| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 1 | 含有易除去加溶基的可溶发色团 | CN96112105.X | 1996-07-27 | CN1192009C | 2005-03-09 | V·霍尔-戈勒 |
| 右式化合物A(B)x (I)，其中x为1-4的整数，A是发色基团如二氢喹吖啶二酮，蒽醌，苝，靛蓝，醌型邻苯二酮(quinophthalone)，异二氢吲哚酮，异二氢吲哚，二噁嗪，酞菁，二酮吡咯并吡咯，或偶氮类，其中A含有x个N原子与B相连，优选至少有一个直接相邻或共轭的羰基，B是右式基团且，如果x＝2，3或4，可以是1个，2个或3个氢原子，其中Q是下式基团这些可溶性发色团可通过加热容易地转化为相应的颜料，甚至以溶解形式掺入底物中也很容易转化。R1-R8定义如权利要求1。 | ||||||
| 2 | 制造脱取代的化合物的方法、有机半导体膜和其制造方法 | CN200880115752.5 | 2008-09-09 | CN101855740A | 2010-10-06 | 高桥庆太; 北村哲; 渡边哲也 |
| 本发明公开一种制造脱取代的化合物的方法，其包括向具有溶剂可溶性基团B的化合物A-(B)m施加外部刺激(其中A代表溶剂不溶性化合物的残基，B代表特定的溶剂可溶性基团，m代表自然数，所述溶剂可溶性基团B与溶剂不溶性化合物的残基A的碳原子键合)，使所述溶剂可溶性基团B脱取代，和将所述化合物转化成由氢原子代替所述溶剂可溶性基团B而键合的溶剂不溶性化合物。本发明还公开一种制造有机半导体膜的方法，其包括在基板上形成具有式(2-I)代表的取代基的π-共轭化合物的膜，和使所述取代基从所述化合物脱取代；本发明还公开了通过这些方法得到的有机半导体膜和有机电子器件：式(2-I)其中R11代表氢原子之外的取代基。 | ||||||
| 3 | 含有易除去加溶基的可溶发色团 | CN96112105.X | 1996-07-27 | CN1148585A | 1997-04-30 | V·霍尔-戈勒 |
| 下式化合物A(B)x(I)，其中x为1-4的整数，A是发色基团如二氢喹吖啶二酮，蒽醌，苝，靛蓝，醌型邻二(quinophthalone)，异二氢吲哚酮，异二氢吲哚，二噁嗪，酞菁，二酮吡咯并吡咯，或偶氮类，其中A含有x个N原子与B相连，优选至少有一个直接相邻或共轭的羰基，B是II式基团且，如果x=2，3或4，可以是1个，2个或3个氢原子，其中Q是III式基团，这些可溶性发色团可通过加热容易地转化为相应的颜料，甚至以溶解形式掺入底物中也很容易转化。R1-R8定义如权利要求1。 | ||||||
| 4 | JPS4827237B2 - | JP4640871 | 1971-06-28 | JPS4827237B2 | 1973-08-20 | |
| 1324615 Dyeing processes FARBWERKE HOECHST AG 30 June 1971 [30 June 1970] 30693/71 Heading D1B Hydrophobic fibres, e.g. cellulose 2¢ and tri-acetates, polyacrylonitrile, polyamide, polyurethane and polyesters are dyed or printed at temperatures above 50‹C in the presence of a protein donor with an aqueous solution of a dye of formula F-X-CO-N-SO 3 M in M in which F is the radical of a water-insoluble dyestuff, M is an alkali metal ion or atom or ammonium ion, the bond between M and the nitrogen atom or sulph oxide group being ionic or covalent, X is -O- or -S- or -NR- in which R is H an alkyl or aryl group, an acyl or a sulphonyl group, preferably alkyl sulphonyl or arylsulphonyl group. The dyeing may be effected by exhaustion processes or by podding or printing followed by steaming or thermosolisation, carriers may also be used. Proton donors include ammonium sulphate, magnesium chloride, sodium N-benzyl-sulphanilate, tartaric acid dialkyl esters and phosphoric acid trialkyl ester. | ||||||
| 5 | Fluorescent pigments | US09778324 | 2001-02-06 | US06486332B2 | 2002-11-26 | Zhimin Hao; John S. Zambounis; Abul Iqbal |
| Compounds of formula A(B)x, (I) wherein x is an integer from 1 to 4, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group, B is a group of formula and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R1, R2, R3, R4, X, Y, Z, m and n, are as defined in claim 1. These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated. | ||||||
| 6 | Novel fluorescent pigments | US09778324 | 2001-02-06 | US20010039358A1 | 2001-11-08 | Zhimin Hao; John S. Zambounis; Abul Iqbal |
| Compounds of formulaA(B)x,nullnull(I),wherein x is an integer from 1 to 4, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group, B is a group of formula 1 and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R1, R2, R3, R4, X, Y, Z, m und n, are as defined in claim 1. These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated. | ||||||
| 7 | Pyrocarbonic acid diesters and the preparation and use thereof | US09006360 | 1998-01-13 | US06222047B1 | 2001-04-24 | John Zambounis; Véronique Hall-Goulle |
| The invention relates to the preparation of pyrocarbonic acid diesters by an improved process and to the novel pyrocarbonic acid diesters prepared according to said process as well as to the use thereof. The core of the invention is a process for the preparation of a pyrocarbonic acid diester of formula (I) wherein R1 and R1′ are each independently of the other branched or straight-chain C1-C24alkyl, C3-C24alkenyl, C3-C24alkynyl, C4-C12cycloalkyl, C4-C12cycloalkenyl or C7-C24aralkyl, each of which is unsubstituted or substituted by one or more than one substituent which is inert under the reaction conditions, by reacting at least one ester carbonate of formula (II) with 40-50 mol % of a sulfochloride of formula (IV) in the presence of 0.8-5 mol % of a catalyst of formula (V) and with minor amounts of a heterocyclic aromatic amine in a nonpolar inert solvent, in which process the amount of heterocyclic aromatic amine is 1-3 mol % and the reaction is carried out in the temperature range from −10° C. to +25° C., all molar amounts being based on 100 mol % of ester carbonate of formula (II). | ||||||
