| 序号 | 专利名 | 申请号 | 申请日 | 公开（公告）号 | 公开（公告）日 | 发明人 |
|---|---|---|---|---|---|---|
| 61 | Catalyst mixtures for polyisocyanurate foam | US889560 | 1986-07-25 | US4710521A | 1987-12-01 | Thomas G. Soukup; John P. Oliver |
| Rigid polyisocyanurate foams are prepared by (a) bringing together on a continuously advancing conveyor an organic polyisocyanate, a minor amount of a polyester polyol, a blowing agent and, in an organic solvent, a catalyst mixture comprising: (i) a salt of a low molecular weight carboxylic acid selected from the group consisting of an alkali metal salt and an alkaline earth metal salt and mixtures thereof, and (ii) a tertiary amine, the amount of the salt of the low molecular weight carboxylic acid being sufficient and the molecular weight of the carboxylic acid of the salt being sufficiently low to provide a firm foam having a non-friable surface, and (b) foaming the foam-forming mixture. | ||||||
| 62 | Urethane bonding method and laminate | US742821 | 1985-06-10 | US4636425A | 1987-01-13 | Malcolm C. Johnson; Theodore O. Stolz |
| A method of surface bonding elements with a two component polyurethane foam, particularly where one of the surfaces to be joined is relatively porous, including contoured fiberglass panels, carpet, foam and fibrous paneling and the resultant bonded structure. The method includes spraying the liquid foamable polyurethane in a fine mist under pressure on one of the surfaces to be bonded to form dispersed discrete liquid polyurethane droplets; permitting the polyurethane droplets to foam and expand in discrete foam pods; applying the second surface to be joined while said polyurethane foam pods are between 20% and 60% of full cure; and, completing the cure of the polyurethane foam, preferably under moderate heat and pressure. | ||||||
| 63 | Polyurethane compositions useful as adhesives for insulation materials and/or facings | US608326 | 1984-05-08 | US4489176A | 1984-12-18 | Hermann Kluth; Robert Bachmann; Georg Boerner |
| A polyurethane composition containing a polyurethane prepolymer, a foam stabilizer, a diluent, and optional auxiliary agents, useful as an adhesive for building insulation and/or decorative facing on a variety of substrates. | ||||||
| 64 | Polyisocyanurate foams based on esterified DMI oxidation residue additive | US81325 | 1979-10-03 | US4237238A | 1980-12-02 | David T. DeGuiseppi; Richard A. Kolakowski |
| Polyisocyanurate foams are disclosed which are characterized by a combination of a high degree of fire resistance with low smoke evolution, low foam friability yet high compressive strength, and, most unexpectedly, the formation of a protective intumescent char over unburnt foam when the foam is subjected to combustion.This combination of advantageous features is achieved by employing in the foam forming reaction a minor amount of a polyol mixture prepared by the transesterification, with a glycol of molecular weight from about 60 to about 400, of a residue obtained from the manufacture of dimethyl terephthalate. | ||||||
| 65 | Polyisocyanurate structural laminate and process for producing same | US32278273 | 1973-01-11 | US3903346A | 1975-09-02 | DELEON ALBERTO; HIPCHEN DONALD E; SKOWRONSKI MICHAEL J |
| A process for producing a structural laminate having a polyisocyanurate foam core wherein a mixture of an organic polyisocyanate and diethylene glycol are applied to a facing sheet. The facing sheet comprises paper coated on both sides with a moisture vapor impermeable material. The coated facing sheet is then placed in an oven at 150* to 200* F, whereupon the mixture cures to a polyisocyanurate foam of uniform strength.
