| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 41 | Mineral stains for wood and other substrates | US11131937 | 2005-05-17 | US20050283921A1 | 2005-12-29 | Stephen Auger |
| According to the invention, a metal salt and an oxygen source are applied to penetrate or impregnate a suitable substrate sequentially in effective amounts so as to react in contact with the substrate and produce a mineral compound fixed within the surface of the substrate. The inventive combination of a mutually compatible metal salt, oxygen source, and substrate brings about an in situ reaction, and modifies the substrate to bring about a lasting desired effect. The mineral compound that is produced according to the invention is linked to the substrate, is stable and long-lasting or permanent, and is immobilized or insolubilized in the substrate. The mineral compound is bound or contained within and on the surface of the substrate, so it may be said to be ingrained in the fibers or matrix of the substrate, or embedded within the substrate. The desired effect is preferably a color. A wide variety of metal salts may be used depending on the desired effect. The oxygen source is preferably a peroxide, and the substrate is preferably a cellulose product such as wood, cotton, or paper; leather; or masonry. The invention contemplates methods of treating substrates, treatment kits, and treated products. With wood products, the invention provides a water-based stain of low toxicity useful for soft woods. | ||||||
| 42 | Method for preparing the reactive tinting compound and the tinted contact lens | US11134206 | 2005-05-20 | US20050251929A1 | 2005-11-17 | Shinn-Gwo Hong |
| A method for preparing the tinted contact lens with the covalently bonded novel reactive tinting compound is disclosed. The reactive tinting compound with mono vinyl functionality is prepared by reacting the reactive dye with a hydrophilic monomer containing both pendent hydroxyl and vinyl groups under an alkaline condition. The water soluble reactive dyes containing either difluoro-chloropyrimidine or β-sulphatoethylsulphone reactive groups are used for synthesis of the reactive tinting dye. The lens forming materials is photo-polymerized in the presence of the reactive tinting compound to prepare a tinted contact lens. The reactive tinting compound is copolymerized with the lens forming monomers in a single photo-polymerization step that required no subsequently alkaline soaking or developing step as used in the prior art. In addition, the covalently bonded dye is stable and durable in the lens and does not fade or leach out after multiple high-pressure thermal sterilization. | ||||||
| 43 | Process for surface functionalsation of polymeric substrates using diaryl carbenes as reactive intermediates | US10741288 | 2003-12-19 | US20040127691A1 | 2004-07-01 | Mark Gerard Moloney; Warren Ebenezer; Karim Awenat |
| An alternative technique whereby highly reactive carbene or nitrene species are generated from inert precursors under less harsh photolytic, and sometimes thermolytic, conditions has also been investigated for application to dyeing and other surface modifying processes of various natural and synthetic polymers. The chemistry of cargenes and nitrenes is well documented, and these reactive entities are known to form covalent bonds with many types of functional group groups. The application of these species to the surface modification or organic solids using different approaches both for the generation of the required carbenes or nitrenes, and for their reaction with the solid surface has been reported. Interestingly, although nitrenes (often generated from an azide or sulfonylazide precursor under photolytic or thermolytic conditions) are more stable, and therefore less reactive, than their carbene analogues, they have used much more widely for the dyeing of polymeric substrates. | ||||||
| 44 | Process for surface functionalization of polymeric substrates using diaryl carbenes as reactive intermediates | US09830829 | 2001-08-21 | US06699527B1 | 2004-03-02 | Mark Gerard Moloney; Warren Ebenezer; Karim Awenat |
| A process for the surface functionalization of a polymeric substrate, which process comprises: a) contacting the substrate with a diarylcarbene precursor, b) generating a carbene reactive intermediate from the diarylcarbene precursor so that it reacts with the substrate to functionalize the surface, and c) further functionalizing the activated substrate obtained in step (b). | ||||||
| 45 | Mineral stains for wood and other substrates | US09932976 | 2001-08-21 | US20020004951A1 | 2002-01-17 | Stephen B. Auger |
