| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 21 | Process for producing dyeings | US26184239 | 1939-03-14 | US2204933A | 1940-06-18 | CHARLES GRAENACHER |
| 22 | SOLUBLE CHROMOPHORES HAVING IMPROVED SOLUBILISING GROUPS | EP98904092.8 | 1998-01-17 | EP0968250A1 | 2000-01-05 | HALL-GOULLE, Véronique; BIZE, Aline |
| Compounds of formula (I): A(B)x wherein x is an integer from 1 to 8; A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, indanthrone, isoindolinone, isoindoline, dioxazine, azo, phthalocyanine or diketopyrrolopyrrole series that is bonded to x groups B via one or more hetero atoms, those hetero atoms being selected from the group consisting of N, O and S and forming part of the radical A; each group B independently of any other(s) is hydrogen or a group of formula α, at least one group B being a group of said formula, wherein Q is p, q-C2-C12alkylene that is unsubstituted or mono- or poly-substituted by C1-C12alkoxy, C1-C12alkylthio or by C2-C24dialkylamino, p and q being different position numbers; X is a hetero atom selected from the group consisting of N, O and S, m being the number 0 when X is O or S and m being the number 1 when X is N, and L1 and L2 are each independently of the other [-(p',q'-C2-C12alkylene)-Z-]n-C1-C12alkyl or C1-C12alkyl that is unsubstituted or mono- or poly-substituted by C1-C12alkoxy, C1-C12alkylthio, C2-C24dialkylamino, C6-C12aryloxy, C6-C12arylthio, C7-C24arylalkylamino or by C12-C24diarylamino, wherein n is a number from 1 to 1000, p' and q' are different position numbers, each Z independently of any other(s) is a hetero atom O, S or C1-C12alkyl-substituted N, and C2-C12alkylene in the repeating units [-C2-C12alkylene-Z-] may be identical or different; and L1 and L2 may be saturated or one- to ten-fold unsaturated, uninterrupted or interrupted at any desired points by from 1 to 10 groups selected from the group consisting of -(C=O)- and -C6H4-, and may carry no substituents or may carry from 1 to 10 further substituents selected from the group consisting of halogen, cyano and nitro; with the proviso that when -Q- is -(CH2)r-, wherein r is a number from 2 to 12, and X is S, L2 may not be unsubstituted, saturated and uninterrupted C1-C4alkyl. The compounds according to the invention are used in high-molecular-weight organic materials, thermo-, photo- or chemo-sensitive recording materials, light-sensitive negative or positive resist compositions, ink compositions for ink-jet printing and colour tapes for thermal transfer printing. | ||||||
| 23 | Pyrokohlensäurediester und deren Herstellung sowie Verwendung | EP96810475.2 | 1996-07-19 | EP0764628A1 | 1997-03-26 | Zambounis, John; Hall-Goulle, Véronique |
Die Erfindung betrifft die Herstellung von Pyrokohlensäurediestern nach einem verbesserten Verfahren sowie nach diesem Verfahren hergestellte neue Pyrokohlensäurediester und deren Verwendung. Kernpunkt der Erfindung ist ein Verfahren zur Herstellung eines Pyrokohlensäurediesters der Formel (I),
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| 24 | Neue Fluoreszenzfarbstoffe | EP94810581.2 | 1994-10-04 | EP0648817A1 | 1995-04-19 | Hao, Zhimin, Dr.; Zambounis, John S., Dr.; Iqbal, Abul, Dr. |
Verbindungen der Formel Für die Bedeutung von Q, R₁, R₂, R₃, R₄, X, Y, Z, m und n, wird auf Anspruch 1 verwiesen. Diese Carbamatgruppen enthaltende lösliche Chromophore zeichnen sich durch eine ausserordentliche Festkörperfluoreszenz in UV sowie durch die Leichtigkeit, mit der sie selbst im Substrat, in welchem sie eingearbeitet sind, zu den entsprechenden Pigmenten umgewandelt werden können, aus. |
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| 25 | Soluble chromophores having improved solubility groups | JP53154998 | 1998-01-17 | JP4558106B2 | 2010-10-06 | オール−グール，ベロニク; ビゼ，アリーヌ |
| 26 | New fluorescent pigment | JP2005147555 | 2005-05-20 | JP2006008997A | 2006-01-12 | HAO ZHIMIN; ZAMBOUNIS JOHN S; IQBAL ABUL |
| <P>PROBLEM TO BE SOLVED: To provide a pigment which exhibits very high solid phase fluorescent light in the ultraviolet light region and can easily be converted into the corresponding pigment in a substrate to be mixed with the same. <P>SOLUTION: The compound of formula (I) : A(B)<SB>x</SB>(I) [(x) is 1 to 4; A is the residue of quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or an azo series chromophoric group; the residue contains x N-atoms bound to B; B is a specific alkoxycarbonyl or aminoxycarbonyl]. <P>COPYRIGHT: (C)2006,JPO&NCIPI | ||||||
