序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
21 MINERAL STAINS FOR WOOD AND OTHER SUBSTRATES US12355500 2009-01-16 US20090119850A1 2009-05-14 Stephen B. Auger
According to the invention, a metal salt and an oxygen source are applied to penetrate or impregnate a suitable substrate sequentially in effective amounts so as to react in contact with the substrate and produce a mineral compound fixed within the surface of the substrate. The inventive combination of a mutually compatible metal salt, oxygen source, and substrate brings about an in situ reaction, and modifies the substrate to bring about a lasting desired effect. The mineral compound that is produced according to the invention is linked to the substrate, is stable and long-lasting or permanent, and is immobilized or insolubilized in the substrate. The mineral compound is bound or contained within and on the surface of the substrate, so it may be said to be ingrained in the fibers or matrix of the substrate, or embedded within the substrate. The desired effect is preferably a color. A wide variety of metal salts may be used depending on the desired effect. The oxygen source is preferably a peroxide, and the substrate is preferably a cellulose product such as wood, cotton, or paper; leather; or masonry. The invention contemplates methods of treating substrates, treatment kits, and treated products. With wood products, the invention provides a water-based stain of low toxicity useful for soft woods.
22 Retroreflective inks US09889282 2000-01-12 US07175901B1 2007-02-13 Brian Sagar
The combination of ingredients, especially for use in the formulation of a one or two-pack retroreflective ink, comprising retroreflective elements, microbeads additional to said retroreflective elements and/or constituting said retroreflective elements at least in part, binder chemicals for attaching the retroreflective elements and microbeads to a substrate to which the ink is to be applied, and a coupling agent for coupling the microbeads and cross-linking the binder chemicals, the coupling agent being unreactive until the printing process is carried out.
23 Mineral stains for wood and other substrates US11521988 2006-09-15 US20070011820A1 2007-01-18 Stephen Auger
According to the invention, a metal salt and an oxygen source are applied to penetrate or impregnate a suitable substrate sequentially in effective amounts so as to react in contact with the substrate and produce a mineral compound fixed within the surface of the substrate. The inventive combination of a mutually compatible metal salt, oxygen source, and substrate brings about an in situ reaction, and modifies the substrate to bring about a lasting desired effect. The mineral compound that is produced according to the invention is linked to the substrate, is stable and long-lasting or permanent, and is immobilized or insolubilized in the substrate. The mineral compound is bound or contained within and on the surface of the substrate, so it may be said to be ingrained in the fibers or matrix of the substrate, or embedded within the substrate. The desired effect is preferably a color. A wide variety of metal salts may be used depending on the desired effect. The oxygen source is preferably a peroxide, and the substrate is preferably a cellulose product such as wood, cotton, or paper; leather; or masonry. The invention contemplates methods of treating substrates, treatment kits, and treated products. With wood products, the invention provides a water-based stain of low toxicity useful for soft woods.
24 Textile surface coatings of iron oxide and aluminum oxide US09281089 1999-03-30 US06764969B1 2004-07-20 Hans H. Kuhn; Peter K. Kang
A textile substrate is provided which is coated with a film comprising iron (III) oxide hydroxide and aluminum oxide hydroxide. This film or coating is formed by contacting the textile substrate with an aqueous solution comprising ferrous or ferric salts and aluminum salts. The iron (II), iron (III), and aluminum ions are hydrolyzed and the iron (II) ions are also oxidized under controlled conditions. These hydrolyzed species then, it is believed, coprecipitate or copolymerized to on the textile surface to form a smooth, coherent, substantially amorphous iron (III) oxide/aluminum oxide hydroxide film or coating on the surface of the substrate without forming an insoluble iron (III) or aluminum hydroxide precipitate in the solution. This is accomplished by controlling the reaction conditions such that the rates of adsorption onto the substrate surface of both iron (III) and aluminum oxide hydroxides are greater than the rates of formation of said same oxide hydroxide particles. The resultant coating is substantially amorphous with extremely limited crystalline formation. The obtained substrate has very good color fastness, bacteriostatic, and virus removing properties and can be utilized as an inexpensive and effective water filtration article.