| According to the invention, a metal salt and an oxygen source are applied to penetrate or impregnate a suitable substrate sequentially in effective amounts so as to react in contact with the substrate and produce a mineral compound fixed within the surface of the substrate. The inventive combination of a mutually compatible metal salt, oxygen source, and substrate brings about an in situ reaction, and modifies the substrate to bring about a lasting desired effect. The mineral compound that is produced according to the invention is linked to the substrate, is stable and long-lasting or permanent, and is immobilized or insolubilized in the substrate. The mineral compound is bound or contained within and on the surface of the substrate, so it may be said to be ingrained in the fibers or matrix of the substrate, or embedded within the substrate. The desired effect is preferably a color. A wide variety of metal salts may be used depending on the desired effect. The oxygen source is preferably a peroxide, and the substrate is preferably a cellulose product such as wood, cotton, or paper; leather; or masonry. The invention contemplates methods of treating substrates, treatment kits, and treated products. With wood products, the invention provides a water-based stain of low toxicity useful for soft woods. | ||||||
| 46 | Enzymatic method for textile dyeing | US09802190 | 2001-03-08 | US20010037532A1 | 2001-11-08 | Martin Barfoed; Ole Kirk; Sonja Salmon |
| The present invention relates to methods of dyeing a material which involve contacting the material with a dyeing system which comprises: (a) a mixture of (i) an aromatic diamine and (ii) one or more of a naphthol and an aminonaphthalene and (b) an oxidation system comprising (i) a hydrogen peroxide source and an enzyme exhibiting peroxidase activity or (ii) an enzyme exibiting oxidase activity on one or more of the compounds of mixture (a). The material may be a fabric, yarn, fiber, garment or film made of fur, hide, leather, silk or wool, or made of cationic polysaccharide, cotton, diacetate, flax, linen, lyocel, polyacrylic, synthetic polyamide, polyester, ramie, rayon, triacetate, or viscose. | ||||||
| 47 | Method for authenticating a textile product and a thread and a woven label usable therewith | US260386 | 1999-03-01 | US6086966A | 2000-07-11 | Arshavir Gundjian; Abraham Kuruvilla |
| A method for authenticating a textile product, wherein a colorless composition is applied to at least one portion of at least one thread of the textile product. The composition comprises one of a pair of a colorformer and an activator which react when mixed to produce a spectral response. The textile product is authenticated as genuine by applying the other of the pair of the colorformer and activator to at least one portion of the at least one thread to produce the spectral response. The textile product may be a thread or a woven label. | ||||||
| 48 | Enzymatic method for textile dyeing | US770760 | 1996-12-19 | US6036729A | 2000-03-14 | Martin Barfoed; Ole Kirk |
| The present invention relates to methods of dyeing a material, comprising (a) soaking the material in an aqueous solution which comprises one or more mono-, di- or polycyclic aromatic or heteroaromatic compounds; and (b) treating the soaked material in an aqueous solution with (i) a hydrogen peroxide source and an enzyme exhibiting peroxidase activity or (ii) an enzyme exibiting oxidase activity on the one or more aromatic or heteroaromatic compounds; wherein the material is a fabric, yarn, fiber, garment or film made of fur, hide, leather, silk or wool. | ||||||
| 49 | Method for authenticating a textile product and a thread and a woven label usable therewith | US928910 | 1997-09-12 | US5941572A | 1999-08-24 | Arshavir Gundjian; Abraham Kuruvilla |
| A method for authenticating a textile product, wherein a colorless composition is applied to at least one portion of at least one thread of the textile product. The composition comprises one of a pair of a colorformer and an activator which react when mixed to produce a spectral response. The textile product is authenticated as genuine by applying the other of the pair of the colorformer and activator to at least one portion of the at least one thread to produce the spectral response. The textile product may be a thread or a woven label. | ||||||
| 50 | Dyeing method | US193401 | 1994-02-07 | US5478361A | 1995-12-26 | Masaaki Sumii; Yasuyuki Yoshimura |
| The invention provides the following dyeing method: A method of dyeing a cellulosic textile article characterized by immersing the article in an aqueous dispersion containing a cation-treated coloring agent in the first place and, then, immersing it in an aqueous solution or dispersion of an anionic compound. | ||||||
| 51 | Method for insitu coloring crosslinked cellulosic materials | US789298 | 1985-10-18 | US4615708A | 1986-10-07 | Eugene J. Blanchard; Joseph S. Bruno |
