序号 | 专利名 | 申请号 | 申请日 | 公开(公告)号 | 公开(公告)日 | 发明人 |
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161 | Low temperature curable organic resin compositions | US122280 | 1980-02-19 | US4239725A | 1980-12-16 | James V. Crivello |
Low temperature curable organic resin compositions, for example, epoxy resins are provided, which can be either exothermically cured or cured in several minutes or less at relatively low temperatures. Certain diaryliodonium salts have been found to spontaneously release strong protonic acids when used in combination with a copper salt and a reducing agent. | ||||||
162 | Heat curable compositions | US098096 | 1979-11-28 | US4238587A | 1980-12-09 | James V. Crivello |
Diaryliodonium salts have been found to be effective thermal initiators for the polymerization of a variety of cationically polymerizable materials including epoxides, cyclic ethers, phenol formaldehyde resins, etc., when used in combination with various cocatalysts. Among the cocatalysts which have been found to be effective are, for example, copper chelates and mixtures of such copper chelates with various reducing agents such as ascorbic acid, tin.sup.+2 salts, etc. | ||||||
163 | Process for the production of organic halosilicon acid resinous products and their reaction products utilizing phenol compounds | US32411 | 1979-04-23 | US4238375A | 1980-12-09 | David H. Blount |
Dry granular silicon acid, an organic phenol and a silicon halide are mixed simultaneously to produce an organic halosilicon acid resinous product. | ||||||
164 | Process for the preparation of silicious polymeric materials and their applications in the separation of fluids in gaseous phase | US919656 | 1978-06-28 | US4190425A | 1980-02-26 | Wilhelm Bruening; Inai M. R. deA. Bruening |
This invention relates to a process for the preparation of silicious polymeric materials and their use in the separation of fluids in the gaseous phase, wherein the materials are obtained through three basic procedures: (a) polymerization of monomeric substances in the presence of high purity submicroscopic silica particles in which the polymerization of the monomers can be followed by a deactivation reaction with silylating agent; (b) addition of high purity submicroscopic silica particles to monomeric substances, and coupling regents, which will react with surface hydroxyl groups on the silica and a polymer or monomers which are forming a polymer in the reaction medium; (c) through dispersion of the high purity submicroscopic particles in plymeric organic substances. The materials obtained in this invention are solid, usually white, highly porous, of relatively high surface area, thermally stable and have good mechanical strength, and when used as a packing material in a gas chromatographic column provide excellent results with respect to permeability, efficiency, and selectivity. | ||||||
165 | Bispiperazido phosphorus polyamides | US918248 | 1978-06-23 | US4176226A | 1979-11-27 | Johny C. Hermans |
Novel polymers, useful as films or filaments, are prepared as by the reaction of a bispiperazide with a reactive derivative of an acid. | ||||||
166 | Colored polyurethane foams and a process for their production | US923762 | 1978-07-11 | US4166163A | 1979-08-28 | Eugene P. DiBella; Morris Dunkel; Henry Gould |
Colored polyurethane foams are prepared by the reaction of a polyisocyanate with a component that contains at least two compounds having functional groups containing active hydrogen atoms and that comprises a polyol and a dispersion of a pigment in a low-viscosity, semi-reactive vehicle that comprises a glycol monocarboxylate, such as 1,2-propylene glycol mononeodecanoate. | ||||||
167 | Liquid vinylidene terminated polymers | US738194 | 1976-11-03 | US4147854A | 1979-04-03 | Douglas E. Skillicorn |
Liquid vinylidene (CH.sub.2 .dbd.C<) terminated polymers are prepared by the reaction of a (1) liquid polymer having a terminal functional group selected from the group consisting of carboxyl, hydroxyl, mercaptan, amine and epoxy and (2) a compound containing both an epoxy group ##STR1## and a vinylidene group. The reaction can be catalyzed using a base. The polymers cure readily to solid elastomers which are useful as sealants, caulks, potting compounds, coatings and the like. | ||||||
168 | Liquid vinylidene terminated polymers | US738195 | 1976-11-03 | US4129713A | 1978-12-12 | Douglas E. Skillicorn |
