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序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
101 FORMULATIONS FOR OXIDATION PROTECTION OF COMPOSITE ARTICLES US14671637 2015-03-27 US20160280585A1 2016-09-29 Anthony M. Mazany
The present disclosure includes carbon-carbon composite articles having oxidation protection coatings for limiting thermal and catalytic oxidation reactions and methods for applying oxidation protection coatings to carbon-carbon composite articles.
102 Protective coatings for metals US13443855 2012-04-10 US20120196119A1 2012-08-02 Hamlin Jennings; Jeffrey J. Thomas; Ramille M. Capito
Metal products having improved properties and processes for preparing the metal products are provided. In an embodiment, the present disclosure provides for a metal product comprising a metal surface, an oxide layer and a glass layer. The glass layer is provided by coating a stable aqueous silicate or borosilicate solution onto the metal surface and curing the aqueous solution to produce a glass layer. The metal products have surface characteristics that outperform current anodized metal surfaces.
103 PROCESS FOR THE PRODUCTION OF ENAMELLED STEEL SHEET OR PART US12747105 2008-10-23 US20110070425A1 2011-03-24 Lode Duprez; Philippe Gousselot; Marc Leveaux; Javier Gonzalez Jimenez
The invention relates to a steel sheet or part whose composition is suitable for enamelling, and which is coated with a coating consisting of a matrix of polymer in which particles of non-oxide ceramic are homogeneously dispersed. It also relates to the use of this coated steel sheet or part for producing an enamelled steel sheet or part, and to a process for producing an enamelled steel sheet or part allowing a decrease of firing temperature and time compared with conventional firing temperatures and times.
104 CHEMICAL PROTECTION OF A LITHIUM SURFACE US11944906 2007-11-26 US20080113261A1 2008-05-15 Lutgard De Jonghe; Steven J. Visco; Yevgeniy S. Nimon; A. Mary Sukeshini
Disclosed are compositions and methods for alleviating the problem of reaction of lithium or other alkali or alkaline earth metals with incompatible processing and operating environments by creating an ionically conductive chemical protective layer on the lithium or other reactive metal surface. Such a chemically produced surface layer can protect lithium metal from reacting with oxygen, nitrogen or moisture in ambient atmosphere thereby allowing the lithium material to be handled outside of a controlled atmosphere, such as a dry room. Production processes involving lithium are thereby very considerably simplified. One example of such a process is the processing of lithium to form negative electrodes for lithium metal batteries.
105 Process for preparation of an article made of enameled sheet steel by a direct method US09045771 1998-03-23 US06199263B1 2001-03-13 Vicent Cholet; Daniel Vonner
Process using the following stages in the following order: a) scouring, b) initial surface treatment in a single operation meeting three criteria relating to resistance to corrosion, lubrication and cleanability, c) shaping, d) second so-called nickeling surface treatment, e) enameling. With the aid of this order of operations and the criteria defining the initial surface treatment, scouring may be carried out on line on the installations for production of sheet-steel strips.
106 Painting method by spraying glassy material US932243 1986-11-19 US4740388A 1988-04-26 Mikio Nakashima
A glassy material and painting method comprising exposing a plain surface of a metal material to be painted, applying a vaporizable rust preventive on the surface, and then spraying a powdered glassy material onto the surface thus obtained to form a glassy surface coat.
107 Process for treating steel sheets for the purpose of enamelling the sheets US555923 1975-03-06 US4012239A 1977-03-15 Charles Georges Henri Brun; Philippe Marcel Rene Tirmarche
For treating a steel sheet for subsequent enamelling of the sheet with one coat of enamel: After rolling the sheet, there is deposited thereon a coat of nickel and/or cobalt, a salt of said metals or mixtures of said salts. After drying, the sheet is annealed in a decarburizing atmosphere so as to substantially totally decarburize it and, during the cooling of the annealing cycle, the coated sheet is subjected to the action of an oxidizing atmosphere containing 2 to 7% of water vapor and having an H.sub.2 /H.sub. 2 O ratio which is less than 6.
