating by the axis of rotation and contains the turntable(10,10') with the port which is installed to be inclined to top and bottom at the other side of the upper main body; the up-down operating device(13) working by the cylinder(12) at the middle of the bottom of the operation part(11); the connector which is installed at the side area of the cap(16) to shut tightly the nozzle(14) and the port(15) and the fastener in which the connector for the preparation supply and sensor for measuring temperature is inserted into one among the ports installed at either side the turntable.
70	메탈릭사와 폴리에스테르사를 원료로 이용한 편직물의 염색 방법 및 이러한 방법으로 제조된 편직물	KR1020110118196	2011-11-14	KR1020110134355A	2011-12-14	우정하; 김선진; 조성현
PURPOSE: A method for dyeing a knitted material using metallic yarn and polyester yarn is provided to prevent peeling of metallic yarn and staining into the metallic layer. CONSTITUTION: A method foe dyeing a knitted material using metallic yarn and polyester yarn comprises: a step of weaving the knitted material using metallic yarn and polyester yarn of high pressure dyeing; a step of adding a dye solution and performing dyeing bath of the knitted material at 35-45°C for 30-50 minutes and at 90-100°C for 15-25 minutes; and a step of washing the knitted material. The dyeing solution contains one or more compounds selected from acetic acid, dispersing agent, softening agent, and anti-fouling agent.
71	목재 및 그 밖의 기질용 무기물 착색제	KR1019997010857	1998-05-01	KR1020010012891A	2001-02-26	아거스테펜,비.
발명에따라서, 금속염및 산소원은기질과접촉하여반응하고기질의표면내에고정된무기물화합물을제조하도록연속적으로효과적인양으로적절한기질을침투또는함침하기위해적용된다. 상호양립가능한금속염, 산소원및 기질의발명의결합은제자리에서반응을일으키고, 지속적인원하는효과를일으키도록기질을개질한다. 발명에따라서제조된무기물화합물은기질에연결되고, 안정하고장기간또는영구적이며, 기질에고정되거나불용해성이다. 무기물화합물은기질의기질내 및위에서화합하거나포함되어지며, 그래서기질의섬유질또는매트릭스에깊이배어들거나기질내에파묻힌다고할 수있다. 원하는효과는바람직하게는착색이다. 금속염의넓은변형은원하는효과에의존하여사용될수 있다. 산소원은바람직하게는과산화물이고, 기질은바람직하게는목재, 면, 또는종이등의셀룰로오즈제품; 가죽; 또는석조이다. 발명은기질을처리하는방법, 처리키트및 처리된제품을예상한다. 목재제품과함께, 발명은연질목재를위해유용한저독성의수계착색제를제공한다.
72	METHOD FOR DYEING TEXTILES USING METALLIC YARN AND POLYESTER YARN AND TEXTILE MANUFACTURED THEREBY	EP12849539	2012-05-30	EP2781647A4	2015-08-26	WOO JUNG HA; KIM SUN JIN; CHO SUNG HYUN

73	Methods for forming dyed microspheres and populations of dyed microspheres	EP12184453.4	2005-10-11	EP2559738B1	2014-07-09	Hoffacker, Kurt; Lugade, Anada, G.; Terpetschnig, Ewald