Liquid vinylidene (CH.sub.2 .dbd.C<) terminated polymers are prepared by the reaction of a (1) liquid polymer having a terminal functional group selected from the group consisting of carboxyl, hydroxyl, mercaptan, amine and epoxy and (2) a compound containing both an epoxy group ##STR1## and a vinylidene group. The reaction can be catalyzed using a base. The polymers cure readily to solid elastomers which are useful as sealants, caulks, potting compounds, coatings and the like. | ||||||
169 | Light sensitive materials | US636363 | 1975-12-01 | US4117039A | 1978-09-26 | Allen Peter Gates; Allan Saunderson |
A light sensitive material suitable for coating onto a support to produce a light sensitive plate for use in, for example, the manufacture of a printing plate comprises groups of the formula: ##STR1## attached to carbon atoms of a polymer, wherein --Z-- is --o-- or ##STR2## or ##STR3## wherein R.sub.5 represents a hydrogen atom or an alkyl group; R is an aromatic radical; a is zero or unity; R.sub.1, R.sub.2 and R.sub.3 are hydrogen atoms, halogen atoms, cyano groups, or specified aliphatic or aromatic groups; X is a deactivating group; R.sub.4 is a hydrogen atom, a carboxyl group, a cyano group or a specified aliphatic or aromatic group; and Ph is a phenyl group. The material may be produced by reacting a polymer containing epoxide groups, hydroxyl groups, or primary and/or secondary amino groups with the halosulphonyl group of a compound having the formula: ##STR4## wherein R, R.sub.1, R.sub.2 R.sub.3, and a having the above meanings, wherein X has the above meaning or is a halosulphonyl group and R.sub.4 has the above meaning or, in the case where X is a deactivating group, is a halosulphonyl substituted group. | ||||||
170 | Antionic polymerization | US539729 | 1975-01-09 | US4116887A | 1978-09-26 | Jean-Marie Lehn; Francois Schue; Sylvia Boileau; Bernd Kaempf; Alain Andre Cau; Jean Robert Moinard; Serge Fernand Raynal |
A novel process for polymerization or copolymerization of monomers is described, according to which the reaction is carried out in the presence of an anionic initiator and a macroheterocyclic complexing agent of formula ##STR1## in which: EACH R.sub.1 is a hydrogen atom, a hydrocarbon group or an alkoxycarbonyl group, or the two R.sub.1 together can form a group of the general formula: ##STR2## THAT IS TO SAY FORMING A THIRD BRIDGE BETWEEN THE TWO NITROGEN ATOMS IN THE MOLECULE, A is a hydrocarbon group,D is an oxygen or sulfur atom or a hydrocarbon group, with the proviso that at least two of the groups D are oxygen or sulfur atoms and that, if each R.sub.1 is hydrogen, a hydrocarbon group or an alkoxycarbonyl group, one of these two groups D is oxygen or sulfur and the other is oxygen,n and p are integers ranging from 1 to 3, andm is 2 or 3. | ||||||
171 | Curable compositions and method for curing such compositions | US705149 | 1976-07-14 | US4108747A | 1978-08-22 | James V. Crivello |
Cationically polymerizable compositions are provided, such as epoxides, vinyl ethers, and N-vinyl compounds having an effective amount of aryl onium trifluoromethane sulfonate salts, such as a triphenyl sulfonium trifluoromethane sulfonate and diphenyliodonium trifluoromethane sulfonate. The curable compositions are polymerizable under ultraviolet radiation. In addition to being used as adhesives, encapsulents and in coating applications, the aforementioned curable compositions can be employed as photoresists and as printing inks. | ||||||
172 | Heavy metal-binding agent process | US546446 | 1975-02-03 | US4039446A | 1977-08-02 | Kouichi Ban; Yasumiti Namba; Yukihiro Sekine; Masaaki Matsuda |
A novel heavy metal-binding agent is obtained by reacting a resin containing in its molecular chain --NH--, --NH.sub.2, or both thereof with carbon disulfide and, if necessary, treating the reaction product thus obtained with a base. As compared with conventionally known metal-binding agents, the present metal-binding agent can remove heavy metals more effectively from solutions or gases containing these metals even in a range of extremely low concentrations, and, hence, is useful for pollution control. | ||||||
173 | Liquid vinylidene-terminated polymers | US585962 | 1975-06-11 | US4013710A | 1977-03-22 | Douglas E. Skillicorn |