| 8 | Fluorescent indigo pigments | US89142 | 1998-06-02 | US6127549A | 2000-10-03 | Zhimin Hao; John S. Zambounis; Abul Iqbal |
| Compounds of formula:A(B).sub.x, (I),wherein x is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula: ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m und n, are as defined in claim 1.These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated. | ||||||
| 9 | Fluorescent dioxazine pigments | US677287 | 1996-07-09 | US5780627A | 1998-07-14 | Zhimin Hao; John S. Zambounis; Abul Iqbal |
| Compounds of formula A(B).sub.x, (I), wherein x is an integer from 1 to 4, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group, B is a group of formula ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m und n, are as defined in claim 1. These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated. | ||||||
| 10 | Dyeing and printing hydrophobic fiber in aqueous sulfonyl carbamic acid-type dyestuff solutions | US3708258D | 1971-06-28 | US3708258A | 1973-01-02 | VON DER ELTZ H; GUNTHER D; VOLLMANN H; KRELL K; MATTERSTOCK K |
| PROCESS FOR THE DYEING AND PRINTING OF HYDROPHOBIC FIBER MATERIALS BY TREATING THE GOODS IN THE PRESENCE OF AN ACID DONOR AT TEMPERATURES ABOVE 50* C. WITH AQUEOUS SOLUTIONS OF DYESTUFFS HAVING THE GENERAL FORMULA
F-X-CO-N(-ME)-SO3-ME WHEREIN F REPRESENTS THE RADICAL OF AN ORGANIC DYESTUFF WATER-INSOLUBLE PER SE, X REPRESENTS AN --O--, A --S-OR --NR-- BRIDGE MEMBER (R=A HYDROGEN ATOM OR AN ALKYL, ARYL, ACYL OR ALKYL OR ARYLSULFONYL GROUP) AND ME IS AN ALKALI METAL OR AMMONIUM ION. |
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| 11 | Insoluble carboxy containing dyestuff compositions | US3485572D | 1966-07-01 | US3485572A | 1969-12-23 | TAUBE CARL; FREYTAG KARL-HEINZ |
| 12 | Process for the colouration of fibres based on polyacrylonitrile | US4454860 | 1960-07-22 | US3084988A | 1963-04-09 | MICHEL SUREAU ROBERT FREDERIC; GILBERT KREMER; JOSEPH OBELLIANNE PIERRE MARIE |
| 13 | Pyrocarbonic acid diesters and the preparation and use thereof | US09767313 | 2001-01-23 | US06359122B1 | 2002-03-19 | John Zambounis; Véronique Hall-Goulle |
| The invention relates to the preparation of pyrocarbonic acid diesters by an improved process and to the novel pyrocarbonic acid diesters prepared according to said process as well as to the use thereof. The core of the invention is a process for the preparation of a pyrocarbonic acid diester of formula (I) wherein R1 and R1′ are each independently of the other branched or straight-chain C1-C24alkyl, C3-C24alkenyl, C3-C24alkynyl, C4-C12cycloalkyl, C4-C12cycloalkenyl or C7-C24aralkyl, each of which is unsubstituted or substituted by one or more than one substituent which is inert under the reaction conditions, by reacting at least one ester carbonate of formula (II) with 40-50 mol % of a sulfochloride of formula (IV) in the presence of 0.8-5 mol % of a catalyst of formula (V) and with minor amounts of a heterocyclic aromatic amine in a nonpolar inert solvent, in which process the amount of heterocyclic aromatic amine is 1-3 mol % and the reaction is carried out in the temperature range from −10° C. to +25° C., all molar amounts being based on 100 mol % of ester carbonate of formula (II). | ||||||
| 14 | Fluorescent anthraquinoid pigments | US08677285 | 1996-07-09 | US06271401B1 | 2001-08-07 | Zhimin Hao; John S. Zambounis; Abul Iqbal |
| Compounds of formula A(B)x, (I), wherein x is an integer from 1 to 4, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group, B is a group of formula and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R1, R2, R3, R4, X, Y, Z, m and n, are as defined in claim 1. These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated. | ||||||