108 Direct-on ceramic coating of carbon-rich iron US608961 1975-09-02 US3971120A 1976-07-27 Clifford G. Ruderer
A process is disclosed for preparing an iron workpiece containing at least 0.03% by weight carbon for a direct-on, one-fire ceramic or enamel coat. A substantially continuous layer of substantially pure iron is pressure-bonded onto a surface of the carbon-rich iron workpiece. Thereafter, the workpiece and bonded iron layer are placed in an electroconducting liquid medium and, while using the workpiece as an anode, some of the deposited iron is electrolytically removed to produce an exposed, fissured, textured surface in the pure iron layer. When a ceramic coat is conventionally applied over the fissured surface, it adheres well, even though the iron workpiece may contain appreciable amounts of carbon which normally prevent such adherence for a direct-on ceramic coat. Optionally, the pressure-bonded layer may be followed by an electrodeposit of a porous, substantially pure iron layer prior to applying a ceramic coat.
109 Preparation of nickel and chromium substrates for ceramic coating US436180 1974-01-24 US3962490A 1976-06-08 Rodney L. Ward
A process and product are disclosed relating to the preparation of a metallic substrate of a workpiece for a subsequent deposition of a ceramic coating, such as porcelain enamel, in which the metal of the substrate is one that is not sufficiently electrochemically active to be coated by electrophoresis, for example, stainless steel or those alloys containing principally nickel and/or chromium. In one form, the metallic substrate is first covered with an oxide, and preferably a thermally decomposable compound, of a transition metal selected from Groups IIIB through Group IIB of the Periodic Table of The Elements. The workpiece is then heated to alloy the transition metal with the substrate of the workpiece, after which a ceramic coat may be applied. When the transition metal is present as a thermally decomposable compound, the compound must decompose prior to reaching an alloying temperature.
110 Direct-on ceramic coating of carbon-rich iron US53544174 1974-12-23 US3923611A 1975-12-02 RUDERER CLIFFORD G
A process is disclosed for preparing an iron workpiece containing at least 0.03% by weight carbon for a direct-on, onefire ceramic or enamel coat. A substantially continuous layer of substantially pure iron is electrodeposited on a surface of the carbon-rich iron workpiece from a liquid medium containing iron ions while using the workpiece as a cathode. The polarity of the electrodeposition is then reversed to remove some of the iron deposited and produce an exposed, fissured, textured surface in the pure iron layer. When a ceramic coat is conventionally applied over the fissured surface, it adheres well, even though the iron workpiece may contain appreciable amounts of carbon which normally would prevent such adherence for a direct-on ceramic coat. Optionally, the cathodic deposition of iron may comprise a deposition of a non-porous layer followed by an overlay of porous iron and/or take place from an aqueous medium having an acidic pH. A film of a covering metal such as nickel may also be deposited over the fissured layer prior to depositing the ceramic coat.
111 Process for preparing steel for enameling US36060873 1973-05-15 US3911177A 1975-10-07 HUMBERT MAURICE; STREEL DOMINIQUE
Low carbon steel having less than 0.012% carbon, is prepared for enameling by degreasing and rinsing, then heating the steel to 200* to 800*C. and depositing thereon by vacuum evaporation an alloy of iron with another Group VIII metal such as nickel or cobalt, the nickel or the like being present in the alloy in an amount 1 to 15% and preferably 4 to 8% by weight, balance iron, and being present on the steel in an amount 0.5 to 4 grams per square meter and preferably 1 to 3 grams per square meter. The previous need to pickle the steel between degreasing and enameling is thus eliminated, and the number of steps and the cost of equipment and operation is reduced.
112 Process of treating sheet steel US34125973 1973-03-14 US3906125A 1975-09-16 UHER JOSEPH F
An improved surface on sheet steel having a carbon content below 0.01%, preferably below 0.003%, for subsequent porcelain enameling or the deposition of a metal or organic, e.g., paint, coating thereon or in preparation of the sheet steel for a subsequent laminating operation, is provided by subjecting the sheet steel having a carbon content below about 0.1% by weight to oxidation in the presence of air under conditions to build up on the surface of the sheet steel undergoing oxidation an oxide layer having a thickness in the range 0.1-1.5 mils and such that the oxidized sheet steel exhibits a gain in weight of at least about 0.5 grams per square foot of oxidized surface, followed by subjecting the resulting oxidized sheet steel to reduction in an atmosphere consisting essentially of nitrogen and hydrogen, preferably at a temperature isothermal with the aforesaid oxidation temperature, such as at a temperature in the range 1000*-1500*F., to reduce substantially all of the oxide layer to metal and then subjecting the resulting oxidized-reduced sheet steel to decarburization at a temperature in the range 1000*1500*F. in an atmosphere consisting essentially of nitrogen, hydrogen and water vapor.