Liquid vinylidene (CH.sub.2 =C<) terminated polymers are prepared by the reaction of a (1) liquid polymer having a terminal functional group selected from the group consisting of carboxyl, hydroxyl, mercaptan, amine and epoxy and (2) a compound containing both an epoxy group ##STR1## and a vinylidene group. The reaction can be catalyzed using a base. The polymers cure readily to solid elastomers which are useful as sealants, caulks, potting compounds, coatings and the like.This is a division of application Ser. No. 292,926, filed Sept. 28, 1972, now U.S. Pat. No. 3,910,992. | ||||||
174 | Chemically joined phase separated thermoplastic graft copolymers | US563278 | 1975-03-28 | US3989768A | 1976-11-02 | Ralph Milkovich; Mutong T. Chiang |
The present invention relates to thermoplastic graft copolymers comprised of copolymeric backbones containing a plurality of uninterrupted repeating units of the backbone polymer and at least one integrally copolymerized moiety per backbone polymer chain having chemically bonded thereto a substantially linear polymer which forms a copolymerized sidechain to the backbone, wherein each of the polymeric sidechains has substantially the same molecular weight and each polymeric sidechain is chemically bonded to only one backbone polymer. | ||||||
175 | Production of resins | US457409 | 1974-04-03 | US3972849A | 1976-08-03 | Hilmar Bruenemann; Guenter Stoeckelmann; Volker Radtke |
A process for the production of milled particulate resins which comprises carrying out the reaction of the resin components in a moving reaction vessel containing carrier bodies. The new process is particularly suitable for the production of pigmented resins, for example daylight fluorescent pigments. | ||||||
176 | US47917574 | 1974-06-13 | USB479175I5 | 1976-02-17 | ||
177 | Liquid vinylidene-terminated polymers | US29292672 | 1972-09-28 | US3910992A | 1975-10-07 | SKILLICORN DOUGLAS E |
Liquid vinylidene (CH2 C<) terminated polymers are prepared by the reaction of a (1) liquid polymer having a terminal functional group selected from the group consisting of carboxyl, hydroxyl, mercaptan, amine and epoxy and (2) a compound containing both an epoxy group
and a vinylidene group. The reaction can be catalyzed using a base. The polymers cure readily to solid elastomers which are useful as sealants, caulks, potting compounds, coatings and the like. |
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178 | Latent catalyst systems for cationically polymerizable materials | US37702673 | 1973-07-06 | US3907706A | 1975-09-23 | ROBINS JANIS |
A multi-component catalyst system that is latent at a first elevated temperature but is rapidly activated at a second temperature only slightly elevated over the first temperature comprises 1) metal salts of fluoroalkane sulfonic acids or bis(fluoroalkylsulfonyl)methanes, and 2) a thermally decomposable ester reaction product of a tertiary alkyl alcohol and an acid that forms a chelation complex with the metal ion of the metal salt. In some embodiments the catalyst system further includes a buffering compound that retards activity of the catalyst system.
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179 | Polymerization process | US12200171 | 1971-03-08 | US3887442A | 1975-06-03 | GILCHRIST ALLAN E |
Monomer, prepolymer, or oligomer feed that is polymerizable into a fluent polymer is dispersed with electrolyte in an autoionizable liquid bath, such as an aqueous bath, and percolated through a porous, charged d.c. electrode for promoting its polymerization into synthetic resin.
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180 | Polyblends of chemically joined, phase separated thermoplastic graft copolymers | US43331474 | 1974-01-14 | US3879494A | 1975-04-22 | MILKOVICH RALPH; CHIANG MUTONG T; SCHULZ GERALD O |
The present invention relates to polyblends of at least one polymer blended with thermoplastic graft copolymers comprised of copolymeric backbones containing a plurality of uninterrupted repeating units of the backbone polymer and at least one integrally copolymerized moiety per backbone polymer chain having chemically bonded thereto a substantially linear polymer which forms a copolymerized sidechain to the backbone, wherein each of the polymeric sidechains has substantially the same molecular weight and each polymeric sidechain is chemically bonded to only one backbone polymer.
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