| 15 | Process for the preparation of fluorescent pigments | US095618 | 1998-06-10 | US6013777A | 2000-01-11 | Zhimin Hao; John S. Zambounis; Abul Iqbal |
| Compounds of formulaA(B).sub.x, (I),wherein x is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m and n, are as defined in claim 1.These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated. | ||||||
| 16 | Fluorescent pigments | US97096 | 1998-06-12 | US5886160A | 1999-03-23 | Zhimin Hao; John S. Zambounis; Abul Iqbal |
| Compounds of formulaA(B).sub.x, (I),wherein x is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m and n, are as defined in claim 1.These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated. | ||||||
| 17 | Fluorescent carbamate-modified phthalocyanine pigments | US677486 | 1996-07-09 | US5811543A | 1998-09-22 | Zhimin Hao; John S. Zambounis; Abul Iqbal |
| Compounds of the formula A(B).sub.x (I), wherein x is an integer from 1 to 4, A is the radical of a chromophore of the phthalocyanine series, which radical contains x B groups attached to N-atoms, preferably with at least one directly adjacent to or conjugated with a carbonyl group, B is a group of the formula ##STR1## and, if x is 2,3 or 4, may also be one, two or three hydrogen atoms, wherein the symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, Y, Z, m and n, are as defined in the disclosure These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated. | ||||||
| 18 | Pyrocarbonic acid diesters and the preparation and use thereof | US681205 | 1996-07-22 | US5750758A | 1998-05-12 | John Zambounis; Veronique Hall-Goulle |
| This invention is a process for the preparation of a pyrocarbonic acid diester of formula (I) ##STR1## wherein R.sub.1 and R.sub.1 ' are each, independently of the other, an optionally substituted branched or straight-chain C.sub.1 -C.sub.24 alkyl, C.sub.3 -C.sub.24 alkenyl, C.sub.3 -C.sub.24 alkynyl, C.sub.4 -C.sub.12 cycloalkyl, C.sub.4 -C.sub.12 cycloalkenyl or C.sub.7 -C.sub.24 aralkyl, by reacting at least one ester carbonate of formula (II) ##STR2## with 40-50 mol % of a sulfochloride of formula (IV) ##STR3## in the presence of 0.8-5 mol % of a catalyst of formula (V) ##STR4## and with minor amounts of a heterocyclic aromatic amine in a nonpolar inert solvent, in which process the amount of heterocyclic aromatic amine is 1-3 mol % and the reaction is carried out in the temperature range from -10.degree. C. to +25.degree. C., all molar amounts being based on 100 mol % of ester carbonate of formula (II). | ||||||
| 19 | Fluorescent quinacridone pigments | US319399 | 1994-10-06 | US5561232A | 1996-10-01 | Zhimin Hao; John S. Zambounis; Abul Iqbal |
| Compounds of formulaA(B).sub.x, (I),whereinx is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m and n, are as defined in claim 1. These carbamate group-containing soluble chromophores am distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated. | ||||||
| 20 | Water-soluble dyestuffs readily convertible into insoluble form and process for preparing them | US157667 | 1971-06-28 | US3972904A | 1976-08-03 | Hans-Ulrich von der Eltz; Dieter Gunther; Karl-Heinz Krell; Karl Matterstock; Hansjorg Vollmann |
| Water-soluble dyestuffs of the general formula ##EQU1## WHEREIN F represents the radical of a water-insoluble anthraquinone dyestuff, X represents an oxygen atom, a sulfur atom or a nitrogen atom which is substituted by a hydrogen atom, a lower alkyl, phenyl, lower acyl or sulfonyl group and Me represents an alkali metal or ammonium ion made by solubilizing insoluble dyestuffs which may be indigo, nitro, azo, imide, anthraquinone, oxazine, thiazine, dioxazine, quinoline, methine, polymethine or phthalocyanine dyestuffs. The water-soluble dyestuffs are adapted to be used in dyeing and printing synthetic fibers and are characterized by the fact that they can easily be converted during the process of dyeing to the original water-insoluble dyestuffs by the influence of heat. They are especially useful for the dyeing of polyester in which material they yield deep dyeings. | ||||||
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