序号 专利名 申请号 申请日 公开(公告)号 公开(公告)日 发明人
81 Prepolymers, prepolymer compositions, high-molecular-weight polymers with pore structure, and dielectric films US10577311 2004-10-20 US20070078256A1 2007-04-05 Akira Takaragi; Yoshinori Funaki; Jiichiro Hashimoto
A prepolymer is a reaction product of a compound A and a compound B, in which the compounds A and B each have two or more functional groups or sets of functional groups in one molecule and are capable of undergoing polymerization as a result of binding of the functional groups or sets of functional groups of one compound with the functional groups or sets of functional groups of the other compound to thereby form a high-molecular-weight polymer with a porous structure. The prepolymer has a weight-average molecular weight of about 200 to about 100000. The functional groups or sets of functional groups of the compound A are preferably each a carboxyl group or an amino group, and the functional groups or sets of functional groups of the compound B are preferably two amino groups, an amino group and a hydroxyl group, an amino group and a mercapto group, or two carboxyl groups.
82 Process for increasing the molecular weight of polycondensates US09703782 2000-11-01 US06706824B1 2004-03-16 Rudolf Pfaendner; Kurt Hoffmann; Heinz Herbst
By heating at above the melting point and/or glass transition point of the polycondensate and adding an aromatic dicyanate; or adding a mixture comprising an aromatic dicyanate and a polyfunctional compound selected from the class of sterically hindered hydroxyphenyl-alkyl-phosphonic esters and monoesters, diphosphonites and secondary aromatic amines; or adding a mixture comprising (i) an aromatic dicyanate, (ii) at least one polyfunctional compound selected from the class of sterically hindered hydroxyphenyl-alkyl-phosphonic esters and monoesters, diphosphonites and secondary amines, and (iii) a difunctional epoxide, it is possible to bring about an increase in the molecular weight and/or viscosity of virgin polycondensate and polycondensate recyclates.
83 Cascade polymer bound complexing compounds, their complexes and conjugates, processes for their production, and pharmaceutical agents containing them US10316094 2002-12-11 US20030232017A1 2003-12-18 Johannes Platzek; Heribert Schmitt-Willich; Heinz Gries; Gabriele Schuhmann-Giampieri; Hubert Vogler; Hanns-Joachim Weinmann; Hans Bauer
Cascade polymers, containing complex-forming ligands, optionally at least five ions of an element of atomic numbers 21-29, 39, 42, 44 or 57-83, as well as, if desired, cations of inorganic and/or organic bases, amino acids or amino acid amides, are valuable complexing compounds and complexes for diagnostics and therapy.
84 Coating composition comprising a bicyclo- or spiro-orthoester functional compound US09935308 2001-08-22 US06593479B2 2003-07-15 Keimpe Jan van den Berg; Klaus Hobel; Huig Klinkenberg; Arie Noomen; Josephus Christiaan van Oorschot
The invention pertains to a coating composition comprising a first compound comprising at least one bicyclo- or spiro-orthoester group and a second compound comprising at least two hydroxyl-reactive groups. The invention also comprises a process for curing the present coating composition. More particularly, the latent hydroxyl groups of the bicyclo- or spiro-orthoester groups have to be deblocked and reacted with the hydroxyl-reactive groups of the second compound if the present coating composition is to be cured. Further, a process for making bicyclo-orthoester compounds from the corresponding oxetane compound is described, as are polymers comprising at least one bicyclo- or spiro-orthoester group.
85 Cascade polymer bound complexing compounds, their complexes and conjugates, process for their production and pharmaceutical agents containing them US09973836 2001-10-11 US06576222B2 2003-06-10 Johannes Platzek; Heribert Schmitt-Willich; Heinz Gries; Gabriele Schuhmann-Giampieri; Hubert Vogler; Hanns-Joachim Weinmann; Hans Bauer
Cascade polymers, containing complex-forming ligands, optionally at least five ions of an element of atomic numbers 21-29, 39, 42, 44 or 57-83, as well as, if desired, cations of inorganic and/or organic bases, amino acids or amino acid amides, are valuable complexing compounds and complexes for diagnostics and therapy.
86 Coating composition comprising a bicyclo- or spiro-orthoester functional compound US09935308 2001-08-22 US20020161135A1 2002-10-31 Keimpe Jan van den Berg; Klaus Hobel; Huig Klinkenberg; Arie Noomen; Josephus Christiaan van Oorschot
The invention pertains to a coating composition comprising a first compound comprising at least one bicyclo- or spiro-orthoester group and a second compound comprising at least two hydroxyl-reactive groups. The invention also comprises a process for curing the present coating composition. More particularly, the latent hydroxyl groups of the bicyclo- or spiro-orthoester groups have to be deblocked and reacted with the hydroxyl-reactive groups of the second compound if the present coating composition is to be cured. Further, a process for making bicyclo-orthoester compounds from the corresponding oxetane compound is described, as are polymers comprising at least one bicyclo- or spiro-orthoester group.