113 Architectural products formed of glass or ceramic-to-metal composites US44098274 1974-02-11 US3867799A 1975-02-25 PRYOR MICHAEL J; POPPLEWELL JAMES M
Architectural products comprising a glass or ceramic-to-metal composite sheet which comprises at least one glass or ceramic component bonded to a copper base alloy component containing from about 2 to about 12% aluminum. The composite sheet may be employed as a panel supported or unsupported by a backing member. The composite sheet may also be employed in building curtain wall.
114 Decorative composite articles US23183472 1972-03-06 US3826627A 1974-07-30 PRYOR M; POPPLEWELL J
THE PRESENT INVENTION RELATES TO A DECORATIVE COMPOSITE ARTICLE HAVING A DECORATIVE PORTION AND COMPRISING AT LEAST ONE FIRST METAL COMPONENT AND A SECOND METAL COMPONENT OF DIFFERENT COMPOSITION FROM THE FIRST METAL COMPONENT BONDED THERETO WHEREIN THE FIRST COMPONENT HAS ON ITS SURFACE AN ALUMINUM OXIDE LAYER. THE DECORATIVE PATTERN OF THE COMPOSITE ARTICLE IS FURTHER COATED WITH A GLASS OR CERAMIC.

D R A W I N G
115 Pretreatment of metal sheets which are coated after a forming operation US3696498D 1970-12-03 US3696498A 1972-10-10 LEONTARITIS LAMBIS; SCHON NIKOLAUS; HOFFMANN HANS; SAYED AZIZ EL
This invention relates to an improved process for the pretreatment of metallic materials wherein the material is subjected to a surface treatment, subsequently covered with a removable layer of a water soluble, film-forming organic polymer, formed and provided with a firmly adhering protective layer.
116 Uniting of fusible porcelain to a precious metal base member US3585064D 1968-05-31 US3585064A 1971-06-15 PROSEN EMII M
FUSIBLE PORCELAIN IS UNITED IN A THIN LAYER TO A PRECIOUS METAL BASE MEMBER BY FIRST FORMING ON SUCH PRECIOUS METAL BASE MEMBER A GOLD COAT HAVING A CARPET-LIKE, IRREGULAR SURFACE COMPOSED OF GOLD PARTICLES WHICH ARE SOLDERED OR SWEATED TO THE BASE MEMBER AND ARE LATERALLY SEPARATED FROM EACH OTHER, AND THEN APPLYING TO SUCH CARPET-LIKE, IRREGULAR SURFACE A PASTE OF A RELATIVELY LOWFUSING PORCELAIN WHICH UPON BEING FUSED IN SITU IS MECHANICALLY UNITED TO SAID CARPET-LIKE SURFACE BY INTERLOCKING TO SUCH GOLD PARTICLES. THE INTERLOCK THUS FORMED OF THE PORCELAIN LAYER WITH THE PURE GOLD PARTICLES HAS BEEN FOUND TO PERMIT OF LIMITED DIFFERENTIAL EXPANSION AND CONTRACTION BETWEEN THE PORCELAIN LAYER AND THE BASE MEMBER UNDER THE SAME HEAT CONDITIONS DUE TO THE FACT THAT THE PURE GOLD PARTICLES YIELD WITH MOVEMENT OF THE PORCELAIN. THERE IS ALSO PROVIDED TH NOVEL COMPOSITE STRUCTURE OF A PRECIOUS METAL BASE MEMBER, A GOLD COAT LAYER HAVING SPACED GOLD PARTICLES SOLDERED OR SWEATED T THE BASE MEMBER, AND A PORCELAIN LAYER INTERLOCKED TO SUCH GOLD COAT PARTICLES.
117 Oxidation-resistant coatings US3544285D 1967-11-08 US3544285A 1970-12-01 GRAHAM ROBERT LESLIE; MORTON PETER HARLOW
118 Method of providing high temperature protective coatings US10324361 1961-04-17 US3298936A 1967-01-17 MICHAEL HAROLD J
119 Method of enameling anodized aluminum US75608158 1958-08-20 US3222266A 1965-12-07 PAGE HAROLD A
120 Process of preparing a ferrous surface for one-fire porcelain enameling US3813660 1960-06-23 US3078180A 1963-02-19 ZANDER JASON M; RICHARD DELOTT
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