25 Process for brown mineral dyeings of cellulosics without oxidative degradation (tendering), from a single bath US3791786D 1972-04-05 US3791786A 1974-02-12 CONNER C
Cellulosic textiles have been imparted controllable shades of ''''bistre-brown'''' or of ''''reddish-brown'''' coloration which have proved to be durable to laundering. These coloration have been imparted mainly to cotton fabrics through single bath mineral dyeings with inorganic compounds or mixtures thereof by impregnating the cellulosic textile with an aqueous solution containing potassium permanganate and a methylolated ethylene urea, removing the excess solution, then curing the wet impregnated textile. The reddish-brown varieties are prepared by incorporating small quantities of zirconia in the solutions. Whereas the treatment with permanganate alone severely degrades the cellulosic by oxidation, the incorporation of a methylol urea inhibits the cellulosic oxidation and subsequent degradation.
26 Bright pink, lavender and blue mineral dyeing single bath process for cellulosics US3779702D 1972-05-05 US3779702A 1973-12-18 CONNER C
A certain cobalt organic salt was found to produce a water soluble aqueous complex with zirconyl ammonium carbonate, from which an insoluble pink deposit of cobalt and zirconia is deposited on cellulosics by heat. The deposit is bright pink and is completely resistant to hot water washings. The incorporation of varying amounts of copper metaborate into the aqueous cobalt complex produces compatible, uniform, soluble single bath complexes of copper, cobalt, and zirconia which produce lavender to bright blue insoluble deposits on cellulosics by heating (curing). By increasing the ratio of zirconia (ZrO2) to cobalt (Co) by about 7 or 8 to 1, in the bath, lavender to bluish-pink deposits are produced by heat curing without copper. Using low ratios of approximately 1:1 of cobalt and zirconia, produces bright pink mineral pigments on heating (curing), while gradually increasing the copper ratio to cobalt, from 1:1 to 1.5 to 1, produces lavender to bright blue insoluble deposits on heating (curing). The copper containing mineral dyeings on cellulosic are fungicidal and algaecidal. Bright color shades, resistant to light and microorganisms, are desirable for the protection and sales appeal of textiles and other cellulosics.
27 Pad bath formulation of iron salt,ammonium oxalate and zirconyl ammonium carbonate US3702753D 1972-03-21 US3702753A 1972-11-14 CONNER CHARLES J
ORANGE TO BROWN MINERAL DYEINGS ARE CONVENTIONALLY PREPARED FROM TWO BATH SYSTEMS, WHERE THE FABRIC IS WETTED WITH ONE BATH CONTAINING AN IRON SALT, AND THEN WETTED WITH ANOTHER BATH CONTAINING ALKALI TO CAUSE THE COLORED IRON OXIDE TO DEPOSIT IN THE FABRIC AS A MINERAL DYE. THIS BEEN NECESSARY UP TO NOW SINCE IT HAS BEEN CHEMICALLY INCOMPATIBLE TO HAVE THE IRON IN THE SAME ALKALINE BATH WITH THE ALKALI, THIS INVENTION DEMONSTRATES THAT A HEAT DECOMPOSABLE COMPLEX OF THE IRON, WITH OR WITHOUT MANGANESE, CAN BE COMPATIBLE WITH ALKALINE ZIRCONYL AMMONIUM CARBONATE SOLUTIONS IN THE SAME BATH, WHEN CELLULOSICS CAN BE WETTED IN THIS BATH, AND SUBSEQUENTLY MINERAL