87 Coating composition comprising a bicyclo- or spiro-orthoester functional compound US08804485 1997-02-21 US06297329B1 2001-10-02 Keimpe Jan van den Berg; Klaus Hobel; Huig Klinkenberg; Arie Noomen; Josephus Christiaan van Oorschot
The invention pertains to a coating composition comprising a first compound comprising at least one bicyclo- or spiro-orthoester group and a second compound comprising at least two hydroxyl-reactive groups. The invention also comprises a process for curing the present coating composition. More particularly, the latent hydroxyl groups of the bicyclo- or spiro-orthoester groups have to be deblocked and reacted with the hydroxyl-reactive groups of the second compound if the present coating composition is to be cured. Further, a process for making bicyclo-orthoester compounds from the corresponding oxetane compound is described, as are polymers comprising at least one bicyclo- or spiro-orthoester group.
88 Cascade polymer bound complexing compounds, their complexes and conjugates, processes for their production, and pharmaceutical agents containing them US09510363 2000-02-22 US06193950B1 2001-02-27 Johannes Platzek; Heribert Schmitt-Willich; Heinz Gries; Gabriele Schuhmann-Giampieri; Hubert Vogler; Hanns-Joachim Weinmann; Hans Bauer
Cascade polymers, containing complex-forming ligands, optionally at least five ions of an element of atomic numbers 21-29, 39, 42, 44 or 57-83, as well as, if desired, cations of inorganic and/or organic bases, amino acids or amino acid amides, are valuable complexing compounds and complexes for diagnostics and therapy.
89 Block polymer having functional groups at both ends US11329 1998-02-05 US5929177A 1999-07-27 Kazunori Kataoka; Masao Kato; Yukio Nagasaki; Teruo Okano
The present invention provides a block polymer which has functional groups on its both ends, and which comprises hydrophilic/hydrophobic segments. As for the functional groups on its both ends, the block polymer has amino group, carboxyl group or mercapto group on .alpha.-terminal, and hydroxyl group, carboxyl group, aldehyde group or vinyl group on .omega.-terminal. Hydrophilic segment comprises polyethylene oxide, while hydrophobic segment is derived from lactide, lactone or (meth)acrylic acid ester. The block polymer of this invention forms a polymeric micelle which is usable as bio-compatible materials.
90 Electroset composite articles and process US107047 1993-08-17 US5904977A 1999-05-18 Ronald P. Reitz
A process for fabrication of composite articles using electroset materials. Conductive substrates are formed defining the shape of the product to be formed. Electroset material is placed between the substrates and the substrates energized by high voltage. Fluid between the conductive portions of the substrates is under the Winslow effect whereas fluid between nonconductive portions of the substrate is not so affected. The fluid between conductive portions is retained by the Winslow effect and cured.
91 Non-crosslinked, polybranched polymers US376100 1995-01-20 US5773527A 1998-06-30 Donald A. Tomalia; David M. Hedstrand; Rui Yin
This invention discloses non-crosslinked, poly-branched polymers having a comb-burst configuration and a process for preparing such polymers.
92 Compounds in the form of 5,6-dihydroxyindole polymers, their process of preparation and compositions comprising them US548195 1995-10-25 US5721333A 1998-02-24 Laurent Marrot
Novel 5,6-dihydroxyindole polymers, which are soluble in an aqueous or aqueous-alcoholic medium and a process for the preparation of these polymers and to compositions containing these polymers, especially cosmetic compositions.
93 Method for producing a polymer coating inside hollow plastic articles US553614 1996-06-17 US5677010A 1997-10-14 Klaus Esser; Ulrich Karsch; Ju rgenel; Heinrich nwald; Klaus Nauenburg; Ju rgenhart; Christoph Diener
A method for producing at least a polymer surface layer on at least part of the inner surface of a hollow article that is at least partially of plastic, comprising coating said at least part of the inner surface of the hollow article by establishing a low pressure gas atmosphere within the hollow article, formin a polymerizable plasma within the article by excitation of the gas atmospher within the article by high-frequency electromagnetic energy, and allowing polymerization of the gas atmosphere to take place, whereby a polymerized coating is applied to said part of the inner surface, the gas atmospherre that forms the plasma containing a component that predominantly forms chains at sufficient speed and can be polymerized under the particular plasma conditions, and a component that forms predominantly branching or cross-linking points and can be polymerized under the particular plasma conditions.
94 Cascade polymer bound complexing compounds, their complexes and conjugates, processes for their production, and pharmaceutical agents containing them US353390 1994-12-02 US5650136A 1997-07-22 Johannes Platzek; Heribert Schmitt-Willich; Heinz Gries; Gabriele Schuhmann-Giampieri; Hubert Vogler; Hanns-Joachim Weinmann; Hans Bauer
Cascade polymers, containing complex-forming ligands, optionally at least five ions of an element of atomic numbers 21-29, 39, 42, 44 or 57-83, as well as, if desired, cations of inorganic and/or organic bases, amino acids or amino acid amides, are valuable complexing compounds and complexes for diagnostics and therapy.