74	SURFACE FUNCTIONALISATION	EP99952694.0	1999-11-03	EP1124791B1	2005-01-12	MOLONEY, Mark Gerard, Dept. of Chemistry; EBENEZER, Warren, Dept. of Chemistry; AWENAT, Karim, Dept. of Chemistry
A process for the surface functionalisation of a polymeric substrate, which process comprises: a) contacting the substrate with a diarylcarbene precursor, b) generating a carbene reactive intermediate from the diarylcarbene precursor so that it reacts with the substrate to functionalise the surface, and c) further functionalising the activated substrate obtained in step (b).
75	Dyeing process	EP00104363.7	1996-04-09	EP1013818A3	2001-01-10	Hutchings, Michael Gordon; Brennan, Colin Michael; Tallant, Neil Anthony; Shawcross, Andrew Paul; Patel, Prakash; Ebenezer, Warren James
A process for the colouration of a substrate comprises (1) applying thereto in an aqueous medium each of(i) a water soluble dye having at least two electrophilic groups each capable of reaction with a respective amino group and(ii) a nucleophilic agent having a molecular weight below 600 and at least two aliphatic amino groups so as to be thereby capable of reaction with the said water-soluble dye at a pH and temperature at which the electrophilic groups and amino groups are capable of reaction with one another but the dye does not react to a significant extent with the substrate before it reacts with the nucleophilic agent, (2) allowing the said dye and nucleophilic agent to react with one another and thereafter (3) increasing at least one of the pH and temperature to exhaust the dye onto the substrate, the said nucleophilic agent being selected from the following species: (a) a nucleophilic agent having two aliphatic primary amino groups and no secondary aliphatic amino groups; (b) a nucleophilic agent having three aliphatic primary amino groups and no secondary aliphatic amino groups; (C) a nucleophilic agent having one aliphatic primary amino group and one secondary aliphatic amino group; (d) a nucleophilic agent having two aliphatic primary amino groups and one aliphatic secondary amino group; and (e) a nucleophilic agent having at least two aliphatic secondary amino groups selected from HO(CH2CH2NH)2CH2CH2OH, HO2CCH2NHCH2CH2NHCH2CO2H, PhCH2NHCH2CH2NHCH2Ph, (-NHCH2CH2-)3,4 or 5, piperazine, 2-methylpiperazine, 2,5- and 2,6-dimethylpiperazine, H2N(CH2CH2NH)nH wherein n is 3,4 or 5, CH3NHCH2CH2NHCH3, (-NHCH2CH2CH2-)4, 1,4,7,10,13-(6-hexaazacyclooctadecane), (CH3O)3Si(CH2CH2NH)2CH2CH2CO2CH3 and (CH3O)3Si(CH2CH2NH)2CH2CH2NH2.
76	MINERAL STAINS FOR WOOD AND OTHER SUBSTRATES	EP98920036.5	1998-05-01	EP1012374A1	2000-06-28	Auger, Stephen, B.
According to the invention, a metal salt and an oxygen source are applied to penetrate or impregnate a suitable substrate sequentially in effective amounts so as to react in contact with the substrate and produce a mineral compound fixed within the surface of the substrate. The inventive combination of a mutually compatible metal salt, oxygen source, and substrate brings about an in situ reaction, and modifies the substrate to bring about a lasting desired effect. The mineral compound that is produced according to the invention is linked to the substrate, is stable and long-lasting or permanent, and is immobilized or insolubilized in the substrate. The mineral compound is bound or contained within and on the substrate of the substrate, so it may be said to be ingrained in the fibers or matrix of the substrate, or embedded within the substrate. The desired effect is preferably a color. A wide variety of metal salts may be used depending on the desired effect. The oxygen source is preferably a peroxide, and the substrate is preferably a cellulose product such as wood, cotton, or paper; leather; or masonry. The invention contemplates methods of treating substrates, treatment kits, and treated products. With wood products, the invention provides a water-based stain of low toxicity useful for soft woods.
77	ENZYMATIC METHOD FOR OVERDYEING CELLULOSIC TEXTILES	EP97936294.0	1997-07-24	EP0938605A1	1999-09-01	BARFOED, Martin; KIRK, Ole
The present invention relates to methods of overdyeing a dyed fabric or article, comprising treating the fabric or article in an aqueous dye liquor with a dye system which comprises an effective amount of (a) one or more mono-, di- or polycyclic aromatic or heteroaromatic compounds and (b) (i) a hydrogen peroxide source and at least one enzyme exhibiting peroxidase activity and/or (ii) at least one enzyme exhibiting oxidase activity on the one or more aromatic or heteroaromatic compounds. The present invention also relates to aqueous dye liquors for imparting an overdyed appearance on the cellulosic fabric or article, comprising (a) one or more mono-, di- or polycyclic aromatic or heteroaromatic compounds and (b) (i) a hydrogen peroxide source and at least one enzyme exhibiting peroxidase activity and/or (ii) at least one enzyme exhibiting oxidase activity on the one or more aromatic or heteroaromatic compounds, in amounts effective to impart an overdyed appearance to the fabric or article. The present invention also relates to fabric or article treatment compositions, comprising (a) one or more mono-, di- or polycyclic aromatic or heteroaromatic compounds and (b) (i) a hydrogen peroxide source and at least one enzyme exhibiting peroxidase activity and/or (ii) at least one enzyme exhibiting oxidase activity on the one or more aromatic or heteroaromatic compounds, in amounts effective to impart an overdyed appearance to the fabric or article.
78	ENZYMATIC METHOD FOR TEXTILE DYEING	EP96945649.0	1996-12-20	EP0873444A1	1998-10-28	KIRK, Ole; BARFOED, Martin
The present invention relates to methods of dyeing a material, comprising (a) soaking the material in an aqueous solution which comprises one or more mono-, di-, or polycyclic aromatic or heteroaromatic compounds; and (b) treating the soaked material in an aqueous solution with (i) a hydrogen peroxide source and an enzyme exhibiting peroxidase activity or (ii) an enzyme exhibiting oxidase activity on the one or more aromatic or heteroaromatic compounds; wherein the material is a fabric, yarn, fiber, garment or film made of fur, hide, leather, silk or wool.
79	TINTING HYDROGEL MATERIALS WITH VAT DYES	EP95921509	1995-05-26	EP0764190A4	1998-10-21	EVANS JOHN M
Disclosed are processes for tinting hydrogel materials, such as contact lenses, by dissolving a leuco sulfate ester of a vat dye in a compatible monomer solution, adding an oxidizing initiator to the monomer solution, and oxidizing and polymerizing the monomer solution and dye in the same solution. In one aspect, the oxidation and polymerization are conducted simultaneously whereas in another embodiment, the oxidation of the soluble leuco sulfate ester of a vat dye to the insoluble vat dye and polymerization are conducted sequentially in the same reaction medium.
80	METHOD FOR ACTIVATING COLORANT ASSOCIATED WITH AN ARTICLE	EP12733299.7	2012-06-20	EP2723579A1	2014-04-30	NELLENBACH, Eva Grace; AVERY JR., Robert Avery
Methods for activating colorant in selected regions of an article in which the colorant is incorporated are described. The colorant activation can create various desired visual aspects. Energy is directed to the article through the open area of a mask, while the article is moved and the mask is stationary.

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