| Cellulosic materials, such as cotton fabrics, can be colored insitu by first treating the fabric with N-phenyldiethanolamine and a crosslinking agent for cellulose, such as dimethylol dihydroxyethyleneurea. After the fabric has been cured it is then colored by treating with sufficient concentrations of nitrous acid to form the colored nitroso derivative of the tertiary aromatic amine. The colors obtained are shades of green and yellow which are determined by: concentration of the N-phenyldiethanolamine; type of crosslinking agent; strength of the nitrous acid, and reaction times. | ||||||
| 52 | Dyeing cellulosic fiber with phthalocyanines | US44410642 | 1942-05-22 | US2339739A | 1944-01-18 | HAROLD BLACKSHAW; HULTON HADDOCK NORMAN |
| 53 | Methods for forming dyed microspheres and populations of dyed microspheres | US13246486 | 2011-09-27 | US08361169B2 | 2013-01-29 | Kurt D. Hoffacker; Ananda G. Lugade; Ewald Terpetschnig |
| Various methods for forming dyed microspheres are provided. One method includes activating a chemical structure coupled to a dye using heat or light to form a reaction intermediate in the presence of a microsphere. The reaction intermediate covalently attaches to a polymer of the microsphere thereby coupling the dye to the polymer and forming the dyed microsphere. Additional methods are provided for forming a dyed microsphere coupled to a molecule. These methods include dyeing the microspheres as described above in addition to synthesizing the molecule on an outer surface of the dyed microspheres. A population of dyed microspheres is also provided. Each of the dyed microspheres of the population includes a dye attached to a polymer of each of the dyed microspheres by a chemical structure. A coefficient of variation in dye characteristics of the population of dyed microspheres attributable to the dye is less than about 10%. | ||||||
| 54 | METHOD FOR ACTIVATING COLORANT ASSOCIATED WITH AN ARTICLE | US13528338 | 2012-06-20 | US20120329647A1 | 2012-12-27 | Eva Grace Nellenbach; Robert Clark Avery, JR. |
| Methods and apparatuses for activating colorant in selected regions of an article in which the colorant is incorporated are described. The colorant activation can create various desired visual aspects. | ||||||
| 55 | MINERAL STAINS FOR WOOD AND OTHER SUBSTRATES | US12623205 | 2009-11-20 | US20100068390A1 | 2010-03-18 | Stephen B. Auger |
| According to the invention, a metal salt and an oxygen source are applied to penetrate or impregnate a suitable substrate sequentially in effective amounts so as to react in contact with the substrate and produce a mineral compound fixed within the surface of the substrate. The inventive combination of a mutually compatible metal salt, oxygen source, and substrate brings about an in situ reaction, and modifies the substrate to bring about a lasting desired effect. The mineral compound that is produced according to the invention is linked to the substrate, is stable and long-lasting or permanent, and is immobilized or insolubilized in the substrate. The mineral compound is bound or contained within and on the surface of the substrate, so it may be said to be ingrained in the fibers or matrix of the substrate, or embedded within the substrate. The desired effect is preferably a color. A wide variety of metal salts may be used depending on the desired effect. The oxygen source is preferably a peroxide, and the substrate is preferably a cellulose product such as wood, cotton, or paper; leather; or masonry. The invention contemplates methods of treating substrates, treatment kits, and treated products. With wood products, the invention provides a water-based stain of low toxicity useful for soft woods. | ||||||
| 56 | MINERAL STAINS FOR WOOD AND OTHER SUBSTRATES | US12100371 | 2008-04-09 | US20080187668A1 | 2008-08-07 | Stephen B. AUGER |
| According to the invention, a metal salt and an oxygen source are applied to penetrate or impregnate a suitable substrate sequentially in effective amounts so as to react in contact with the substrate and produce a mineral compound fixed within the surface of the substrate. The inventive combination of a mutually compatible metal salt, oxygen source, and substrate brings about an in situ reaction, and modifies the substrate to bring about a lasting desired effect. The mineral compound that is produced according to the invention is linked to the substrate, is stable and long-lasting or permanent, and is immobilized or insolubilized in the substrate. The mineral compound is bound or contained within and on the surface of the substrate, so it may be said to be ingrained in the fibers or matrix of the substrate, or embedded within the substrate. The desired effect is preferably a color. A wide variety of metal salts may be used depending on the desired effect. The oxygen source is preferably a peroxide, and the substrate is preferably a cellulose product such as wood, cotton, or paper; leather; or masonry. The invention contemplates methods of treating substrates, treatment kits, and treated products. With wood products, the invention provides a water-based stain of low toxicity useful for soft woods. | ||||||