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| 66 | HIGH-TEMPERATURE-RESISTANT FOAMS HAVING LOW THERMAL CONDUCTIVITY | PCT/EP2012057847 | 2012-04-27 | WO2012150201A3 | 2013-03-14 | WEGENER DIRK; REITER STEPHAN; RASSELNBERG HARALD; SCHORNSTEIN MARCEL; ARNTZ HANS-DETLEF; BRUENING DIRK |
| The invention relates to high-temperature-resistant foams having low thermal conductivity, to the production thereof from organic polyisocyanates and polyepoxides, and to the use of the foams. | ||||||
| 67 | Composite elements composed from thermoplastic polymers and polyurethanes, and process for production thereof | US14235102 | 2012-07-25 | US09751279B2 | 2017-09-05 | Rolf William Albach; Hartmut Nefzger; Harald Knaup; Frank Hahn; Petra Venner; Monika Haselbach |
| The invention relates to composite elements comprising a thermoplastic polymer and an adjacent polyurethane bonded thereto, to a process for production thereof and to the use thereof. | ||||||
| 68 | MOUNTING FOAM COMPOSITIONS | US15363356 | 2016-11-29 | US20170152363A1 | 2017-06-01 | Tomasz Pawlus; Nina Kulis |
| A mounting foam contains polyols, isocyanates, plasticizers, surfactants, a catalyst and gases. The foam contains polyols from 30% to 35% and gases from 15.5% to 17.5%, where the ratio of NCO:OH is from 3.4 to 3.9. The foam is used as an adhesive for coatings and to fill voids in structures. | ||||||
| 69 | COMPOSITE ELEMENTS COMPOSED FROM THERMOPLASTIC POLYMERS AND POLYURETHANES, AND PROCESS FOR PRODUCTION THEREOF | US14235102 | 2012-07-25 | US20140199540A1 | 2014-07-17 | Rolf William Albach; Hartmut Nefzger; Harald Knaup; Frank Hahn; Petra Venner; Monika Haselbach |
| The invention relates to composite elements comprising a thermoplastic polymer and an adjacent polyurethane bonded thereto, to a process for production thereof and to the use thereof. | ||||||
| 70 | TWO-PART FOAMABLE ADHESIVE WITH RENEWABLE POLYOL | US13380795 | 2010-07-01 | US20120208957A1 | 2012-08-16 | Nicholas John Berard; Michael Lewis Kerman; Wayne Mazorow |
| An adhesive composition for use on a roofing substrate includes two components that are mixed prior to application on the roofing substrate. The first component includes renewable polyols, catalysts, fumed silicas, water, and surfactants. The renewable polyols are selected from any non-petroleum based polyol that is derived from a renewable source. The second component includes isocyanates, polyols, surfactants, fumed silicas, and a catalyst. | ||||||
| 71 | Composite roof structures prepared using one-part moisture curing polyurethane foaming adhesive compositions containing a reversibly blocked catalyst | US10664052 | 2003-09-16 | USRE39764E1 | 2007-08-14 | Roger L. Streets |
| The present invention relates to composite roof structures and their preparation. The composite roof structure is prepared by applying a one-part, moisture curable, foaming, polyurethane adhesive composition to the roof deck, placing the roofing material in contact with the adhesive composition, and allowing the adhesive mixture to foam, fill, and cure. If multiple layer of the roofing material are used to form the composite roof structure, then the above procedure may be used to adhere each of the roofing material layers. | ||||||
| 72 | Two-part polyurethane adhesive for bonding insulation boards to a roof deck | US10683050 | 2003-10-10 | US07205374B2 | 2007-04-17 | John W. Fieldhouse; Joseph J. Kalwara; Edward G. Kane; John B. Letts |
| A method of preparing an adhesive, the method comprising combining an isocyanate, a polyhydroxyl phenol-containing compound, a polyol, and a trimerization catalyst. | ||||||
| 73 | Bio-based, multipurpose adhesive | US11104199 | 2005-04-12 | US20060276614A1 | 2006-12-07 | Lance Niemann |
| The invention is a two part urethane adhesive in which the B side component is derived chiefly from a vegetable oil, preferably soy oil. Preferably the vegetable oil derivative is a hydroxylated vegetable oil which is present in the B side component at a concentration from 65 to 98 weight percent Optionally, a phosphated soy oil can be present in an amount from 0.1 to 15 weight percent to enhance the adhesive properties, particularly for use on metals. Also, water can be present in an amount from 0.1 to 10 weight percent with a slight amount of a surfactant to stabilize the mixture. Catalysts are included in the B side component to reduce the amount of the A side component and to accelerate curing of the adhesive. The A and B side components are admixed in amounts which provide from 40 to 90 weight percent of bio-based content in the adhesive. The adhesive also has a volatile organic content (VOC) less than 2 weight percent and most preferably no VOC. | ||||||
| 74 | Method for protecting sensitive surfaces | US11488268 | 2006-07-18 | US20060257640A1 | 2006-11-16 | Uwe Schumann; Nicolai Bohm; Kirstin Weiland |