95 Process for producing hyper-comb-branched polymers US408833 1995-03-21 US5631329A 1997-05-20 Rui Yin; Donald A. Tomalia; David M. Hedstrand; Douglas R. Swanson
The specification discloses a process for producing poly-branched polymer having relatively high molecular weight by forming a first set of branches by polymerizing monomers which are either protected against or are non-reactive to branching and grafting during polymerization, grafting that first set of branches to a core having a plurality of reactive sites capable of reacting with the reactive end units of said branches, either deprotecting or activating a plurality of monomeric units on each of said branches to create branch reactive sites, forming a second set of branches in the same manner as the first set of branches were formed, grafting the second set of branches to the first set of branches by reacting the reactive end units of the second set of branches with each said branch reactive site on said first set of branches and repeating the foregoing steps reiteratively to form and attach subsequent sets of branches to prior branch sets until a desired number of iterations has been effected.
96 Metallospheres and superclusters US196292 1994-02-14 US5516810A 1996-05-14 George R. Newkome; Charles N. Moorefield
Unimolecular micelles, generally referred to as cascade polymers, are constructed via the addition of successive layers, or tiers, of designed monomers, or building blocks, that possess a predetermined, branched superstructure consisting of connected physical matter inherently defining an internal void volume or void area within the molecular framework. Reactive sites located on the framework and hence within the void regions are capable of being chemically transformed to allow covalent and noncovalent incorporation of one or more guest species into the said void regions. Further, a method is described for making such cascade polymers that includes the steps of forming a unimolecular micelle containing internal void areas with accessible reactive sites capable of bonding to at least one guest after construction of the said unimolecular micelle. The guests are contained within the internal void volume of the cascade polymer and are available and accessible for additional chemical modification.
97 Macromonomers having reactive side groups US458976 1995-06-02 US5512630A 1996-04-30 Robert R. Gagne; Matthew L. Marrocco, III; Mark S. Trimmer; Neil H. Hendricks
Rigid-rod macromonomers, and methods for preparing such macromonomers, having a polyaromatic backbone, solubilizing side groups, and reactive side groups are provided. The macromonomers are chemically incorporated into polymer systems to provide stronger, stiffened polymers.
98 Complex oligomeric or polymeric compounds for the generation of metal seeds on a substrate US337669 1994-11-10 US5503877A 1996-04-02 Lutz Stamp; Elisabeth Zettelmeyer; Heinrich Meyer; Gonzalo U. Desmaison
Complex compounds are disclosed comprising a metal of the 8th to 11th groups of the Periodic Table with at least one organic ligand, wherein the complex exists in an oligomeric or polymeric form, and the organic ligand preferably contains at least one N or O atom, or a multiple bond, or several of these elements. The complex compounds are useful for the generation of metal seeds on a non-metallic substrate.
99 Ultraviolet light-absorbing compounds and sunscreen formulations and polymeric materials containing such compounds or residues thereof US308863 1994-09-19 US5442086A 1995-08-15 James J. Krutak; Max A. Weaver; Clarence A. Coates, Jr.; Samuel D. Hilbert; Terry A. Oldfield; William W. Parham; Wayne P. Pruett
Disclosed are certain poly-methine compounds having the formula ##STR1## wherein each R.sup.1 is independently selected from cyano; carboxy; alkenyloxycarbonyl; an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; an unsubstituted or substituted, carbocyclic or heterocyclic aryl radical; an unsubstituted or substituted alkanoyl, cycloalkanoyl or aroyl radical; an unsubstituted or substituted carbamoyl radical; or an unsubstituted or substituted alkylsulfonyl, cycloalkylsulfonyl or arylsulfonyl radical; each R.sup.2 is independently selected from cyano or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; each A is independently selected from an unsubstituted or substituted 1,2-phenylene or 1,2-naphthylene radical; each Z is independently selected from --0-- or --S--; and L is an organic linking group bonded by non-oxo carbon atoms to each Z atom. Also disclosed are sunscreen formulations and polymeric compositions containing at least one of the poly-methine compounds or the reactive residue thereof.
100 Metallospheres and superclusters US226655 1994-04-12 US5422379A 1995-06-06 George R. Newkome; Charles N. Moorefield
Unimolecular micelles, generally referred to as cascade polymers, are constructed via the addition of successive layers, or tiers, of designed monomers, or building blocks, that possess a predetermined, branched superstructure consisting of connected physical matter inherently defining an internal void volume or void area within the molecular framework. Each of the branches define a flexible arm from a central core atom and terminate with a hydrodynamic reactive group. A method is described for manipulating such cascade polymers.
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