| 57 | Mineral stains for wood and other substrates | US11818004 | 2007-06-11 | US20070240265A1 | 2007-10-18 | Stephen Auger |
| According to the invention, a metal salt and an oxygen source are applied to penetrate or impregnate a suitable substrate sequentially in effective amounts so as to react in contact with the substrate and produce a mineral compound fixed within the surface of the substrate. The inventive combination of a mutually compatible metal salt, oxygen source, and substrate brings about an in situ reaction, and modifies the substrate to bring about a lasting desired effect. The mineral compound that is produced according to the invention is linked to the substrate, is stable and long-lasting or permanent, and is immobilized or insolubilized in the substrate. The mineral compound is bound or contained within and on the surface of the substrate, so it may be said to be ingrained in the fibers or matrix of the substrate, or embedded within the substrate. The desired effect is preferably a color. A wide variety of metal salts may be used depending on the desired effect. The oxygen source is preferably a peroxide, and the substrate is preferably a cellulose product such as wood, cotton, or paper; leather; or masonry. The invention contemplates methods of treating substrates, treatment kits, and treated products. With wood products, the invention provides a water-based stain of low toxicity useful for soft woods. | ||||||
| 58 | Methods for forming dyed microspheres and populations of dyed microspheres | US11247942 | 2005-10-11 | US20060085925A1 | 2006-04-27 | Kurt Hoffacker; Ananda Lugade; Ewald Terpetschnig |
| Various methods for forming dyed microspheres are provided. One method includes activating a chemical structure coupled to a dye using heat or light to form a reaction intermediate in the presence of a microsphere. The reaction intermediate covalently attaches to a polymer of the microsphere thereby coupling the dye to the polymer and forming the dyed microsphere. Additional methods are provided for forming a dyed microsphere coupled to a molecule. These methods include dyeing the microspheres as described above in addition to synthesizing the molecule on an outer surface of the dyed microspheres. A population of dyed microspheres is also provided. Each of the dyed microspheres of the population includes a dye attached to a polymer of each of the dyed microspheres by a chemical structure. A coefficient of variation in dye characteristics of the population of dyed microspheres attributable to the dye is less than about 10%. | ||||||
| 59 | Process for surface functionalsation of polymeric substrates using diaryl carbenes as reactive intermediates | US10741288 | 2003-12-19 | US07034129B2 | 2006-04-25 | Mark Gerard Moloney; Warren Ebenezer; Karim Awenat |
| A process for the surface functionalisation of a polymeric substrate, which process comprises: (a) contacting the substrate with a diarylcarbene precursor, (b) generating a carbene reactive intermediate from the diarylcarbene precursor so that it reacts with the substrate to functionalise the surface, and (c) further functionalising the activated substrate obtained in step (b). | ||||||
| 60 | Mineral stains for wood and other substrates | US09932976 | 2001-08-21 | US06905520B2 | 2005-06-14 | Stephen B. Auger |
| According to the invention, a metal salt and an oxygen source are applied to penetrate or impregnate a suitable substrate sequentially in effective amounts so as to react in contact with the substrate and produce a mineral compound fixed within the surface of the substrate. The inventive combination of a mutually compatible metal salt, oxygen source, and substrate brings about an in situ reaction, and modifies the substrate to bring about a lasting desired effect. The mineral compound that is produced according to the invention is linked to the substrate, is stable and long-lasting or permanent, and is immobilized or insolubilized in the substrate. The mineral compound is bound or contained within and on the surface of the substrate, so it may be said to be ingrained in the fibers or matrix of the substrate, or embedded within the substrate. The desired effect is preferably a color. A wide variety of metal salts may be used depending on the desired effect. The oxygen source is preferably a peroxide, and the substrate is preferably a cellulose product such as wood, cotton, or paper; leather; or masonry. The invention contemplates methods of treating substrates, treatment kits, and treated products. With wood products, the invention provides a water-based stain of low toxicity useful for soft woods. | ||||||
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