| A self-adhesive surface protective film, particularly for automobile paint surfaces, having a backing layer and a self-adhesive layer based on a foamed polyurethane. | ||||||
| 75 | Thermosettable compositions useful for producing structural adhesive foams | US10128720 | 2002-04-23 | US20040082673A1 | 2004-04-29 | Rajat K. Agarwal |
| The use of an adduct of an isocyanate resin and an isocyanate-reactive epoxy resin in an expandable thermosettable composition helps to reduce the tackiness of the composition and also increases its dimensional stability, as compared to compositions in which only non-adducted epoxy resins are present. | ||||||
| 76 | Thermosettable compositions useful for producing structural adhesive foams | US09844200 | 2001-04-27 | US20030018095A1 | 2003-01-23 | Rajat K. Agarwal |
| The use of an adduct of an isocyanate resin and an isocyanate-reactive liquid or semi-solid epoxy resin in an expandable thermosettable composition helps to reduce the tackiness of the composition and also increases its dimensional stability, as compared to compositions in which only non-adducted liquid or semi-solid epoxy resins are present | ||||||
| 77 | Protective film for paint surfaces with a self-adhesive composition based on a polyurethane foam | US10007924 | 2001-12-07 | US20020114939A1 | 2002-08-22 | Uwe Schumann; Nicolai Bohm; Kirstin Weiland |
| A self-adhesive surface protective film, particularly for automobile paint surfaces, having a backing layer and a self-adhesive layer based on a foamed polyurethane. | ||||||
| 78 | Foamed pressure sensitive tapes | US877060 | 1997-06-17 | US5780523A | 1998-07-14 | Dominique Petit; Michel Ladang |
| The present invention relates to a pressure sensitive adhesive foam with a percentage of theoretical density less than 90 wherein the foam has an intrinsic adhesion of greater than about 1 N/cm and a compression set under constant deflection of less than about 60%. The present invention further includes a pressure sensitive adhesive foam comprising a thermoplastic block copolymer; a tackifying resin; an isocyanate terminated monomer or oligomer; a polymer comprising a backbone of selected from the group consisting of polybutadiene, polyester and polyether, wherein the polymer contains at least 2 active hydrogens capable of reacting with the isocyanate terminated monomer; and expandable particulate materials. The invention finally further comprises a method of forming the above film. | ||||||
| 79 | Preparation of polyurethane rigid foams | US591328 | 1996-01-25 | US5688835A | 1997-11-18 | Karin Scherbel; Katrin Ebert; Hartmut Appenroth; Peter von Malotki |
| A process for producing polyurethane rigid foams comprises reacting a) organic polyisocyanates b) relatively high molecular weight compounds containing at least two respective hydrogen atoms and, if desired, c) low molecular weight chain extenders and/or crosslinkers in the presence of d) blowing agents e) catalysts and, if desired, f) auxiliaries and additives, wherein the relatively high molecular weight compounds containing at least two reactive hydrogen atoms comprise a mixture of a1) one or more high-functional, polyether alcohols having functionalities of from 6 to 8 and mean equivalent masses of from 125 to 200, a2) one or more polyether alcohols based on aliphatic amines having functionalities of from 3 to 4 and mean equivalent masses of from 70 to 130, a3) one or more low-functional polyether alcohols having functionalities of from 2 to 3 and mean equivalent masses of from 67 to 250, and a4) an OH-containing fatty acid ester. | ||||||
| 80 | Three component polyol blend for use in insulating rigid polyurethane foams | US756647 | 1996-11-26 | US5684057A | 1997-11-04 | Walter R. White, III; James A. Mullins; Thomas B. Lee; Keith McLellan; Ronald J. Wierzbicki |
| There is now provided a polyisocyanate based rigid closed cell foam made by reacting an organic isocyanate with a polyol composition in the presence of a blowing agent, where the polyol composition contains at least: a) an aromatic amine initiated polyoxyalkylene polyether polyol having an hydroxyl number of 200 meq polyol/g KOH or more; b) an aliphatic amine initiated polyoxyalkylene polyether polyol having an hydroxyl number of 200 meq polyol/g KOH or more; and c) an aromatic polyester polyol having an hydroxyl number of 200 meq. polyol/g KOH or more. The blowing agent is selected from the group consisting of cyclopentane, HFC's, HCFC's, and mixtures thereof in an amount of 5.0 weight percent or more based on the weight of the polyol composition. Preferably, the blowing agent is soluble in the polyol composition without sacrificing, and advantageously improving, the thermal insulation and dimensional stability of the resulting polyurethane foam. Also disclosed are a storage stable polyol composition and methods for making a polyisocyanate based rigid closed cell foam. | ||||||
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