DYED BY HEAT CURING, WHEN THE COMPLEX OF IRON DECOMPOSES TO DEPOSIT IRON OXIDE WITH ZIRCONIA, THE ZIRCONYL AMMONIUM CARBONATE DECOMPOSING AT THE SAME TIME TO DEPOSIT ZIRCONIA, WHEN HEPTAVALENT MANGANESE (KMNO4) IS INCORPORATED INTO THE BATH WITH THE COMPLEXED IRON, IT IS SOLUBLE AND COMPATIBLE, PRODUCING MANGANESE DIOXIDE (MNO2) BY REDUCTION PRODUCTS FROM THE IRON COMPLEX, RESULTING IN VARIOUS SHADES OR ORANGE TO BROWN WITH THE IRON OXIDE AND ZICONIA ALSO DEPOSITED. THIS PROCESS MAKES IT POSSIBLE TO DEPOSIT ORANGE TO BROWN WASH-FAST MINERAL DYEINGS FROM A SINGLE BATH, THE DEPOSITIED ZIRCONIA ATTRIBUTES A DEGREE OF WATER REPELENCY AND ALAGAECIDAL RESISTANCE TO THE FABRIC, AND A COPPER OR PHENYL-MERCURY SALT CAN BE INCORPORATED INTO THE ZIRONYL AMMONIUM CARBONATE COMPONENT OF THE SYSTEM TO DEPOSIT A FUNGICIDAL MINERAL DYE OF ORANGE TO BROWN SHADE ON HEAT CURING, MAKING IT POSSIBLE TO APPLY AN IRON AND/ OR MANGANESE MINERAL DYE WITH OR WITHOUT FUNGICIDE FROM A SINGLE BATH, REDUCING CONVENTIONAL DYEING PROCEDURES FROM TWO OR MORE BATHS, TO A SINGLE BATH REQUIRING ONLY A SIMPLE PAD. DRY, AND CURE PROCEDURE TO EFFECT THE DYEING. THE FABRICS ARE NOT SERIOUSLY TENDERED, AND THE RESIDUAL BY-PRODUCT SALTS MAY OR MAY NOT BE REMOVED BY WASHING, SINCE THE FABRIC IS NOT STIFFENED BY THEIR PRESENCE AND THE DYED COLORS ARE UNAFFECTED ON STANDING.
28 Zirchrome mineral dyeing process for producing cellulosic materials with a plurality of degradation resistance factors US3431059D 1967-01-30 US3431059A 1969-03-04 CONNER CHARLES J; DANNA GARY S
29 Method of marking compositions with an indelible ink and composition therefor US48810955 1955-02-14 US2880108A 1959-03-31 PERCY FRASER REGINALD
30 Mineral dye liquor and method US4674135 1935-10-25 US2082087A 1937-06-01 WHITE CLARENCE B
31 Coloring of textile materials US34266729 1929-02-25 US1870408A 1932-08-09 CAMILLE DREYFUS; MILES GEORGE W; HERBERT PLATT
32 Dyeing process US67596123 1923-11-20 US1716218A 1929-06-04 AUGUSTE ESCAICH; PAUL WORMS JEAN
33 Process of dyeing khaki. US1900018772 1900-06-01 US655854A 1900-08-14 COMBER GEORGE; CHORLEY JOHN CHRISTMAS
34 Process of dyeing. US1899718284 1899-05-25 US630507A 1899-08-08 HORROCKS FRANK ISHERWOOD
35 Improvement in bluing-powders for laundry use US155239D US155239A 1874-09-22
36 Improvement in the manufacture of colors and figments US88291D US88291A 1869-03-30
37 Improvement in the manufacture of colors US87270D US87270A 1869-02-23
38 John reynolds US73756D US73756A 1868-01-28
39 Improvement in the process of coloring hats, furs US746D US746A 1838-05-25
40 Colored textile EP10158323.5 2010-03-30 EP2305880A3 2014-04-16 Nurmalasari, NiPutuDewi; Chu, Chia-Lung

Disclosed herein is a colored textile, which includes a textile substrate, a titanium layer and a layer of transparent metal oxide. The titanium layer and the layer of transparent metal oxide are disposed in sequence on the textile substrate, and the thickness of the deposited transparent metal oxide layer is adjusted so as to allow the textile substrate to exhibit at least one color without including a pigment or a dye therein.

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