| 27 | Novel fluorescent pigment | JP24663394 | 1994-10-13 | JP3708569B2 | 2005-10-19 | イクバル アブール; エス．ツァンボウニス ジョーン; ハオ ツィミン |
| 28 | Pyrocarbonic diester, its production and use thereof | JP19727496 | 1996-07-26 | JPH0952868A | 1997-02-25 | JIYON TSUAMUBOUNISU; BUERONIKU HOORUUGOURU |
| PROBLEM TO BE SOLVED: To obtain in high yield and extremely in high purity a pyrocarbonic diester useful for e.g. producing soluble pigment precursors, by reaction between an ester carbonate and a sulfochloride by a specific means. SOLUTION: This compound, a carbonic diester, of formula IV (R' 1 is a straight-chain or branched 1-24C alkyl, 3-24C alkenyl, etc.) is obtained by reaction between 100mol% of an ester carbonate of formula I (M + is Na +, K +, etc.; R 1 is the same as R' 1) and 40-50mol% of a sulfochloride of formula II (R 6 is H, CH 3, etc.) (pref. benzenesulfochloride) in a nonpolar insoluble solvent (pref. toluene) in the presence of 0.8-5mol% of a catalyst of formula III (R 2 to R 5 are each H, a 1-18C alkyl, etc.; X - is a non-nucleophilic anion) (pref. benzyltrimethylammonium chloride) and 1-5mol% of a heterocyclic aromatic amine (pref. pyridine) at -10 to 25°C. COPYRIGHT: (C)1997,JPO | ||||||
| 29 | PROCESS FOR PRODUCTION OF DESUBSTITUTED COMPOUNDS, ORGANIC SEMICONDUCTOR FILM AND PROCESS FOR PRODUCTION OF THE FILM | EP08830424.1 | 2008-09-09 | EP2192631A1 | 2010-06-02 | TAKAHASHI, Keita; KITAMURA, Tetsu; WATANABE, Tetsuya |
A method of producing a desubstituted compound, including: applying an external stimulation to a compound A-(B)m having a solvent-soluble group B (wherein A represents a residue of a solvent-insoluble compound, B represents a specific solvent-soluble group, and m represents a natural number, and the solvent-soluble group B bonds to a carbon atom of the residue A of a solvent-insoluble compound), to cause desubstitution of the solvent-soluble group B, and converting the compound to a solvent-insoluble compound to which a hydrogen atom bonds in place of the solvent-soluble group B; a method of producing an organic semiconductor film, including: forming a film of a π-conjugated compound having a substituent represented by formula (2-1), on a substrate; and causing desubstitution of the substituent from the compound; and an organic semiconductor film and an organic electronic device each obtained by these methods:
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| 30 | Method of producing organic pigment fine-particles, and organic pigment fine-particles obtained thereby and liquid dispersion of the same | EP07005915.9 | 2007-03-22 | EP1840172A3 | 2009-06-24 | Sato, Tadahisa; Maeta, Hideki |
A method of producing organic pigment fine-particles, comprising: bringing a solution of an organic pigment soluble form dissolved in an organic solvent in a flow reactor; and converting the organic pigment soluble form into an organic pigment in the course of flow of said solution. |
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| 31 | Method of producing organic pigment fine-particles, and organic pigment fine-particles obtained thereby and liquid dispersion of the same | EP07005915.9 | 2007-03-22 | EP1840172A2 | 2007-10-03 | Sato, Tadahisa; Maeta, Hideki |
A method of producing organic pigment fine-particles, comprising: bringing a solution of an organic pigment soluble form dissolved in an organic solvent in a flow reactor; and converting the organic pigment soluble form into an organic pigment in the course of flow of said solution. |
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| 32 | Neue Fluoreszenzfarbstoffe | EP94810581.2 | 1994-10-04 | EP0648817B1 | 1999-11-10 | Hao, Zhimin, Dr.; Zambounis, John S., Dr.; Iqbal, Abul, Dr. |
| 33 | METHOD OF PRODUCING A DESUBSTITUTED COMPOUND, ORGANIC SEMICONDUCTOR FILM AND METHOD OF PRODUCING THE SAME | US12677781 | 2008-09-09 | US20100193777A1 | 2010-08-05 | Keita Takahashi; Tetsu Kitamura; Tetsuya Watanabe |
| A method of producing a desubstituted compound, including: applying an external stimulation to a compound A-(B)m having a solvent-soluble group B (wherein A represents a residue of a solvent-insoluble compound, B represents a specific solvent-soluble group, and m represents a natural number, and the solvent-soluble group B bonds to a carbon atom of the residue A of a solvent-insoluble compound), to cause desubstitution of the solvent-soluble group B, and converting the compound to a solvent-insoluble compound to which a hydrogen atom bonds in place of the solvent-soluble group B; a method of producing an organic semiconductor film, including: forming a film of a π-conjugated compound having a substituent represented by formula (2-I), on a substrate; and causing desubstitution of the substituent from the compound; and an organic semiconductor film and an organic electronic device each obtained by these methods: wherein R11 represents a substituent other than a hydrogen atom. | ||||||
| 34 | Soluble chromophores having improved solubilizing groups | US09465868 | 1999-12-16 | US06274728B1 | 2001-08-14 | Véronique Hall-Goulle; Aline Bize |
| Compounds of formula A(B)x (I), wherein x is an integer from 1 to 8, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, indanthrone, isoindolinone, isoindoline, dioxazine, azo, phthalocyanine or diketopyrrolopyrrole series that is bonded to x groups B via one or more hetero atoms, those hetero atoms being selected from the group consisting of N, O and S and forming part of the radical A, each group B independently of any other(s) is hydrogen or a group of the formula at least one group B being a group of the formula The compounds according to the invention are used in high-molecular-weight organic materials, thermo-, photo- or chemo-sensitive recording materials, light-sensitive negative or positive resist compositions, ink compositions for ink-jet printing and color tapes for thermal transfer printing. | ||||||
| 35 | Fluorescent pigments | US09095838 | 1998-06-11 | US06261359B1 | 2001-07-17 | Zhimin Hao; John S. Zambounis; Abul Iqbal |
| Compounds of formula A(B)x, (I), wherein x is an integer from 1 to 4, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group, B is a group of formula and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R1, R2, R3, R4, X, Y, Z, m and n, are as defined in claim 1. These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated | ||||||
| 36 | Soluble chromophores containing solubilising groups which can be easily removed | US681204 | 1996-07-22 | US6063924A | 2000-05-16 | Veronique Hall-Goulle |
| Compounds of formulaA(B).sub.x (I),wherein x is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine, diketopyrrolopyrrole or azo series, which radical A contains x N-atoms linked with B, preferably with at least one immediately adjacent or conjugated carbonyl group.B is a group of formula ##STR1## and, if x=2, 3 or 4, can also be one, two or three hydrogen atom(s), and wherein Q is a group of formula ##STR2## These soluble chromophores can be readily converted to the corresponding pigments by heating, even in the substrate into which they can be incorporated without any difficulty in dissolved form.R.sub.1 -R.sub.9 are as defined herein. | ||||||
| 37 | Fluorescent azo pigments | US89140 | 1998-06-02 | US6013776A | 2000-01-11 | Zhimin Hao; John S. Zambounis; Abul Iqbal |
| Compounds of formulaA(B).sub.x, (I),wherein x is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m and n, are as defined in claim 1.These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated. | ||||||
| 38 | Fluorescent perylene pigments | US89143 | 1998-06-02 | US5874580A | 1999-02-23 | Zhimin Hao; John S. Zambounis; Abul Iqbal |
| Compounds of formulaA(B).sub.x, (I),wherein x is an integer from 1 to 4, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula ##STR1## and, if x is 2,3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m und n, are as defined in claim 1.These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated. | ||||||
| 39 | Fluorescent isoindoline pigments | US677286 | 1996-07-09 | US5723626A | 1998-03-03 | Zhimin Hao; John S. Zambounis; Abul Iqbal |
| Compounds of formula A(B).sub.x, (I), wherein x is an integer from 1 to 4, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group, B is a group of formula ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m und n, are as defined in claim 1. These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated. | ||||||
| 40 | Anthraquinone dyestuffs | US3763193D | 1971-02-17 | US3763193A | 1973-10-02 | VOLKER H; GUNTER G; BEIN H |
| ANTHRAQUINONE DYESTUFFS USEFUL IN THE DYEING OF CELLULOSE ESTERS, POLYAMIDES, OR POLYESTER FIBRE MATERIALS CONTAINING FROM TWO TO FOUR AUXOCHROMES IN THE ALPHA POSITION AND AN ACYLOXY GROUP IN THE BETA POSITION, SAID ACYLOXY GROUP BEING PREFERABLY A SULPHONOXY GROUP CONTAINING AN ARYL, ALKYL, OR DIALKYLAMINO SUBSTITUENT.
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